Rate Law for Photoelectrochemical Water Splitting Over CuO

Photocatalytic splitting of water over p-type semiconductors is a promising strategy for production of hydrogen.However,the determination of rate law is rarely reported.To this purpose,copper oxide(CuO)is selected as a model photocathode in this study,and the photogenerated surface charge density,interfacial charge transfer rate constant and their relation to the water reduction rate(in terms of photocurrent)were investigated by a combination of(photo)electrochemical techniques.The results showed that the charge transfer rate constant is exponential-dependent on the surface charge density,and that the photocurrent equals to the product of the charge transfer rate constant and surface charge density.The reaction is first-order in terms of surface charge density.Such an unconventional rate law contrasts with the reports in literature.The charge density-dependent rate constant results from the Fermi level pinning(i.e.,Galvani potential is the main driving force for the reaction)due to accumulation of charge in the surface states and/or Frumkin behavior(i.e.,chemical potential is the main driving force).This study,therefore,may be helpful for further investigation on the mechanism of hydrogen evolution over a CuO photocathode and for designing more efficient CuO-based photocatalysts.

Determination of Chlorine and Bromine in Plant Materials by Ion Chromatography

A method was developed for determination of chlorine and bromine in plant materials by ion chromatography using temperature programing-semi molten for sample preparation. Values of detection limits of the method found were 1.0×10^-5 for CI and 1.3×10^-6 for Br. The measuring range of the method found were 0.3-20.0 mg/L for CI and 4,0-120,0 μg/L for Br. The results obtained agreed quite well with those reference values.

Simulation of pavement roughness based on time domain model

In order to describe pavement roughness more intuitively and effectively, a method of pavement roughness simulation, i.e., the stochastic sinusoidal wave, is introduced. The method is based on the primary idea that pavement roughness is denoted as the sum of numerous sines or cosines with stochastic phases, and uses the discrete spectrum to approach the target stochastic process. It is a discrete numerical method used to simulate pavement roughness. According to a given pavement power spectral density （PSD） coefficient, under the condition that the character of displacement frequency based on the time domain model is in accordance with the given pavement surface spectrum, the pavement roughness is optimized to stochastic equivalent vibrations by computer simulation, and the curves that describe pavement roughness under each grade are obtained. The results show that the stochastic sinusoidal wave is suitable for simulation of measured pavement surface spectra based on the time domain model. The method of the stochastic sinusoidal wave is important to the research on vehicle ride comfort due to its rigorous mathematical derivation, extensive application range and intuitive simulation curve. Finally, a roughness index defined as the nominal roughness index （NRI） is introduced, and it has correlation with the PSD coefficient.

Expression Profile Changes of Genes Involved in Lipid Metabolism Pathway During Liver Regeneration in Mice

[ Objective ] The aim of the research was to study the expression profile changes of genes involved in lipid metabolism pathway during liver regeneration in mice. [ Method] The CCI4 induced mouse model of liver regeneration was established and the total RNA was isolated from liver tissue of mouse. Then the changes of genes involved in lipid metabolism pathway during different stages of liver regeneration were detected through micro-array chip gene technique and their specific functions were also analyzed. [ Result] Dudng the process of liver regeneration, the expression level of 98 genes involved in lipid metabolism pathway changed, which were divided into eight groups according to change trend. In the mass, the expression of genes was inhibited in the early stage and up-regulated in the late phase. And the gene expression associated with fatty acid synthesis pathway was mainly up-regulated while the catabolic pathway did not change significantly. Most of genes involved in bile acid synthesis pathway were suppressed before 4.5 d and up-regulated after 4.5 d or 7 d. [ Conclusion] During the process of liver regeneration, the genes associated with lipid metabolism are expressed in different trends, and this data should provide a specific range of genes for further studying the regulation effect of lipid metabolism related pathway on liver regeneration.

Generation of artificial earthquakes for matching target response unsmooth spectrum via wavelet package transform

The seismic records of target response spectrum used in the time-history analysis should be allowed to meet the norms. However, the previous fitting methods of target spectrum are mostly for the situations that the target spectrum is a smooth curve. In many cases, it needs to match unsmooth target spectrum for single determined response spectrum. An adjustment of time history via wavelet packet transform was presented, which is able to fit unsmooth target spectrum. It was found that there is a certain bias between the band center frequency of the component of seismic record after wavelet packet decomposition and the peak frequency of response spectra of wavelet packet components. For this reason, five strategies were presented to select iteration points, and the effects of the five strategies were compared with two calculation examples. It was turned out that the peak frequency of the response spectrum of wavelet packet component can lead to good fitting effect when it is selected as the iteration point. In the iteration process, it shows great promise in fitting non-smooth target spectrum and has a trend of converge.

