ZSM-5 zeolite microparticles （MPs） were synthesized under hydrothermal condition using a low crystal seed addition approach without template. The synthesis parameters such as the seed addition amount, the SiOJA1203 ...ZSM-5 zeolite microparticles （MPs） were synthesized under hydrothermal condition using a low crystal seed addition approach without template. The synthesis parameters such as the seed addition amount, the SiOJA1203 ratio, the aluminum source, the feeding addition method, aging, and crystallization were investigated. The structure, morphology and composition of the as-synthesized ZSM-5 zeolite MPs were characterized by X-ray powder diffraction （XRD）, scanning electron microscopy （SEM）, laser particle size distribution （PSD） measurements, and inductively coupled plasma-atomic emission spectrometry （ICP-AES）. The SIO2/A1203 ratio of ZSM-5 zeolite MPs was in the range of 20~80. The low seed addition was beneficial to improving the crystallinity and shortening the crystallization time, and the suitable amount of seed was 0.25% （SIO2）. The ZSM-5 zeolite MPs synthesized with aluminium nitrate nonahydrate used as the aluminum source exhibited a relatively high crystallinity. An appropriate aging time could eliminate the effect of feeding addition method and effectively adjust particle size. The particle size of ZSM-5 zeolite obtained at an aging time of 20 h was around 2.0 I.tm. Prolonging the aging time appropriately could also shorten the high-temperature crystallization time. The suitable aging time was 24 h, and the relative crystallinity of ZSM-5 zeolite could reach up to 99% after crystallization for 24 h at 180 ℃展开更多
The Streak-breasted Scimitar Babblers of the Pomatorhinus ruficollis species complex are found in most of the forested habitats across southern and eastern Asia. The diversification history of this group is obscured b...The Streak-breasted Scimitar Babblers of the Pomatorhinus ruficollis species complex are found in most of the forested habitats across southern and eastern Asia. The diversification history of this group is obscured by high plumage variation across populations and conflicting genetic signal across loci. We combined genetic and geographic data from several recent studies to investigate how these species diversified across China using both phylogenetic and ecological niche modeling analyses. These two lines of evidence are consistent in showing that two well-sampled species, P. reconditus and P. nigrostellatus, in central and southern China respectively, likely experienced a history of isolation and expansion as suitable habitat contracted during the last interglacial and expanded in patchy extent during the glacial maximum. The genetic analysis showed that populations of P. nigrostellatus on Hainan Island are very similar to the ones in nearby mainland southern China. We recovered two well-supported clades within P. reconditus that were not geographically structured with both containing individuals from the same localities across central China. This phylogenetic result corresponded to the ecological niche models that showed expansion from refugia since the last interglacial. This study illustrates the value of using an integrative approach and detailed geographic sampling to help understand the recent diversification of birds in China [Current Zoology 61 （5）： 910-921, 2015].展开更多
Adaptive cluster sampling （ACS） has been widely used for data collection of environment and natural resources. However, the randomness of its final sample size often impedes the use of this method. To control the fi...Adaptive cluster sampling （ACS） has been widely used for data collection of environment and natural resources. However, the randomness of its final sample size often impedes the use of this method. To control the final sample sizes, in this study, a k-step ACS based on Horvitz-Thompson （HT） estimator was developed and an unbiased estimator was derived. The k-step ACS-HT was assessed first using a simulated example and then using a real survey for numbers of plants for three species that were characterized by clustered and patchily spatial distributions. The effectiveness of this sampling design method was assessed in comparison with ACS Hansen-Hurwitz （ACS-HH） and ACS- HT estimators, and k-step ACS-HT estimator. The effectiveness of using different k- step sizes was also compared. The results showed that k-step ACS^HT estimator was most effective and ACS-HH was the least. Moreover, stable sample mean and variance estimates could be obtained after a certain number of steps, but depending on plant species, k-step ACS without replacement was slightly more effective than that with replacement. In k-step ACS, the variance estimate of one-step ACS is much larger than other k-step ACS （k 〉 1）, but it is smaller than ACS. This implies that k-step ACS is more effective than traditional ACS, besides, the final sample size can be controlled easily in population with big clusters.展开更多
