Core D (21°23′02″N, 116°47′13″E, water depth 405 m) was sampled from the upper slope from the northeastern South China Sea (SCS) and applied to analyze the sedimentary environmental change in this se...Core D (21°23′02″N, 116°47′13″E, water depth 405 m) was sampled from the upper slope from the northeastern South China Sea (SCS) and applied to analyze the sedimentary environmental change in this sea area since the last glacial stage. The results of grain size analysis, diatom analysis and detrital mineral analysis were well matched. We divided the core D into two layers. The surface sand layer (0 - 2 cm) consisted of residual sediments, which might be originally the sediment in the late Pleistocene and later suffered from being transformed in the post glacial transgression. The lower layer (2 - 130 cm) was quite different from the surface one, which might mainly result from a neritic sedimentary environment in the last glacial stage. Two sedimentary cycles could be detected in the core D: regression during Marine isotope stage (MIS) 4 to transgression during MIS 3 and regression during MIS 2 to transgression during the post glacial.展开更多
The contamination and environmental risk assessment of the toxic elements in sediments from the middle-downstream (Zhuzhou-Changsha section) of the Xiangjiang River in Hunan Province of China were studied. The results...The contamination and environmental risk assessment of the toxic elements in sediments from the middle-downstream (Zhuzhou-Changsha section) of the Xiangjiang River in Hunan Province of China were studied. The results show that As, Cd, Pb and Zn are major contaminants in sediments, and average concentrations of these elements significantly exceed both the Control Standards for Pollutants in Sludge of China (GB4284-84) for agricultural use in acidic soils and the effect range median (ERM) values. The average concentrations of As, Cd and Pb in the river water slightly exceed the limit of Surface Water Environment Quality Standard (GB3838-2002). The concentrations of As and Cr in depth profiles extensively change, but slight changes are observed in Pb and Zn. Cd and Zn in most sediment samples can easily enter the food-chain and bring possible ecotoxicological risk to organisms living in sediments according to the risk assessment code.展开更多
The average size of the sand of dune in the vicinity of Tumen River is 0.12~0.30 mm, its standard deviation is 0.45~0.99 φ and the frequency cumulative distribution curve is divided into the single peak and the dou...The average size of the sand of dune in the vicinity of Tumen River is 0.12~0.30 mm, its standard deviation is 0.45~0.99 φ and the frequency cumulative distribution curve is divided into the single peak and the double peak. The Ski of the single peak is negative and the double peak is positive. There are two different areas in the plot of the Ski versus σi* It is shown that the sedimentary environment of the dunes is neritic deposit by the expressions of the grain-size parameters. All of the characters show that the sand dunes in Estuary of Tumen River may be the dunes of sea facies which were changed again by weathering and fluvialaction.展开更多
For the past 20 years, numerous studies have been carried out on the application of equilibrium partitioning approach (EqPA) for the derivation of sediment quality guidelines (SQGs). However, for metals, few Equil...For the past 20 years, numerous studies have been carried out on the application of equilibrium partitioning approach (EqPA) for the derivation of sediment quality guidelines (SQGs). However, for metals, few Equilibrium-partitioning- based numerical SQGs have been developed or are currently available because of the confounding factors mediating the bioavailability of metals. A study was conducted at Dianchi Lake, which is a heavily eutrophicated lake on the Yunnan- Guizhou Plateau, China with the focus on the measurement of partitioning coefficient (Kp) and SQGs derivation and normalization to acid volatile sulfide (AVS), fine material, and organic carbon. Using new normalization methods, SQGs were formulated for seven metals including copper, zinc, lead, cadmium, chromium, mercury, and arsenic in Dianchi Lake. In Dianchi Lake sediments, the fine material contributed 25.4%-36.0% to the SQG values, with the largest contribution to the SQG value of mercury; AVS contributed 2.9%-75.0% to the SQG values, with the largest contribution to the SQG value of cadmium. This indicated that the fine material and the AVS were the most important controlling factors to the bioavailability of mercury and caximium, respectively. The contribution of total organic carbon (TOC) to the SQG values of copper and leaxi was 3.8% and 7.1%, respectively, indicating that at relatively lower concentrations, the contribution of TOC was not significant. In addition to normalization methods, appropriate procedures for the application of EqPA including sample collection, storage, and analysis are also essential to improve the reliability of SQGs. The normalized Dianchi Lake SQGs were higher than most of the empirically based SQGs developed in North America, but lower than Hong Kong interim SQGs except for cadmium and arsenic. The differences could be attributed to the approaches used for derivation of SQGs and the water quality criteria adopted and the differences in the physical and chemical characteristics of the sediments.展开更多
