TiO2 fibers were prepared via alternatively introducing water vapor and Ti precursor carried by N2 to an APCVD (chemical vapor deposition under atmospheric pressure) reactor at ≤200 ℃. Activated carbon fibers (A...TiO2 fibers were prepared via alternatively introducing water vapor and Ti precursor carried by N2 to an APCVD (chemical vapor deposition under atmospheric pressure) reactor at ≤200 ℃. Activated carbon fibers (ACFs) were used as templates for deposition and later removed by calcinations. The obtained catalysts were characterized by scanning electron micros- copy (SEM), transmission electron microscopy (TEM), Brunauer, Emmett and Teller (BET) and X-ray diffraction (XRD) analysis The pores within TiO2 fibers included micro-range and meso-range, e.g., 7 nm, and the specific surface areas for TiO2 fibers were 141 m^2/g and 148 m^2/g for samples deposited at 100 ℃ and 200℃ (using ACFI700 as template), respectively. The deposition temperature significantly influenced TiO2 morphology. The special advantages of this technique for preparing porous nano-material include no consumption of organic solvent in the process and easy control of deposition conditions and speeds.展开更多
The authors give the solution to the problem of one-dimensional conso l idation of double-layered ground with the use of the differential quadrature me t hod. Case studies showed that the computational results for por...The authors give the solution to the problem of one-dimensional conso l idation of double-layered ground with the use of the differential quadrature me t hod. Case studies showed that the computational results for pore-water pressure in soil layer agreed with those of analytical solution; and that in the computat ional results for the interface of soil layer also agreed with those of the anal ytical solution except for the small discrepancies during shortly after the star t of computation. The advantages of the solution presented in this paper are tha t compared with the analytical solution, it avoids the cumbersome work in solvin g the transcendental equation for eigenvalues, and in the case of the Laplace transform s olution, it can resolve the precision problem in the numerical solution of long time inverse Laplace transform. Because of the matrix form of the solution in th is paper, it is convenient for formulating computational program for engineering practice. The formulas for calculating double-layered ground consolidation may be easily extended to the case of multi-layered soils.展开更多
In order to improve the understanding of the fundamental mechanism of rainfall infiltration induced landslides in accumulation slope and to clarify some important characteristics of slope performance,artificial rainfa...In order to improve the understanding of the fundamental mechanism of rainfall infiltration induced landslides in accumulation slope and to clarify some important characteristics of slope performance,artificial rainfall simulation tests and field synthetic monitoring were carried out on a typical accumulation slope of Shangrui Freeway in Guizhou Province,China.The monitoring results show that the most accumulation landslides caused by rainfall infiltration are shallow relaxation failure,whose deformation zone lies within the top 0-4 m soil layer.The deformation of slope gradually reduces from the surface,where the greatest deformation lies in,to the deep part of slope.The average percentage of infiltration during the first 2 h is 86%,and then it reduces gradually with time because of the increase of the surface runoff.The average percentage of infiltration drop to a relatively stable value(50%)after 6 h.Rainfall infiltration causes obvious increase of pore-water pressure,which may result in a reduction of shear strength due to a decrease in effective stress and wetting-induced softening.The double-effect of rainfall infiltration is the main reason of rainfall infiltration induced landslides in accumulation slope.展开更多
The sedimentary facies of the subaqueous Changjiang (Yangtze) River delta since the late Pleistocene was studied based on lithology and foraminifera analysis for two boreholes, CJK07 and CJK11, along with 14C dating...The sedimentary facies of the subaqueous Changjiang (Yangtze) River delta since the late Pleistocene was studied based on lithology and foraminifera analysis for two boreholes, CJK07 and CJK11, along with 14C dating. Four sedimentary facies were identified, namely fluvial, tidal flat, offshore, and prodelta facies. The fluvial sedimentary facies is comprised of fluvial channel lag deposits, fluvial point bar deposits, and floodplain deposits, showing a fining-upward sequence in general with no benthic foraminifera. A layer of stiff clay overlies the fluvial deposits in core CJK07, indicating a long-term exposure environment during the Last Glacial Maximum (LGM). During the postglacial sea-level rise around 13-7.5 cal ka BP, the tidal flat facies was deposited in core CJK11, characterized by abundant silt-clay couplets. Euryhaline species dominate the subtidal fiat foraminiferal assemblages, while almost no foraminifera was found in the intertidal fiat. The offshore environment was