几种有机配体与硫酸亚铁的配合物稳定常数

采用电位滴定法、酸碱中和滴定法及分光光度法,对硫酸亚铁、间苯二酚、没食子酸、葡萄糖醛酸以及HCl和NaOH标准溶液浓度进行标定。在恒定离子强度(I=0.1)条件下,利用pH电位法测定了间苯二酚、没食子酸、葡萄糖醛酸3种配体,在不同温度(10、20、30℃)下的加质子常数及与FeSO4的配合物稳定常数。结果显示:没食子酸加质子常数最大;配体加质子常数及配合物稳定常数,均随温度的升高而降低;3种配体与FeSO4的配位能力差别较大,没食子酸(lgK1=10.72,10℃)>间苯二酚(lgK1=7.28,10℃)>葡萄糖醛酸(lgK1=2.43,10℃)。

高阶段大直径深孔采场稳定性影响因素分析及回采技术措施

安庆铜矿采用高阶段大直径深孔采矿法,回采阶段高度近120m。采场稳定是该采矿法成败的关键。影响采场稳定性的主要因素有矿岩特性、原岩应力、采场结构、回采顺序、充填强度及回采工艺技术等。对这些影响进行了分析,并介绍了回采的技术措施。

Determination of Stability Constants of Cadmium-Glycine Complexes by a Unified Treatment for Potentiometric and Polarographic Data

The cadmium（Ⅱ）-glycine system was studied by the two experimental techniques, ion sensitive electrode （ISE） and differential pulse polarography （DPP）, and the experimental data obtained were used by a unified mathematical treatment to calculate the complex stability constants. The combination of the two techniques is of many advantages as ISE can be performed at low [LT]：[MT] ratios and significantly higher [MT], whereas DPP could be used well at large [LT]：[MT] ratios and much smaller [MT]. This makes it possible to study a metal-ligand system in a relatively broader range of experimental conditions that, in turn, provides more information about the metakligand system of interest. Applying the unified mathematical treatment to the cadmium-glycine system, two new complexes MHL and ML2（OH） as well as three complexes ML, ML2 and ML3, reported in literatures, could be modeled and all their stability constants have been refined.

Stability constants of Sb^5+with Cl−and thermodynamics of Sb−S−Cl−H2O system involving complex behavior of Sb with Cl

The stability constants of Sb^5+with Cl−as well as thermodynamics of the Sb−S−Cl−H2O system were calculated.The stability constants of Sb5+with Cl−were obtained by theoretical calculations of the absorbance of a Sb5+-containing solution at different Cl^−concentrations,which was detected by spectrophotometric analysis at certain wavelengths of light(380 nm).The logarithmic values versus 10 of stability constants of Sb^5+with Cl−were 1.795,3.150,4.191,4.955,5.427 and 5.511,respectively,and partly filled the data gaps in the hydrometallurgy of antimony.The presence and distribution of pentavalent antimony compounds under different conditions were analyzed based on equilibrium calculations.Thermodynamic equilibrium calculations were performed for Sb−S−Cl−H2O system,which included the complex behavior of Sb with Cl,and the equilibrium equations of related reactions in this system were integrated into the potential−pH diagram.

Method of Calculation of Stability Constants of Fulvic Complexes on the Example of Copper

On the example of copper fulvate, it is discussed the method of calculation of stability constants of fulvic complexes. At pH = 8, the complex formation of copper（ll） ions with fulvic acids was studied by the solubility method. Fulvic acids were separated from the river Mtkvari by the adsorption-chromotographic method. The charcoal （BAU, Russia） was used as a sorbent. The suspension of copper（If） hydroxide was used as the solid phase, on which was added the increasing quantity of standard solution of fulvic acids. In diluted solutions, at pH = 8 the dominant form of copper（lI） is copper dihydroxo complex Cu（OH）^zO. It was established that in the Cu（OH）2 （solid）-Cu（OH）^20 （solution）-FA^2-H20 system, dominates copper dyhydroxo fulvate complex with the structure 1：1, [Cu（OH）2FA]^2. The average stability constant of copper dyhydroxo fulvate complex was calculated based on experimental data fl [Cu（OH）2FAJ^2 = 4.5× l0^5.

