According to the configuration,mixed-conducting membranes are classified as symmetric membranes and asymmetric membranes consisting of a thin dense layer and a porous support.In this study,these two kinds of SrCo0.4Fe...According to the configuration,mixed-conducting membranes are classified as symmetric membranes and asymmetric membranes consisting of a thin dense layer and a porous support.In this study,these two kinds of SrCo0.4Fe0.5Zr0.1O3-δ oxide-based membranes were systematically compared in terms of oxygen permeability and chemical stability,and their differences were elucidated by means of the theoretical calculation.For the oxygen permeability,the asymmetric membrane was greater than the symmetric membrane due to the significant decrease of bulk diffusion resistance in the thin dense layer of the asymmetric membrane.In regard to the chemical stability,the increase of oxygen partial pressure on the asymmetric membrane surface at CH4 side produced the stable time of over 1032h in partial oxidation of methane at 1123K,while the symmetric membrane was only of 528h.This study demonstrated that the asymmetric membrane was a promising geometrical configuration for the practical application.展开更多
This paper is concerned with the issue of stabilization for the linear neutral systems with mixed delays. The attention is focused on the design of output feedback controllers which guarantee the asymptotical stabilit...This paper is concerned with the issue of stabilization for the linear neutral systems with mixed delays. The attention is focused on the design of output feedback controllers which guarantee the asymptotical stability of the closed-loop systems. Based on the model transformation of neutral type, the Lyapunov-Krasovskii functional method is employed to establish the delay-dependent stability criterion. Then, through the controller parameterization and some matrix transformation techniques, the desired parameters are determined under the delay-dependent design condition in terms of linear matrix inequalities (LMIs), and the desired controller is explicitly formulated. A numerical example is given to illustrate the effectiveness of the proposed method.展开更多
In this paper, the global existence of weak s olutions to the initial boundary value problem for Boltzmann-Poisson system is proved. The proof is based on the regularization and the stability of the veloci ty averages...In this paper, the global existence of weak s olutions to the initial boundary value problem for Boltzmann-Poisson system is proved. The proof is based on the regularization and the stability of the veloci ty averages and the compactness results on L 1-theory.展开更多
The robust guaranteed cost sampled-data control was studied for a class of uncertain nonlinear systems with time-varying delay. The parameter uncertainties are time-varying norm-bounded and appear in both the state an...The robust guaranteed cost sampled-data control was studied for a class of uncertain nonlinear systems with time-varying delay. The parameter uncertainties are time-varying norm-bounded and appear in both the state and the input control matrices. By applying an input delay approach, the system was transformed into a continuous time-delay system. Attention was focused on the design of a robust guaranteed cost sampled-data control law which guarantees that the closed-loop system is asymptotically stable and the quadratic performance index is less than a certain bound for all admissible uncertainties. By applying Lyapunov stability theory, the theorems were derived to provide sufficient conditions for the existence of robust guaranteed cost sampled-data control law in the form of linear matrix inequalities (LMIs), especially an optimal state-feedback guaranteed cost sampled-data control law which ensures the minimization of the guaranteed cost was given. The effectiveness of the proposed method was illustrated by a simulation example with the asymptotically stable curves of system state under the initial condition of x(0)=[0.679 6 0].展开更多
Polymer‐stabilized Au nano clusters (NCs) with mean diameters of 2–10 nm exhibit unique catalytic properties. Several studies have shown that the key factors affecting the catalytic activity of poly‐mer‐stabiliz...Polymer‐stabilized Au nano clusters (NCs) with mean diameters of 2–10 nm exhibit unique catalytic properties. Several studies have shown that the key factors affecting the catalytic activity of poly‐mer‐stabilized Au NCs are control of the Au NC size, appropriate selection of polymers and optimi‐zation of the reaction conditions. This is because polymer‐stabilized Au NCs exhibit a clear size effect in several catalytic reactions, and the catalytic activity differs with the type of polymer used and the reaction conditions. In order to elucidate the reason underlying the catalytic activity of the polymer‐stabilized Au NCs, much attention is being devoted to the interplay of theoretical calcula‐tions and experiments in catalysis by polymer stabilized Au NCs. The present article mainly summa‐rizes our progress in understanding this interplay in polymer‐stabilized Au NC catalysis.展开更多
