Group testing is a method that can be used to estimate the prevalence of rare infectious diseases,which can effectively save time and reduce costs compared to the method of random sampling.However,previous literature ...Group testing is a method that can be used to estimate the prevalence of rare infectious diseases,which can effectively save time and reduce costs compared to the method of random sampling.However,previous literature only demonstrated the optimality of group testing strategy while estimating prevalence under some strong assumptions.This article weakens the assumption of misclassification rate in the previous literature,considers the misclassification rate of the infected samples as a differentiable function of the pool size,and explores some optimal properties of group testing for estimating prevalence in the presence of differential misclassification conforming to this assumption.This article theoretically demonstrates that the group testing strategy performs better than the sample by sample procedure in estimating disease prevalence when the total number of sample pools is given or the size of the test population is determined.Numerical simulation experiments were conducted to evaluate the performance of group tests in estimating prevalence in the presence of dilution effect.展开更多
Aiming at the problems of bispectral analysis when applied to machinery fault diagnosis, a machinery fault feature extraction method based on sparseness-controlled non-negative tensor factorization (SNTF) is propose...Aiming at the problems of bispectral analysis when applied to machinery fault diagnosis, a machinery fault feature extraction method based on sparseness-controlled non-negative tensor factorization (SNTF) is proposed. First, a non-negative tensor factorization(NTF) algorithm is improved by imposing sparseness constraints on it. Secondly, the bispectral images of mechanical signals are obtained and stacked to form a third-order tensor. Thirdly, the improved algorithm is used to extract features, which are represented by a series of basis images from this tensor. Finally, coefficients indicating these basis images' weights in constituting original bispectral images are calculated for fault classification. Experiments on fault diagnosis of gearboxes show that the extracted features can not only reveal some nonlinear characteristics of the system, but also have intuitive meanings with regard to fault characteristic frequencies. These features provide great convenience for the interpretation of the relationships between machinery faults and corresponding bispectra.展开更多
A scheme to design a simultaneous multichannel receiver is proposed to process multichannel signals in parallel, which is achieved by exploiting the attractive characteristics of a fast filter bank( FFB), such as ca...A scheme to design a simultaneous multichannel receiver is proposed to process multichannel signals in parallel, which is achieved by exploiting the attractive characteristics of a fast filter bank( FFB), such as cascaded structure, high frequency selectivity and lowcomputational complexity. Based on the minimization of the objective function, quantified in terms of the total number of multiplications required, subject to prescribed allowable ripples in the passband and stopband, the impulse response coefficients of the prototype filter in each stage are obtained to meet the requirements of the overall specifications for each channel at the receiver side. Simulations and experimental results on the frequency modulation( FM) broadcast mutlichannel signal receiving system with the FM range from88 to 108 MHz, built upon the proposed FFB structure, are performed to verify its performance. Those results indicate that the proposed scheme is efficient in FM audio indexing applications and has a lower computational complexity, which is approximately 66. 4% of the weighted overlap and add( WOLA) filter banks based solution.展开更多
The microstructure of WE93 alloy in different states and the mechanical properties at room temperature were investigated, and the creep behavior of the extruded and aged alloy at 200 ℃and at stress of 100, 125 and 15...The microstructure of WE93 alloy in different states and the mechanical properties at room temperature were investigated, and the creep behavior of the extruded and aged alloy at 200 ℃and at stress of 100, 125 and 150 MPa was also discussed. The result shows that the microstructure of as-cast WE93 alloy consists of α-Mg, Mg 12 (MM) and Mg 24 Y 5 with an average grain size of 45 μm. After being homogenized at 535 ℃for 18 h, the Mg 24 Y 5 phase is dissolved completely and there is only Mg 12 (MM) phase left around the grain boundaries. The grains do not grow up as prolonging the homogenization time. The extruded alloy has better mechanical properties than the as-cast alloy, especially the elongation increases to 12.5%. The extruded and aged alloy exhibits the highest yield strength and ultimate tensile strength of 315 and 385 MPa, respectively, however, the elongation decreases to 6.5%. The extruded and aged alloy exhibits good creep resistance at 200 ℃and at stress of 100 150 MPa. The creep stress exponent n is 2.97, suggesting that grain boundary sliding plays a dominant role at the corresponding temperature and applied stresses.展开更多
