Abstract: Based on the analysis of core samples from the hole of Zk23 in the East China Sea Continental Shelf and by means of sedimentary stratigraphy, biostratigraphy and chronostratigraphy, the authors consider tha...Abstract: Based on the analysis of core samples from the hole of Zk23 in the East China Sea Continental Shelf and by means of sedimentary stratigraphy, biostratigraphy and chronostratigraphy, the authors consider that the fine-sand deposition in borehole was part of buried ancient estuary sand ridges of the Yangtze River. The deposition history of study area around the hole before and after the glacial period as well as postglacial period is made clear after our research: (1) the estuarine sublayer -undersea delta facies strata was deposited under the fast sea level rise about 15 kaB.P; (2) sand ridges mostly consisting of fine-sand, were formed when the sea level was the fluctuant range of 60 - 80 m of isoba during the deglacial period around 15 - 12 kaB.P; (3) first silty clay and clay silt strata above the sand ridges were deposited during the period when the sea level rose fast from 12 to 7 kaB.P, and then it keeps stable to the present.展开更多
This paper reviews the current status of investigation on snow accumulation on the bogies of high-speed trains(HSTs) running in snowy region. First, the background of the snow issue occurring to the HST and the contra...This paper reviews the current status of investigation on snow accumulation on the bogies of high-speed trains(HSTs) running in snowy region. First, the background of the snow issue occurring to the HST and the contra-measures for the snow issue proposed in the past decades are provided by reviewing previous studies. Next, the methodology for investigating the snow issue developed by High-Speed Train Research Center of Central South University is introduced, including the numerical simulation research platform and the experimental devices for two-phase flow wind tunnel tests. Then, effective anti-snow flow control schemes for guiding the underbody airflow and their impact on the motion and accretion of snow in the installation region of the bogies are presented. Finally, the remaining investigating challenge for the snow issue of HST and the future research with respect to the challenge are provided from an engineering application viewpoint.展开更多
High-performance and cost-effective catalysts for water splitting are key components of hydrogen-based energy technologies. Metal-organic framework(MOF)-derived metal phosphide composites have immense potential as hig...High-performance and cost-effective catalysts for water splitting are key components of hydrogen-based energy technologies. Metal-organic framework(MOF)-derived metal phosphide composites have immense potential as highly active and stable electrocatalysts but suffer from the poor efficacy of available electrode assembly methods. In this study, an MOF-derived nitrogen-doped porous carbon/Co/Co P/carbon paper(NC/Co/Co P/CP) composite electrode was assembled by electrophoretic deposition and post-processing reactions. The binder-free electrode showed good catalytic activity, significantly higher than that of traditional electrodes. The electrode required overpotentials of 208 and 350 m V to achieve a current density of 10 m A/cm^2 for the hydrogen and oxygen evolution reactions, respectively. This facile synthetic method provides a promising route for designing metal-doped and multi-metal phase MOF-derived composite electrodes for energy storage and conversion devices.展开更多
This paper deals with the integrability of a finite-dimensional Hamiltonian system linked with the generalized coupled KdV hierarchy. For this purpose the associated Lax representation is presented after an elementary...This paper deals with the integrability of a finite-dimensional Hamiltonian system linked with the generalized coupled KdV hierarchy. For this purpose the associated Lax representation is presented after an elementary calculation. It is shown that the Lax representation enjoys a dynamical r-matrix formula instead of a classical one in the Poisson bracket on R2N. Consequently the resulting system is proved to be completely integrable in view of its r-matrix structure.展开更多
The determinant role of upwelling in fine sediment patches is examined from the viewpoints of physical process and biological process respectively. It is pointed out that physical and biological processes are usually ...The determinant role of upwelling in fine sediment patches is examined from the viewpoints of physical process and biological process respectively. It is pointed out that physical and biological processes are usually coexistent and interact with each other during the sedimentation of suspended matters. This study used available figures showing the circulation pattern and surface sediment distribution in the whole China Seas, the Gulf of Maine, the Irish Sea and the North Sea, and additional data to verify that wherever upwelling exists on the continental shelf, mud must occur; and that wherever downwelling occurs, coarse sediment substitutes for mud.展开更多