Full grown oocytes derived from Bufo Bufo gargarizans rearing at high temperature environment (24℃),never underwent GVBD after progesterone treatment. No p34cdc2, H1 kinase activity was detected in the oocytes after ...Full grown oocytes derived from Bufo Bufo gargarizans rearing at high temperature environment (24℃),never underwent GVBD after progesterone treatment. No p34cdc2, H1 kinase activity was detected in the oocytes after progesterone stimulation or OA microinjection; Western blotting analysis showed that the level of p3cdc2, and p33 in the oocytes are significantly lower than those in the oocytes derived from the hibernating toads (below 10 ℃). 25S-Met incorporation analysis showed that when the oocytes were incubated at 6℃, synthesis of about thirty defferent polypeptides was promoted or induced, including p34cdc2 and some other p13suc1-binding proteins. All these results indicated that a low temperature environment is essential for the oocytes of Bufo Bufo gargarizans to express and store some cell cycle drivers and its regulators, and to gain the maturation competence. These results will also provide a new clue for explaining the molecular mechanisms why gametogenesis of some organisms depends on a relative low temperature and how to maintain the geographical distribution of some animals.展开更多
This paper presents an improved Voice Activity Detection (VAD) algorithm which uses the Signal-to-Noise Ratio (SNR) measure. We assume that noise Power Spectral Density (PSD) in each spectral bin follows a Rayle...This paper presents an improved Voice Activity Detection (VAD) algorithm which uses the Signal-to-Noise Ratio (SNR) measure. We assume that noise Power Spectral Density (PSD) in each spectral bin follows a Rayleigh distribution. Rayleigh distributions with its asymmetric tail characteristics give a better description of the noise PSD distribution than Gaussian distribution. Under this asstlmption, a new threshold updating expression is derived. Since the analytical integral of the false alarm probability, the threshold updating expression can be represented without the inverse complementary error function and low computational complexity is achieved in our system. Experimental results show that the proposed VAD outperforms or at least is comparable with the VAD scheme presented by Davis under several noise environments and has a lower computational complexity.展开更多
Anthracite coal was used as raw material to prepare activated carbons as the carbon support in the carbonization-activation process. Modification of the pore size of the activated carbon by chemical vapor deposition o...Anthracite coal was used as raw material to prepare activated carbons as the carbon support in the carbonization-activation process. Modification of the pore size of the activated carbon by chemical vapor deposition of carbon from benzene was examined. These samples were characterized by adsorption of N2 at 77 K and CH4 and N2 at 303 K. The microporosity of these samples was evaluated by the Dubinin-Astakhov Equation. The pore size distribution was obtained by the DFT method applied to the N2 adsorption data at 77 K. The separation selectivity was obtained by the Langmuir Equation. The surface morphology was characterized by an environmental scanning electron microscope. It was observed that all samples of carbon molecular sieves studied were microporous carbonaceous materials. CMS-2 prepared in the present study has a better N2/CH4 separation performance; it can satisfy the requirements of the pressure swing adsorption for concentrating CH4 from the N2/CH4 mixture gas.展开更多
The bottom sediment samples were gathered during island investigation in 1994 and in the period of carrying out the natural science fund project of Fujian in 1999. The composition, distribution and assemblage characte...The bottom sediment samples were gathered during island investigation in 1994 and in the period of carrying out the natural science fund project of Fujian in 1999. The composition, distribution and assemblage characteristics of heavy minerals which granularity distributes from 0.063 to 0.125 mm in the sediment from Jiulong River estuary are studied in the paper. The results show that there are 49 kinds of heavy minerals and the average content of them is 9.38 %. The dominant and characteristic minerals are magnetite, hematite, epidote, ilmenite, limonite, hornblende, zircon, andalusite, biotite and so on. 4 mineral assemblage ⅠⅡzones (.The watercourse gateway of Jiulong River mineral zone, . The northern estuary ⅢⅣof Jiulong River mineral zone, . The southern estuary mineral zone, . The eastern estuary of Jiulong River mineral zone ), can be divided based on the heavy mineral contents and the distribution characteristics, which not only relates to the matter sources but also is controlled by hydrodynamic condition and the sedimentary environment in the Jiulong River estuary.展开更多
