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Sn在锆合金氧化膜中稳定价态的第一性原理研究
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作者 徐晨皓 谢耀平 +1 位作者 吴江桅 胡丽娟 《上海金属》 CAS 2022年第5期104-110,共7页
合金元素在锆合金氧化膜中的稳定价态对研究氧化膜的微观结构有着重要意义。采用第一性原理计算方法研究了Sn在锆合金氧化膜中的稳定价态。结果表明:通过缺陷形成能计算及电子结构分析,可以获得合金元素在锆合金氧化膜中的稳定价态。Sn... 合金元素在锆合金氧化膜中的稳定价态对研究氧化膜的微观结构有着重要意义。采用第一性原理计算方法研究了Sn在锆合金氧化膜中的稳定价态。结果表明:通过缺陷形成能计算及电子结构分析,可以获得合金元素在锆合金氧化膜中的稳定价态。Sn在m-ZrO和t-ZrO中的稳定价态均为+4价,说明锆合金氧化膜发生相变不会改变Sn的稳定价态。 展开更多
关键词 二氧化锆 第一性原理计算 稳定价态 电子结构
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氧化物体系中Eu^(2+)的价态稳定和转换 被引量:2
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作者 刘应亮 冯德雄 +1 位作者 杨培慧 石春生 《物理化学学报》 SCIE CAS CSCD 北大核心 1999年第5期426-430,共5页
采用光谱方法研究了氧化物体系中Eu2+的价态稳定和转换问题.研究表明体系中Eu2+的价态稳定与取代离子的半径、电荷及基质晶相等密切相关.运用晶格能理论和晶体结构变化对实验结果进行了计算和讨论.
关键词 铕离子 氧化物体系 稳定 转换 荧光材料
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KCaF_3中Eu^(2+)的光谱性质和价态稳定 被引量:1
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作者 刘应亮 石春山 《无机化学学报》 SCIE CAS CSCD 北大核心 1996年第2期172-177,共6页
本文报道 KCa F3 基质中 Eu2 +的光谱特征及浓度对 Eu2 +发光的影响并观察到 Eu2 +对 Tb3 +产生能量传递的新现象 ,详细讨论 Eu2 +在基质中的价态稳定及其转换。
关键词 氟化钙钾 光谱性质 稳定
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HNO_3介质中Np价态测定过程中稳定性的研究 被引量:1
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作者 何建玉 田保生 《核化学与放射化学》 CAS CSCD 北大核心 1997年第2期11-15,共5页
用TTA和TOPO作萃取剂,测定了1mol/LHNO3中Np(Ⅳ)、Np(Ⅴ)、Np(Ⅵ)的分配比;研究了不同稳定剂对Np混合价态的作用及Np(Ⅵ)在TTA萃取过程中对Np(Ⅴ)-Np(Ⅵ)价态稳定性和测定结果的影响。
关键词 萃取 TTA TOPO 稳定 硝酸 分配比
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稳定态纳米零价铁-厌氧菌联合处理法降解2,4,6-三氯苯酚 被引量:2
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作者 舒亚婕 万金泉 +1 位作者 关泽宇 马邕文 《化工环保》 CAS CSCD 北大核心 2014年第3期210-214,共5页
利用SEM、XRD、FTIR等手段对稳定态纳米零价铁(NH2-SiO2@NZVI)进行表征,并考察NH2-SiO2@NZVI-厌氧菌体系对2,4,6-三氯苯酚(2,4,6-TCP)的降解效果。实验结果表明:NH2-SiO2@NZVI具有较强的抗氧化能力及较好的分散性;当2,4,6-TCP质量浓度50... 利用SEM、XRD、FTIR等手段对稳定态纳米零价铁(NH2-SiO2@NZVI)进行表征,并考察NH2-SiO2@NZVI-厌氧菌体系对2,4,6-三氯苯酚(2,4,6-TCP)的降解效果。实验结果表明:NH2-SiO2@NZVI具有较强的抗氧化能力及较好的分散性;当2,4,6-TCP质量浓度50 mg/L、NH2-SiO2@NZVI加入量1 g/L、初始pH 7.00、反应120 h时,2,4,6-TCP的去除率为34.76%,一级降解速率常数为0.022 1,均远大于普通纳米零价铁颗粒;在NH2-SiO2@NZVI-厌氧菌体系中,2,4,6-TCP的去除率可达82.70%,NH2-SiO2@NZVI与厌氧微生物之间表现出明显的协同效应,能有效缓解2,4,6-TCP对厌氧微生物的抑制作用,稳定体系pH,提高微生物的降解活性和产甲烷活性。 展开更多
关键词 稳定纳米零 2 4 6-三氯苯酚 表面修饰 厌氧处理
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异质同构晶体的结构演变对Eu^(2+)/Eu^(3+)稳定性的影响
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作者 夏志国 廖立兵 刘海坤 《矿物学报》 CAS CSCD 北大核心 2012年第S1期60-61,共2页
Eu具有2种价态,一般来说,还原条件的选择和控制是合成低价Eu材料的关键。而大量的实验结果也表明:基质晶体结构、取代离子半径和电荷以及电荷补偿剂等对Eu的价态改变和价态稳定性都有影响。
关键词 异质同构 结构演变 化合物 稳定 基质结构 还原条件 磷灰石 晶体结构 荧光发射光谱 晶体场
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谈中学化学常见纯净物的稳定性
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作者 游子良 《化学教学》 CAS 北大核心 1997年第7期38-40,共3页
关键词 中学化学 稳定 纯净物 物质稳定 稳定 介质环境 歧化反应 分子比 酸性介质 含氧酸盐
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固态化合物中铕的价态研究进展 被引量:13
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作者 刘应亮 冯德雄 +1 位作者 杨培慧 石春山 《化学通报》 CAS CSCD 北大核心 1999年第5期14-19,共6页
介绍了近年来关于变价稀土元素Eu价态研究的最新进展,总结了Eu2+的价态稳定和转换及其与基质结构、取代离子半径电荷。
关键词 稳定 转换关系 化合物
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镧系元素十八元六氮大环配合物的研究 被引量:10
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作者 王耕霖 苗蓝 《高等学校化学学报》 SCIE EI CAS 1984年第3期281-286,共6页
本文采用“模板反应”合成了十四个三价镧系金属和一个二价铕的十八元六氮大环固体配合物和一个自由大环,推测了所合成的配合物的组成、结构和配位数,研究了某些配合物的热稳定性、价态稳定性和在水溶液中的行为。
关键词 模板反应 镧系金属 大环配合物 镧系元素 配位数 固体配合物 稳定 水溶液
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镎铀共存有机体系的光化学研究