八十年代过程分析仪器展望

过程分析仪器处于快速变化之中。为窥测八十年代过程分析仪器的概貌,本文将探讨主要技术发展动向。微处理机的应用最引人注目,目前主要用于一些多组分分析仪器,预料其应用将扩展到一些较简单的单组分分析仪器。过去除气相色谱法外,多组分分析技术的在线应用很难普及。预计今后面貌将会改变,若干种过程谱仪将在许多生产流程中推广使用。探索和发展简易选择性直接探头的工作越来越受人重视,早期产品中所存在的弱点将因微处理机的采用而减轻或消除。系统设计和分析系统中分析仪器以外的辅助环节越来越受重视,所谓“预装分析系统”应运而生,取样和试样预处理概念、技术和系统设计将发生重大变革。

Advancing Hierarchical Equations of Motion for Efficient Evaluation of Coherent Two-dimensional Spectroscopy

To advance hierarchical equations of motion as a standard theory for quantum dissipative dynamics, we put forward a mixed Heisenberg-SchrSdinger scheme with block-matrix implementation on efficient evaluation of nonlinear optical response function. The new approach is also integrated with optimized hierarchical theory and numerical filtering algorithm. Different configurations of coherent two-dimensional spectroscopy of model excitonic dimer systems are investigated, with focusing on the effects of intermolecular transfer coupling and bi-exciton interaction.

New Integrable Couplings of Generalized Kaup-Newell Hierarchy and Its Hamiltonian Structures

A new isospectral problem is firstly presented, then we derive integrable system of soliton hierarchy. Also we obtain new integrable couplings of the generalized Kaup-Newell soliton equations hierarchy and its Hamiltonian structures by using Tu scheme and the quadratic-form identity. The method can be generalized to other soliton hierarchy.

A IP_N×IP_N Spectral Element Projection Method for the Unsteady Incompressible Navier-Stokes Equations

In this paper,we present a IP_N×IP_N spectral element method and a detailed comparison with existing methods for the unsteady incompressible Navier-Stokes equa- tions.The main purpose of this work consists of:(i) detailed comparison and discussion of some recent developments of the temporal discretizations in the frame of spectral el- ement approaches in space;(ii) construction of a stable IP_N×IP_N method together with a IP_N→IP_(N-2) post-filtering.The link of different methods will be clarified.The key feature of our method lies in that only one grid is needed for both velocity and pressure variables,which differs from most well-known solvers for the Navier-Stokes equations. Although not yet proven by rigorous theoretical analysis,the stability and accuracy of this one-grid spectral method are demonstrated by a series of numerical experiments.

Spectral characteristics of micro-seismic signals obtained during the rupture of coal

This study was performed to investigate the spectral characteristics of micro-seismic signals observed during the rupture of coal. Coal rupture micro-seismic observations were obtained on a test system that included an electro-hydraulic servo pressure tester controlled by a YAW microcomputer, a micro-seismic sensor, a loading system, and a signal collection system. The results show that the micro-seismic signal increases with increasing compressive stress at the beginning of coal rupture. The signal remains stable for a period at this stage. A large number of micro-seismic signals appear immediately before the main rupture event. The frequency of micro-seismic events reaches a maximum immediately after the coal ruptures. Micro-seismic signals were decomposed into several Intrinsic Mode Functions (IMF's) by the empirical mode decomposition (EMD) method using a Hilbert-Huang transform (HHT). The main fre- quency band of the micro-seismic signals was found to range from 10 to 100 Hz in the Hilbert energy spectrum and from marginal spectrum calculations. The advantage of applying an HHT is that this can extract the main features of the signal. This fact was confirmed by an HHT analysis of the coal micro-seis- mic signals that shows the technique is useful in the field of coal rupture.

Raman spectroscopy investigation of structural and textural change in C/C composites during braking

The microstructure and texture of C/C composites with a resin-derived carbon, a rough laminar （RL） pyrocarbon and a smooth laminar pyrocarbon, before and after braking tests, were investigated by Raman spectroscopy. The full width at half maximum （FWHM） of the D-band indicates the amount of defects in the in-plane lattice, while the G-to-D band intensity （peak area） ratios （lC/ID） is used to evaluate the degree of graphitization. The results show that the FWHM of D-band of sample with RL pyrocarbon changes greatly from 36 cm-1 to 168 cm 1 after braking tests, which indicates that a large number of lattice defects are produced on its wear surface. However, the graphitization degree of resin-derived carbon sample rises significantly, because the IC/1D increases from 0.427 to 0.928. Braking tests under normal loading conditions, involving high temperature and high pressure, produce a lot of lattice defects on the wear surface, and induce the graphitization of the surface. Sample with RL pyrocarbon having a low hardness is easy to deform, and has the most lattice defects on the wear surface after braking. While raw materials with resin-derived carbon have the lowest graphitization degree which rises greatly during braking.