The sea level changes in the Paleozoic epicontinental basin were of high frequency and the transgressive events were episodic.This kind of sea level changes controlled both the basin filling and the coal accumulation ...The sea level changes in the Paleozoic epicontinental basin were of high frequency and the transgressive events were episodic.This kind of sea level changes controlled both the basin filling and the coal accumulation within the basin.Coal accumulation in the transgressive process is one of the typical features of the North China epicontinental basin.High resolution sequence analysis to the Permo carboniferous coal series based on the core observation indicates that the epicontintental coal bearing succession can be divided into 1 tectonic sequence (the original type of basin filling), 3 supersequences, 12 third order sequences and about 48 parasequences.The third order sequences are of dual configuration sequences that are composed of transgressive systems tract in the lower part and highstand systems tract in the upper part.The transgressive systems tracts are relatively thin in thickness and have fewer parasequences (commonly 1 to 2), while the highstand systems tracts are thick, generally consist of several parasequences.展开更多
There has been a significant debate about the nature and causes of the Pleistocene evolution of the Nihewan Basin, North China. We studied the eastern Nihewan Basin sedimentary facies at two main sites, Hutouliang and...There has been a significant debate about the nature and causes of the Pleistocene evolution of the Nihewan Basin, North China. We studied the eastern Nihewan Basin sedimentary facies at two main sites, Hutouliang and Donggou. A combination of field observations and measurements of sediment grain-size distribution was used to reconstruct the sequence of sedimentary environments since the middle Pleistocene, and optically-stimulated luminescence measurements were used to date the sediments. Our results indicate that a shallow lake occupied the basin center along the Sanggan River, probably lasting until -440 kyr ago before disappearing completely -340 kyr ago. It was succeeded by a phase of fluvial-dominated sediment accumulation which ended -30 kyr ago. We suggest that the formation of the gorge resulted from the relative uplift of the Niuxin Mountain along the Liulengshan fault -140 kyr ago. However, since -30 kyr ago the fault may have become inactive and the river downcutting near Shixia was no longer offset by the relative uplift, which caused a shift from deposition to denudation in the Nihewan Basin from then on. The disappearance of the paleolake -340 kyr ago may have been the culmination of the ongoing process of basin infilling.展开更多
The environment of estuarine wetlands has been attracting worldwide attention. To study the spatial distribution of pollutants in the tidal flats of the Yangtze Estuary, Southeast China, the Eastern Tidal Flat of Chon...The environment of estuarine wetlands has been attracting worldwide attention. To study the spatial distribution of pollutants in the tidal flats of the Yangtze Estuary, Southeast China, the Eastern Tidal Flat of Chongming Island (EC) and the Jiuduansha Shoal (JS) of the estuary were selected as the study sites. At each of the two sites, a cross-transect from land to sea was established and topsoil and soil core samples in the cross-transect were collected spatially and seasonally to determine their contents of heavy metals (Cu, Zn, Pb, Cd, Cr, Ni, Mn, and Fe) and grain-size characteristics. The results showed that the heavy metal loads were commonly higher in the soils of nearshore high tidal flats and had a tendency of decreasing from land to sea at both of the study sites. The contents of heavy metals in the soils of the high and medial tidal flats were mostly higher in April and November but lower in July. Corresponding spatial and seasonal variations in grain size of the intertidal soils were also observed at the two study sites. The soils in the nearshore high tidal flats were finer and gradually got coarser seawards; they were relatively finer in April and November but coarser in July. Furthermore, the contents of heavy metals in the intertidal soils of both the sites EC and JS were significantly positively correlated with the clay (<2 μm) and 2-20 μm fractions, but negatively with the sand (>63 μm) and 20-63 μm fractions, which suggested that the heavy metals in the intertidal soils were primarily combined with the fine particulate fraction (<20 μm), especially clay, and hence the spatial and seasonal variations in heavy metals were actually caused by the change of the grain-size characteristics of the intertidal soils due to the different sedimentary environments in the estuary. The results of this study may also contribute to a better understanding of the soil formation and classification in the tidal flats of the Yangtze Estuary.展开更多
