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用稳定态处理法求反应的级数
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作者 梅燕 《邢台师范高专学报》 1996年第4期82-84,共3页
在复合反应动力学中,我们很难求得反应的速率与反应的级数.因为复合反应是由几个简单的反应组合而成的,而且组合并不是简单的反应加合.因此,要想求出复合反应的级数是非常困难的.为此,我们常采用一些近似的方法来处理复合反应.最常用的... 在复合反应动力学中,我们很难求得反应的速率与反应的级数.因为复合反应是由几个简单的反应组合而成的,而且组合并不是简单的反应加合.因此,要想求出复合反应的级数是非常困难的.为此,我们常采用一些近似的方法来处理复合反应.最常用的近似处理法为稳定态处理法.稳定态处理法即假设中间产物的生成速率和消耗速率近似相等的处理方法.例如对反应A(?)B(?)C,反应进行一段时间后,中间产物B有可能实现近似稳定态,即B的生成速率与消耗速率相差甚微,几乎可以忽略不计,用数学表达式为:d[B]/dt=k_1[A]-k_2[B]=0显然稳定态处理法只能用于开放的流动体系,对于封闭的反应体系则不能使用;另外,稳定态处理法必须应用到中间产物上,而且该产物非常活泼,其浓度很小.那么,我们如何把稳定态处理法应用到反应中去呢?举例如下:对于反应:H_2+Cl_2→2HCl遵照简单反应的质量作用定律,其速率公式可表达为:d[HCL]/dt=k·[H_2][Cl_2] 展开更多
关键词 化学反应 动力学 稳定处理 级数
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道路冻胀破坏的机理与防治 被引量:1
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作者 崔岩 赵洪波 闫淑杰 《中国公路.建设市场专刊》 2004年第11期87-87,共1页
在我国北方寒冷地区.冻胀现象已经成为道路产生破坏的一种主要形式。而春融期,由于路基土中冰晶体的融解,会导致土基或垫层承载力降低而产生翻浆等现象,使道路出现严重病害。
关键词 道路冻胀 置换 隔温 稳定处理法 防治措施
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Preconditioned BiCGSTAB algorithm and its applications to eddy current solutions 被引量:1
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作者 朱发熙 余海涛 胡敏强 《Journal of Southeast University(English Edition)》 EI CAS 2009年第3期362-366,共5页
A new favorable iterative algorithm named as PBiCGSTAB (preconditioned bi-conjugate gradient stabilized) algorithm is presented for solving large sparse complex systems. Based on the orthogonal list, the special tec... A new favorable iterative algorithm named as PBiCGSTAB (preconditioned bi-conjugate gradient stabilized) algorithm is presented for solving large sparse complex systems. Based on the orthogonal list, the special technique of only storing non-zero elements is carried out. The incomplete LU factorization without fill-ins is adopted to reduce the condition number of the coefficient matrix. The BiCGSTAB algorithm is extended from the real system to the complex system and it is used to solve the preconditioned complex linear equations. The locked-rotor state of a single-sided linear induction machine is simulated by the software programmed with the finite element method and the PBiCGSTAB algorithm. Then the results are compared with those from the commercial software ANSYS, showing the validation of the proposed software. The iterative steps required for the proposed algorithm are reduced to about one-third, when compared to the BiCG method, therefore the algorithm is fast. 展开更多
关键词 preconditioned bi-conjugate gradient stabilized BiCGSTAB algorithm incomplete LU decomposition orthogonal list finite dement method(FEM) eddy current
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One-step post-synthesis treatment for preparing hydrothermally stable hierarchically porous ZSM-5 被引量:5
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作者 Jian Ding Teng Xue +1 位作者 Haihong Wu Mingyuan He 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2017年第1期48-57,共10页
Hierarchically porous ZSM‐5 (SiO2/Al2O3 ≈ 120) containing phosphorus was prepared by a one‐step post‐synthesis treatment involving controlled desilication and phosphorous modification. The hierarchically porous ZS... Hierarchically porous ZSM‐5 (SiO2/Al2O3 ≈ 120) containing phosphorus was prepared by a one‐step post‐synthesis treatment involving controlled desilication and phosphorous modification. The hierarchically porous ZSM‐5 featured high thermal and hydrothermal stability. The obtained ZSM‐5zeolites were systematically characterized by X‐ray diffraction, scanning electron microscopy,transmission electron microscopy, N2 adsorption‐desorption, NH3 temperature‐programmed desorption,and 27Al and 31P magic‐angle spinning nuclear magnetic resonance spectroscopy. Theprepared ZSM‐5 displayed enhanced activity and prolonged lifetime toward hydrocarbon cracking.The high activity was attributed to improved coke tolerance owing to the presence of the highlystable mesoporous network of ZSM‐5 and acid sites introduced upon phosphorus modification.Additionally a mechanism of the stabilization of the zeolites by phosphorus was proposed and discussed. 展开更多
关键词 DESILICATION Phosphorus stabilization One‐step modification Hydrothermal stability Hydrocarbon cracking
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层流扩散燃烧在GPU上的并行计算和数值分析
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作者 魏浩洋 曾国荪 丁春玲 《计算机应用》 CSCD 北大核心 2013年第9期2428-2431,2435,共5页
在实际工程应用中,使用传统的CPU串行计算来开展燃烧数值模拟往往难以满足对模拟速度的要求。利用GPU比CPU更强的计算能力,通过在交错网格上将燃烧物理方程离散化,使用预处理稳定双共轭梯度法(PBiCGSTAB)求解离散化方程,并且探索面向GP... 在实际工程应用中,使用传统的CPU串行计算来开展燃烧数值模拟往往难以满足对模拟速度的要求。利用GPU比CPU更强的计算能力,通过在交错网格上将燃烧物理方程离散化,使用预处理稳定双共轭梯度法(PBiCGSTAB)求解离散化方程,并且探索面向GPU编程的矩阵向量乘并行算法和逆矩阵向量乘并行算法,从而给出一种在GPU上数值求解层流扩散燃烧的可行方法。实验结果表明,GPU并行程序获得了相对串行CPU程序约10倍以上的加速效果,且计算结果与实际情况相符,因而所提方法是可行且高效的。 展开更多
关键词 层流扩散燃烧 数值模拟 GPU并行计算 处理稳定双共轭梯度 加速比
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Improving plasticity of the Zr46Cu46Al8 bulk metallic glass via thermal rejuvenation 被引量:9
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作者 Wenli Song Xiaohe Meng +5 位作者 Yuan Wu Di Cao Hui Wang Xiongjun Liu Xianzhen Wang Zhaoping Lu 《Science Bulletin》 SCIE EI CSCD 2018年第13期840-844,共5页
In this paper, effects of cryogenic thermal cycling on deformation behavior and thermal stability of the Zr46Cu46AI8 bulk metallic glass (BMG) were studied. The results show that with the increase of the number of c... In this paper, effects of cryogenic thermal cycling on deformation behavior and thermal stability of the Zr46Cu46AI8 bulk metallic glass (BMG) were studied. The results show that with the increase of the number of cryogenic thermal cycles (CTC), thermal stability remains almost unchanged, while the plasticity is increased, indicating that the cryogenic thermal cyclic treatment is an effective way to improve plasticity of metallic glasses without distinctly deteriorating thermal stability. Our analysis suggests that the increase in the defect density resulted from the cryogenic thermal treatments are responsible for the plasticity increment. Variation of yield strength can be well interpreted from microstructural percolation which affected by both density and characteristic volume of the defect sites. 展开更多
关键词 Bulk metallic glasses Cryogenic thermal cycling Defect density PLASTICITY
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