Effects of Cr3C2,VC and La2O3 additions on the WC grain morphology,hardness and toughness of WC-10Co alloys were investigated.To intensify the grain growth driving force,nano W and nano C,instead of the conventionally...Effects of Cr3C2,VC and La2O3 additions on the WC grain morphology,hardness and toughness of WC-10Co alloys were investigated.To intensify the grain growth driving force,nano W and nano C,instead of the conventionally used WC,were used as the starting materials.To obtain a three-dimensional WC grain morphology,the natural sinter skins of the alloys were observed directly by scanning electron microscopy.It is shown that the additions have a strong ability in regulating the WC grain morphological and grain size distribution characteristics and the combinations of hardness and toughness.Due to the formation of regular and homogeneous triangular platelet WC grains,WC-10Co-0.6Cr3C2-0.06La2O3 alloy shows an excellent combination of hardness and toughness.The morphological regulation mechanism,the relationship between the WC grain morphology and the properties were discussed.展开更多
This study aimed to investigate the toxicity of rare earth ion yttrium under the stress of leaching agent ammonium sulfate (NH4)2SO4. [Method] By using earthworms as indicator organisms of environmental pol ution, a...This study aimed to investigate the toxicity of rare earth ion yttrium under the stress of leaching agent ammonium sulfate (NH4)2SO4. [Method] By using earthworms as indicator organisms of environmental pol ution, acute toxic ef-fects of rare earth yttrium on earthworms under the stress of ammonium sulfate were investigated with filter paper contact method. [Result] Under single stress of rare earth yttrium, the semi-lethal concentration after 48 and 24 h was LC50=213.41 mg/L and LC50=322.63 mg/L, respectively. ② Under single stress of ammonium sul-fate, the semi-lethal concentration after 48 h and 24 h was LC50=13.89 g/L and LC50=15.05 g/L, respectively. ③ In combined treatment of low concentration (10 g/L) of ammonium sulfate and different doses of rare earth yttrium, the semi-lethal con-centration after 48 and 24 h was LC50=198.65 g/L and LC50=399.85 g/L, respective-ly; in combined treatment of middle concentration (14 g/L) of ammonium sulfate and different doses of rare earth yttrium, the semi-lethal concentration after 48 and 24 h was LC50=167.3 mg/L and LC50=256.73 mg/L, respectively; in combined treatment of high concentration (20 g/L) of ammonium sulfate and different doses of rare earth yttrium, the semi-lethal concentration after 48 h and 24 h was LC50=31.03 mg/L and LC50=127.65 mg/L, respectively. [Conclusion] Low concentration of ammonium sulfate could reduce the toxicity of rare earth yttrium to earthworms and produce certain antagonism against rare earth yttrium; middle concentration ammonium sulfate in-creased the toxicity of rare earth yttrium to earthworms and produced relatively sig-nificant synergistic effects; high concentration ammonium sulfate significantly in-creased the toxicity of rare earth yttrium to earthworms. Compared with ammonium sulfate, dead earthworms exposed to rare earth yttrium were more easily fractured, and living earthworms showed insensitive response to acupuncture.展开更多
The uncertainty of standard solution plays an important role in detection of pesticide residues. It may affect the accuracy of detection results. In this study, the 14 organophosphorus pesticides mixed standard soluti...The uncertainty of standard solution plays an important role in detection of pesticide residues. It may affect the accuracy of detection results. In this study, the 14 organophosphorus pesticides mixed standard solution was used as the material to analyze all the influencing factors for the preparation of mixed standard solution with uncertainty as the only judging index. The preparation uncertainty of mixed standard solution was calculated with the top-down calculation method. In the end, the expanded uncertainty was presented. The results showed that the preparation of mixed standard solution from stock solution with precise pipettes had a relatively low uncertainty.展开更多