Correspondence analysis and fuzzy C-means cluster methods were used to divide the stratigraphy of heavy mineral assemblages, and the sediment sources and depositional dynamics of the environment reconstructed. The ass...Correspondence analysis and fuzzy C-means cluster methods were used to divide the stratigraphy of heavy mineral assemblages, and the sediment sources and depositional dynamics of the environment reconstructed. The assemblages were taken from marine sediments from the late Pleistocene to the Holocene in Core Q43 situated on the outer shelf of the East China Sea. Based on the variable boundaries of the mineral assemblage at 63 and 228 cmbsf (cm below sea floor), the core might have previously been divided into three sediment strata marked with units Ⅰ, Ⅱ and Ⅲ, which would be consistent with the divided sediment stratum of the core using minor element geochemistry. The downcore distribution of heavy minerals divided the sedimentary sequence into three major units, which were further subdivided into four subunits. The interval between 0 and 63 cmbsf of the core (unit Ⅰ), which spans the Holocene and the uppermost late Pleistocene, is characterized by a hornblende-epidote-pyroxene assemblage, and contains relatively a smaller amount of schistic mineral and authigenic pyrite. In comparison, the interval between 63 and 228 cmbsf (unit Ⅱ), is representative of the Last Glacial Maximum (LGM), and features a hornblende-epidote-magnetite-ilmenite assemblage containing the highest concentrations of heavy minerals and opaque minerals. However, the interval between 228 and 309 cmbsf (unit Ⅲ), which spans the subinterglacial period, is characterized by a hornblende-authigenic-pyrite-mica assemblage. Relative ratios of some heavy minerals can be used as tracers of clastic sediment sources. The lower part of the sediment core shows the highest magnetite/ilmenite ratio and relatively high hornblende/augite and hornblende/epidote ratios. The middle core shows the highest hornblende/augite and hornblende/epidote ratios, and the lowest magnetite/ilmenite ratio. The upper part exhibits a slightly higher magnetite/ilmenite ratio, and also the lowest hornblende/augite and hornblende/epidote ratios. The distribution of the mineral ratio is consistent with stratigraphic division in heavy mineral data using correspondence analysis and fuzzy C-means clustering. Variations in heavy mineral association and mineral ratio in core Q43 revealed changes in provenance and depositional environment of the southern outer shelf of the East China Sea since the late Pleistocene, well corresponding to interglacial and glacial cycles.展开更多
Large areas of muddy sediments on the coastal shelves of China provide important samples for studying climate and ecological changes. Analysis of a large number of such samples, which is essential for systematic study...Large areas of muddy sediments on the coastal shelves of China provide important samples for studying climate and ecological changes. Analysis of a large number of such samples, which is essential for systematic study on environmental information recorded in mud areas because of complicated sedimentary environment and variable sedimentary rate, requires a fast and economical method. In this study, we investigated the potential of X-ray fluorescence core scanner (XRFS), a fast analytical instrument for measuring the elemental concentrations of muddy sediments, and observed a significant correlation between the element concentrations of muddy sediments determined by regular X-ray fluorescence spectrometer (XRF) and XRFS, respectively. The correlations are mainly determined by excitation energy of elements, but also influenced by solubility of element ions. Furthermore, we found a striking link between A1 concentrations and marine-originated organic carbon (MOC), a proxy of marine primary productivity. This indicates that MOC is partly controlled by sedimentary characteristics. Therefore, XRFS method has a good potential in fast analysis of a large number of muddy sediment samples, and it can also be used to calibrate MOC in ecological study of coastal seas.展开更多
In order to reveal the relationship between the penecontemporaneous karstification and sedimentary microtopography in sequence stratigraphy,the sequence stratigraphic framework of Lianglitage formation in Upper Ordovi...In order to reveal the relationship between the penecontemporaneous karstification and sedimentary microtopography in sequence stratigraphy,the sequence stratigraphic framework of Lianglitage formation in Upper Ordovician is studied according to the well drilling,logging,geophysical data,detailed observations of core and the paleontology.The Lianglitage formation belongs to the sequence Ⅳ of Ordovician.The second member of Lianglitage formation is prograde sedimentation in highstand systems tract,and is favorable for developing reef flat.The development scale and thickness of reef flat are controlled by the variation of secondary sea level.The types and characteristics of karst in the highstand systems tract show that the late highstand systems tract is dissolved and cemented by the meteoric fresh water and mixed water.Penecontemporaneous karstification is developed at the top of parasequence and high place of geomorphology.Atmospheric diagenetic lens is formed.The developing regulations and controlling factors of penecontemporaneous karstification can provide new clues to the prediction and exploration of favorable reservoir in this area.展开更多
The well-known Three Gorges Dam(TGD) within the Yangtze catchment launched its operation in 2003. The effect of the TGD operation on the sediment size on the East China Sea shelf is rarely known. High resolution(0.5 c...The well-known Three Gorges Dam(TGD) within the Yangtze catchment launched its operation in 2003. The effect of the TGD operation on the sediment size on the East China Sea shelf is rarely known. High resolution(0.5 cm sampling) grain size analysis and 137 Cs and 210 Pb dating of the DH8-1 core were conducted with core collected from the distal part of a main sink for the modern Yangtze sediment entering the sea, the Min-Zhe Coastal Mud Deposits(MZCMD) on the inner East China Sea shelf. The 137 Cs dating results show that the core DH8-1 formed during 1946–2012 with a mean deposition rate of 0.65 cm yr^(-1), indicating that the 0.5 cm sampling for grain size analysis in this local area could reflect environmental changes generally on a one-year time scale. The mean grain size of DH8-1 core sediment that deposited after 2003 is significantly larger than that deposited during 1988–2002. After