We analyze high-resolution anisotropy of magnetic susceptibility (AMS) of the loess-paleosol successions at Luochuan, central Chinese Loess Plateau, in order to investigate the AMS characteristics and their climatic i...We analyze high-resolution anisotropy of magnetic susceptibility (AMS) of the loess-paleosol successions at Luochuan, central Chinese Loess Plateau, in order to investigate the AMS characteristics and their climatic implications. Our results indicate a normal sedimentary magnetic fabric for almost of all samples, characterized by minimum susceptibility axes grouped in an almost vertical direction. Magnetic foliation and anisotropy degree show upwards decreasing trend due to decreasing post-depositional compaction. Magnetic lineations show no preferred directions and thus cannot indicate paleowind patterns. AMS parameters at Luochuan are controlled by particle size, pedogenesis, and sedimentary compaction. The high peaks of magnetic foliation and anisotropy degree of L2, L3, L6, L9, and L15 correspond to the coarse particle sizes of these loess beds, indicating the grain-size dependence of AMS.展开更多
Formation and preservation of greigite can indicate the physicochemical characteristics of sedimentary environment. Presence of greigite can be diagnosed in the late Pleistocene fluvio-lacustrine sedimentary layers of...Formation and preservation of greigite can indicate the physicochemical characteristics of sedimentary environment. Presence of greigite can be diagnosed in the late Pleistocene fluvio-lacustrine sedimentary layers of 29.4–29.7 and 26.1–27.1 m in core ZK30 of the Yellow River delta, based on analysis of particle size, magnetic properties, scanning electron microscope(SEM) and X-ray diffraction(XRD) measurements. These layers are the transition zones from shallow marine facies to fluvio- lacustrine facies, and from fluvio-lacustrine facies to salt marsh facies in an ascending order, respectively. They are characterized by higher SIRM and SIRM/χ(>30 kA m-1) values than those of other layers, suggesting the possible existence of greigite. Both SEM and XRD analyses confirm its presence. However, sediment layer of 29.4–29.7 m are coarser, and greigite coexists with pyrite, but sediment layer of 26.1–27.1 m are finer and the occurrence of greigite is not accompanied by pyrite. The different occurrence of greigite in the two layers suggests that different climate condition and sedimentary environment control its formation and preservation.展开更多
文摘Core D (21°23′02″N, 116°47′13″E, water depth 405 m) was sampled from the upper slope from the northeastern South China Sea (SCS) and applied to analyze the sedimentary environmental change in this sea area since the last glacial stage. The results of grain size analysis, diatom analysis and detrital mineral analysis were well matched. We divided the core D into two layers. The surface sand layer (0 - 2 cm) consisted of residual sediments, which might be originally the sediment in the late Pleistocene and later suffered from being transformed in the post glacial transgression. The lower layer (2 - 130 cm) was quite different from the surface one, which might mainly result from a neritic sedimentary environment in the last glacial stage. Two sedimentary cycles could be detected in the core D: regression during Marine isotope stage (MIS) 4 to transgression during MIS 3 and regression during MIS 2 to transgression during the post glacial.
基金Project (20507022) supported by the National Natural Science Foundation of ChinaProject (EREH050303) supported by the Foundation of Ministry of Education Key Laboratory of Environmental Remediation and Ecosystem Health
文摘The contamination and environmental risk assessment of the toxic elements in sediments from the middle-downstream (Zhuzhou-Changsha section) of the Xiangjiang River in Hunan Province of China were studied. The results show that As, Cd, Pb and Zn are major contaminants in sediments, and average concentrations of these elements significantly exceed both the Control Standards for Pollutants in Sludge of China (GB4284-84) for agricultural use in acidic soils and the effect range median (ERM) values. The average concentrations of As, Cd and Pb in the river water slightly exceed the limit of Surface Water Environment Quality Standard (GB3838-2002). The concentrations of As and Cr in depth profiles extensively change, but slight changes are observed in Pb and Zn. Cd and Zn in most sediment samples can easily enter the food-chain and bring possible ecotoxicological risk to organisms living in sediments according to the risk assessment code.