To improve the reconstruction performance of the greedy algorithm for sparse signals, an improved greedy algorithm, called sparsity estimation variable step-size matching pursuit, is proposed. Compared with state-of-t...To improve the reconstruction performance of the greedy algorithm for sparse signals, an improved greedy algorithm, called sparsity estimation variable step-size matching pursuit, is proposed. Compared with state-of-the-art greedy algorithms, the proposed algorithm incorporates the restricted isometry property and variable step-size, which is utilized for sparsity estimation and reduces the reconstruction time, respectively. Based on the sparsity estimation, the initial value including sparsity level and support set is computed at the beginning of the reconstruction, which provides preliminary sparsity information for signal reconstruction. Then, the residual and correlation are calculated according to the initial value and the support set is refined at the next iteration associated with variable step-size and backtracking. Finally, the correct support set is obtained when the halting condition is reached and the original signal is reconstructed accurately. The simulation results demonstrate that the proposed algorithm improves the recovery performance and considerably outperforms the existing algorithm in terms of the running time in sparse signal reconstruction.展开更多
To solve the problem that the signal sparsity level is time-varying and not known as a priori in most cases,a signal sparsity level prediction and optimal sampling rate determination scheme is proposed.The discrete-ti...To solve the problem that the signal sparsity level is time-varying and not known as a priori in most cases,a signal sparsity level prediction and optimal sampling rate determination scheme is proposed.The discrete-time Markov chain is used to model the signal sparsity level and analyze the transition between different states.According to the current state,the signal sparsity level state in the next sampling period and its probability are predicted.Furthermore,based on the prediction results,a dynamic control approach is proposed to find out the optimal sampling rate with the aim of maximizing the expected reward which considers both the energy consumption and the recovery accuracy.The proposed approach can balance the tradeoff between the energy consumption and the recovery accuracy.Simulation results show that the proposed dynamic control approach can significantly improve the sampling performance compared with the existing approach.展开更多
The competition-density effect of plant populations is of significance in theory and practice of forest management and has been studied for long time. The differences between the two reciprocal equations of the compet...The competition-density effect of plant populations is of significance in theory and practice of forest management and has been studied for long time. The differences between the two reciprocal equations of the competition-density effect in nonself-thinning populations and self-thinning populations were analyzed theoretically. This supplies a theoretical basis for analyzing the dynamics of forest populations and evaluating the effect of forest management.展开更多
A diluted magnetic 4H-SiC has been prepared by implanting Fe ions into the substrate. Its Curie temperature reaches as high as 320K and its technology is compatible with current IC. Moreover, the process includes thre...A diluted magnetic 4H-SiC has been prepared by implanting Fe ions into the substrate. Its Curie temperature reaches as high as 320K and its technology is compatible with current IC. Moreover, the process includes three annealing steps,named HNH annealing in this paper. Each step during this annealing has been analyzed. Comparisons have been made with different Fe concentrations and experimental results demonstrate that when the concentration of Fe is 0. 051, the Curie temperature is the highest. According to measurements, some explanation of this phenomenon is given.展开更多
The effect of Mn substitution for partial Fe in RFe 11Ti on structure and magnetic properties of compounds was researched. RFe 7Mn 4Ti samples (R=Y,Tb,Dy,Ho,Er) were prepared by means of vacuum arc-melting and s...The effect of Mn substitution for partial Fe in RFe 11Ti on structure and magnetic properties of compounds was researched. RFe 7Mn 4Ti samples (R=Y,Tb,Dy,Ho,Er) were prepared by means of vacuum arc-melting and subsequent vacuum annealing. The structure and magnetic properties of RFe 7Mn 4Ti compounds were investigated by X-ray powder diffraction and magnetic measurements. The following conclusions were obtained: all the RFe tMn 4Ti compounds crystallize in the ThMn 12-type structure. The lattice constants and the unit-cell volume changed with the increase of atomic number for R=Y, Tb, Dy, Ho, and Er. The compensation characters appear for the DyFe 7Mn 4Ti and HoFe 7Mn 4Ti compounds, and the compensation temperatures were about 123 K and 90 K, respectively. The Curie temperature, the saturation magnetization, and saturation moment of RFe 7Mn 4Ti compounds were given.展开更多