ruling out other possible factors, we infer that the sediment coarsening of DH8-1 core after 2003 is attributed to the TGD operation which causes the erosion of the Yangtze subaqueous delta. Specifically, the TGD operation significantly intensifies the declining trend of the Yangtze sediment loads to the sea despite no decreased water discharge, which results in extensive erosion of the Yangtze subaqueous delta. The relatively coarse sediment of the subaqueous delta is eroded and resuspended by ocean dynamics and then transported by coastal current, finally depositing on the MZCMD area. In addition, the general sediment fining of core DH8-1 that deposited during 1988–2002, comparing with 1946–1987, is mainly caused by dam construction and soil and water conservation within the Yangtze catchment. Our findings are helpful for better understanding the effects of such a huge dam as the TGD on a sediment sink like the MZCMD of such a large river as the Yangtze River.展开更多
In this study, bamboo scaffolding was used to produce activated carbon by carbonization at 600 ℃ and 900 ℃with the purge of nitrogen. The 600 ℃ char was then further modified chemically by acids and alkalis by refl...In this study, bamboo scaffolding was used to produce activated carbon by carbonization at 600 ℃ and 900 ℃with the purge of nitrogen. The 600 ℃ char was then further modified chemically by acids and alkalis by reflux for 6 hours. The produced chars were then characterized by nitrogen adsorption isotherm, He pyncometry, pH, elemental analysis and Boehm titration. For most of the chemically modified carbons, the micropore surface areas and volumes have increased compared with the 600 ~C char, while the mesopore surface areas and volumes slightly decreased, which may have been due to the dissolving of some of the permeated inorganic matter and oxidizing deposited carbon that blocks the pore openings. For the acidic modified carbons, larger amounts of acidic groups were present in the carbons after being activated by phosphoric acid, phosphoric acid furth, er treated with 2 mol-L-1nitric-acid, and calcium hydroxide. Although carbon treated with 2 mol.L-1 and 5 mol·L-1 nitric acid also produced high acidity, the surface areas and pore volumes were relatively low, due to the destruction of pores by nitric acid oxidation. The reduction of porosity may impair the adsorption capacity.展开更多
Coronary stents are metal coils or mesh tubes delivered to blocked vessels through catheters, whic Recently, special drugs h are expanded by balloons to reopen and scaffold target vessels. are carried by stents (drug...Coronary stents are metal coils or mesh tubes delivered to blocked vessels through catheters, whic Recently, special drugs h are expanded by balloons to reopen and scaffold target vessels. are carried by stents (drug-eluting stents) to further reduce instent restenosis rate after stenting procedure. However, continual study on biomechanical characteristics of stents is necessary provide a more suitable drug loading for better interactions between stents and tissue, or to platform for drug-eluting stents. The purpose of this paper is to show how finite element methods can be used to study cell area and strut distribution changes of bent coronary stents. A same bending deformation was applied to two commercial coronary stent models by a rigid curved vessel. Results show that the stent design influenced the changes of cell area and strut distribution under bending situation. The stent with links had more cell area changes at outer curvature, and the stent with peak-peak ( 〉 〈 ) strut design could have strut contact and overlapping at inner curvature. In conclusion, this finite element method can be used to study and compare cell area and strut distribution changes of bent stents, and to provide a convenient tool for designers in testing and improving biomechanical characteristics of new stents.展开更多
Terrestrial organic matter(TOM) is an important component of marine sedimentary OM, and revealing the origins and transport mechanisms of TOM to the East China Sea(ECS) is important for understanding regional carbon c...Terrestrial organic matter(TOM) is an important component of marine sedimentary OM, and revealing the origins and transport mechanisms of TOM to the East China Sea(ECS) is important for understanding regional carbon cycle. A novel approach combining molecular proxies and compound-specific carbon isotopes is used to quantitatively constrain the origins and transport mechanisms of TOM in surface sediments from the ECS shelf. The content of terrestrial biomarkers of(C_(27)+C_(29)+C_(31)) n-alkanes(52 to 580 ng g^(-1)) revealed a seaward decreasing trend, the δ^(13)CTOC values(-20.6‰ to-22.7‰) were more negative near the coast, and the TMBR(terrestrial and marine biomarker ratio) values(0.06 to 0.40) also revealed a seaward decreasing trend. These proxies all indicated more TOM(up to 48%) deposition in the coastal areas. The Alkane Index, the ratio of C_(29)/(C_(29)+C_(31)) n-alkanes indicated a higher proportion of grass vegetation in the coastal area; While the δ13C values of C_(29) n-alkane(-_(29).3‰ to-33.8‰) indicated that terrestrial plant in the sediments of the ECS shelf were mainly derived from C_3 plants. Cluster analysis afforded detailed estimates of different-sourced TOM contributions and transport mechanisms. TOM in the Zhejiang-Fujian coastal area was mostly delivered by the Changjiang River, and characterized by higher %TOM(up to 48%), higher %C_3 plant OM(68%-85%) and higher grass plant OM(56%-61%); TOM in the mid-shelf area was mostly transported by aerosols, and characterized by low %TOM(less than 17%), slightly lower C_3 plant OM(56%-72%) and lower grass plant OM(49%-55%).展开更多