Comparative study on activating fly ash by quick lime and slaked lime: effects and kinetics

Lime, which is a frequently used activating agent of fly ash (FA), has two main states: slaked lime and quick lime. We studied the effects of slaked lime and quick lime on activating FA, and discussed their kinetics. The results show that slaked lime is more beneficial for activating FA than quick lime given the condition of equivalent CaO amount. The use of slaked lime has superiority in technology and economy on activating FA. Theoretical analysis revealed that the kinetic constant of the activation reaction using slaked lime is higher than using quick lime, credited to the better volume stability and fineness, and smaller water demand of slaked lime.

Inclusion behavior of oxybutynin with hydroxypropyl-β-cyclodextrin

Inclusion behavior of oxybutynin （OBN） with hydroxypropyl-β-cyclodextrin （HP-β-CD） was investigated by ultraviolet absorption spectrum and fluorescence spectrum. A reliable determination of the complex stoichiometry was provided by the continuous variation technique. Alcohol was added to further investigate the mechanism of the inclusion behavior. Thermodynamic constants AG, AH and AS for inclusion interaction of OBN and HP-β-CD were determined. The results show that host-guest complex with molar ratio of 1：1 is formed, and inclusion stability constant between OBN and HP-β-CD is 54.9 L/mol determined by ultraviolet spectrum and 11.1 L/mol determined by fluorescence spectrum. OBN has weak binding ability with HP-β-CD in aqueous solution （stability constant 〈102 L/mol） and addition of alcohol leads to a decrease of stability constant, which indicates that the hydrophobic force contributes to the inclusion process. AG, AH and AS are all less than zero, which indicates that the inclusion process is a spontaneous and exothermic process.

The Determination of Average Stability Constant of NickeI-FA Complex at pH = 8,0 by the Solubility Method

At pH = 8, the complex formation process of Ni（Ⅱ） ions with FA was studied by the solubility method. FA were separated from the river Mtkvari by the adsorption-chromotographic method. The charcoal （BAU, Russia） was used as a sorbent. The old suspension of Ni（Ⅱ） hydroxide was used as the solid phase, on which was added the increasing quantity of standard solution of FA. In diluted solutions, at pH = 8.0 the dominant form of Ni（Ⅱ） is nickel dihydroxocomplex Ni（OH）2^0. It was established that in the Ni（OH）2（solid）-Ni（OH）2^0（solution）-FA2-H20 system dominates nickel dyhydroxofulvate complex with the structure 1：1, [Ni（OH）2FA]2-. The average stability constant of nickel dyhydroxofulvate complex was calculated based on experimental data flNi（OH）2FA2＂ = 5.3 × 105.

Cosmological Constant and Stability of the Cosmological Models

The importance of cosmological constant for the cosmological models is given. The variations of the cosmological model for parameters and were discussed respectively. Near , the cosmological model is unstable with the change of , and near , the cosmological model is unstable with the change of . So when we consider the stable cosmological model, we must consider the nonzero cosmological constant.

Spectrophotometric Determination of Compex Formation of Cerium（Ⅲ） with 1-phenyl-2,3-dimethylpyrazolone-5-azo-4-pyrogallole in the Presence of Cetylpyridine Chloride

Complex formation of cerium （Ⅲ） with l-phenyl-2,3-dimethylpyrazolone-5-azo-4-pyrogallole （L） in the presence and absence ofcetylpyridine chloride （CPC） was investigated. Homogeneous CeL- and mixed ligand CeL-CPC compounds are formed at pH 6. Constants of stability of the complexes are （IgKD 5.15±0.02 （CeL）, 7.98±0.03 （CeL-CPC）. Ratio of reagents in composition of homogeneous is （1 ：2） and in different ligand it equals to （1：2：2）. Beer＇s law is observed in interval of concentration 1.12-11.2 μg/ml Ce. The technique for photometric determination of cerium was worked out in artificial mixture.