The solubility of trans-1,2-cyclohexanediol in water, methyl acetate, acetic ester, propyl acetate, butyl acetate, methyl acrylate, ethyl acrylate, 2-pentanone and acetoacetic ester was measured at temperatures rangin...The solubility of trans-1,2-cyclohexanediol in water, methyl acetate, acetic ester, propyl acetate, butyl acetate, methyl acrylate, ethyl acrylate, 2-pentanone and acetoacetic ester was measured at temperatures ranging from about 300 K to 330 K, using a modification of the experimental technique of laser monitoring observation system. The solubilities were calculated by λh method, in which new parameters were introduced to express the activity coefficients of trans-1,2-cyclohexanediol, and determined from the experimental data. The new parameters provide good calculated results. The experimental data were also correlated with a simple model, and results were compared with present λh model.展开更多
In order to provide practical fundamental data for rare-earth elements (REEs) recovery from phosphoric acid and to betterunderstand REEs behavior during the phosphoric acid evaporation process, the solubilities of R...In order to provide practical fundamental data for rare-earth elements (REEs) recovery from phosphoric acid and to betterunderstand REEs behavior during the phosphoric acid evaporation process, the solubilities of REEs in phosphoric acid with variousconcentrations of phosphorus at different temperatures were measured. A simple linear model between REEs solubility andphosphoric acid concentration is built and the experimental data are found to fit it very well (R2〉0.94). Hydrogen-ion concentration isfound to be the predominant factor controlling the solubility of REEs in phosphoric acid. In addition, the solubility of REEs inphosphoric acid is found to sharply decrease with increasing temperature, which can be attributed to the increase of the Gibbs energyof the REEPO4 dissolution reaction or the restraint of the disassociation of phosphoric acid molecules owing to the elevatedtemperature.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.72091212).
文摘Group testing is a method that can be used to estimate the prevalence of rare infectious diseases,which can effectively save time and reduce costs compared to the method of random sampling.However,previous literature only demonstrated the optimality of group testing strategy while estimating prevalence under some strong assumptions.This article weakens the assumption of misclassification rate in the previous literature,considers the misclassification rate of the infected samples as a differentiable function of the pool size,and explores some optimal properties of group testing for estimating prevalence in the presence of differential misclassification conforming to this assumption.This article theoretically demonstrates that the group testing strategy performs better than the sample by sample procedure in estimating disease prevalence when the total number of sample pools is given or the size of the test population is determined.Numerical simulation experiments were conducted to evaluate the performance of group tests in estimating prevalence in the presence of dilution effect.
基金The National Natural Science Foundation of China (No.50875048)the Natural Science Foundation of Jiangsu Province (No.BK2007115)the National High Technology Research and Development Program of China (863 Program)(No.2007AA04Z421)
文摘Aiming at the problems of bispectral analysis when applied to machinery fault diagnosis, a machinery fault feature extraction method based on sparseness-controlled non-negative tensor factorization (SNTF) is proposed. First, a non-negative tensor factorization(NTF) algorithm is improved by imposing sparseness constraints on it. Secondly, the bispectral images of mechanical signals are obtained and stacked to form a third-order tensor. Thirdly, the improved algorithm is used to extract features, which are represented by a series of basis images from this tensor. Finally, coefficients indicating these basis images' weights in constituting original bispectral images are calculated for fault classification. Experiments on fault diagnosis of gearboxes show that the extracted features can not only reveal some nonlinear characteristics of the system, but also have intuitive meanings with regard to fault characteristic frequencies. These features provide great convenience for the interpretation of the relationships between machinery faults and corresponding bispectra.
