To improve the low-temperature performances of Li-ion cells, three types of linear carboxylic ester-based electrolyte, such as EC/EMC/EA(1:1:2, mass ratio), EC/EMC/EP(1:1:2, mass ratio) and EC/EMC/EB(1:1:2,...To improve the low-temperature performances of Li-ion cells, three types of linear carboxylic ester-based electrolyte, such as EC/EMC/EA(1:1:2, mass ratio), EC/EMC/EP(1:1:2, mass ratio) and EC/EMC/EB(1:1:2, mass ratio), were prepared to substitute for industrial electrolyte(EC/EMC/DMC). Then, 18650-type Li Mn2O4-graphite cells(nominal capacity of 1150 mA ·h) were assembled and studied. Results show that the cells containing three types of electrolyte are able to undertake 5C discharging current with above 93% capacity retention at-20 °C. Electrochemical impedance spectra show that the discharge capacity fading of Li-ion cells at low temperature is mainly ascribed to the charge transfer resistance increasing with temperature decreasing. In comparison, the cells containing electrolyte of 1.0 mol/L LiPF6 in EC/EMC/EA(1:1:2, mass ratio) have the highest capacity retention of 90% at-40 °C and 44.41% at-60 °C, due to its lowest charge-transfer resistance.展开更多
In this paper, the effect of hydrogen reduction of silver ions on the performance and structure of new solid polymer electrolyte polyetherimide (PEI)/Pebax2533 (Polynylonl2/tetramethylene oxide block copolymer, PA1...In this paper, the effect of hydrogen reduction of silver ions on the performance and structure of new solid polymer electrolyte polyetherimide (PEI)/Pebax2533 (Polynylonl2/tetramethylene oxide block copolymer, PA12-PTMO)/AgBF4 composite membranes is investigated. For PEI/Pebax2533/AgBF4 composite membranesprepared with dillerent AgBF4 concentration, the permeances of propylene and ethylene increase with the increase of AgBF4 concentration due to the carrier-facilitated transport, resulting in a high selectivity. But for propyl- ene/propane mixture, the mixed-gas selectivity is lower than its ideal selectivity. The hydrogen reduction strongly influences the membrane performance, which causes the decrease of propylene permeance and the increase of pro-pane permeance. With the increase of hydrogen reduction time, the membranes show a clearly color change from white to brown, yielding a great selectivity loss. The data of X-ray diffraction and FT-IR prove that silver ions are reduced to Ago after hydrogen reduction, and aggregated on the surface of PEI/Pebax2533/AgBF4 composite mem- branes.展开更多
The synthesis of methylene diphenyl dimethylcarbamate (4,4'-MDC) from methyl N-phenyl carbonate (MPC) and formaldehyde (HCHO) was conducted in the presence of sulfonic acid-functionalized ionic liquids (ILs) ...The synthesis of methylene diphenyl dimethylcarbamate (4,4'-MDC) from methyl N-phenyl carbonate (MPC) and formaldehyde (HCHO) was conducted in the presence of sulfonic acid-functionalized ionic liquids (ILs) as dual solvent-catalyst. The influences of the kind of anion in the ionic liquids, reaction conditions and the recycle of the ionic liquid on 4,4'-MDC synthesis reaction were investigated. In addition, the acid strength of ILs was de-termined by the Hammett method with UV-visible spectroscopy, and the acid strength-catalytic activity relationship was correlated. The activity estimation results showed that [HSO3-bmim]CF3SO3 was the optimal dual solvent-catalyst. Under the suitable reaction conditions of 70℃, 40 min, molar ratio of nMPC/nHCHO= 10/1 and mass ratio of WILs/WMPC = 4.5/1, the yield of 4,4'-MDC based on HCHO was 89.9 % and the selectivity of 4,4'-MDC with respect to MPC was 74.9%. Besides, [HSO3-bmim]CF3SO3 was reused four times after being purified and no significant loss in the catalytic activity was observed.展开更多