The crossflow instability of a three-dimensional (3-D) boundary layer is an important factor which affects the transition over a swept-wing.In this report,the primary instability of the incompressible flow over a swep...The crossflow instability of a three-dimensional (3-D) boundary layer is an important factor which affects the transition over a swept-wing.In this report,the primary instability of the incompressible flow over a swept wing is investigated by solving nonlinear parabolized stability equations (NPSE).The Floquet theory is applied to study the dependence of the secondary and high-frequency instabilities on curvature,Reynolds number and angle of swept (AOS).The computational results show that the curvature in the present case has no significant effect on the secondary instabilities.It is generally believed that the secondary instability growth rate increases with the magnitude of the nonlinear mode of crossflow vortex.But,at a certain state,when the Reynolds number is 3.2 million,we find that the secondary instability growth rate becomes smaller even when the magnitude of the nonlinear mode of the crossflow vortex is larger.The effect of the angle of swept at 35,45 and 55 degrees,respectively,is also studied in the framework of the secondary linear stability theory.Larger angles of swept tend to decrease the spanwise spacing of the crossflow vortices,which correspondingly helps the stimulation of 'z' mode.展开更多
The crossflow instability of a three-dimensional boundary layer is a main factor affecting the transition around the swept-wing.The three-dimensional boundary layer flow affected by the saturated crossflow vortex is v...The crossflow instability of a three-dimensional boundary layer is a main factor affecting the transition around the swept-wing.The three-dimensional boundary layer flow affected by the saturated crossflow vortex is very sensitive to the high frequency disturbances,which foreshadows that the swept wing flow transition will happen.The primary instability of the compressible flow over a swept wing is investigated with nonlinear parabolized stability equations (NPSE).The Floquet theory is then applied to the analysis of the influence of localized steady suction on the secondary instability of crossflow vortex.The results show that suction can significantly suppress the growth of the crossflow mode as well as the secondary instability modes.展开更多
Nonlinear parabolized stability equations are employed in this work to investigate the nonlinear development of the G6rtler insta- bility up to the saturation stage. The perturbed boundary layer is highly inflectional...Nonlinear parabolized stability equations are employed in this work to investigate the nonlinear development of the G6rtler insta- bility up to the saturation stage. The perturbed boundary layer is highly inflectional both in the normalwise and spanwise directions and receptive to the secondary instabilities. The Floquet theory is applied to solve the fundamental, subharmonic and detuned secondary instabilities. With the Gortler-vortices-distorted base flow, two classes of secondary disturbances, i.e. odd modes and even modes, are identified according to the eigenfunctions of the disturbances. These modes may result in different patterns in the late stages of the transition process. Li and Malik [ 1 ] have shown the sinuous and varicose types of breakdown originating from the odd and even modes. The current study focuses on the four most amplified modes termed the even modes I & Ⅱ and odd modes I & lI. Odd mode II was missing in the work of Li and Malik [1] probably due to their inviscid simplifeation. The detuned modes are confirmed to be less amplifed than the fundamental (for the odd mode I) and subharmonic modes (for even modes I & II and the odd mode II).展开更多
The polarizabilities and hyperpolarizabilities of the tetrahydropyrrole diradical in different electronic states have been investigated using ab initio and density functional theory (DFT) methods combined with the f...The polarizabilities and hyperpolarizabilities of the tetrahydropyrrole diradical in different electronic states have been investigated using ab initio and density functional theory (DFT) methods combined with the finite field (FF) approach. The polarizability average value as is a maximum for the singlet state, while that for the closed-shell is a minimum. The trend in second hyperpolarizability average value yis in good agreement with that for as The yvalues of the singlet and triplet states are, respectively, about 3 and 2 times larger than that of the closed-shell. The order of the first hyperpolarizability total effective value βtot is βot (closed shell) βtot (singlet) 〉 βtot (triplet). The as, βtot, and 7 values of different electronic states obtained using the B3LYP and MP4SDQ methods are close to those obtained using the reliable CCSD method. The nonlinear optical (NLO) properties of two systems isoelectronic with the tetrahydropyrrole diradical-cyclopentane and tetrahydrofuran diradicalsshow that the polarizabilities and hyperpolarizabilities of these systems are all smaller than those of the tetrahydropyrrole diradical in the three electronic states.展开更多