文摘The average size of the sand of dune in the vicinity of Tumen River is 0.12~0.30 mm, its standard deviation is 0.45~0.99 φ and the frequency cumulative distribution curve is divided into the single peak and the double peak. The Ski of the single peak is negative and the double peak is positive. There are two different areas in the plot of the Ski versus σi* It is shown that the sedimentary environment of the dunes is neritic deposit by the expressions of the grain-size parameters. All of the characters show that the sand dunes in Estuary of Tumen River may be the dunes of sea facies which were changed again by weathering and fluvialaction.
基金Project supported by the State Key Laboratory of Soil and Sustainable Agriculture, China (No. 5022505)the National Natural Science Foundation of China (No. 40771128)
文摘For the past 20 years, numerous studies have been carried out on the application of equilibrium partitioning approach (EqPA) for the derivation of sediment quality guidelines (SQGs). However, for metals, few Equilibrium-partitioning- based numerical SQGs have been developed or are currently available because of the confounding factors mediating the bioavailability of metals. A study was conducted at Dianchi Lake, which is a heavily eutrophicated lake on the Yunnan- Guizhou Plateau, China with the focus on the measurement of partitioning coefficient (Kp) and SQGs derivation and normalization to acid volatile sulfide (AVS), fine material, and organic carbon. Using new normalization methods, SQGs were formulated for seven metals including copper, zinc, lead, cadmium, chromium, mercury, and arsenic in Dianchi Lake. In Dianchi Lake sediments, the fine material contributed 25.4%-36.0% to the SQG values, with the largest contribution to the SQG value of mercury; AVS contributed 2.9%-75.0% to the SQG values, with the largest contribution to the SQG value of cadmium. This indicated that the fine material and the AVS were the most important controlling factors to the bioavailability of mercury and caximium, respectively. The contribution of total organic carbon (TOC) to the SQG values of copper and leaxi was 3.8% and 7.1%, respectively, indicating that at relatively lower concentrations, the contribution of TOC was not significant. In addition to normalization methods, appropriate procedures for the application of EqPA including sample collection, storage, and analysis are also essential to improve the reliability of SQGs. The normalized Dianchi Lake SQGs were higher than most of the empirically based SQGs developed in North America, but lower than Hong Kong interim SQGs except for cadmium and arsenic. The differences could be attributed to the approaches used for derivation of SQGs and the water quality criteria adopted and the differences in the physical and chemical characteristics of the sediments.
文摘Full grown oocytes derived from Bufo Bufo gargarizans rearing at high temperature environment (24℃),never underwent GVBD after progesterone treatment. No p34cdc2, H1 kinase activity was detected in the oocytes after progesterone stimulation or OA microinjection; Western blotting analysis showed that the level of p3cdc2, and p33 in the oocytes are significantly lower than those in the oocytes derived from the hibernating toads (below 10 ℃). 25S-Met incorporation analysis showed that when the oocytes were incubated at 6℃, synthesis of about thirty defferent polypeptides was promoted or induced, including p34cdc2 and some other p13suc1-binding proteins. All these results indicated that a low temperature environment is essential for the oocytes of Bufo Bufo gargarizans to express and store some cell cycle drivers and its regulators, and to gain the maturation competence. These results will also provide a new clue for explaining the molecular mechanisms why gametogenesis of some organisms depends on a relative low temperature and how to maintain the geographical distribution of some animals.
基金Supported by the National Natural Science Foundation of China (No. 60874060)
文摘This paper presents an improved Voice Activity Detection (VAD) algorithm which uses the Signal-to-Noise Ratio (SNR) measure. We assume that noise Power Spectral Density (PSD) in each spectral bin follows a Rayleigh distribution. Rayleigh distributions with its asymmetric tail characteristics give a better description of the noise PSD distribution than Gaussian distribution. Under this asstlmption, a new threshold updating expression is derived. Since the analytical integral of the false alarm probability, the threshold updating expression can be represented without the inverse complementary error function and low computational complexity is achieved in our system. Experimental results show that the proposed VAD outperforms or at least is comparable with the VAD scheme presented by Davis under several noise environments and has a lower computational complexity.