Swinging up a Real-Time Inverted Pendulum System

In this study, a real-time control of the cart inverted pendulum system was developed using Mamdani type Fuzzy Logic Controller. Swing-up and stabilization of the inverted pendulum were implemented directly in a Fuzzy Logic Controller. The fuzzy logic controller was designed in the Matlab-Simulink environment and applied into in a Quasar controller board. Swing-up algorithm brings the pendulum near to its inverted position in 5 seconds from downward position. External forces were applied on the inverted pendulum to test the robustness of the fuzzy logic controller under internal as well as external disturbances. The inverted pendulum system showed an acceptable robustness to the external and internal disturbances.

Magnetoelastic Instability in Ring-Shaped Molecule Magnets with Next-Nearest Neighbor Coupling

In considering next-nearest neighbor （NNN） coupling, we numerically investigate the magnetoelastic instability in ring-shaped mesoscopic antiferromagnetic Heisenberg spin 1/2 systems with spin-phonon interaction. The results indicate that, for antiferromagnetic NNN coupling J2, there may be a critical value J2^c, at which the ground state is dimerized for arbitrary lattice spring constant and beyond and below which the magnetoelastic instability behavior is different from each other. The values of J2^c are irrelevant to the system size. For ferromagnetic NNN coupling, only continuous transition is present from dimerized phase to uniform phase as lattice spring constant is increased.

Relaxation of Magnetic Nanoparticle Chain without Applied Field

The relaxation of a one-dimensional magnetic nanoparticle linear chain with lattice constant a is investigated in absence of applied field. There is an equilibrium state （or steady state） where a11 magnetic moments of particles lie along the chain （x-axis）, back to which the magnetic nanoparticle chain at other state will relax. It is found that the relaxation time T= is determined by Tx = 10β×α3. This relaxation is compared with that of single magnetic nanoparticle system.

Regular Black Holes with Cosmological Constant

We present a class of regular black holes with cosmological constant A in nonlinear electrodynamics. Instead of usual singularity behind black hole horizon, all fields and curvature invariants are regular everywhere for the regular black holes. Through gauge invariant approach, the linearly dynamical stability of the regular black hole is studied. In odd-parity sector, we find that the A term does not appear in the master equations of perturbations, which shows that the regular black hole is stable under odd-parity perturbations. On the other hand, for the even-parity sector, the master equations are more complicated than the case without the cosmological constant. We obtain the sufficient conditions for stability of the regular black hole. We also investigate the thermodynamic properties of the regular black hole. and find that those thermodynamic quantities do not satisfy the differential form of first law of black hole thermodynamics. The reason for violating the first law is revealed.

Output feedback robust model predictive control with unmeasurable model parameters and bounded disturbance

The output feedback model predictive control(MPC),for a linear parameter varying(LPV) process system including unmeasurable model parameters and disturbance(all lying in known polytopes),is considered.Some previously developed tools,including the norm-bounding technique for relaxing the disturbance-related constraint handling,the dynamic output feedback law,the notion of quadratic boundedness for specifying the closed-loop stability,and the ellipsoidal state estimation error bound for guaranteeing the recursive feasibility,are merged in the control design.Some previous approaches are shown to be the special cases.An example of continuous stirred tank reactor(CSTR) is given to show the effectiveness of the proposed approaches.