Integrated pest management (IPM) is a long-term management strategy and has been proved to be more effective in pest control. To well-understand the mechanism and effect of the action of IPM, the geometric theory of...Integrated pest management (IPM) is a long-term management strategy and has been proved to be more effective in pest control. To well-understand the mechanism and effect of the action of IPM, the geometric theory of the involved semi-continuous dynamic systems is becoming more and more important. In this work, a geometric approach is applied to analyze the stability of the positive order-one periodic solution in semi-continuous dynamic systems. A stability criterion to test the stability of the order-one periodic solution is established. As an application, a stage-structure model involved chemical control is presented to show the efficiency of the proposed method. The sufficient conditions to insure the existence of the periodic solution are provided. In addition, the number and the stability of the periodic solutions are discussed accordingly. The simulations are carried out to verify the results.展开更多
The quasinormal mode frequencies can be understood from the massless particles trapped at the unstable circular null geodesics and slowly leaking out to infinity. Based on this viewpoint, in this paper, we semiclassic...The quasinormal mode frequencies can be understood from the massless particles trapped at the unstable circular null geodesics and slowly leaking out to infinity. Based on this viewpoint, in this paper, we semiclassically construct the entropy spectrum of the static and stationary black holes from the null geodesics. The result shows that the spacing of the entropy spectrum only depends on the property of the black hole in the eikonal limit. Moreover, for a black hole far from the extremal case, the spacing is found to be smaller than 2π for any dimension, which is very different from the result of the previous work by using the usual quasinormal mode frequencies.展开更多
基金Supported by the National Basic Research Program of China (2009CB623406), the National Natural Science Foundation of China (20636020), the National High Technology Research and Development Program of China (2006AA030204) and the Specialized Research Fund for the Doctoral Program of Higher Education of China (20060291003).
文摘According to the configuration,mixed-conducting membranes are classified as symmetric membranes and asymmetric membranes consisting of a thin dense layer and a porous support.In this study,these two kinds of SrCo0.4Fe0.5Zr0.1O3-δ oxide-based membranes were systematically compared in terms of oxygen permeability and chemical stability,and their differences were elucidated by means of the theoretical calculation.For the oxygen permeability,the asymmetric membrane was greater than the symmetric membrane due to the significant decrease of bulk diffusion resistance in the thin dense layer of the asymmetric membrane.In regard to the chemical stability,the increase of oxygen partial pressure on the asymmetric membrane surface at CH4 side produced the stable time of over 1032h in partial oxidation of methane at 1123K,while the symmetric membrane was only of 528h.This study demonstrated that the asymmetric membrane was a promising geometrical configuration for the practical application.
基金the National Natural Science Foundation of China (No. 50708094)the Hi-Tech Research and Development Program (863) of China (No. 2007AA11Z216)
文摘This paper is concerned with the issue of stabilization for the linear neutral systems with mixed delays. The attention is focused on the design of output feedback controllers which guarantee the asymptotical stability of the closed-loop systems. Based on the model transformation of neutral type, the Lyapunov-Krasovskii functional method is employed to establish the delay-dependent stability criterion. Then, through the controller parameterization and some matrix transformation techniques, the desired parameters are determined under the delay-dependent design condition in terms of linear matrix inequalities (LMIs), and the desired controller is explicitly formulated. A numerical example is given to illustrate the effectiveness of the proposed method.