文摘Anthracite coal was used as raw material to prepare activated carbons as the carbon support in the carbonization-activation process. Modification of the pore size of the activated carbon by chemical vapor deposition of carbon from benzene was examined. These samples were characterized by adsorption of N2 at 77 K and CH4 and N2 at 303 K. The microporosity of these samples was evaluated by the Dubinin-Astakhov Equation. The pore size distribution was obtained by the DFT method applied to the N2 adsorption data at 77 K. The separation selectivity was obtained by the Langmuir Equation. The surface morphology was characterized by an environmental scanning electron microscope. It was observed that all samples of carbon molecular sieves studied were microporous carbonaceous materials. CMS-2 prepared in the present study has a better N2/CH4 separation performance; it can satisfy the requirements of the pressure swing adsorption for concentrating CH4 from the N2/CH4 mixture gas.
基金The natural science fund of Fujian ( Numbering item: D9910006 )
文摘The bottom sediment samples were gathered during island investigation in 1994 and in the period of carrying out the natural science fund project of Fujian in 1999. The composition, distribution and assemblage characteristics of heavy minerals which granularity distributes from 0.063 to 0.125 mm in the sediment from Jiulong River estuary are studied in the paper. The results show that there are 49 kinds of heavy minerals and the average content of them is 9.38 %. The dominant and characteristic minerals are magnetite, hematite, epidote, ilmenite, limonite, hornblende, zircon, andalusite, biotite and so on. 4 mineral assemblage ⅠⅡzones (.The watercourse gateway of Jiulong River mineral zone, . The northern estuary ⅢⅣof Jiulong River mineral zone, . The southern estuary mineral zone, . The eastern estuary of Jiulong River mineral zone ), can be divided based on the heavy mineral contents and the distribution characteristics, which not only relates to the matter sources but also is controlled by hydrodynamic condition and the sedimentary environment in the Jiulong River estuary.
文摘The sea level changes in the Paleozoic epicontinental basin were of high frequency and the transgressive events were episodic.This kind of sea level changes controlled both the basin filling and the coal accumulation within the basin.Coal accumulation in the transgressive process is one of the typical features of the North China epicontinental basin.High resolution sequence analysis to the Permo carboniferous coal series based on the core observation indicates that the epicontintental coal bearing succession can be divided into 1 tectonic sequence (the original type of basin filling), 3 supersequences, 12 third order sequences and about 48 parasequences.The third order sequences are of dual configuration sequences that are composed of transgressive systems tract in the lower part and highstand systems tract in the upper part.The transgressive systems tracts are relatively thin in thickness and have fewer parasequences (commonly 1 to 2), while the highstand systems tracts are thick, generally consist of several parasequences.
基金supported by the Chinese Geological Survey(Grant No.12120113005600)the National Natural Science Foundation of China(Grant Nos.41472138&41371203)
文摘There has been a significant debate about the nature and causes of the Pleistocene evolution of the Nihewan Basin, North China. We studied the eastern Nihewan Basin sedimentary facies at two main sites, Hutouliang and Donggou. A combination of field observations and measurements of sediment grain-size distribution was used to reconstruct the sequence of sedimentary environments since the middle Pleistocene, and optically-stimulated luminescence measurements were used to date the sediments. Our results indicate that a shallow lake occupied the basin center along the Sanggan River, probably lasting until -440 kyr ago before disappearing completely -340 kyr ago. It was succeeded by a phase of fluvial-dominated sediment accumulation which ended -30 kyr ago. We suggest that the formation of the gorge resulted from the relative uplift of the Niuxin Mountain along the Liulengshan fault -140 kyr ago. However, since -30 kyr ago the fault may have become inactive and the river downcutting near Shixia was no longer offset by the relative uplift, which caused a shift from deposition to denudation in the Nihewan Basin from then on. The disappearance of the paleolake -340 kyr ago may have been the culmination of the ongoing process of basin infilling.