In this paper, the structural parameters, and density of the states of TaB2 compound have been calculated, and investigated in hexagonal phase with P6/mmm space group. The calculations have been performed with ultra-s...In this paper, the structural parameters, and density of the states of TaB2 compound have been calculated, and investigated in hexagonal phase with P6/mmm space group. The calculations have been performed with ultra-soft pseudo-potential in the frame work of Density Functional Theory (DFT) by using the Quantum Espresso package. With respect to high quantity of bulk modulus, and low quantity of the volume it is being understood that this compound has a very hard structure. The figure of density of states shows that this compound is a kind of metal. The obtained results from this research have good accord with experimental results, and with the same researches.展开更多
Evidence from lithology, foraminiferal assemblages, and high-resolution X-ray fluorescence scanning data of core SFK-1 indicates tidally influenced paleo-fluvial sedimentation during the last glacial maximum (LGM) on ...Evidence from lithology, foraminiferal assemblages, and high-resolution X-ray fluorescence scanning data of core SFK-1 indicates tidally influenced paleo-fluvial sedimentation during the last glacial maximum (LGM) on the outer shelf of the East China Sea. The paleo-fluvial deposits consist of river channel facies and estuarine incised-valley-filling facies. Different reflections on the seismic profile across core SFK-1 suggest that the river channels shifted and overlapped. River channel deposition formed early in the LGM when sea level fell and the estuary extended to the outer shelf. Channel sediments are yellowish- brown in color and rich in foraminifera and shell fragments owing to the strong tidal influence. Following the LGM, the paleo-river mouth retreated and regressive deposition of estuarine and incised-valley-filling facies with an erosion base occurred. The river channel facies and estuarine incised-valley-filling facies have clearly different sedimentary characteristics and provenances. The depositional environment of the paleo-river system on the wide shelf was reconstructed from the foraminiferal assemblages, CaCO3 content and Ca/Ti ratio. The main results of this study provide further substantial constraints on the recognition of late Quaternary stratigraphy and land-sea interactions on the ECS shelf.展开更多
The pursuit of high-mileage models results in the recurrence of lithium metal batteries(LMBs)to researchers’horizon.However,the lithium(Li)metal anode for LMBs undergoes the uncontrollable formation of Li dendrites a...The pursuit of high-mileage models results in the recurrence of lithium metal batteries(LMBs)to researchers’horizon.However,the lithium(Li)metal anode for LMBs undergoes the uncontrollable formation of Li dendrites and infinite volume change during cycling,impeding its practical application.To overcome these challenges,we developed a metal-organic framework(MOF)-derived pathway to construct lithiophilic three-dimensional(3D)skeleton using different substrates(e.g.,carbon cloth(CC)and Cu mesh)for dendrite-free lithium metal anodes.As a typical example,the MOF-derived ZnO/nitrogen-doped carbon(NC)nanosheet-modified 3D CC was well-constructed as a lithiophilic hierarchical host(CC@ZnO/NC@Li)for molten Li infiltration.Benefiting from the lithiophilic N-functional groups and LiZn alloy,the synthesized CC@ZnO/NC@Li composite anode promoted the uniform distribution of Li,resulting in a dendrite-free morphology.Meanwhile,the 3D conductive carbon skeleton enhanced the reaction kinetics and buffered the volume change of the electrode.The CC@ZnO/NC@Li composite anode presented a prolonged lifespan of over 1000 cycles at 5 mA cm^(−2) with a low overpotential of 19 mV.Coupled with a LiFePO_(4) cathode,the CC@ZnO/NC@Li composite anode also exhibited superior electrochemical properties in the full-cell system.This versatile strategy may open up the channel of designing multi-functional lithiophilic 3D hosts for the Li metal anode.展开更多
In this paper, similarity symplectic geometry for curves is proposed and studied. Explicit expressions of the symplectic invariants, Frenet frame and Prenet formulae for curves in similarity symplectic geometry are ob...In this paper, similarity symplectic geometry for curves is proposed and studied. Explicit expressions of the symplectic invariants, Frenet frame and Prenet formulae for curves in similarity symplectic geometry are obtained by using the equivariant moving frame method. The relationships between the Euclidean symplectic invariants, Frenet frame, Frenet formulae and the similarity symplectic invariants, Frenet frame, Frenet formulae for curves are established. Invariant curve flows in four-dimensional similarity symplectic geometry are also studied. It is shown that certain intrinsic invariant curve flows in four-dimensional similarity symplectic geometry are related to the integrable Burgers and matrix Burgers equations.展开更多
文摘Abstract: Based on the analysis of core samples from the hole of Zk23 in the East China Sea Continental Shelf and by means of sedimentary stratigraphy, biostratigraphy and chronostratigraphy, the authors consider that the fine-sand deposition in borehole was part of buried ancient estuary sand ridges of the Yangtze River. The deposition history of study area around the hole before and after the glacial period as well as postglacial period is made clear after our research: (1) the estuarine sublayer -undersea delta facies strata was deposited under the fast sea level rise about 15 kaB.P; (2) sand ridges mostly consisting of fine-sand, were formed when the sea level was the fluctuant range of 60 - 80 m of isoba during the deglacial period around 15 - 12 kaB.P; (3) first silty clay and clay silt strata above the sand ridges were deposited during the period when the sea level rose fast from 12 to 7 kaB.P, and then it keeps stable to the present.