基金The National Natural Science Foundation of China(No.61201173,61271058,61401094)the Specialized Research Fund for the Doctoral Program of Higher Education of China(No.20110092110008)+1 种基金the Natural Science Foundation of Jiangsu Province(No.SBK201140040,BK2011060,BK20140645)the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry of China
文摘A scheme to design a simultaneous multichannel receiver is proposed to process multichannel signals in parallel, which is achieved by exploiting the attractive characteristics of a fast filter bank( FFB), such as cascaded structure, high frequency selectivity and lowcomputational complexity. Based on the minimization of the objective function, quantified in terms of the total number of multiplications required, subject to prescribed allowable ripples in the passband and stopband, the impulse response coefficients of the prototype filter in each stage are obtained to meet the requirements of the overall specifications for each channel at the receiver side. Simulations and experimental results on the frequency modulation( FM) broadcast mutlichannel signal receiving system with the FM range from88 to 108 MHz, built upon the proposed FFB structure, are performed to verify its performance. Those results indicate that the proposed scheme is efficient in FM audio indexing applications and has a lower computational complexity, which is approximately 66. 4% of the weighted overlap and add( WOLA) filter banks based solution.
基金Projects(2007CB613704,2007CB613705)supported by the National Basic Research Program of China
文摘The microstructure of WE93 alloy in different states and the mechanical properties at room temperature were investigated, and the creep behavior of the extruded and aged alloy at 200 ℃and at stress of 100, 125 and 150 MPa was also discussed. The result shows that the microstructure of as-cast WE93 alloy consists of α-Mg, Mg 12 (MM) and Mg 24 Y 5 with an average grain size of 45 μm. After being homogenized at 535 ℃for 18 h, the Mg 24 Y 5 phase is dissolved completely and there is only Mg 12 (MM) phase left around the grain boundaries. The grains do not grow up as prolonging the homogenization time. The extruded alloy has better mechanical properties than the as-cast alloy, especially the elongation increases to 12.5%. The extruded and aged alloy exhibits the highest yield strength and ultimate tensile strength of 315 and 385 MPa, respectively, however, the elongation decreases to 6.5%. The extruded and aged alloy exhibits good creep resistance at 200 ℃and at stress of 100 150 MPa. The creep stress exponent n is 2.97, suggesting that grain boundary sliding plays a dominant role at the corresponding temperature and applied stresses.
基金Project (51074189) supported by the National Natural Science Foundation of ChinaProject (20100162110001) supported by Research Fund for the Doctoral Program of Higher Education of ChinaProject (2011BAE09B02) supported by the National Science & Technology Special Foundation of China
文摘Effects of Cr3C2,VC and La2O3 additions on the WC grain morphology,hardness and toughness of WC-10Co alloys were investigated.To intensify the grain growth driving force,nano W and nano C,instead of the conventionally used WC,were used as the starting materials.To obtain a three-dimensional WC grain morphology,the natural sinter skins of the alloys were observed directly by scanning electron microscopy.It is shown that the additions have a strong ability in regulating the WC grain morphological and grain size distribution characteristics and the combinations of hardness and toughness.Due to the formation of regular and homogeneous triangular platelet WC grains,WC-10Co-0.6Cr3C2-0.06La2O3 alloy shows an excellent combination of hardness and toughness.The morphological regulation mechanism,the relationship between the WC grain morphology and the properties were discussed.