This work focuses on the multicell multi-user distributed massive MIMO(DM-MIMO)systems,of which each user is equipped with single antenna and the base stations(BSs)consists of distributed antenna units. We first inves...This work focuses on the multicell multi-user distributed massive MIMO(DM-MIMO)systems,of which each user is equipped with single antenna and the base stations(BSs)consists of distributed antenna units. We first investigate the arbitrary BS antenna topology scenario. The derivation indicates that in this case the achievable uplink rate of an arbitrary user in central cell depends on both the number of BS's antennas and the users' access distance to each distributed antenna unit(DAU). As a result,the performance analysis based on the derivations is difficult. To overcome this issue and achieve clearer insight,we then consider a circularly distributed BS antenna array and obtain the asymptotic uplink rate of an arbitrary user by considering the asymptotic case where the number of antennas of BSs tends to infinity. It is achieved that the asymptotic uplink rate only depends on the distance from users' position to the center of reference cell. The presented numerical results show clearly that the distributed massive MIMO systems outperform the centralized ones. Moreover,it is also achieved that the interference from the adjacent cells imposes great impact on system performance. Besides this,in numerical analysis the averageasymptotic uplink rate of a user is presented,which is free of the users' position and only depends on the radius of circular antenna arrays. It is achieved the maximum average uplink rate would be achieved when the radius of circularly distributed antenna array goes to its optimization location.展开更多
Activated carbon(AC)in organic electrolytebased electric double-layer capacitors(EDLCs)usually suffers from low specific capacitance.Most studies on AC focus on improving its surface area and optimizing pore structure...Activated carbon(AC)in organic electrolytebased electric double-layer capacitors(EDLCs)usually suffers from low specific capacitance.Most studies on AC focus on improving its surface area and optimizing pore structures to enhance its electrochemical performance in EDLCs.Unfortunately,the interfacial microenvironment,which is composed of nanoporous carbon and the organic electrolyte confined in it,is always ignored.Herein,a simple and powerful strategy to create AC with an ionophobic surface is proposed to address the poor efficiency of the electric doublelayer process.The polar C±F bonds formed in the AC material are characterized through near-edge X-ray absorption fine structure and X-ray photoelectron spectroscopy.The ionophobic characteristic of YP-F60 s in an organic electrolyte is extensively studied via contact angle measurements and smallangle X-ray scattering spectroscopy.An EDLC constructed with YP-F60 s as the electrode and 1 mol L^(-1) tetraethylammonium tetrafluoroborate/propylene carbonate as the electrolyte demonstrates high specific capacitance,low internal resistance,and excellent cycling stability.Our results successfully demonstrate the importance of the interfacial microenvironment of AC and its confined electrolyte to the electrochemical performance of EDLCs.Our work also offers new perspectives on the use of the CF;plasma technique to fabricate low-cost superior carbon for EDLCs.展开更多
The single event effect(SEE) is an important consideration in electronic devices used in space environments because it can lead to spacecraft anomalies and failures. The linear energy transfer(LET) of ions is commonly...The single event effect(SEE) is an important consideration in electronic devices used in space environments because it can lead to spacecraft anomalies and failures. The linear energy transfer(LET) of ions is commonly investigated in studies of SEE. The use of a thin detector is an economical way of directly measuring the LET in space. An LET telescope consists of a thin detector as the front detector(D1), along with a back detector that indicates whether D1 was penetrated. The particle radiation effect monitor(PREM) introduced in this paper is designed to categorize the LET into four bins of 0.2–0.4, 0.4–1.0, 1.0–2.0 and 2.0–20 Me V·cm^2/mg, and one integral bin of LET>20 Me V·cm^2/mg. After calibration with heavy ions and Geant4 analysis, the LET boundaries of the first four bins are determined to be 0.236, 0.479, 1.196, 2.254, and 17.551 Me V·cm^2/mg, whereas that of the integral bin is determined to be LET>14.790 Me V·cm^2/mg. The acceptances are calculated by Geant4 analysis as 0.452, 0.451, 0.476, 0.446, and 1.334, respectively. The LET accuracy is shown to depend on the thickness of D1; as D1 is made thinner, the accuracy of the measured values increases.展开更多
