近年来,MC-ICP-MS的出现使得同位素分析技术得到了迅速的发展(Cocherie et al.,2008),尤其是副矿物如锆石、金红石的激光(多接收)等离子质谱(LA-(MC)-ICP-MS)U-Pb定年技术的分析精度方面有了很大的进步(侯可军等,2009;谢烈文等,2008;Sim...近年来,MC-ICP-MS的出现使得同位素分析技术得到了迅速的发展(Cocherie et al.,2008),尤其是副矿物如锆石、金红石的激光(多接收)等离子质谱(LA-(MC)-ICP-MS)U-Pb定年技术的分析精度方面有了很大的进步(侯可军等,2009;谢烈文等,2008;Simonetti et al.,2006;Cocherie et al.,2008)。相对于其他定年方法,LA-(MC)-ICP-MSU-Pb定年技术有着明显的优点:制样流程简单;展开更多
On the example of copper fulvate, it is discussed the method of calculation of stability constants of fulvic complexes. At pH = 8, the complex formation of copper（ll） ions with fulvic acids was studied by the solubi...On the example of copper fulvate, it is discussed the method of calculation of stability constants of fulvic complexes. At pH = 8, the complex formation of copper（ll） ions with fulvic acids was studied by the solubility method. Fulvic acids were separated from the river Mtkvari by the adsorption-chromotographic method. The charcoal （BAU, Russia） was used as a sorbent. The suspension of copper（If） hydroxide was used as the solid phase, on which was added the increasing quantity of standard solution of fulvic acids. In diluted solutions, at pH = 8 the dominant form of copper（lI） is copper dihydroxo complex Cu（OH）^zO. It was established that in the Cu（OH）2 （solid）-Cu（OH）^20 （solution）-FA^2-H20 system, dominates copper dyhydroxo fulvate complex with the structure 1：1, [Cu（OH）2FA]^2. The average stability constant of copper dyhydroxo fulvate complex was calculated based on experimental data fl [Cu（OH）2FAJ^2 = 4.5× l0^5.展开更多
The nuclei around magic number N=126 are investigated in the deformed relativistic mean field (RMF)model with effective interactions TMA.We focus investigations on the N=126 isotonic chain.The N=126 shellevolution is ...The nuclei around magic number N=126 are investigated in the deformed relativistic mean field (RMF)model with effective interactions TMA.We focus investigations on the N=126 isotonic chain.The N=126 shellevolution is studied by analyzing the variations of two-neutron (proton) separation energies,quadruple deformations,single particle levels etc.The good agreement of two-neutron separation energies between experimental data and calculatedvalues is reached.The RMF theory predicts that the sizes of N=126 shell become smaller and smaller withthe increasing of proton number Z.However,the N=126 shell exists in our calculated region all along.According tothe calculated two-proton separation energies,the RMF theory suggests ^(220)Pu is a two-proton drip-line nucleus in theN=126 isotonic chain.展开更多
Pores,microcracks and density of plasma sprayed Cr2O3 coatings before and after high-intensity pulsed ion beam(HIPIB) irradiation were investigated using the ultrasonic reflection coefficient spectroscopy(URCS).The UR...Pores,microcracks and density of plasma sprayed Cr2O3 coatings before and after high-intensity pulsed ion beam(HIPIB) irradiation were investigated using the ultrasonic reflection coefficient spectroscopy(URCS).The URCS was analyzed based on an acoustic transmission model for the multi-layered structure.The longitudinal velocity in the coatings was calculated from the experimental URCS,and the attenuation coefficient expression was deduced by comparing the experimental and numerical fitting amplitude spectral lines.The longitudinal velocity of as-sprayed Cr2O3 coating is 2 002 m/s,and increases to 2 099 and 2 148 m/s after being irradiated by HIPIB with 1 and 5 shots.Correspondingly,the factor A changes from 0.046 to 0.026 and 0.020 and n from 1.702 to 1.658 and 1.649 in the attenuation coefficient expression of α=Af n.It is observed that the surface morphology of Cr2O3 coatings changes from rough and porous to smooth and uniform with the increase of shot number,which accords with the ultrasonic analyses reasonably.The URCS seems to provide a convenient and nondestructive method to characterize surface modification of the plasma sprayed coatings.展开更多
2006＇s research work in the Plasma Theory and Simulation Division was unfolded mainly around the following two aspects. First, the numerical simulations, supporting the modification of HL-2A and the experiments of HL...2006＇s research work in the Plasma Theory and Simulation Division was unfolded mainly around the following two aspects. First, the numerical simulations, supporting the modification of HL-2A and the experiments of HL-2A, were carried out. Secondly, some hot theoretical subjects, such as the interaction between electron temperature gradient turbulence and steamer and the formation mechanism of magnetohydrodynamics （MHD） flow and transport barriers were investigated numerically.展开更多
This paper focuses on the distributed parameter modeling of the zinc electrowinning process(ZEWP)to reveal the spatiotemporal distribution of concentration of zinc ions(CZI)and sulfuric acid(CSA)in the electrolyte.Con...This paper focuses on the distributed parameter modeling of the zinc electrowinning process(ZEWP)to reveal the spatiotemporal distribution of concentration of zinc ions(CZI)and sulfuric acid(CSA)in the electrolyte.Considering the inverse diffusion of such ions in the electrolyte,the dynamic distribution of ions is described by the axial dispersion model.A parameter estimation strategy based on orthogonal approximation has been proposed to estimate the unknown parameters in the process model.Different industrial data sets are used to test the effectiveness of the spatiotemporal distribution model and the proposed parameter estimation approach.The results demonstrate that the analytical model can effectively capture the trends of the electrolysis reaction in time and thus has the potential to implement further optimization and control in the ZEWP.展开更多
