This study investigates the photodegradation of the organic dye rhodamine B by Ag‐nanoparticlecontaining BiVO4catalysts under different irradiation conditions.The catalysts consist of Ag nanoparticles deposited on ox...This study investigates the photodegradation of the organic dye rhodamine B by Ag‐nanoparticlecontaining BiVO4catalysts under different irradiation conditions.The catalysts consist of Ag nanoparticles deposited on oxygen‐vacancy‐containing BiVO4.The morphology of the BiVO4is olive shaped,and it has a uniform size distribution.The BiVO4possesses a high oxygen vacancy density,and the resulting Ag nanoparticle‐BiVO4catalyst exhibits higher photocatalytic activity than BiVO4.The RhB degradation by the Ag nanoparticle‐BiVO4catalyst is99%after100min of simulated solar irradiation.BiVO4containing oxygen vacancies as a rationally designed support extends the catalyst response into the near‐infrared region,and facilitates the trapping and transfer of plasmonic hot electrons.The enhanced photocatalytic efficiency is attributed to charge transfer from the BiVO4to Ag nanoparticles,and surface plasmon resonance of the Ag nanoparticles.These insights into electron‐hole separation and charge transfer may arouse interest in solar‐driven wastewater treatment and water splitting.?2018,Dalian Institute of Chemical Physics,Chinese Academy of Sciences.Published by Elsevier B.V.All rights reserved.展开更多
Put forward a new kind of polishing method,ultrasonic magnetic abrasive fin-ishing(UMAF),and studied its mechanism of improving polishing efficiency.By analyzingall kind of forces acting on single abrasive particle in...Put forward a new kind of polishing method,ultrasonic magnetic abrasive fin-ishing(UMAF),and studied its mechanism of improving polishing efficiency.By analyzingall kind of forces acting on single abrasive particle in the polishing process and calculatingthe Size of the composition of forces,get the conclusion that UMAF will enhance the effi-ciency of the normal magnetic abrasive finishing(MAF)due to the ultrasonic vibration in-creases the cutting force and depth.At last the idea of designing the UMAF system basedon numerical control milling machine is put forward which is convenient to setup and willaccelerate the practical application of MAF.展开更多
The watermiscible room temperature ionic liquid 1butyl3methylimidazolium tetrafluorob orate （[bmim] [BF4]） is a model system for studying the interactions between ionic liquid and water molecules. In this work the o...The watermiscible room temperature ionic liquid 1butyl3methylimidazolium tetrafluorob orate （[bmim] [BF4]） is a model system for studying the interactions between ionic liquid and water molecules. In this work the orientational structure of the low concentrated aqueous solution of [bmim] [BF4] at the air/liquid interface was investigated by sum frequency gener ation vibrational spectroscopy. It has been found that at very low concentrations, the butyl chain exhibited a significant gauche defect, indicating a disordered conformation; and the cation ring oriented with a fairly small tilting angle at the surface. When the concentration increased, the cation ring tended to lie flat at the surface, and the gauche defects of the butyl chain decreased due to the intermolecular chainchain interactions and the consequent more ordered interfacial molecular arrangement. Additionally, the antisymmetric stretching mode in the PPP and SPS spectra exhibited a peak shift, showing that there exists more than one kind of orientation or chemical environment for the butyl CH3 group. These results may shed new light on understanding the surface behavior of watermiscible ionic liquids as well as the imidazolium based surfactants.展开更多
基金supported by the National Natural Science Foundation of China(21476033)~~
文摘This study investigates the photodegradation of the organic dye rhodamine B by Ag‐nanoparticlecontaining BiVO4catalysts under different irradiation conditions.The catalysts consist of Ag nanoparticles deposited on oxygen‐vacancy‐containing BiVO4.The morphology of the BiVO4is olive shaped,and it has a uniform size distribution.The BiVO4possesses a high oxygen vacancy density,and the resulting Ag nanoparticle‐BiVO4catalyst exhibits higher photocatalytic activity than BiVO4.The RhB degradation by the Ag nanoparticle‐BiVO4catalyst is99%after100min of simulated solar irradiation.BiVO4containing oxygen vacancies as a rationally designed support extends the catalyst response into the near‐infrared region,and facilitates the trapping and transfer of plasmonic hot electrons.The enhanced photocatalytic efficiency is attributed to charge transfer from the BiVO4to Ag nanoparticles,and surface plasmon resonance of the Ag nanoparticles.These insights into electron‐hole separation and charge transfer may arouse interest in solar‐driven wastewater treatment and water splitting.?2018,Dalian Institute of Chemical Physics,Chinese Academy of Sciences.Published by Elsevier B.V.All rights reserved.
基金Supported by Ningbo Key Technology R&D Program(2005B100058)
文摘Put forward a new kind of polishing method,ultrasonic magnetic abrasive fin-ishing(UMAF),and studied its mechanism of improving polishing efficiency.By analyzingall kind of forces acting on single abrasive particle in the polishing process and calculatingthe Size of the composition of forces,get the conclusion that UMAF will enhance the effi-ciency of the normal magnetic abrasive finishing(MAF)due to the ultrasonic vibration in-creases the cutting force and depth.At last the idea of designing the UMAF system basedon numerical control milling machine is put forward which is convenient to setup and willaccelerate the practical application of MAF.
文摘The watermiscible room temperature ionic liquid 1butyl3methylimidazolium tetrafluorob orate （[bmim] [BF4]） is a model system for studying the interactions between ionic liquid and water molecules. In this work the orientational structure of the low concentrated aqueous solution of [bmim] [BF4] at the air/liquid interface was investigated by sum frequency gener ation vibrational spectroscopy. It has been found that at very low concentrations, the butyl chain exhibited a significant gauche defect, indicating a disordered conformation; and the cation ring oriented with a fairly small tilting angle at the surface. When the concentration increased, the cation ring tended to lie flat at the surface, and the gauche defects of the butyl chain decreased due to the intermolecular chainchain interactions and the consequent more ordered interfacial molecular arrangement. Additionally, the antisymmetric stretching mode in the PPP and SPS spectra exhibited a peak shift, showing that there exists more than one kind of orientation or chemical environment for the butyl CH3 group. These results may shed new light on understanding the surface behavior of watermiscible ionic liquids as well as the imidazolium based surfactants.