基金Project(2016YFB1200404)supported by the National Key Research and Development Program of ChinaProjects(51605044,U1534210)supported by the National Science Foundation of China。
文摘This paper reviews the current status of investigation on snow accumulation on the bogies of high-speed trains(HSTs) running in snowy region. First, the background of the snow issue occurring to the HST and the contra-measures for the snow issue proposed in the past decades are provided by reviewing previous studies. Next, the methodology for investigating the snow issue developed by High-Speed Train Research Center of Central South University is introduced, including the numerical simulation research platform and the experimental devices for two-phase flow wind tunnel tests. Then, effective anti-snow flow control schemes for guiding the underbody airflow and their impact on the motion and accretion of snow in the installation region of the bogies are presented. Finally, the remaining investigating challenge for the snow issue of HST and the future research with respect to the challenge are provided from an engineering application viewpoint.
基金supported by the National Natural Science Foundation of China(21573033)Shandong Provincial Natural Science Foundation,China(ZR2018BB037)+1 种基金Project of Shandong Province Higher Educational Science and Technology Program(J17KA104)Project of Qingdao Applied Basic Research Programs of Science and Technology(18-2-2-10-jch and 18-2-2-35-jch)~~
文摘High-performance and cost-effective catalysts for water splitting are key components of hydrogen-based energy technologies. Metal-organic framework(MOF)-derived metal phosphide composites have immense potential as highly active and stable electrocatalysts but suffer from the poor efficacy of available electrode assembly methods. In this study, an MOF-derived nitrogen-doped porous carbon/Co/Co P/carbon paper(NC/Co/Co P/CP) composite electrode was assembled by electrophoretic deposition and post-processing reactions. The binder-free electrode showed good catalytic activity, significantly higher than that of traditional electrodes. The electrode required overpotentials of 208 and 350 m V to achieve a current density of 10 m A/cm^2 for the hydrogen and oxygen evolution reactions, respectively. This facile synthetic method provides a promising route for designing metal-doped and multi-metal phase MOF-derived composite electrodes for energy storage and conversion devices.
文摘This paper deals with the integrability of a finite-dimensional Hamiltonian system linked with the generalized coupled KdV hierarchy. For this purpose the associated Lax representation is presented after an elementary calculation. It is shown that the Lax representation enjoys a dynamical r-matrix formula instead of a classical one in the Poisson bracket on R2N. Consequently the resulting system is proved to be completely integrable in view of its r-matrix structure.
文摘The determinant role of upwelling in fine sediment patches is examined from the viewpoints of physical process and biological process respectively. It is pointed out that physical and biological processes are usually coexistent and interact with each other during the sedimentation of suspended matters. This study used available figures showing the circulation pattern and surface sediment distribution in the whole China Seas, the Gulf of Maine, the Irish Sea and the North Sea, and additional data to verify that wherever upwelling exists on the continental shelf, mud must occur; and that wherever downwelling occurs, coarse sediment substitutes for mud.
