The non-isothermal kinetics of mechanochemical reduction of Ag2O with graphite was studied by DSC and TGA with a model of fitting Malek approach and a model-free advanced isoconversional method of Vyazovkin. To evalua...The non-isothermal kinetics of mechanochemical reduction of Ag2O with graphite was studied by DSC and TGA with a model of fitting Malek approach and a model-free advanced isoconversional method of Vyazovkin. To evaluate the kinetics parameters, Ag2O–graphite mixture of as-received and milled for 2 and 4 h samples were selected. Based on the results obtained by Vyazovkin method calculation, however, the difference between the maximum and minimum values of activation energy is less than 20%-30%of the average activation energy ((99.38±2.36) kJ/mol) and thermal decomposition of mechanically activated Ag2O for 2 h is a multi-step process. Moreover, the thermal decomposition of mechanically activated Ag2O–graphite powder activated for 4 h is a single-step process (the average activation energy=(93.68±2.26) kJ/mol). The kinetics modeling shows that the complexity of thermal decomposition of as-received Ag2O–graphite mixture is higher than that of the others. While, the autocatalytic tendency of as-received Ag2O–graphite mixture is lower than that of the others.展开更多
The van Genuchten model is the most widely used soil water retention curve (SWRC) model. Two undisturbed soils (clay and loam) were used to evaluate the accuracy of the integral method to estimate van Genuchten mo...The van Genuchten model is the most widely used soil water retention curve (SWRC) model. Two undisturbed soils (clay and loam) were used to evaluate the accuracy of the integral method to estimate van Genuchten model parameters and to determine SWRCs of undisturbed soils. SWRCs calculated by the integral method were compared with those measured by a high speed centrifuge technique. The accuracy of the calculated results was evaluated graphically, as well as by root mean square error (RMSE), normalized root mean square error (NRMSE) and Willmott's index of agreement (1). The results obtained from the integral method were quite similar to those by the centrifuge technique. The RMSEs (4.61 ×10^-5 for Eum-Orthic Anthrosol and 2.74 × 10^-4 for Los-Orthic Entisol) and NRMSEs (1.56 × 10^-4 for Eum- Orthic Anthrosol and 1.45 ×10^-3 for Los-Orthic Entisol) were relatively small. The 1 values were 0.973 and 0.943 for Eum-Orthic Anthrosol and Los-Orthic Entisol, respectively, indicating a good agreement between the integral method values and the centrifuge values. Therefore, the integral method could be used to estimate SWRCs of undisturbed clay and loam soils.展开更多
This paper investigated an effective and robust mechanism for detecting simple mail transfer protocol (SMTP) traffic anomaly. The detection method cumulates the deviation of current delivering status from history beha...This paper investigated an effective and robust mechanism for detecting simple mail transfer protocol (SMTP) traffic anomaly. The detection method cumulates the deviation of current delivering status from history behavior based on a weighted sum method called the leaky integrate-and-fire model to detect anomaly. The simplicity of the detection method is that the method need not store history profile and low computation overhead, which makes the detection method itself immunes to attacks. The performance is investigated in terms of detection probability, the false alarm ratio, and the detection delay. The results show that leaky integrate-and-fire method is quite effective at detecting constant intensity attacks and increasing intensity attacks. Compared with the non-parametric cumulative sum method, the evaluation results show that the proposed detection method has shorter detection latency and higher detection probability.展开更多
Reasonable selection and optimization of a filter used in model estimation for a multiple model structure is the key to improve tracking accuracy of maneuvering target.Combining with the cubature Kalman filter with it...Reasonable selection and optimization of a filter used in model estimation for a multiple model structure is the key to improve tracking accuracy of maneuvering target.Combining with the cubature Kalman filter with iterated observation update and the interacting multiple model method,a novel interacting multiple model algorithm based on the cubature Kalman filter with observation iterated update is proposed.Firstly,aiming to the structural features of cubature Kalman filter,the cubature Kalman filter with observation iterated update is constructed by the mechanism of iterated observation update.Secondly,the improved cubature Kalman filter is used as the model filter of interacting multiple model,and the stability and reliability of model identification and state estimation are effectively promoted by the optimization of model filtering step.In the simulations,compared with classic improved interacting multiple model algorithms,the theoretical analysis and experimental results show the feasibility and validity of the proposed algorithm.展开更多
A new mathematical model to estimate the parameters of the probability-integral method for mining subsidence prediction is proposed.Based on least squares support vector machine(LS-SVM) theory, it is capable of improv...A new mathematical model to estimate the parameters of the probability-integral method for mining subsidence prediction is proposed.Based on least squares support vector machine(LS-SVM) theory, it is capable of improving the precision and reliability of mining subsidence prediction.Many of the geological and mining factors involved are related in a nonlinear way.The new model is based on statistical theory(SLT) and empirical risk minimization(ERM) principles.Typical data collected from observation stations were used for the learning and training samples.The calculated results from the LS-SVM model were compared with the prediction results of a back propagation neural network(BPNN) model.The results show that the parameters were more precisely predicted by the LS-SVM model than by the BPNN model.The LS-SVM model was faster in computation and had better generalized performance.It provides a highly effective method for calculating the predicting parameters of the probability-integral method.展开更多