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作者 孟庆英 刘冰 《核科学与工程》 CSCD 北大核心 1996年第4期379-382,共4页
镎铀共存有机体系的光化学研究孟庆英刘冰(天津大学分析中心)关键词镎铀有机体系光化还原1引言Np、U的化学行为有许多相似之处,这给提纯和分离带来了困难;然而,在价态稳定性、氧化还原能力、络合物化学和萃取行为等方面又有... 镎铀共存有机体系的光化学研究孟庆英刘冰(天津大学分析中心)关键词镎铀有机体系光化还原1引言Np、U的化学行为有许多相似之处,这给提纯和分离带来了困难;然而,在价态稳定性、氧化还原能力、络合物化学和萃取行为等方面又有明显的差异,这给提取回收提供了方便... 展开更多
关键词 有机体系 光化还原 络合物化学 萃取 稳定
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Stability analysis of intermediate product dynamic price in two-level supply chain
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作者 汪文利 王海燕 《Journal of Southeast University(English Edition)》 EI CAS 2007年第S1期23-27,共5页
In two cases that upstream and downstream firms have the decision power of intermediate product prices in a two-level supply chain,the dynamic pricing mechanism of intermediate products is studied.When a party who has... In two cases that upstream and downstream firms have the decision power of intermediate product prices in a two-level supply chain,the dynamic pricing mechanism of intermediate products is studied.When a party who has the decision power of pricing gives prices of intermediate products,the other side will give the supply or demand quantity of intermediate products which maximizes its own profits,then the party who decides price has two pricing strategies.One uses the matching price which meets the other party's demand or supply needs according to the prices of intermediate products in the next cycle.The other uses the convex combinations of the current price and the matching price which satisfies the other party's demand or supply as the price of the intermediate product in the next cycle.No matter which side has the decision power of intermediate product prices between upstream and downstream firms,results show that in the first pricing strategy,only in one case of the pricing of intermediate products stable;but in the second pricing strategy,both of the cases of pricing of intermediate products are stable in a certain field of combined parameters. 展开更多
关键词 supply chain intermediate products dynamic price STABILITY
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Preliminary study on road-region ecosystem stability evaluation 被引量:1
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作者 QIN Zhi-bin LIU Zhao-hui LI Yu-zhi 《Journal of Environmental Science and Engineering》 2008年第5期48-54,共7页
A scientific and rational evaluation on road-region ecosystem stability is the premise to properly deal with the relationship between highway constructing and ecological environment protecting to a sustainable develop... A scientific and rational evaluation on road-region ecosystem stability is the premise to properly deal with the relationship between highway constructing and ecological environment protecting to a sustainable development. Based on the connotative meaning and the procedure of evaluation on road-region ecosystem stability, this paper studied the principles and the method on determining the evaluation index system on road-region ecosystem stability. It put forward an index system for assessing road-region ecosystem stability as a reference. On the basis of detailed analyze of the multidimensional space of road-region ecosystem, a new multi-objective comprehensive evaluation method for road-region ecosystem stability is presented and a calculation tormula for multi-objective comprehensive level of road-region ecosystem stability. This method was used to evaluate road-region ecosystem stability of Lin-Chang highway. This method possessed definite theoretical value and reliability in practice. 展开更多