基金Supported by the National Natural Science Foundation of China (Nos. 40176014,40067013)
文摘Correspondence analysis and fuzzy C-means cluster methods were used to divide the stratigraphy of heavy mineral assemblages, and the sediment sources and depositional dynamics of the environment reconstructed. The assemblages were taken from marine sediments from the late Pleistocene to the Holocene in Core Q43 situated on the outer shelf of the East China Sea. Based on the variable boundaries of the mineral assemblage at 63 and 228 cmbsf (cm below sea floor), the core might have previously been divided into three sediment strata marked with units Ⅰ, Ⅱ and Ⅲ, which would be consistent with the divided sediment stratum of the core using minor element geochemistry. The downcore distribution of heavy minerals divided the sedimentary sequence into three major units, which were further subdivided into four subunits. The interval between 0 and 63 cmbsf of the core (unit Ⅰ), which spans the Holocene and the uppermost late Pleistocene, is characterized by a hornblende-epidote-pyroxene assemblage, and contains relatively a smaller amount of schistic mineral and authigenic pyrite. In comparison, the interval between 63 and 228 cmbsf (unit Ⅱ), is representative of the Last Glacial Maximum (LGM), and features a hornblende-epidote-magnetite-ilmenite assemblage containing the highest concentrations of heavy minerals and opaque minerals. However, the interval between 228 and 309 cmbsf (unit Ⅲ), which spans the subinterglacial period, is characterized by a hornblende-authigenic-pyrite-mica assemblage. Relative ratios of some heavy minerals can be used as tracers of clastic sediment sources. The lower part of the sediment core shows the highest magnetite/ilmenite ratio and relatively high hornblende/augite and hornblende/epidote ratios. The middle core shows the highest hornblende/augite and hornblende/epidote ratios, and the lowest magnetite/ilmenite ratio. The upper part exhibits a slightly higher magnetite/ilmenite ratio, and also the lowest hornblende/augite and hornblende/epidote ratios. The distribution of the mineral ratio is consistent with stratigraphic division in heavy mineral data using correspondence analysis and fuzzy C-means clustering. Variations in heavy mineral association and mineral ratio in core Q43 revealed changes in provenance and depositional environment of the southern outer shelf of the East China Sea since the late Pleistocene, well corresponding to interglacial and glacial cycles.
基金supported by the National Basic Research Program of China(2010CB428902)National Natural Science Foundation of China(40876088)
文摘Large areas of muddy sediments on the coastal shelves of China provide important samples for studying climate and ecological changes. Analysis of a large number of such samples, which is essential for systematic study on environmental information recorded in mud areas because of complicated sedimentary environment and variable sedimentary rate, requires a fast and economical method. In this study, we investigated the potential of X-ray fluorescence core scanner (XRFS), a fast analytical instrument for measuring the elemental concentrations of muddy sediments, and observed a significant correlation between the element concentrations of muddy sediments determined by regular X-ray fluorescence spectrometer (XRF) and XRFS, respectively. The correlations are mainly determined by excitation energy of elements, but also influenced by solubility of element ions. Furthermore, we found a striking link between A1 concentrations and marine-originated organic carbon (MOC), a proxy of marine primary productivity. This indicates that MOC is partly controlled by sedimentary characteristics. Therefore, XRFS method has a good potential in fast analysis of a large number of muddy sediment samples, and it can also be used to calibrate MOC in ecological study of coastal seas.
基金Project(2008ZX05004-004)supported by the State Key Scientific Research Programs,ChinaProject(SZD0414)supported by the Sichuan Province Key Discipline Construction Project,ChinaProject(KZCX2-YW-Q05-01)supported by the Chinese Academy of Sciences Innovation Engineering Directional Project
文摘In order to reveal the relationship between the penecontemporaneous karstification and sedimentary microtopography in sequence stratigraphy,the sequence stratigraphic framework of Lianglitage formation in Upper Ordovician is studied according to the well drilling,logging,geophysical data,detailed observations of core and the paleontology.The Lianglitage formation belongs to the sequence Ⅳ of Ordovician.The second member of Lianglitage formation is prograde sedimentation in highstand systems tract,and is favorable for developing reef flat.The development scale and thickness of reef flat are controlled by the variation of secondary sea level.The types and characteristics of karst in the highstand systems tract show that the late highstand systems tract is dissolved and cemented by the meteoric fresh water and mixed water.Penecontemporaneous karstification is developed at the top of parasequence and high place of geomorphology.Atmospheric diagenetic lens is formed.The developing regulations and controlling factors of penecontemporaneous karstification can provide new clues to the prediction and exploration of favorable reservoir in this area.