the major sedimentary environment when the sea level reached its highest level around 7.5 cal ka BP, with a maximum accumulation rate of 10 mm/a found in core CJK11. Prodelta sediments have been deposited in core CJK11 since -3 cal ka BP, after the formation of the Changjiang River delta. The difference in sedimentary facies between core CJK07 and CJK11 is due to their location: core CJK07 was in an interfluve while core CJK11 was in an incised valley during the LGM. Furthermore, AMS 14C dating of core CJK07 shows poor chronological order, indicating that the sediments were reworked by strong tidal currents and that sediment deposited since -7.7 cal ka BP in core CJK07 was eroded away by modem hydrodynamic forces caused by the southward shift of the Changjiang River delta depocenter.展开更多
Although information regarding the initiation processes of debris flows is important for the development of mitigation measures,field data regarding these processes are scarce.We conducted field observations of debris...Although information regarding the initiation processes of debris flows is important for the development of mitigation measures,field data regarding these processes are scarce.We conducted field observations of debris-flow initiation processes in the upper Ichinosawa catchment of the Ohya landslide,central Japan.On 19 June 2012,our videocamera monitoring systems recorded the moment of debris-flow initiation on channel deposits(nine surges) and talus slopes(eight surges).The initiation mechanisms of these surges were classified into three types by analyzing the video images: erosion by the surface flow,movement of deposits as a mass,and upward development of the fluid area.The first type was associated with the progress of surface flow from the upper stream on unsaturated channel deposits.The second type was likely caused by an increase in the pore water pressure associated with the rising in the groundwater level in channel deposits;a continuous water supply from the upper stream by the surface flow might have induced this saturation.The third type was associated with changes in the downstream topography caused by erosion.The flow velocity of most surges was less than 3 m s^(-1) and they usually stopped within 100 m from the initiation point.Surges with abundant pore fluid had a higher flow velocity(about 3- 5 m s^(-1)) and could travel for alonger duration.Our observations indicate that the surface flow plays an important role in the initiation of debris flows on channel deposits and talus slopes.展开更多
Mesoporous CeO2 was first synthesized by hydrothermal method,and then used to synthesize different contents of CuO)x/CeO2(x:molar ratio of Cu to Ce) by deposition-precipitation method.These materials were characterize...Mesoporous CeO2 was first synthesized by hydrothermal method,and then used to synthesize different contents of CuO)x/CeO2(x:molar ratio of Cu to Ce) by deposition-precipitation method.These materials were characterized by X-ray diffraction(XRD),N2 adsorption and desorption,H2 temperature programmed reduction(H2-TPR) and O2 temperature programmed desorption(O2-TPD) to study the crystal structure,surface area,and the mechanism of CO oxidation.The results show that,on XRD patterns,no evidence of CuO diffraction peaks is present until Cu loading is increased to 20%.The BET surface area decreases noticeably with the increase of Cu content.Compared with other samples,the better reducibility and activity oxygen species of(CuO)10%/CeO2coincide with its better catalytic activity.展开更多
LIMAS and Tio1 proposed the term meningeal melanocytoma first time in 1972 to describe a primary melanotic tumor of the leptomeninges with prolonged clinical course and benign histology.Meningeal melanocytoma of the c...LIMAS and Tio1 proposed the term meningeal melanocytoma first time in 1972 to describe a primary melanotic tumor of the leptomeninges with prolonged clinical course and benign histology.Meningeal melanocytoma of the central nervous system is rare and benign primary meningeal melanocytoma (PMM) is more exceptional,and also less usual than the malignant types.2 This rare tumor falls under the subclassification of primary melanocytic lesions in the World Health Organization's classification of central nervous system tumors.3 PMM located in the foramen magnum region is an unusual cause of bulbus medullae and fourth ventricle compression.Here we report a 48-year-old man with a PMM which is located in the foramen magnum inducing supratentorial obstructive hydrocephalus.展开更多