We report the observation of mirror mode structures by Cluster spacecraft at around X^-16 RE in the Earth’s magnetotail.The wavelength of the mirror structure is larger than 7000 km,corresponding to tens of ion gyror...We report the observation of mirror mode structures by Cluster spacecraft at around X^-16 RE in the Earth’s magnetotail.The wavelength of the mirror structure is larger than 7000 km,corresponding to tens of ion gyroradii.Features of the mirror structures are similar to those detected in the magnetosheath:the anti-correlation between the magnetic field strength and plasma density,zero phase velocity in the plasma rest frame and linear polarization.The structures were observed in a region bounded by two dipolarizations during a substorm intensification.Thus,the dipolarization process may provide a plasma condition facilitating the growth of the mirror mode structures.Another interesting feature is the electron dynamics within the mirror structures.Thermal electron energy flux has an enhancement at 0°and 180°pitch angles inside the magnetic dips of the first three mirror structures and an enhancement at 90°pitch angle inside the magnetic dip of the last structure.The different electron distribution inside the mirror structures might be a result of different evolution stages of the mirror wave.The last structure may be in the nonlinear stage of the mirror instability,whereas the three others with quasi-sinusoidal waveforms may be in the linear stage.In addition,we found that intense whistler waves were confined within the magnetic dips.We conjecture that whistler waves observed in the first three dips were generated in a remote region,then they were trapped in the mirror mode troughs and transported toward the spacecraft;while the whistler wave detected in the last dip was excited locally by the electron anisotropy instability.展开更多
基金Project(2007BAE12B01)supported by the National Key Technology Research and Development Program of ChinaProject(20803095)supported by the National Natural Science Foundation of China
文摘To improve the low-temperature performances of Li-ion cells, three types of linear carboxylic ester-based electrolyte, such as EC/EMC/EA(1:1:2, mass ratio), EC/EMC/EP(1:1:2, mass ratio) and EC/EMC/EB(1:1:2, mass ratio), were prepared to substitute for industrial electrolyte(EC/EMC/DMC). Then, 18650-type Li Mn2O4-graphite cells(nominal capacity of 1150 mA ·h) were assembled and studied. Results show that the cells containing three types of electrolyte are able to undertake 5C discharging current with above 93% capacity retention at-20 °C. Electrochemical impedance spectra show that the discharge capacity fading of Li-ion cells at low temperature is mainly ascribed to the charge transfer resistance increasing with temperature decreasing. In comparison, the cells containing electrolyte of 1.0 mol/L LiPF6 in EC/EMC/EA(1:1:2, mass ratio) have the highest capacity retention of 90% at-40 °C and 44.41% at-60 °C, due to its lowest charge-transfer resistance.
基金Supported by the National Natural Science Foundation of China (20776137) and the National High Technology Research and Develooment Prozram of China (2008AA06Z325).
文摘In this paper, the effect of hydrogen reduction of silver ions on the performance and structure of new solid polymer electrolyte polyetherimide (PEI)/Pebax2533 (Polynylonl2/tetramethylene oxide block copolymer, PA12-PTMO)/AgBF4 composite membranes is investigated. For PEI/Pebax2533/AgBF4 composite membranesprepared with dillerent AgBF4 concentration, the permeances of propylene and ethylene increase with the increase of AgBF4 concentration due to the carrier-facilitated transport, resulting in a high selectivity. But for propyl- ene/propane mixture, the mixed-gas selectivity is lower than its ideal selectivity. The hydrogen reduction strongly influences the membrane performance, which causes the decrease of propylene permeance and the increase of pro-pane permeance. With the increase of hydrogen reduction time, the membranes show a clearly color change from white to brown, yielding a great selectivity loss. The data of X-ray diffraction and FT-IR prove that silver ions are reduced to Ago after hydrogen reduction, and aggregated on the surface of PEI/Pebax2533/AgBF4 composite mem- branes.