基金the National Natural Science Foundation of China for its financial support (Nos. 41376052, 41030856, 40906024)
文摘The well-known Three Gorges Dam(TGD) within the Yangtze catchment launched its operation in 2003. The effect of the TGD operation on the sediment size on the East China Sea shelf is rarely known. High resolution(0.5 cm sampling) grain size analysis and 137 Cs and 210 Pb dating of the DH8-1 core were conducted with core collected from the distal part of a main sink for the modern Yangtze sediment entering the sea, the Min-Zhe Coastal Mud Deposits(MZCMD) on the inner East China Sea shelf. The 137 Cs dating results show that the core DH8-1 formed during 1946–2012 with a mean deposition rate of 0.65 cm yr^(-1), indicating that the 0.5 cm sampling for grain size analysis in this local area could reflect environmental changes generally on a one-year time scale. The mean grain size of DH8-1 core sediment that deposited after 2003 is significantly larger than that deposited during 1988–2002. After ruling out other possible factors, we infer that the sediment coarsening of DH8-1 core after 2003 is attributed to the TGD operation which causes the erosion of the Yangtze subaqueous delta. Specifically, the TGD operation significantly intensifies the declining trend of the Yangtze sediment loads to the sea despite no decreased water discharge, which results in extensive erosion of the Yangtze subaqueous delta. The relatively coarse sediment of the subaqueous delta is eroded and resuspended by ocean dynamics and then transported by coastal current, finally depositing on the MZCMD area. In addition, the general sediment fining of core DH8-1 that deposited during 1988–2002, comparing with 1946–1987, is mainly caused by dam construction and soil and water conservation within the Yangtze catchment. Our findings are helpful for better understanding the effects of such a huge dam as the TGD on a sediment sink like the MZCMD of such a large river as the Yangtze River.
基金the support of Hong Kong University of Science and Technology through the Undergraduate Research Opportunity Program
文摘In this study, bamboo scaffolding was used to produce activated carbon by carbonization at 600 ℃ and 900 ℃with the purge of nitrogen. The 600 ℃ char was then further modified chemically by acids and alkalis by reflux for 6 hours. The produced chars were then characterized by nitrogen adsorption isotherm, He pyncometry, pH, elemental analysis and Boehm titration. For most of the chemically modified carbons, the micropore surface areas and volumes have increased compared with the 600 ~C char, while the mesopore surface areas and volumes slightly decreased, which may have been due to the dissolving of some of the permeated inorganic matter and oxidizing deposited carbon that blocks the pore openings. For the acidic modified carbons, larger amounts of acidic groups were present in the carbons after being activated by phosphoric acid, phosphoric acid furth, er treated with 2 mol-L-1nitric-acid, and calcium hydroxide. Although carbon treated with 2 mol.L-1 and 5 mol·L-1 nitric acid also produced high acidity, the surface areas and pore volumes were relatively low, due to the destruction of pores by nitric acid oxidation. The reduction of porosity may impair the adsorption capacity.
文摘Coronary stents are metal coils or mesh tubes delivered to blocked vessels through catheters, whic Recently, special drugs h are expanded by balloons to reopen and scaffold target vessels. are carried by stents (drug-eluting stents) to further reduce instent restenosis rate after stenting procedure. However, continual study on biomechanical characteristics of stents is necessary provide a more suitable drug loading for better interactions between stents and tissue, or to platform for drug-eluting stents. The purpose of this paper is to show how finite element methods can be used to study cell area and strut distribution changes of bent coronary stents. A same bending deformation was applied to two commercial coronary stent models by a rigid curved vessel. Results show that the stent design influenced the changes of cell area and strut distribution under bending situation. The stent with links had more cell area changes at outer curvature, and the stent with peak-peak ( 〉 〈 ) strut design could have strut contact and overlapping at inner curvature. In conclusion, this finite element method can be used to study and compare cell area and strut distribution changes of bent stents, and to provide a convenient tool for designers in testing and improving biomechanical characteristics of new stents.
基金the Key Laboratory of Marine Hydrocarbon Resources and Environmental Geology, Ministry of Land and Resources (No. MRE201301)the National Natural Science Foundation of China (No. 41506087)the ‘111’ Project (No. B13030)
文摘Terrestrial organic matter(TOM) is an important component of marine sedimentary OM, and revealing the origins and transport mechanisms of TOM to the East China Sea(ECS) is important for understanding regional carbon cycle. A novel approach combining molecular proxies and compound-specific carbon isotopes is used to quantitatively constrain the origins and transport mechanisms of TOM in surface sediments from the ECS shelf. The content of terrestrial biomarkers of(C_(27)+C_(29)+C_(31)) n-alkanes(52 to 580 ng g^(-1)) revealed a seaward decreasing trend, the δ^(13)CTOC values(-20.6‰ to-22.7‰) were more negative near the coast, and the TMBR(terrestrial and marine biomarker ratio) values(0.06 to 0.40) also revealed a seaward decreasing trend. These proxies all indicated more TOM(up to 48%) deposition in the coastal areas. The Alkane Index, the ratio of C_(29)/(C_(29)+C_(31)) n-alkanes indicated a higher proportion of grass vegetation in the coastal area; While the δ13C values of C_(29) n-alkane(-_(29).3‰ to-33.8‰) indicated that terrestrial plant in the sediments of the ECS shelf were mainly derived from C_3 plants. Cluster analysis afforded detailed estimates of different-sourced TOM contributions and transport mechanisms. TOM in the Zhejiang-Fujian coastal area was mostly delivered by the Changjiang River, and characterized by higher %TOM(up to 48%), higher %C_3 plant OM(68%-85%) and higher grass plant OM(56%-61%); TOM in the mid-shelf area was mostly transported by aerosols, and characterized by low %TOM(less than 17%), slightly lower C_3 plant OM(56%-72%) and lower grass plant OM(49%-55%).