基金Supported by National Natural Science Foundation of China(Grant No.21067003,51364015)National High-Tech Research and Development Program of China(GrantNo.2012BAC11B07)+1 种基金Natural Science Foundation of Jiangxi Province(Grant No.20114BAB203024)Science and Technology Project of the Education Department ofJiangxi Province~~
文摘This study aimed to investigate the toxicity of rare earth ion yttrium under the stress of leaching agent ammonium sulfate (NH4)2SO4. [Method] By using earthworms as indicator organisms of environmental pol ution, acute toxic ef-fects of rare earth yttrium on earthworms under the stress of ammonium sulfate were investigated with filter paper contact method. [Result] Under single stress of rare earth yttrium, the semi-lethal concentration after 48 and 24 h was LC50=213.41 mg/L and LC50=322.63 mg/L, respectively. ② Under single stress of ammonium sul-fate, the semi-lethal concentration after 48 h and 24 h was LC50=13.89 g/L and LC50=15.05 g/L, respectively. ③ In combined treatment of low concentration (10 g/L) of ammonium sulfate and different doses of rare earth yttrium, the semi-lethal con-centration after 48 and 24 h was LC50=198.65 g/L and LC50=399.85 g/L, respective-ly; in combined treatment of middle concentration (14 g/L) of ammonium sulfate and different doses of rare earth yttrium, the semi-lethal concentration after 48 and 24 h was LC50=167.3 mg/L and LC50=256.73 mg/L, respectively; in combined treatment of high concentration (20 g/L) of ammonium sulfate and different doses of rare earth yttrium, the semi-lethal concentration after 48 h and 24 h was LC50=31.03 mg/L and LC50=127.65 mg/L, respectively. [Conclusion] Low concentration of ammonium sulfate could reduce the toxicity of rare earth yttrium to earthworms and produce certain antagonism against rare earth yttrium; middle concentration ammonium sulfate in-creased the toxicity of rare earth yttrium to earthworms and produced relatively sig-nificant synergistic effects; high concentration ammonium sulfate significantly in-creased the toxicity of rare earth yttrium to earthworms. Compared with ammonium sulfate, dead earthworms exposed to rare earth yttrium were more easily fractured, and living earthworms showed insensitive response to acupuncture.
文摘The uncertainty of standard solution plays an important role in detection of pesticide residues. It may affect the accuracy of detection results. In this study, the 14 organophosphorus pesticides mixed standard solution was used as the material to analyze all the influencing factors for the preparation of mixed standard solution with uncertainty as the only judging index. The preparation uncertainty of mixed standard solution was calculated with the top-down calculation method. In the end, the expanded uncertainty was presented. The results showed that the preparation of mixed standard solution from stock solution with precise pipettes had a relatively low uncertainty.
基金The National Basic Research Program of China(973Program)(No.2013CB329003)
文摘To improve the reconstruction performance of the greedy algorithm for sparse signals, an improved greedy algorithm, called sparsity estimation variable step-size matching pursuit, is proposed. Compared with state-of-the-art greedy algorithms, the proposed algorithm incorporates the restricted isometry property and variable step-size, which is utilized for sparsity estimation and reduces the reconstruction time, respectively. Based on the sparsity estimation, the initial value including sparsity level and support set is computed at the beginning of the reconstruction, which provides preliminary sparsity information for signal reconstruction. Then, the residual and correlation are calculated according to the initial value and the support set is refined at the next iteration associated with variable step-size and backtracking. Finally, the correct support set is obtained when the halting condition is reached and the original signal is reconstructed accurately. The simulation results demonstrate that the proposed algorithm improves the recovery performance and considerably outperforms the existing algorithm in terms of the running time in sparse signal reconstruction.