基金Supported by the National Natural Science Foundation of China (20576025). the National Key Basic Project of China (2005CCA06100), the Science and Technological Research and Development Project of Hebei Province (07215602D) and the Natural Science Foundation of Hebei Province 032007000010).
文摘The synthesis of methylene diphenyl dimethylcarbamate (4,4'-MDC) from methyl N-phenyl carbonate (MPC) and formaldehyde (HCHO) was conducted in the presence of sulfonic acid-functionalized ionic liquids (ILs) as dual solvent-catalyst. The influences of the kind of anion in the ionic liquids, reaction conditions and the recycle of the ionic liquid on 4,4'-MDC synthesis reaction were investigated. In addition, the acid strength of ILs was de-termined by the Hammett method with UV-visible spectroscopy, and the acid strength-catalytic activity relationship was correlated. The activity estimation results showed that [HSO3-bmim]CF3SO3 was the optimal dual solvent-catalyst. Under the suitable reaction conditions of 70℃, 40 min, molar ratio of nMPC/nHCHO= 10/1 and mass ratio of WILs/WMPC = 4.5/1, the yield of 4,4'-MDC based on HCHO was 89.9 % and the selectivity of 4,4'-MDC with respect to MPC was 74.9%. Besides, [HSO3-bmim]CF3SO3 was reused four times after being purified and no significant loss in the catalytic activity was observed.
基金supported by the Natural Science Foundation of China under Grant 61261015 and 61561043the 973 project 2013CB329104,the Natural Science Foundation of China under Grant 61372124,61363059,and 61302100+1 种基金the projects BK2011027,the Natural Science Foundation of Gansu Province for Distinguished Young Scholars(1308RJDA007)by the Foundation Research Funds for the University of Gansu Province:‘Massive MIMO channels modeling and estimation over millimeter wave band for 5G’
文摘This work focuses on the multicell multi-user distributed massive MIMO(DM-MIMO)systems,of which each user is equipped with single antenna and the base stations(BSs)consists of distributed antenna units. We first investigate the arbitrary BS antenna topology scenario. The derivation indicates that in this case the achievable uplink rate of an arbitrary user in central cell depends on both the number of BS's antennas and the users' access distance to each distributed antenna unit(DAU). As a result,the performance analysis based on the derivations is difficult. To overcome this issue and achieve clearer insight,we then consider a circularly distributed BS antenna array and obtain the asymptotic uplink rate of an arbitrary user by considering the asymptotic case where the number of antennas of BSs tends to infinity. It is achieved that the asymptotic uplink rate only depends on the distance from users' position to the center of reference cell. The presented numerical results show clearly that the distributed massive MIMO systems outperform the centralized ones. Moreover,it is also achieved that the interference from the adjacent cells imposes great impact on system performance. Besides this,in numerical analysis the averageasymptotic uplink rate of a user is presented,which is free of the users' position and only depends on the radius of circular antenna arrays. It is achieved the maximum average uplink rate would be achieved when the radius of circularly distributed antenna array goes to its optimization location.
