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高核稀土-氧簇的合成策略及模块组装
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作者 郑秀英 孔祥建 +1 位作者 龙腊生 郑兰荪 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 2020年第5期837-849,共13页
稀土-氧簇是一类由多个稀土离子通过氧桥连接形成的多核稀土配合物.基于多金属间的协同作用,稀土-氧簇具有独特的光、电、磁和催化性质.由于具有漂亮的分子结构和多领域的潜在应用,高核稀土-氧簇受到研究者的广泛关注.本文概述了高核稀... 稀土-氧簇是一类由多个稀土离子通过氧桥连接形成的多核稀土配合物.基于多金属间的协同作用,稀土-氧簇具有独特的光、电、磁和催化性质.由于具有漂亮的分子结构和多领域的潜在应用,高核稀土-氧簇受到研究者的广泛关注.本文概述了高核稀土-氧簇的有效合成策略,即配体控制稀土水解法和阴离子模板法,总结了高核稀土-氧簇的模块组装规律,并展望高核稀土-氧簇的未来研究方向. 展开更多
关键词 高核稀土-氧簇 合成策略 稀土水解 阴离子模板 模块组装规律
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Hydrolysis Activities of the Particle of Agarose-Ce^(4+) Complex for Compounds Containing Phosphodiester or Peptide Bonds 被引量:2
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作者 YU Lina WANG Dongfeng SU Lin LUO Yi SUN Liping XUEChanghu 《Journal of Ocean University of China》 SCIE CAS 2005年第3期272-275,共4页
Hydrolysis activities of PACC (particle of agarose-Ce4+ complex, newly made through double emulsification) forcompounds containing phosphodiester or peptide bonds were studied. The results showed that PACC could hydro... Hydrolysis activities of PACC (particle of agarose-Ce4+ complex, newly made through double emulsification) forcompounds containing phosphodiester or peptide bonds were studied. The results showed that PACC could hydrolyzeorganophosphorous pesticides not only in water but also in vegetable juice or tea extract. Hydrolysis rates of methamidophos,omethoate and chlorpyrifos in water are 32.39%, 27.12% and 46.62% respectively, those of chlorpyrifos and methami-dophos in mung sprout juice 38.28% and 35.45% respectively, and that of chlorpyrifos in tea extract 59.76%. Hydrolysisrates of BSA (bovine serum albumin) in water and protein in tea extract by PACC increase by 54.30% and 86.46% respec-tively as compared with the control. 展开更多
关键词 particle of agarose-Ce^4+ complex hydrolyzation organophosphorous pesticide protein
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