Hybrid mecihanism is a new type of planar controllable mechanism. Position control acouracy of system determines the output aconracy of the mechanism. In order to achieve the desired high acowacy, nonlinear factors as...Hybrid mecihanism is a new type of planar controllable mechanism. Position control acouracy of system determines the output aconracy of the mechanism. In order to achieve the desired high acowacy, nonlinear factors as friction nmst be accurately compensated in the real-time servo control algoritinn. In this paper, the model of a hybrid five-bar mechanism is introduced. In terms of the characteristics of the hybrid mechanism, a hybrid intelligent control algorithm based on proportional-integral-derivative (PID) control and cerebellar model articulation control techniques was presented and used to perform control of hybrid five-bar mechanism for the lust time. The sinmulation results show that the hybrid control method can improve the control effect remarkably, compared with the traditional PID control strategy.展开更多
The Ishimori equation is one of the most important(2+1)-dimensional integrable models,which is an integrable generalization of(1+1)-dimensional classical continuous Heisenberg ferromagnetic spin equations.Based on imp...The Ishimori equation is one of the most important(2+1)-dimensional integrable models,which is an integrable generalization of(1+1)-dimensional classical continuous Heisenberg ferromagnetic spin equations.Based on importance of Lie symmetries in analysis of differential equations,in this paper,we derive Lie symmetries for the Ishimori equation by Hirota's direct method.展开更多
This paper presents a further development of the dual reciprocity boundary element method(DRBEM) with stepwise updating to pave the way for the introduction of boundary element mesh into the discontinuous deformation ...This paper presents a further development of the dual reciprocity boundary element method(DRBEM) with stepwise updating to pave the way for the introduction of boundary element mesh into the discontinuous deformation analysis(DDA). The advantage of the proposed method lies in its adoption of static fundamental solutions and reduction in the size of the governing equations by transforming the inertial term domain integrals to boundary integrals in the dynamic large displacement analysis. The unconditionally stable Newmark-β time integration method involving numerical damping to enhance the numerical stability is implemented for the dynamic analysis. In order to be coupled with the DDA to improve the deformability of the DDA block domains, a stepwise updating algorithm of the system variables is introduced. The stress updating in the analysis involved in the calculation of a domain integral and internal cells are used for the integration of the initial stress term. Several examples are used to verify the geometry-updated DRBEM model and satisfactory results have been obtained.展开更多
文摘The non-isothermal kinetics of mechanochemical reduction of Ag2O with graphite was studied by DSC and TGA with a model of fitting Malek approach and a model-free advanced isoconversional method of Vyazovkin. To evaluate the kinetics parameters, Ag2O–graphite mixture of as-received and milled for 2 and 4 h samples were selected. Based on the results obtained by Vyazovkin method calculation, however, the difference between the maximum and minimum values of activation energy is less than 20%-30%of the average activation energy ((99.38±2.36) kJ/mol) and thermal decomposition of mechanically activated Ag2O for 2 h is a multi-step process. Moreover, the thermal decomposition of mechanically activated Ag2O–graphite powder activated for 4 h is a single-step process (the average activation energy=(93.68±2.26) kJ/mol). The kinetics modeling shows that the complexity of thermal decomposition of as-received Ag2O–graphite mixture is higher than that of the others. While, the autocatalytic tendency of as-received Ag2O–graphite mixture is lower than that of the others.
基金Project supported by the International Partnership Program for Creative Research Teams of the Chinese Academy of Sciences (CAS) & the State Administration of Foreign Experts Affairs (SAFEA), China, and the Hundreds-Talent Program of the Chinese Academy of Sciences, China (No. 90502006)
文摘The van Genuchten model is the most widely used soil water retention curve (SWRC) model. Two undisturbed soils (clay and loam) were used to evaluate the accuracy of the integral method to estimate van Genuchten model parameters and to determine SWRCs of undisturbed soils. SWRCs calculated by the integral method were compared with those measured by a high speed centrifuge technique. The accuracy of the calculated results was evaluated graphically, as well as by root mean square error (RMSE), normalized root mean square error (NRMSE) and Willmott's index of agreement (1). The results obtained from the integral method were quite similar to those by the centrifuge technique. The RMSEs (4.61 ×10^-5 for Eum-Orthic Anthrosol and 2.74 × 10^-4 for Los-Orthic Entisol) and NRMSEs (1.56 × 10^-4 for Eum- Orthic Anthrosol and 1.45 ×10^-3 for Los-Orthic Entisol) were relatively small. The 1 values were 0.973 and 0.943 for Eum-Orthic Anthrosol and Los-Orthic Entisol, respectively, indicating a good agreement between the integral method values and the centrifuge values. Therefore, the integral method could be used to estimate SWRCs of undisturbed clay and loam soils.