基金supported by the National Natural Science Foundation of China(21203008 and 21975025)Beijing Natural Science Foundation(2172051)the State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,Donghua University。
文摘Activated carbon(AC)in organic electrolytebased electric double-layer capacitors(EDLCs)usually suffers from low specific capacitance.Most studies on AC focus on improving its surface area and optimizing pore structures to enhance its electrochemical performance in EDLCs.Unfortunately,the interfacial microenvironment,which is composed of nanoporous carbon and the organic electrolyte confined in it,is always ignored.Herein,a simple and powerful strategy to create AC with an ionophobic surface is proposed to address the poor efficiency of the electric doublelayer process.The polar C±F bonds formed in the AC material are characterized through near-edge X-ray absorption fine structure and X-ray photoelectron spectroscopy.The ionophobic characteristic of YP-F60 s in an organic electrolyte is extensively studied via contact angle measurements and smallangle X-ray scattering spectroscopy.An EDLC constructed with YP-F60 s as the electrode and 1 mol L^(-1) tetraethylammonium tetrafluoroborate/propylene carbonate as the electrolyte demonstrates high specific capacitance,low internal resistance,and excellent cycling stability.Our results successfully demonstrate the importance of the interfacial microenvironment of AC and its confined electrolyte to the electrochemical performance of EDLCs.Our work also offers new perspectives on the use of the CF;plasma technique to fabricate low-cost superior carbon for EDLCs.
基金supported by the National Natural Science Foundation of China(Grant No.41374181)the National Key Scientific Instrument and Equipment Development ProjectsChina(Grant No.2012YQ03014207)
文摘The single event effect(SEE) is an important consideration in electronic devices used in space environments because it can lead to spacecraft anomalies and failures. The linear energy transfer(LET) of ions is commonly investigated in studies of SEE. The use of a thin detector is an economical way of directly measuring the LET in space. An LET telescope consists of a thin detector as the front detector(D1), along with a back detector that indicates whether D1 was penetrated. The particle radiation effect monitor(PREM) introduced in this paper is designed to categorize the LET into four bins of 0.2–0.4, 0.4–1.0, 1.0–2.0 and 2.0–20 Me V·cm^2/mg, and one integral bin of LET>20 Me V·cm^2/mg. After calibration with heavy ions and Geant4 analysis, the LET boundaries of the first four bins are determined to be 0.236, 0.479, 1.196, 2.254, and 17.551 Me V·cm^2/mg, whereas that of the integral bin is determined to be LET>14.790 Me V·cm^2/mg. The acceptances are calculated by Geant4 analysis as 0.452, 0.451, 0.476, 0.446, and 1.334, respectively. The LET accuracy is shown to depend on the thickness of D1; as D1 is made thinner, the accuracy of the measured values increases.
基金supported by the National Natural Science Foundation of China(Grants Nos.41174147,41274170,41331070)Science Foundation of Jiangxi Province(Grants No.20122BAB212002)the Fundamental Research Funds for the Central Universities(Grant No.2012212020206)
文摘We report the observation of mirror mode structures by Cluster spacecraft at around X^-16 RE in the Earth’s magnetotail.The wavelength of the mirror structure is larger than 7000 km,corresponding to tens of ion gyroradii.Features of the mirror structures are similar to those detected in the magnetosheath:the anti-correlation between the magnetic field strength and plasma density,zero phase velocity in the plasma rest frame and linear polarization.The structures were observed in a region bounded by two dipolarizations during a substorm intensification.Thus,the dipolarization process may provide a plasma condition facilitating the growth of the mirror mode structures.Another interesting feature is the electron dynamics within the mirror structures.Thermal electron energy flux has an enhancement at 0°and 180°pitch angles inside the magnetic dips of the first three mirror structures and an enhancement at 90°pitch angle inside the magnetic dip of the last structure.The different electron distribution inside the mirror structures might be a result of different evolution stages of the mirror wave.The last structure may be in the nonlinear stage of the mirror instability,whereas the three others with quasi-sinusoidal waveforms may be in the linear stage.In addition,we found that intense whistler waves were confined within the magnetic dips.We conjecture that whistler waves observed in the first three dips were generated in a remote region,then they were trapped in the mirror mode troughs and transported toward the spacecraft;while the whistler wave detected in the last dip was excited locally by the electron anisotropy instability.