关键词 road-region ecosystem evaluation of stability MULTI-OBJECTIVE multidimensional space
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From Steady 4D Quantization of Valence Electrons to Material Space Paradigm
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作者 Igor E. Bulyzhenkov 《Journal of Chemistry and Chemical Engineering》 2013年第4期370-373,共4页
Potential electric and gravitational fields do not change steady quantized states of electrons in chemical bonds, microscopic clusters of charges and macroscopic superconducting rings. There are no theoretical grounds... Potential electric and gravitational fields do not change steady quantized states of electrons in chemical bonds, microscopic clusters of charges and macroscopic superconducting rings. There are no theoretical grounds to create Squid-type instruments to measure electric and gravitational fields with quantum accuracy basing on the Bohr-Sommerfeld quantization of charged particles. Squid-verified spatial flatness for superfluid electrons corresponds to the material space paradigm for reality. 展开更多
关键词 Continuous electron relativistic quantization.
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Improvement of Pseudo-static Method for Slope Stability Analysis 被引量:3
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作者 YANG Chang-wei ZHANG Jian-jing +2 位作者 FU Xiao ZHU Chuan-bin BI Jun-wei 《Journal of Mountain Science》 SCIE CSCD 2014年第3期625-633,共9页
traditional In this paper, two drawbacks pseudo-static method (vertical of the slice method) in the slope stability evaluation have been studied. First, the sliding mass is divided into vertical slices according to... traditional In this paper, two drawbacks pseudo-static method (vertical of the slice method) in the slope stability evaluation have been studied. First, the sliding mass is divided into vertical slices according to this method, which is irrational to some extent in the seismic design of slope. Second, only peak ground acceleration (PGA) is considered, and the effects of shaking frequency and duration on slope stability are neglected. And then, based on the theory of elastic wave and the summarized geological model, this paper put forwards an improved method of pseudo-method by using the theory of elastic wave and Hilbert-Huang transform. The improved pseudostatic method gives reasonable considerations to the time-frequency effects of seismic wave and its rationality has been verified by the shaking table test. This method can evaluate the safety of a slope, the happening time and the scale of landslides. At the same time, this method also can improve the high accuracy of the evaluation of the safety of the slope. 展开更多
关键词 Pseudo-static analysis Slope stability Elastic wave Hilbert-Huang Transform Transfercoefficient slice
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Rock engineering property of the high-steep open-pit slope and its stability
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作者 PENG Wen-bin YU Wei-jian 《Journal of Coal Science & Engineering(China)》 2010年第1期35-40,共6页