基金Financial support from the Innovation Fund for Elitists of Henan Province,China(No.0221001200)the Talent Training Joint Fund of NSFC-Henan(No.U1204203)the China Postdoctoral Science Foundation(No.2012M511121)
文摘ZSM-5 zeolite microparticles （MPs） were synthesized under hydrothermal condition using a low crystal seed addition approach without template. The synthesis parameters such as the seed addition amount, the SiOJA1203 ratio, the aluminum source, the feeding addition method, aging, and crystallization were investigated. The structure, morphology and composition of the as-synthesized ZSM-5 zeolite MPs were characterized by X-ray powder diffraction （XRD）, scanning electron microscopy （SEM）, laser particle size distribution （PSD） measurements, and inductively coupled plasma-atomic emission spectrometry （ICP-AES）. The SIO2/A1203 ratio of ZSM-5 zeolite MPs was in the range of 20~80. The low seed addition was beneficial to improving the crystallinity and shortening the crystallization time, and the suitable amount of seed was 0.25% （SIO2）. The ZSM-5 zeolite MPs synthesized with aluminium nitrate nonahydrate used as the aluminum source exhibited a relatively high crystallinity. An appropriate aging time could eliminate the effect of feeding addition method and effectively adjust particle size. The particle size of ZSM-5 zeolite obtained at an aging time of 20 h was around 2.0 I.tm. Prolonging the aging time appropriately could also shorten the high-temperature crystallization time. The suitable aging time was 24 h, and the relative crystallinity of ZSM-5 zeolite could reach up to 99% after crystallization for 24 h at 180 ℃
基金We thank Fumin Lei, A. Town Peterson, and Rob Moyle for inviting us to contribute to this special volume. We also are grateful to Feng Dong and Xiao-Jun Yang from Kunming Institute of Zoology for providing us additional data for these analyses. This work was funded by the US National Science Foundation （DEB-0962078 to SR）.
文摘The Streak-breasted Scimitar Babblers of the Pomatorhinus ruficollis species complex are found in most of the forested habitats across southern and eastern Asia. The diversification history of this group is obscured by high plumage variation across populations and conflicting genetic signal across loci. We combined genetic and geographic data from several recent studies to investigate how these species diversified across China using both phylogenetic and ecological niche modeling analyses. These two lines of evidence are consistent in showing that two well-sampled species, P. reconditus and P. nigrostellatus, in central and southern China respectively, likely experienced a history of isolation and expansion as suitable habitat contracted during the last interglacial and expanded in patchy extent during the glacial maximum. The genetic analysis showed that populations of P. nigrostellatus on Hainan Island are very similar to the ones in nearby mainland southern China. We recovered two well-supported clades within P. reconditus that were not geographically structured with both containing individuals from the same localities across central China. This phylogenetic result corresponded to the ecological niche models that showed expansion from refugia since the last interglacial. This study illustrates the value of using an integrative approach and detailed geographic sampling to help understand the recent diversification of birds in China [Current Zoology 61 （5）： 910-921, 2015].
文摘Adaptive cluster sampling （ACS） has been widely used for data collection of environment and natural resources. However, the randomness of its final sample size often impedes the use of this method. To control the final sample sizes, in this study, a k-step ACS based on Horvitz-Thompson （HT） estimator was developed and an unbiased estimator was derived. The k-step ACS-HT was assessed first using a simulated example and then using a real survey for numbers of plants for three species that were characterized by clustered and patchily spatial distributions. The effectiveness of this sampling design method was assessed in comparison with ACS Hansen-Hurwitz （ACS-HH） and ACS- HT estimators, and k-step ACS-HT estimator. The effectiveness of using different k- step sizes was also compared. The results showed that k-step ACS^HT estimator was most effective and ACS-HH was the least. Moreover, stable sample mean and variance estimates could be obtained after a certain number of steps, but depending on plant species, k-step ACS without replacement was slightly more effective than that with replacement. In k-step ACS, the variance estimate of one-step ACS is much larger than other k-step ACS （k 〉 1）, but it is smaller than ACS. This implies that k-step ACS is more effective than traditional ACS, besides, the final sample size can be controlled easily in population with big clusters.