Carbon powders have the ability to remove cholesterol from solution by adsorption. Various combinations from among 12 different types of carbon powders (including two medical carbons), having a wide range of surface...Carbon powders have the ability to remove cholesterol from solution by adsorption. Various combinations from among 12 different types of carbon powders (including two medical carbons), having a wide range of surface area and porosity, were used to perform cholesterol adsorption experiments. The cholesterol concentration in a cyclohexane solvent (37 ~C, shaking 200 rpm) was detected at 215 nm using ultraviolet spectroscopy. Most adsorption occurred in the first 30 to 60 minutes. A Langmuir model was used to fit the amount of cholesterol adsorbed per gram of carbon. The medical carbon, Natural Elements Activated Charcoal, adsorbed 234 mg of cholesterol adsorption per gram of carbon. The experimental percentages of cholesterol removed from solution (maximum 98%) were correlated with nitrogen Branauer-Emmett-Teller (BET) surface areas and micro, meso, and macropore volume distributions. Surface area alone was not a suitable predictor of cholesterol adsorption. However, carbon powders exhibiting a large surface area along with significant meso and macropores were shown to be effective in adsorbing cholesterol from a nonpolar environment. Ingestion of a medically approved carbon powder with a large surface area and sufficient meso and macroporosity may be able to adsorb cholesterol in the intestinal tract and thereby lower cholesterol levels in the body.展开更多
The change of the confined aquifer level reflects the pore pressure change,and the pore pressure change of the aquifer is closely related to the aquifer pressure. This paper uses the tidal response of the well water l...The change of the confined aquifer level reflects the pore pressure change,and the pore pressure change of the aquifer is closely related to the aquifer pressure. This paper uses the tidal response of the well water level data in the North China region to calculate the tidal factor of each well and extract the effective water trend information. Then,the volumetric strain of an existing confined aquifer well in the North China region is inverted,and the contour maps are plotted on a half-year scale from 2009 to 2012. Results show that it can reflect the state of stress and strain in deep crust to a certain extent in the North China region.展开更多
Shenhu Area is one of the most promising areas for gas hydrate exploration in the northern South China Sea (SCS). Pore water sulfate gradient, sulfate-methane interface (SMI) depth, and sulfate flux were analyzed ...Shenhu Area is one of the most promising areas for gas hydrate exploration in the northern South China Sea (SCS). Pore water sulfate gradient, sulfate-methane interface (SMI) depth, and sulfate flux were analyzed at 53 sites in this area. SO42- gradient ranges between 0.33 and 4.43 mmol L-L m-1. SMI depths are from 7.7 to 87.9 mbsf. Sulfate flux varies between 2.0 and 26.9 mmol m-2 yr L, with a mean of 11.7 mmol m-2 yr1. Correlation coefficient between SMI depth and methane flux for the 53 sites is -0.80, implying that methane flux regulates the rate of anaerobic methane oxidation (AMO), SMI depth, and sulfate flux. Twelve anomalous fields with high methane flux and steep sulfate gradients were recognized. Bottom simulating reflector (BSR) is distributed mainly in areas where SMI depth is less than 50 mbsf or places with sulfate flux larger than 3.5 mmol m-2 yr-1. It is suggested that the Baiyun Sag and the Southern Uplift are potential areas for gas hydrate exploration.展开更多
基金Project (No. 20477006) supported by the National Natural ScienceFoundation of China
文摘TiO2 fibers were prepared via alternatively introducing water vapor and Ti precursor carried by N2 to an APCVD (chemical vapor deposition under atmospheric pressure) reactor at ≤200 ℃. Activated carbon fibers (ACFs) were used as templates for deposition and later removed by calcinations. The obtained catalysts were characterized by scanning electron micros- copy (SEM), transmission electron microscopy (TEM), Brunauer, Emmett and Teller (BET) and X-ray diffraction (XRD) analysis The pores within TiO2 fibers included micro-range and meso-range, e.g., 7 nm, and the specific surface areas for TiO2 fibers were 141 m^2/g and 148 m^2/g for samples deposited at 100 ℃ and 200℃ (using ACFI700 as template), respectively. The deposition temperature significantly influenced TiO2 morphology. The special advantages of this technique for preparing porous nano-material include no consumption of organic solvent in the process and easy control of deposition conditions and speeds.
文摘The authors give the solution to the problem of one-dimensional conso l idation of double-layered ground with the use of the differential quadrature me t hod. Case studies showed that the computational results for pore-water pressure in soil layer agreed with those of analytical solution; and that in the computat ional results for the interface of soil layer also agreed with those of the anal ytical solution except for the small discrepancies during shortly after the star t of computation. The advantages of the solution presented in this paper are tha t compared with the analytical solution, it avoids the cumbersome work in solvin g the transcendental equation for eigenvalues, and in the case of the Laplace transform s olution, it can resolve the precision problem in the numerical solution of long time inverse Laplace transform. Because of the matrix form of the solution in th is paper, it is convenient for formulating computational program for engineering practice. The formulas for calculating double-layered ground consolidation may be easily extended to the case of multi-layered soils.