文摘In this paper, the structural parameters, and density of the states of TaB2 compound have been calculated, and investigated in hexagonal phase with P6/mmm space group. The calculations have been performed with ultra-soft pseudo-potential in the frame work of Density Functional Theory (DFT) by using the Quantum Espresso package. With respect to high quantity of bulk modulus, and low quantity of the volume it is being understood that this compound has a very hard structure. The figure of density of states shows that this compound is a kind of metal. The obtained results from this research have good accord with experimental results, and with the same researches.
基金Supported by the National Natural Science Foundation of China (Nos.41040041,41206053,41225020,and 41076018) the Continental Shelf Drilling Program (No.GZH201100202)the China Geological Survey(Nos.1212010611301 and GZH200800501)
文摘Evidence from lithology, foraminiferal assemblages, and high-resolution X-ray fluorescence scanning data of core SFK-1 indicates tidally influenced paleo-fluvial sedimentation during the last glacial maximum (LGM) on the outer shelf of the East China Sea. The paleo-fluvial deposits consist of river channel facies and estuarine incised-valley-filling facies. Different reflections on the seismic profile across core SFK-1 suggest that the river channels shifted and overlapped. River channel deposition formed early in the LGM when sea level fell and the estuary extended to the outer shelf. Channel sediments are yellowish- brown in color and rich in foraminifera and shell fragments owing to the strong tidal influence. Following the LGM, the paleo-river mouth retreated and regressive deposition of estuarine and incised-valley-filling facies with an erosion base occurred. The river channel facies and estuarine incised-valley-filling facies have clearly different sedimentary characteristics and provenances. The depositional environment of the paleo-river system on the wide shelf was reconstructed from the foraminiferal assemblages, CaCO3 content and Ca/Ti ratio. The main results of this study provide further substantial constraints on the recognition of late Quaternary stratigraphy and land-sea interactions on the ECS shelf.
基金supported by the National Natural Science Foundation of China(51771076 and 51621001)Guangdong"Pearl River Talents Plan"(2017GC010218)+1 种基金the R&D Program in Key Areas of Guangdong Province(2020B0101030005)Guangdong Basic and Applied Basic Research Foundation(2020B1515120049)。
文摘The pursuit of high-mileage models results in the recurrence of lithium metal batteries(LMBs)to researchers’horizon.However,the lithium(Li)metal anode for LMBs undergoes the uncontrollable formation of Li dendrites and infinite volume change during cycling,impeding its practical application.To overcome these challenges,we developed a metal-organic framework(MOF)-derived pathway to construct lithiophilic three-dimensional(3D)skeleton using different substrates(e.g.,carbon cloth(CC)and Cu mesh)for dendrite-free lithium metal anodes.As a typical example,the MOF-derived ZnO/nitrogen-doped carbon(NC)nanosheet-modified 3D CC was well-constructed as a lithiophilic hierarchical host(CC@ZnO/NC@Li)for molten Li infiltration.Benefiting from the lithiophilic N-functional groups and LiZn alloy,the synthesized CC@ZnO/NC@Li composite anode promoted the uniform distribution of Li,resulting in a dendrite-free morphology.Meanwhile,the 3D conductive carbon skeleton enhanced the reaction kinetics and buffered the volume change of the electrode.The CC@ZnO/NC@Li composite anode presented a prolonged lifespan of over 1000 cycles at 5 mA cm^(−2) with a low overpotential of 19 mV.Coupled with a LiFePO_(4) cathode,the CC@ZnO/NC@Li composite anode also exhibited superior electrochemical properties in the full-cell system.This versatile strategy may open up the channel of designing multi-functional lithiophilic 3D hosts for the Li metal anode.
基金supported by National Natural Science Foundation of China(Grant Nos.11471174 and 11101332)Natural Science Foundation of Shaanxi Province(Grant No.2014JM-1002)the Natural Science Foundation of Xianyang Normal University of Shaanxi Province(Grant No.14XSYK004)
文摘In this paper, similarity symplectic geometry for curves is proposed and studied. Explicit expressions of the symplectic invariants, Frenet frame and Prenet formulae for curves in similarity symplectic geometry are obtained by using the equivariant moving frame method. The relationships between the Euclidean symplectic invariants, Frenet frame, Frenet formulae and the similarity symplectic invariants, Frenet frame, Frenet formulae for curves are established. Invariant curve flows in four-dimensional similarity symplectic geometry are also studied. It is shown that certain intrinsic invariant curve flows in four-dimensional similarity symplectic geometry are related to the integrable Burgers and matrix Burgers equations.