According to the rock engineering property and stability of high-steep open-pitslopes, various factors were collected on the basis of rock engineering system (RSE) theory,and the interaction matrix of stability evalua... According to the rock engineering property and stability of high-steep open-pitslopes, various factors were collected on the basis of rock engineering system (RSE) theory,and the interaction matrix of stability evaluation was established.Then, the stabilityevaluation index (S_p) of the slope was put forward.Ranges of the S_p value and the correspondingstable state were given on the basis of thirty-six samples.It is found that the followingrelationships exist: unstable (easy landslide): S_p<-0.20; mid-stable (may be landslide):-0.20<S_p<0.63; stable (no landslide): S_p>0.63.Finally, the stability evaluation indexwas applied on the high-steep open-pit slope of one mine.Analysis results and monitoringdata indicate that the index meets the necessity of the property of slope engineering, and ithas an important engineering purpose for landslide forecasting of high-steep slopes. 展开更多
关键词 high-steep slope rock engineering system property stability evaluation open-pit mine
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元素的二次周期性
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作者 侯新发 《衡阳师范学院学报》 1986年第1期65-67,共3页
长期以来,人们通常只注意到或只强调元素性质的变化随原子序数的增加而逐渐单调地增加或减小,对于同一周期如此,对于同一族也是这样。但是,当我们过细地分析研究周期表中第三至第七主族元素的性质时,就会发现它们的变化并不是那样单调... 长期以来,人们通常只注意到或只强调元素性质的变化随原子序数的增加而逐渐单调地增加或减小,对于同一周期如此,对于同一族也是这样。但是,当我们过细地分析研究周期表中第三至第七主族元素的性质时,就会发现它们的变化并不是那样单调地增加或减小的。 展开更多
关键词 次周期性 主族元素 过渡后元素 电离势 周期元素 稳定 周期表 元素性质 基本性质 第二周期性
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超重元素Uus(Z=117)在酸溶液中标准电极电势的理论预测
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作者 常志伟 张登红 董晨钟 《中国科学:物理学、力学、天文学》 CSCD 北大核心 2013年第1期61-68,共8页
基于Born-Haber热力学循环理论,利用多组态Dirac-Fock方法计算的超重元素Uus及其同族元素Cl,Br,I和At的离化势和亲和势及已有的标准电极电势的实验值,拟合得到了Uus的元素电势图.结果表明:在酸溶液中Uus的0价态能够稳定存在,而1,1+和5+... 基于Born-Haber热力学循环理论,利用多组态Dirac-Fock方法计算的超重元素Uus及其同族元素Cl,Br,I和At的离化势和亲和势及已有的标准电极电势的实验值,拟合得到了Uus的元素电势图.结果表明:在酸溶液中Uus的0价态能够稳定存在,而1,1+和5+价态不能稳定存在;在同族元素中,随原子序数Z的增大,0价态和1+态的稳定性逐渐增加,1价态的稳定性逐渐降低;而5+价态的稳定性随原子序数变化并不是单调的.对于这种稳定性随原子序数变化的规律,我们从价电子能级的相对位置以及电子电离或亲和的过程作了定性的解释. 展开更多
关键词 超重元素Uus 标准电极电势 不同稳定
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Value Problems in Chinese Political Studies
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作者 Gu Su 《Fudan Journal of the Humanities and Social Sciences》 2010年第4期1-21,共21页
Since the Keform and Opening, a great change has taken place in Chinese political studies, from an instrument of the ruhng ideology to relatively independent research both in theory and practice, which should be affir... Since the Keform and Opening, a great change has taken place in Chinese political studies, from an instrument of the ruhng ideology to relatively independent research both in theory and practice, which should be affirmed and encouraged. But value problems still need to be resolved. Although absolute value neutrality is infeasible, relative value neutrality is possible and necessary for political studies, which means objective observation of social facts and breaking away from ideology in evaluation of political events and theoretical studies. As there are different levels of value, relative value neutrality requires that universal values he insisted upon as a common ground in political evaluation, which is closely related to overlapping consensus and public reason that China needs to seek for its social stability and harmony. 展开更多
关键词 China REFORM political studies value overlapping consensus
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