基金Project(50678175)supported by the National Natural Science Foundation of China
文摘In order to improve the understanding of the fundamental mechanism of rainfall infiltration induced landslides in accumulation slope and to clarify some important characteristics of slope performance,artificial rainfall simulation tests and field synthetic monitoring were carried out on a typical accumulation slope of Shangrui Freeway in Guizhou Province,China.The monitoring results show that the most accumulation landslides caused by rainfall infiltration are shallow relaxation failure,whose deformation zone lies within the top 0-4 m soil layer.The deformation of slope gradually reduces from the surface,where the greatest deformation lies in,to the deep part of slope.The average percentage of infiltration during the first 2 h is 86%,and then it reduces gradually with time because of the increase of the surface runoff.The average percentage of infiltration drop to a relatively stable value(50%)after 6 h.Rainfall infiltration causes obvious increase of pore-water pressure,which may result in a reduction of shear strength due to a decrease in effective stress and wetting-induced softening.The double-effect of rainfall infiltration is the main reason of rainfall infiltration induced landslides in accumulation slope.
基金Supported by the Marine Public Welfare Research Project(No.200805063)the National Natural Science Foundation of China(Nos.41076023 and 41106065)+1 种基金the Basic Fund Project of National Science and Technology Ministry(No.2008FY220300)the Coastal Investigation and Research Project of China(No.908-02-02-05)
文摘The sedimentary facies of the subaqueous Changjiang (Yangtze) River delta since the late Pleistocene was studied based on lithology and foraminifera analysis for two boreholes, CJK07 and CJK11, along with 14C dating. Four sedimentary facies were identified, namely fluvial, tidal flat, offshore, and prodelta facies. The fluvial sedimentary facies is comprised of fluvial channel lag deposits, fluvial point bar deposits, and floodplain deposits, showing a fining-upward sequence in general with no benthic foraminifera. A layer of stiff clay overlies the fluvial deposits in core CJK07, indicating a long-term exposure environment during the Last Glacial Maximum (LGM). During the postglacial sea-level rise around 13-7.5 cal ka BP, the tidal flat facies was deposited in core CJK11, characterized by abundant silt-clay couplets. Euryhaline species dominate the subtidal fiat foraminiferal assemblages, while almost no foraminifera was found in the intertidal fiat. The offshore environment was the major sedimentary environment when the sea level reached its highest level around 7.5 cal ka BP, with a maximum accumulation rate of 10 mm/a found in core CJK11. Prodelta sediments have been deposited in core CJK11 since -3 cal ka BP, after the formation of the Changjiang River delta. The difference in sedimentary facies between core CJK07 and CJK11 is due to their location: core CJK07 was in an interfluve while core CJK11 was in an incised valley during the LGM. Furthermore, AMS 14C dating of core CJK07 shows poor chronological order, indicating that the sediments were reworked by strong tidal currents and that sediment deposited since -7.7 cal ka BP in core CJK07 was eroded away by modem hydrodynamic forces caused by the southward shift of the Changjiang River delta depocenter.
基金supported by the Grant-in-Aid for Scientific Research of Japan Society for the Promotion of Science (JSPS KAKENHI) (Grant Nos.80378918,26292077)
文摘Although information regarding the initiation processes of debris flows is important for the development of mitigation measures,field data regarding these processes are scarce.We conducted field observations of debris-flow initiation processes in the upper Ichinosawa catchment of the Ohya landslide,central Japan.On 19 June 2012,our videocamera monitoring systems recorded the moment of debris-flow initiation on channel deposits(nine surges) and talus slopes(eight surges).The initiation mechanisms of these surges were classified into three types by analyzing the video images: erosion by the surface flow,movement of deposits as a mass,and upward development of the fluid area.The first type was associated with the progress of surface flow from the upper stream on unsaturated channel deposits.The second type was likely caused by an increase in the pore water pressure associated with the rising in the groundwater level in channel deposits;a continuous water supply from the upper stream by the surface flow might have induced this saturation.The third type was associated with changes in the downstream topography caused by erosion.The flow velocity of most surges was less than 3 m s^(-1) and they usually stopped within 100 m from the initiation point.Surges with abundant pore fluid had a higher flow velocity(about 3- 5 m s^(-1)) and could travel for alonger duration.Our observations indicate that the surface flow plays an important role in the initiation of debris flows on channel deposits and talus slopes.