文摘This paper investigated an effective and robust mechanism for detecting simple mail transfer protocol (SMTP) traffic anomaly. The detection method cumulates the deviation of current delivering status from history behavior based on a weighted sum method called the leaky integrate-and-fire model to detect anomaly. The simplicity of the detection method is that the method need not store history profile and low computation overhead, which makes the detection method itself immunes to attacks. The performance is investigated in terms of detection probability, the false alarm ratio, and the detection delay. The results show that leaky integrate-and-fire method is quite effective at detecting constant intensity attacks and increasing intensity attacks. Compared with the non-parametric cumulative sum method, the evaluation results show that the proposed detection method has shorter detection latency and higher detection probability.
基金Supported by the National Nature Science Foundations of China(No.61300214,U1204611,61170243)the Science and Technology Innovation Team Support Plan of Education Department of Henan Province(No.13IRTSTHN021)+3 种基金the Science and Technology Research Key Project of Education Department of Henan Province(No.13A413066)the Basic and Frontier Technology Research Plan of Henan Province(No.132300410148)the Funding Scheme of Young Key Teacher of Henan Province Universitiesthe Key Project of Teaching Reform Research of Henan University(No.HDXJJG2013-07)
文摘Reasonable selection and optimization of a filter used in model estimation for a multiple model structure is the key to improve tracking accuracy of maneuvering target.Combining with the cubature Kalman filter with iterated observation update and the interacting multiple model method,a novel interacting multiple model algorithm based on the cubature Kalman filter with observation iterated update is proposed.Firstly,aiming to the structural features of cubature Kalman filter,the cubature Kalman filter with observation iterated update is constructed by the mechanism of iterated observation update.Secondly,the improved cubature Kalman filter is used as the model filter of interacting multiple model,and the stability and reliability of model identification and state estimation are effectively promoted by the optimization of model filtering step.In the simulations,compared with classic improved interacting multiple model algorithms,the theoretical analysis and experimental results show the feasibility and validity of the proposed algorithm.
基金Projects 50774080 supported by the National Natural Science Foundation of China200348 by the Foundation for the National Excellent Doctoral Dis-sertation of China
文摘A new mathematical model to estimate the parameters of the probability-integral method for mining subsidence prediction is proposed.Based on least squares support vector machine(LS-SVM) theory, it is capable of improving the precision and reliability of mining subsidence prediction.Many of the geological and mining factors involved are related in a nonlinear way.The new model is based on statistical theory(SLT) and empirical risk minimization(ERM) principles.Typical data collected from observation stations were used for the learning and training samples.The calculated results from the LS-SVM model were compared with the prediction results of a back propagation neural network(BPNN) model.The results show that the parameters were more precisely predicted by the LS-SVM model than by the BPNN model.The LS-SVM model was faster in computation and had better generalized performance.It provides a highly effective method for calculating the predicting parameters of the probability-integral method.
文摘Hybrid mecihanism is a new type of planar controllable mechanism. Position control acouracy of system determines the output aconracy of the mechanism. In order to achieve the desired high acowacy, nonlinear factors as friction nmst be accurately compensated in the real-time servo control algoritinn. In this paper, the model of a hybrid five-bar mechanism is introduced. In terms of the characteristics of the hybrid mechanism, a hybrid intelligent control algorithm based on proportional-integral-derivative (PID) control and cerebellar model articulation control techniques was presented and used to perform control of hybrid five-bar mechanism for the lust time. The sinmulation results show that the hybrid control method can improve the control effect remarkably, compared with the traditional PID control strategy.
文摘The Ishimori equation is one of the most important(2+1)-dimensional integrable models,which is an integrable generalization of(1+1)-dimensional classical continuous Heisenberg ferromagnetic spin equations.Based on importance of Lie symmetries in analysis of differential equations,in this paper,we derive Lie symmetries for the Ishimori equation by Hirota's direct method.
基金supported by the International Postgraduate Research Scholarship(IPRS)Australian Postgraduate Award(APA)sponsored by the Australian Government via the University of Western Australiathe National Natural Science Foundation of China(Grant Nos.41130751&51178012)
文摘This paper presents a further development of the dual reciprocity boundary element method(DRBEM) with stepwise updating to pave the way for the introduction of boundary element mesh into the discontinuous deformation analysis(DDA). The advantage of the proposed method lies in its adoption of static fundamental solutions and reduction in the size of the governing equations by transforming the inertial term domain integrals to boundary integrals in the dynamic large displacement analysis. The unconditionally stable Newmark-β time integration method involving numerical damping to enhance the numerical stability is implemented for the dynamic analysis. In order to be coupled with the DDA to improve the deformability of the DDA block domains, a stepwise updating algorithm of the system variables is introduced. The stress updating in the analysis involved in the calculation of a domain integral and internal cells are used for the integration of the initial stress term. Several examples are used to verify the geometry-updated DRBEM model and satisfactory results have been obtained.