基金Supported by the National Natural Science Foundation of China (Nos. 41130526, 40971126, and 40771093)the Shanghai Leading Academic Discipline Project of China (No. S30109)
文摘The environment of estuarine wetlands has been attracting worldwide attention. To study the spatial distribution of pollutants in the tidal flats of the Yangtze Estuary, Southeast China, the Eastern Tidal Flat of Chongming Island (EC) and the Jiuduansha Shoal (JS) of the estuary were selected as the study sites. At each of the two sites, a cross-transect from land to sea was established and topsoil and soil core samples in the cross-transect were collected spatially and seasonally to determine their contents of heavy metals (Cu, Zn, Pb, Cd, Cr, Ni, Mn, and Fe) and grain-size characteristics. The results showed that the heavy metal loads were commonly higher in the soils of nearshore high tidal flats and had a tendency of decreasing from land to sea at both of the study sites. The contents of heavy metals in the soils of the high and medial tidal flats were mostly higher in April and November but lower in July. Corresponding spatial and seasonal variations in grain size of the intertidal soils were also observed at the two study sites. The soils in the nearshore high tidal flats were finer and gradually got coarser seawards; they were relatively finer in April and November but coarser in July. Furthermore, the contents of heavy metals in the intertidal soils of both the sites EC and JS were significantly positively correlated with the clay (<2 μm) and 2-20 μm fractions, but negatively with the sand (>63 μm) and 20-63 μm fractions, which suggested that the heavy metals in the intertidal soils were primarily combined with the fine particulate fraction (<20 μm), especially clay, and hence the spatial and seasonal variations in heavy metals were actually caused by the change of the grain-size characteristics of the intertidal soils due to the different sedimentary environments in the estuary. The results of this study may also contribute to a better understanding of the soil formation and classification in the tidal flats of the Yangtze Estuary.
基金supported by the National Basic Research Program of China (Grant No. 2010CB833400)Chinese Academy of Sciences (Grant Nos.KZCX2-YW-Q09-06-04, KZCX2-YW-130)National Natural Science Foundation of China (Grant No. 40830104)
文摘We analyze high-resolution anisotropy of magnetic susceptibility (AMS) of the loess-paleosol successions at Luochuan, central Chinese Loess Plateau, in order to investigate the AMS characteristics and their climatic implications. Our results indicate a normal sedimentary magnetic fabric for almost of all samples, characterized by minimum susceptibility axes grouped in an almost vertical direction. Magnetic foliation and anisotropy degree show upwards decreasing trend due to decreasing post-depositional compaction. Magnetic lineations show no preferred directions and thus cannot indicate paleowind patterns. AMS parameters at Luochuan are controlled by particle size, pedogenesis, and sedimentary compaction. The high peaks of magnetic foliation and anisotropy degree of L2, L3, L6, L9, and L15 correspond to the coarse particle sizes of these loess beds, indicating the grain-size dependence of AMS.
基金supported by the National Natural Science Foundation of China(Grant Nos.41030856,41176039,41376054 and 41030856)the Natural Science Foundation of Shandong Province(Grant No.2011ZRE29040)
文摘Formation and preservation of greigite can indicate the physicochemical characteristics of sedimentary environment. Presence of greigite can be diagnosed in the late Pleistocene fluvio-lacustrine sedimentary layers of 29.4–29.7 and 26.1–27.1 m in core ZK30 of the Yellow River delta, based on analysis of particle size, magnetic properties, scanning electron microscope(SEM) and X-ray diffraction(XRD) measurements. These layers are the transition zones from shallow marine facies to fluvio- lacustrine facies, and from fluvio-lacustrine facies to salt marsh facies in an ascending order, respectively. They are characterized by higher SIRM and SIRM/χ(>30 kA m-1) values than those of other layers, suggesting the possible existence of greigite. Both SEM and XRD analyses confirm its presence. However, sediment layer of 29.4–29.7 m are coarser, and greigite coexists with pyrite, but sediment layer of 26.1–27.1 m are finer and the occurrence of greigite is not accompanied by pyrite. The different occurrence of greigite in the two layers suggests that different climate condition and sedimentary environment control its formation and preservation.