The Study of the Influence of Load＇s Chemical Composition in the Coking Process on the Efficiency and the Quality of Coke

This research was performed in order to allow the study of the chemical composition influence of the coking process load on the efficiency and the quality of coke. For this reason, the coking of the following loads was realized： Atmospheric residue （RAT）, vacuum Residue （RSV） and catalytic Residue of cracking （RCC）. （The residues are obtained from an Algerian crude oil）. As the oil residues are rich for their strongly polar composition, such as the asphaltene resins, and complex structures units （SCU）, which has a role in the formation of coke, and as the dispersion of these latter improves the quality of coke, a study on the stability of aggregation was carried out by the addition of one stabilizer （oil Extract） in the coking process load, The Compounding （Extracted from/RCC oil） has been drived to the best efficiency of coke. The study consists of the influence this is characterized by the analyses Infra-red （IR） and x-ray diffraction （XRD）.

Dynamic interaction analysis and pairing evaluation in control configuration design

This paper presents some new dynamic interaction analysis approaches for square or non-square systems and a pairing evaluation method. For square stable systems, an open-loop approach is proposed, which features the tradeoff between the contributions of response time constant and delay time to relative gain. For non-square stable systems, an extension from the proposed open-loop approach for square systems is presented and the corresponding pairing procedure is given. No interaction analysis approach is perfect for all systems, so any recommended pairing needs to be examined. An evaluation method is proposed in closed-loop with optimal controllers for each loop and whether the pairing is appropriate can be evaluated through testing if the equivalent relative gain is within defined scope. The advantages and effectiveness of proposed interaction analysis approaches and pairing evaluation method are highlighted via several examples of industrial processes.

Stability and Boundedness of Retarded Liénard-type Equation

This paper aims to investigate the retarded Liénard-type equation+f 1(x)+f 2(x)(t-τ)+f 3(x)2+φ(x)+g(x(t-τ))=0,where τ is a nonnegative constant, f 1,f 2,f 3,φ and g are continuous functions on R. Using Liapunov functional method, we establish a sufficient condition on the stability and boundedness of the solutions of above equation. This will generalize the main results of reference [2].

Analysis of stable components for extended-range (10-30 days) weather forecast:A case study of continuous overcast-rainy process in early 2009 over the mid-lower reaches of the Yangtze River

A continuous overcast-rainy weather(CORW) process occurred over the mid-lower reaches of the Yangtze River(MLRYR) in China from February 14 to March 9 in 2009,with a large stretch and long duration that was rarely seen in historical records.Using the empirical orthogonal function(EOF),we analyzed the geopotential height anomaly field of the NCEP-DOE Reanalysis II in the same period,and defined the stable components of extended-range(10-30 days) weather forecast(ERWF).Furthermore,we defined anomalous and climatic stable components based on the variation characteristics of the variance contribution ratio of EOF components.The climatic stable components were able to explain the impact of climatically averaged information on the ERWF,and the anomalous stable components revealed the abnormal characteristics of the continuous overcast-rainy days.Our results show that the stable components,especially the anomalous stable components,can maintain the stability for a longer time(more than 10 days) and manifest as monthly scale low-frequency variation and ultra-long-wave activities.They also behave as ultra-long waves of planetary scale with a stable and vertically coherent structure,reflect the variation of general circulation in mid-high latitudes,display the cycle of the zonal circulation and the movement and adjustment of the ultra-long waves,and are closely linked to the surface CORW process.

INVARIANT DENSITY, LYAPUNOV EXPONENT, AND ALMOST SURE STABILITY OF MARKOVIAN-REGIME-SWITCHING LINEAR SYSTEMS

This paper is concerned with stability of a class of randomly switched systems of ordinary differential equations. The system under consideration can be viewed as a two-component process （X（t）, α（t））, where the system is linear in X（t） and α（t） is a continuous-time Markov chain with a finite state space. Conditions for almost surely exponential stability and instability are obtained. The conditions are based on the Lyapunov exponent, which in turn, depends on the associate invaxiant density. Concentrating on the case that the continuous component is two dimensional, using transformation techniques, differential equations satisfied by the invariant density associated with the Lyapunov exponent are derived. Conditions for existence and uniqueness of solutions are derived. Then numerical solutions are developed to solve the associated differential equations.