基金Innovation Funds for Outstanding Graduate Students in School of Information and Communication Engineering in BUPTthe National Natural Science Foundation of China(No.61001115, 61271182)
文摘To solve the problem that the signal sparsity level is time-varying and not known as a priori in most cases,a signal sparsity level prediction and optimal sampling rate determination scheme is proposed.The discrete-time Markov chain is used to model the signal sparsity level and analyze the transition between different states.According to the current state,the signal sparsity level state in the next sampling period and its probability are predicted.Furthermore,based on the prediction results,a dynamic control approach is proposed to find out the optimal sampling rate with the aim of maximizing the expected reward which considers both the energy consumption and the recovery accuracy.The proposed approach can balance the tradeoff between the energy consumption and the recovery accuracy.Simulation results show that the proposed dynamic control approach can significantly improve the sampling performance compared with the existing approach.
文摘The competition-density effect of plant populations is of significance in theory and practice of forest management and has been studied for long time. The differences between the two reciprocal equations of the competition-density effect in nonself-thinning populations and self-thinning populations were analyzed theoretically. This supplies a theoretical basis for analyzing the dynamics of forest populations and evaluating the effect of forest management.
文摘A diluted magnetic 4H-SiC has been prepared by implanting Fe ions into the substrate. Its Curie temperature reaches as high as 320K and its technology is compatible with current IC. Moreover, the process includes three annealing steps,named HNH annealing in this paper. Each step during this annealing has been analyzed. Comparisons have been made with different Fe concentrations and experimental results demonstrate that when the concentration of Fe is 0. 051, the Curie temperature is the highest. According to measurements, some explanation of this phenomenon is given.
文摘The effect of Mn substitution for partial Fe in RFe 11Ti on structure and magnetic properties of compounds was researched. RFe 7Mn 4Ti samples (R=Y,Tb,Dy,Ho,Er) were prepared by means of vacuum arc-melting and subsequent vacuum annealing. The structure and magnetic properties of RFe 7Mn 4Ti compounds were investigated by X-ray powder diffraction and magnetic measurements. The following conclusions were obtained: all the RFe tMn 4Ti compounds crystallize in the ThMn 12-type structure. The lattice constants and the unit-cell volume changed with the increase of atomic number for R=Y, Tb, Dy, Ho, and Er. The compensation characters appear for the DyFe 7Mn 4Ti and HoFe 7Mn 4Ti compounds, and the compensation temperatures were about 123 K and 90 K, respectively. The Curie temperature, the saturation magnetization, and saturation moment of RFe 7Mn 4Ti compounds were given.
基金Supported by the Natural Science Foundation of Henan Province (No. 0211020800)
文摘The solubility of trans-1,2-cyclohexanediol in water, methyl acetate, acetic ester, propyl acetate, butyl acetate, methyl acrylate, ethyl acrylate, 2-pentanone and acetoacetic ester was measured at temperatures ranging from about 300 K to 330 K, using a modification of the experimental technique of laser monitoring observation system. The solubilities were calculated by λh method, in which new parameters were introduced to express the activity coefficients of trans-1,2-cyclohexanediol, and determined from the experimental data. The new parameters provide good calculated results. The experimental data were also correlated with a simple model, and results were compared with present λh model.
基金Project(51674036)supported by the National Natural Science Foundation of ChinaProject(Z161100004916108)supported by the Beijing Nova Program,China
文摘In order to provide practical fundamental data for rare-earth elements (REEs) recovery from phosphoric acid and to betterunderstand REEs behavior during the phosphoric acid evaporation process, the solubilities of REEs in phosphoric acid with variousconcentrations of phosphorus at different temperatures were measured. A simple linear model between REEs solubility andphosphoric acid concentration is built and the experimental data are found to fit it very well (R2〉0.94). Hydrogen-ion concentration isfound to be the predominant factor controlling the solubility of REEs in phosphoric acid. In addition, the solubility of REEs inphosphoric acid is found to sharply decrease with increasing temperature, which can be attributed to the increase of the Gibbs energyof the REEPO4 dissolution reaction or the restraint of the disassociation of phosphoric acid molecules owing to the elevatedtemperature.