基金Project(2011FZ030)supported by the Natural Science Foundation of Yunnan Province,ChinaProjects(2011144,2011221)supported by Analysis and Test Foundation of Kunming University of Science and Technology,China
文摘Mesoporous CeO2 was first synthesized by hydrothermal method,and then used to synthesize different contents of CuO)x/CeO2(x:molar ratio of Cu to Ce) by deposition-precipitation method.These materials were characterized by X-ray diffraction(XRD),N2 adsorption and desorption,H2 temperature programmed reduction(H2-TPR) and O2 temperature programmed desorption(O2-TPD) to study the crystal structure,surface area,and the mechanism of CO oxidation.The results show that,on XRD patterns,no evidence of CuO diffraction peaks is present until Cu loading is increased to 20%.The BET surface area decreases noticeably with the increase of Cu content.Compared with other samples,the better reducibility and activity oxygen species of(CuO)10%/CeO2coincide with its better catalytic activity.
文摘LIMAS and Tio1 proposed the term meningeal melanocytoma first time in 1972 to describe a primary melanotic tumor of the leptomeninges with prolonged clinical course and benign histology.Meningeal melanocytoma of the central nervous system is rare and benign primary meningeal melanocytoma (PMM) is more exceptional,and also less usual than the malignant types.2 This rare tumor falls under the subclassification of primary melanocytic lesions in the World Health Organization's classification of central nervous system tumors.3 PMM located in the foramen magnum region is an unusual cause of bulbus medullae and fourth ventricle compression.Here we report a 48-year-old man with a PMM which is located in the foramen magnum inducing supratentorial obstructive hydrocephalus.
文摘Carbon powders have the ability to remove cholesterol from solution by adsorption. Various combinations from among 12 different types of carbon powders (including two medical carbons), having a wide range of surface area and porosity, were used to perform cholesterol adsorption experiments. The cholesterol concentration in a cyclohexane solvent (37 ~C, shaking 200 rpm) was detected at 215 nm using ultraviolet spectroscopy. Most adsorption occurred in the first 30 to 60 minutes. A Langmuir model was used to fit the amount of cholesterol adsorbed per gram of carbon. The medical carbon, Natural Elements Activated Charcoal, adsorbed 234 mg of cholesterol adsorption per gram of carbon. The experimental percentages of cholesterol removed from solution (maximum 98%) were correlated with nitrogen Branauer-Emmett-Teller (BET) surface areas and micro, meso, and macropore volume distributions. Surface area alone was not a suitable predictor of cholesterol adsorption. However, carbon powders exhibiting a large surface area along with significant meso and macropores were shown to be effective in adsorbing cholesterol from a nonpolar environment. Ingestion of a medically approved carbon powder with a large surface area and sufficient meso and macroporosity may be able to adsorb cholesterol in the intestinal tract and thereby lower cholesterol levels in the body.
基金funded by the 2013 Contract Orientation Tasks of Earthquake Tracing(2013020307)the 2014 Contract Orientation Task of Earthquake Tracing(2014020207)the Spark Program of Earthquake Science and Technology of CEA in 2014(XH14005Y)
文摘The change of the confined aquifer level reflects the pore pressure change,and the pore pressure change of the aquifer is closely related to the aquifer pressure. This paper uses the tidal response of the well water level data in the North China region to calculate the tidal factor of each well and extract the effective water trend information. Then,the volumetric strain of an existing confined aquifer well in the North China region is inverted,and the contour maps are plotted on a half-year scale from 2009 to 2012. Results show that it can reflect the state of stress and strain in deep crust to a certain extent in the North China region.
基金supported by the National Basic Research Program of China (Grant Nos. 2009CB219508 and 2009CB219502)Research Program for Non-profit Industries of the Ministry of Land and Resources of the People’s Republic of China (Grant No. 200811014)
文摘Shenhu Area is one of the most promising areas for gas hydrate exploration in the northern South China Sea (SCS). Pore water sulfate gradient, sulfate-methane interface (SMI) depth, and sulfate flux were analyzed at 53 sites in this area. SO42- gradient ranges between 0.33 and 4.43 mmol L-L m-1. SMI depths are from 7.7 to 87.9 mbsf. Sulfate flux varies between 2.0 and 26.9 mmol m-2 yr L, with a mean of 11.7 mmol m-2 yr1. Correlation coefficient between SMI depth and methane flux for the 53 sites is -0.80, implying that methane flux regulates the rate of anaerobic methane oxidation (AMO), SMI depth, and sulfate flux. Twelve anomalous fields with high methane flux and steep sulfate gradients were recognized. Bottom simulating reflector (BSR) is distributed mainly in areas where SMI depth is less than 50 mbsf or places with sulfate flux larger than 3.5 mmol m-2 yr-1. It is suggested that the Baiyun Sag and the Southern Uplift are potential areas for gas hydrate exploration.