Conventional Pd/γ-A12O3 methane sensors are easily poisoned in a sulfur-containing atmosphere, with a subsequent decrease in sensitivity and the working life of methane sensors. We mainly investigated the effect of n...Conventional Pd/γ-A12O3 methane sensors are easily poisoned in a sulfur-containing atmosphere, with a subsequent decrease in sensitivity and the working life of methane sensors. We mainly investigated the effect of nanotechnology and a cerium co-catalyst on the stability and anti-sulfur performance of methane sensors. In our experiment, an anti-sulfur methane sensor was prepared by immersing cerium-containing γ-alumina nanometer elements into a Pt-Pd bimetallic nanometer catalyst. The experi- ment about the sensitivity and stability performance of different catalytic methane sensors indicate that sensitivity, decreased by catalyst sulfur poisoning, is improved significantly by adding cerium to the vector. As well, the long-term operational stability of methane sensors increased significantly.展开更多
Three kinds of polymeric materials are taken as example for the verification of linear ex-trapolation method from unified master lines with reduced universal equations on creep and stress relaxation tests. The theoret...Three kinds of polymeric materials are taken as example for the verification of linear ex-trapolation method from unified master lines with reduced universal equations on creep and stress relaxation tests. The theoretical values of long-term mechanical behavior and lifetime for a cured epoxide, polypropylene, poly（methyl-methacrylate）, and SBR rubber are directly evaluated with the universal equations on reduced creep compliance and reduced stress relax-ation modulus and are compared with their predicted values by the linear extrapolation from the unified master lines of creep and stress relaxation. The results show that the theoretical values of dimensional stability, bearing ability and lifetime are in an excellent agreement with the predicted values, it shows that the linear extrapolation method is more simple and reliable. The dependences of long-term mechanical behaviors and lifetime on the different aging times are discussed.展开更多
The LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(Ni-rich NCM)cathode materials suffer from electrochemical performance degradation upon cycling due to detrimental cathode interface reactions and irreversible surface phase transiti...The LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(Ni-rich NCM)cathode materials suffer from electrochemical performance degradation upon cycling due to detrimental cathode interface reactions and irreversible surface phase transition when operating at a high voltage(≥4.5 V).Herein,a traditional carbonate electrolyte with lithium difluoro(oxalato)borate(Li DFOB)and tris(trimethylsilyl)phosphate(TMSP)as dual additives that can preferentially oxidize and decompose to form a stable F,B and Si-rich cathode-electrolyte interphase(CEI)that effectively inhibits continual electrolyte decomposition,transition metal dissolves,surface phase transition and gas generation.In addition,TMSP also removes trace H_(2)O/HF in the electrolyte to increase the electrolyte stability.Owing to the synergistic effect of Li DFOB and TMSP,the Li/LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) half cells exhibit the capacity retention 76.3%after 500 cycles at a super high voltage of 4.7 V,the graphite/LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)full cells exhibit high capacity retention of 82.8%after 500 cycles at 4.5 V,and Li/LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)pouch cells exhibit high capacity retention 94%after 200 cycles at 4.5 V.This work is expected to provide an effective electrolyte optimizing strategy compatible with high energy density lithium-ion battery manufacturing systems.展开更多
基金support for this work, provided by the National Natural Science Foundation of China (No60910005)
文摘Conventional Pd/γ-A12O3 methane sensors are easily poisoned in a sulfur-containing atmosphere, with a subsequent decrease in sensitivity and the working life of methane sensors. We mainly investigated the effect of nanotechnology and a cerium co-catalyst on the stability and anti-sulfur performance of methane sensors. In our experiment, an anti-sulfur methane sensor was prepared by immersing cerium-containing γ-alumina nanometer elements into a Pt-Pd bimetallic nanometer catalyst. The experi- ment about the sensitivity and stability performance of different catalytic methane sensors indicate that sensitivity, decreased by catalyst sulfur poisoning, is improved significantly by adding cerium to the vector. As well, the long-term operational stability of methane sensors increased significantly.
基金This work was supported by the National Natural Science Foundation of China （No.50973007）.
文摘Three kinds of polymeric materials are taken as example for the verification of linear ex-trapolation method from unified master lines with reduced universal equations on creep and stress relaxation tests. The theoretical values of long-term mechanical behavior and lifetime for a cured epoxide, polypropylene, poly（methyl-methacrylate）, and SBR rubber are directly evaluated with the universal equations on reduced creep compliance and reduced stress relax-ation modulus and are compared with their predicted values by the linear extrapolation from the unified master lines of creep and stress relaxation. The results show that the theoretical values of dimensional stability, bearing ability and lifetime are in an excellent agreement with the predicted values, it shows that the linear extrapolation method is more simple and reliable. The dependences of long-term mechanical behaviors and lifetime on the different aging times are discussed.
基金supported by the National Natural Science Foundation of China(52172201,51732005,51902118,and 52102249)China Postdoctoral Science Foundation(2019M662609 and 2020T130217)。
文摘The LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(Ni-rich NCM)cathode materials suffer from electrochemical performance degradation upon cycling due to detrimental cathode interface reactions and irreversible surface phase transition when operating at a high voltage(≥4.5 V).Herein,a traditional carbonate electrolyte with lithium difluoro(oxalato)borate(Li DFOB)and tris(trimethylsilyl)phosphate(TMSP)as dual additives that can preferentially oxidize and decompose to form a stable F,B and Si-rich cathode-electrolyte interphase(CEI)that effectively inhibits continual electrolyte decomposition,transition metal dissolves,surface phase transition and gas generation.In addition,TMSP also removes trace H_(2)O/HF in the electrolyte to increase the electrolyte stability.Owing to the synergistic effect of Li DFOB and TMSP,the Li/LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) half cells exhibit the capacity retention 76.3%after 500 cycles at a super high voltage of 4.7 V,the graphite/LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)full cells exhibit high capacity retention of 82.8%after 500 cycles at 4.5 V,and Li/LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)pouch cells exhibit high capacity retention 94%after 200 cycles at 4.5 V.This work is expected to provide an effective electrolyte optimizing strategy compatible with high energy density lithium-ion battery manufacturing systems.