文摘In this paper, the global existence of weak s olutions to the initial boundary value problem for Boltzmann-Poisson system is proved. The proof is based on the regularization and the stability of the veloci ty averages and the compactness results on L 1-theory.
基金Project(12511109) supported by the Science and Technology Studies Foundation of Heilongjiang Educational Committee of 2011, China
文摘The robust guaranteed cost sampled-data control was studied for a class of uncertain nonlinear systems with time-varying delay. The parameter uncertainties are time-varying norm-bounded and appear in both the state and the input control matrices. By applying an input delay approach, the system was transformed into a continuous time-delay system. Attention was focused on the design of a robust guaranteed cost sampled-data control law which guarantees that the closed-loop system is asymptotically stable and the quadratic performance index is less than a certain bound for all admissible uncertainties. By applying Lyapunov stability theory, the theorems were derived to provide sufficient conditions for the existence of robust guaranteed cost sampled-data control law in the form of linear matrix inequalities (LMIs), especially an optimal state-feedback guaranteed cost sampled-data control law which ensures the minimization of the guaranteed cost was given. The effectiveness of the proposed method was illustrated by a simulation example with the asymptotically stable curves of system state under the initial condition of x(0)=[0.679 6 0].
基金supported by Japan Science and Technology Agency (JST)Advanced Low Carbon Technology Research and Development Program (ALCA)Core Research for Evolutional Science and Technology (CREST)
文摘Polymer‐stabilized Au nano clusters (NCs) with mean diameters of 2–10 nm exhibit unique catalytic properties. Several studies have shown that the key factors affecting the catalytic activity of poly‐mer‐stabilized Au NCs are control of the Au NC size, appropriate selection of polymers and optimi‐zation of the reaction conditions. This is because polymer‐stabilized Au NCs exhibit a clear size effect in several catalytic reactions, and the catalytic activity differs with the type of polymer used and the reaction conditions. In order to elucidate the reason underlying the catalytic activity of the polymer‐stabilized Au NCs, much attention is being devoted to the interplay of theoretical calcula‐tions and experiments in catalysis by polymer stabilized Au NCs. The present article mainly summa‐rizes our progress in understanding this interplay in polymer‐stabilized Au NC catalysis.
基金supported by the National Natural Science Foundation of China(Grant Nos. 90505005 and 10932005)
文摘The crossflow instability of a three-dimensional (3-D) boundary layer is an important factor which affects the transition over a swept-wing.In this report,the primary instability of the incompressible flow over a swept wing is investigated by solving nonlinear parabolized stability equations (NPSE).The Floquet theory is applied to study the dependence of the secondary and high-frequency instabilities on curvature,Reynolds number and angle of swept (AOS).The computational results show that the curvature in the present case has no significant effect on the secondary instabilities.It is generally believed that the secondary instability growth rate increases with the magnitude of the nonlinear mode of crossflow vortex.But,at a certain state,when the Reynolds number is 3.2 million,we find that the secondary instability growth rate becomes smaller even when the magnitude of the nonlinear mode of the crossflow vortex is larger.The effect of the angle of swept at 35,45 and 55 degrees,respectively,is also studied in the framework of the secondary linear stability theory.Larger angles of swept tend to decrease the spanwise spacing of the crossflow vortices,which correspondingly helps the stimulation of 'z' mode.
基金supported by the National Natural Science Foundation of China (Grant Nos. 90505005 and 10932005)
文摘The crossflow instability of a three-dimensional boundary layer is a main factor affecting the transition around the swept-wing.The three-dimensional boundary layer flow affected by the saturated crossflow vortex is very sensitive to the high frequency disturbances,which foreshadows that the swept wing flow transition will happen.The primary instability of the compressible flow over a swept wing is investigated with nonlinear parabolized stability equations (NPSE).The Floquet theory is then applied to the analysis of the influence of localized steady suction on the secondary instability of crossflow vortex.The results show that suction can significantly suppress the growth of the crossflow mode as well as the secondary instability modes.
