Extractive agents of extractive distillation separation for mixtures of dichlorobenzene were analyzed and compared, gas-liquid equilibrium data (VLE data) was measured for dichlorobenzene and diphenylamine, the appr...Extractive agents of extractive distillation separation for mixtures of dichlorobenzene were analyzed and compared, gas-liquid equilibrium data (VLE data) was measured for dichlorobenzene and diphenylamine, the appropriate extractive agent was selected by relatively volatility, the temperature was studied on the effect of extractive separation. VLE data was measured for dichlorobenzene, the parameters were simulated in Wilson equation. The infinite dilute activity coefficient of dichlorobenzene in diphenylamine were measured by chromatogram apparatus, the model parameters were correlated by the single parameter method for dichlorobenzene and diphenyl -amine, VLE data of m-dichlorobenzene-p- dichlorobenzene -o-dichlorobenzene-diphenylamine system was measured and calculated by six part model parameters. The results of correlation and experiment were provided a basis for study of extractive distillation simulation and experiment in this work.展开更多
The original van Laar's theory has been modified. The internal pressures of components and mixture are expressed by Frank's relation and the excess entropy for mixing of components is also considered. A new ac...The original van Laar's theory has been modified. The internal pressures of components and mixture are expressed by Frank's relation and the excess entropy for mixing of components is also considered. A new activity coefficient equation, which can be satisfactorily applied to polymer solutions, is obtained. The calculated results for the VLE of 179 polymer solutions show that the accuracy of fit is evidently superior to UNIQUAC equation.展开更多
文摘Extractive agents of extractive distillation separation for mixtures of dichlorobenzene were analyzed and compared, gas-liquid equilibrium data (VLE data) was measured for dichlorobenzene and diphenylamine, the appropriate extractive agent was selected by relatively volatility, the temperature was studied on the effect of extractive separation. VLE data was measured for dichlorobenzene, the parameters were simulated in Wilson equation. The infinite dilute activity coefficient of dichlorobenzene in diphenylamine were measured by chromatogram apparatus, the model parameters were correlated by the single parameter method for dichlorobenzene and diphenyl -amine, VLE data of m-dichlorobenzene-p- dichlorobenzene -o-dichlorobenzene-diphenylamine system was measured and calculated by six part model parameters. The results of correlation and experiment were provided a basis for study of extractive distillation simulation and experiment in this work.
基金Supported by the National Natural Science Foundation of China(No.29376236).
文摘The original van Laar's theory has been modified. The internal pressures of components and mixture are expressed by Frank's relation and the excess entropy for mixing of components is also considered. A new activity coefficient equation, which can be satisfactorily applied to polymer solutions, is obtained. The calculated results for the VLE of 179 polymer solutions show that the accuracy of fit is evidently superior to UNIQUAC equation.