The study area is located in Duhok province-Kurdistan region-Northern Iraq and including two locations the first location is situated in Galbook village and the vegetation cover is trees of （Quercus aegilops L.）, th...The study area is located in Duhok province-Kurdistan region-Northern Iraq and including two locations the first location is situated in Galbook village and the vegetation cover is trees of （Quercus aegilops L.）, the second location is situated in Koradeer village that covered with threes of Prunus dulcis （Mill.） Webb.. Disturbed surface soil samples at depth 0-30 cm were collected at four different distances （1, 5, 10 and 15 m） from the tree with randomized selection three trees in each study location. Soil organic matter decreases with increasing distances from tree in both locations under two different trees species, which is attributed to the effect of tree crown. Ordinarily, organic matter content in both locations correspond to the requirements of Mollisols. Statistical analysis of data showed significant differences in organic matter content between locations. Cation exchange capacity is high under tree crown and decreasing with distances from tree in both locations, as a result of decreasing organic matter and increasing calcium carbonate with distances. Commonly soil pH is slightly increased with increasing distances from tree because of increasing calcium carbonate with distances and decreasing organic matter content. Calcium was not uniform with distances and Mg decreasing with distances in both locations. The values of fine clay/coarse clay and fine clay/total clay of soil samples confirm development of the soils under study. Porosity percentage under tree crown is high and decreasing with distances. Soil bulk density was increased with distances in both locations, as a result of decreasing organic matter content with distances. This study aims to explain the effect of tree distances and species on the mollic horizon properties.展开更多
Electrically conductive composite films ofpolyaniline and nylon-6.6 are prepared by diffusing aniline followed by oxidative polymerization of aniline into nylon-6.6 matrix. In order to determine the diffusion coeffici...Electrically conductive composite films ofpolyaniline and nylon-6.6 are prepared by diffusing aniline followed by oxidative polymerization of aniline into nylon-6.6 matrix. In order to determine the diffusion coefficient for the chloride ion diffusion into the composite matrix electrochemically, galvanostatic pulse method is used and the diffusion coefficient is estimated to be -6.48× 10^-17 cm^2s^-1. The results are discussed in view of them being potential replacement materials for battery. electrodes and sensors devices.展开更多
文摘近年来,MC-ICP-MS的出现使得同位素分析技术得到了迅速的发展(Cocherie et al.,2008),尤其是副矿物如锆石、金红石的激光(多接收)等离子质谱(LA-(MC)-ICP-MS)U-Pb定年技术的分析精度方面有了很大的进步(侯可军等,2009;谢烈文等,2008;Simonetti et al.,2006;Cocherie et al.,2008)。相对于其他定年方法,LA-(MC)-ICP-MSU-Pb定年技术有着明显的优点:制样流程简单;
文摘On the example of copper fulvate, it is discussed the method of calculation of stability constants of fulvic complexes. At pH = 8, the complex formation of copper（ll） ions with fulvic acids was studied by the solubility method. Fulvic acids were separated from the river Mtkvari by the adsorption-chromotographic method. The charcoal （BAU, Russia） was used as a sorbent. The suspension of copper（If） hydroxide was used as the solid phase, on which was added the increasing quantity of standard solution of fulvic acids. In diluted solutions, at pH = 8 the dominant form of copper（lI） is copper dihydroxo complex Cu（OH）^zO. It was established that in the Cu（OH）2 （solid）-Cu（OH）^20 （solution）-FA^2-H20 system, dominates copper dyhydroxo fulvate complex with the structure 1：1, [Cu（OH）2FA]^2. The average stability constant of copper dyhydroxo fulvate complex was calculated based on experimental data fl [Cu（OH）2FAJ^2 = 4.5× l0^5.
基金Supported by National Natural Science Foundation of China under Grant Nos.10535010 and 10775068973 National Major State Basic Research and Development of China (2007CB815004)+2 种基金CAS Knowledge Innovation Project (KJCX2-SW-N02)Research Fund of Education Ministry under contract RFDP (20070284016)Green-blue Project of Jiangsu Province
文摘The nuclei around magic number N=126 are investigated in the deformed relativistic mean field (RMF)model with effective interactions TMA.We focus investigations on the N=126 isotonic chain.The N=126 shellevolution is studied by analyzing the variations of two-neutron (proton) separation energies,quadruple deformations,single particle levels etc.The good agreement of two-neutron separation energies between experimental data and calculatedvalues is reached.The RMF theory predicts that the sizes of N=126 shell become smaller and smaller withthe increasing of proton number Z.However,the N=126 shell exists in our calculated region all along.According tothe calculated two-proton separation energies,the RMF theory suggests ^(220)Pu is a two-proton drip-line nucleus in theN=126 isotonic chain.