基金supported by the National Natural Science Foundation of China(Grant Nos.10932005 and 11202115)
文摘Nonlinear parabolized stability equations are employed in this work to investigate the nonlinear development of the G6rtler insta- bility up to the saturation stage. The perturbed boundary layer is highly inflectional both in the normalwise and spanwise directions and receptive to the secondary instabilities. The Floquet theory is applied to solve the fundamental, subharmonic and detuned secondary instabilities. With the Gortler-vortices-distorted base flow, two classes of secondary disturbances, i.e. odd modes and even modes, are identified according to the eigenfunctions of the disturbances. These modes may result in different patterns in the late stages of the transition process. Li and Malik [ 1 ] have shown the sinuous and varicose types of breakdown originating from the odd and even modes. The current study focuses on the four most amplified modes termed the even modes I & Ⅱ and odd modes I & lI. Odd mode II was missing in the work of Li and Malik [1] probably due to their inviscid simplifeation. The detuned modes are confirmed to be less amplifed than the fundamental (for the odd mode I) and subharmonic modes (for even modes I & II and the odd mode II).
基金supported by the National Natural Science Foundation of China (20873017)the Program for Changjiang Scholars and Innovative Research Teams in University (IRT0714)
文摘The polarizabilities and hyperpolarizabilities of the tetrahydropyrrole diradical in different electronic states have been investigated using ab initio and density functional theory (DFT) methods combined with the finite field (FF) approach. The polarizability average value as is a maximum for the singlet state, while that for the closed-shell is a minimum. The trend in second hyperpolarizability average value yis in good agreement with that for as The yvalues of the singlet and triplet states are, respectively, about 3 and 2 times larger than that of the closed-shell. The order of the first hyperpolarizability total effective value βtot is βot (closed shell) βtot (singlet) 〉 βtot (triplet). The as, βtot, and 7 values of different electronic states obtained using the B3LYP and MP4SDQ methods are close to those obtained using the reliable CCSD method. The nonlinear optical (NLO) properties of two systems isoelectronic with the tetrahydropyrrole diradical-cyclopentane and tetrahydrofuran diradicalsshow that the polarizabilities and hyperpolarizabilities of these systems are all smaller than those of the tetrahydropyrrole diradical in the three electronic states.
文摘Integrated pest management (IPM) is a long-term management strategy and has been proved to be more effective in pest control. To well-understand the mechanism and effect of the action of IPM, the geometric theory of the involved semi-continuous dynamic systems is becoming more and more important. In this work, a geometric approach is applied to analyze the stability of the positive order-one periodic solution in semi-continuous dynamic systems. A stability criterion to test the stability of the order-one periodic solution is established. As an application, a stage-structure model involved chemical control is presented to show the efficiency of the proposed method. The sufficient conditions to insure the existence of the periodic solution are provided. In addition, the number and the stability of the periodic solutions are discussed accordingly. The simulations are carried out to verify the results.
基金supported by the National Natural Science Foundation of China(Grant Nos.1120507411375075 and 11522541)the Fundamental Research Funds for the Central Universities(Grant No.lzujbky-2015-jl01)
文摘The quasinormal mode frequencies can be understood from the massless particles trapped at the unstable circular null geodesics and slowly leaking out to infinity. Based on this viewpoint, in this paper, we semiclassically construct the entropy spectrum of the static and stationary black holes from the null geodesics. The result shows that the spacing of the entropy spectrum only depends on the property of the black hole in the eikonal limit. Moreover, for a black hole far from the extremal case, the spacing is found to be smaller than 2π for any dimension, which is very different from the result of the previous work by using the usual quasinormal mode frequencies.