A New Method to Construct Integrable Coupling System for Burgers Equation Hierarchy by Kronecker Product

It is shown that the Kronecker product can be applied to construct a new integrable coupling system of soliton equation hierarchy in this paper. A direct application to the Burgers spectral problem leads to a novel soliton equation hierarchy of integrable coupling system. It indicates that the Kronecker product is an efficient and straightforward method to construct the integrable couplings.

Spectra of Free Diquark in the Bethe-Salpeter Approach

In this work, we employ the Bethe-Salpeter （B-S） equation to investigate the spectra of free diquarks and their B-S wave functions. We find that the B-S approach can be consistently applied to study the diqaurks with two heavy quarks or one heavy and one light quarks, but for two light-quark systems, the results are not reliable. There are a few free parameters in the whole scenario which can only be fixed phenomenologically. Thus, to determine them, one has to study baryons which are composed of quarks and diquarks.

Meso-damage evolution and mechanical characteristics of low-porosity sedimentary rocks under uniaxial compression

Low pore sedimentary rocks(from Guangxi, China) were subjected to uniaxial compression loading experiment under different initial stresses. The rock samples were investigated by nuclear magnetic resonance before and after the loading. The relationships between the mesoscopic rock damage and macroscopic mechanical parameters were established, and the initial damage stress of the low-porosity sedimentary rock was determined. The results showed that this type of rock has the initial stress of damage. When the initial loading stress is lower than the initial stress of damage, the T2 spectrum area of the rock sample gradually decreases, and the primary pores of the rock are further closed under the stress. The range of the initial stress of damage for this type of rock is 8-16 MPa. When the loading stress exceeds the initial stress of damage, the T2 spectrum area gradually increases, indicating that the porosity of the rock increases and microscopic damage of the rock appears. The rock damage degree is defined, and the nonlinear function between the rock damage degree and the initial loading stress is established.

Oxidation of Mercaptans from Light Oil Sweetening by Fe_2O_3/MgO/Al_2O_3 Supported CoPcS Catalyst

MgO/Al2O3 and Fe2O3/MgO/Al2O3 solid bases were prepared through mixing method. After sulfonated cobalt phthalocyanine （CoPcS） being supported on these solid bases, the catalytic performance of these catalysts was evaluated by means of mercaptan oxidation reaction. The samples were characterized by X-ray diffraction （XRD）, CO2 temperature-programmed desorption （CO2-TPD）, FTIR spectroscopy, and X-ray photoelectron spectroscopy （XPS）. Investigation was focused on the effect of Fe2O3 on activity, crystal structure, basicity, and stability of the catalyst and also on the role of Fe2O3 in the mercaptan oxidation processes. Test results have shown that the Fe2O3/MgO/Al2O3- CoPcS catalyst has a higher initial activity and a much longer service life than the MgO/Al2O3-CoPcS catalyst. The increased types of basic sites coupled with an enhanced oxidation ability resulted from the addition of Fe2O3 have contributed to the improvement of the catalytic activity of the MgO/Al2O3-CoPcS catalyst.

Re-explanation of Weyl Quantization Scheme via Weyl Ordering Approach

We re-explain the Weyl quantization scheme by virtue of the technique of integration within Weyl orderedproduct of operators,i.e.,the Weyl correspondence rule can be reconstructed by classical functions' Fourier transfor-mation followed by an inverse Fourier transformation within Weyl ordering of operators.As an application of thisreconstruction,we derive the quantum operator coresponding to the angular spectrum amplitude of a spherical wave.

Pseudo-spectral Approximations for a Class of the Kdv-Burgers Type Equation

In this paper, the pseudo-spectral approximations for a class of the Kdv-Burgers type equation is presented. Convergence and stability of the approximation have been proved by Sobolev's inequalities and the bounded extensive method of the nonlinear function. Finally, the numerical examples are proposed.

Soliton Solutions for Nonisospectral AKNS Equation by Hirota＇s Method

Bilinear form of the nonisospectral AKNS equation is given. The N-soliton solutions are obtained through Hirota＇s method.

B-Spline with Symplectic Algorithm Method for Solution of Time-Dependent Schrodinger Equations

A B-spline with the symplectic algorithm method for the solution of time-dependent Schrodinger equations （TDSEs） is introduced. The spatial part of the wavefunction is expanded by B-spline and the time evolution is given in a symplectic scheme. This method allows us to obtain a highly accurate and stable solution of TDSEs. The effectiveness and efficiency of this method is demonstrated by the high-order harmonic spectra of one-dimensional atoms in comparison with other references.