基金Project(KM200710015010) supported by the Scientific Research Program of Beijing Municipal Education Commission,China
文摘Pores,microcracks and density of plasma sprayed Cr2O3 coatings before and after high-intensity pulsed ion beam(HIPIB) irradiation were investigated using the ultrasonic reflection coefficient spectroscopy(URCS).The URCS was analyzed based on an acoustic transmission model for the multi-layered structure.The longitudinal velocity in the coatings was calculated from the experimental URCS,and the attenuation coefficient expression was deduced by comparing the experimental and numerical fitting amplitude spectral lines.The longitudinal velocity of as-sprayed Cr2O3 coating is 2 002 m/s,and increases to 2 099 and 2 148 m/s after being irradiated by HIPIB with 1 and 5 shots.Correspondingly,the factor A changes from 0.046 to 0.026 and 0.020 and n from 1.702 to 1.658 and 1.649 in the attenuation coefficient expression of α=Af n.It is observed that the surface morphology of Cr2O3 coatings changes from rough and porous to smooth and uniform with the increase of shot number,which accords with the ultrasonic analyses reasonably.The URCS seems to provide a convenient and nondestructive method to characterize surface modification of the plasma sprayed coatings.
文摘2006＇s research work in the Plasma Theory and Simulation Division was unfolded mainly around the following two aspects. First, the numerical simulations, supporting the modification of HL-2A and the experiments of HL-2A, were carried out. Secondly, some hot theoretical subjects, such as the interaction between electron temperature gradient turbulence and steamer and the formation mechanism of magnetohydrodynamics （MHD） flow and transport barriers were investigated numerically.
基金Project(61673400)supported by the National Natural Science Foundation of ChinaProject(2015cx007)supported by the Innovation-driven Plan in Central South University,China+1 种基金Project(61321003)supported by the Foundation for Innovative Research Groups of the National Natural Science Foundation of ChinaProjects(61590921,61590923)supported by the Major Program of the National Natural Science Foundation of China
文摘This paper focuses on the distributed parameter modeling of the zinc electrowinning process(ZEWP)to reveal the spatiotemporal distribution of concentration of zinc ions(CZI)and sulfuric acid(CSA)in the electrolyte.Considering the inverse diffusion of such ions in the electrolyte,the dynamic distribution of ions is described by the axial dispersion model.A parameter estimation strategy based on orthogonal approximation has been proposed to estimate the unknown parameters in the process model.Different industrial data sets are used to test the effectiveness of the spatiotemporal distribution model and the proposed parameter estimation approach.The results demonstrate that the analytical model can effectively capture the trends of the electrolysis reaction in time and thus has the potential to implement further optimization and control in the ZEWP.
文摘The study area is located in Duhok province-Kurdistan region-Northern Iraq and including two locations the first location is situated in Galbook village and the vegetation cover is trees of （Quercus aegilops L.）, the second location is situated in Koradeer village that covered with threes of Prunus dulcis （Mill.） Webb.. Disturbed surface soil samples at depth 0-30 cm were collected at four different distances （1, 5, 10 and 15 m） from the tree with randomized selection three trees in each study location. Soil organic matter decreases with increasing distances from tree in both locations under two different trees species, which is attributed to the effect of tree crown. Ordinarily, organic matter content in both locations correspond to the requirements of Mollisols. Statistical analysis of data showed significant differences in organic matter content between locations. Cation exchange capacity is high under tree crown and decreasing with distances from tree in both locations, as a result of decreasing organic matter and increasing calcium carbonate with distances. Commonly soil pH is slightly increased with increasing distances from tree because of increasing calcium carbonate with distances and decreasing organic matter content. Calcium was not uniform with distances and Mg decreasing with distances in both locations. The values of fine clay/coarse clay and fine clay/total clay of soil samples confirm development of the soils under study. Porosity percentage under tree crown is high and decreasing with distances. Soil bulk density was increased with distances in both locations, as a result of decreasing organic matter content with distances. This study aims to explain the effect of tree distances and species on the mollic horizon properties.
文摘Electrically conductive composite films ofpolyaniline and nylon-6.6 are prepared by diffusing aniline followed by oxidative polymerization of aniline into nylon-6.6 matrix. In order to determine the diffusion coefficient for the chloride ion diffusion into the composite matrix electrochemically, galvanostatic pulse method is used and the diffusion coefficient is estimated to be -6.48× 10^-17 cm^2s^-1. The results are discussed in view of them being potential replacement materials for battery. electrodes and sensors devices.
