In order to study the effect of time lag and stress loading rates on rock deformation,the conventional stepped stress loading mode was changed into a continuous mode to investigate the effect of effective pressure on ...In order to study the effect of time lag and stress loading rates on rock deformation,the conventional stepped stress loading mode was changed into a continuous mode to investigate the effect of effective pressure on permeability and porosity.The time lag effect of rock deformation illustrating the relationship between changes in permeability and steady time was studied.Permeability reduction ratios were measured under different stress loading rates which were achieved by different pump rate settings.The results show that permeability and porosity gradually decrease with increases in effective pressure.Permeability at high effective pressure attains stability quickly.Steady times at low effective pressure are very long.Reduction in permeability at lower stress loading rates is small,while,in contrast,it is large at high stress loading rates.展开更多
Shallow slope failures induced by rainfall infiltration occur frequently, and the relevant triggering mechanisms have been widely studied.Rainfall-induced landslides are widely recognized to be caused by increases in ...Shallow slope failures induced by rainfall infiltration occur frequently, and the relevant triggering mechanisms have been widely studied.Rainfall-induced landslides are widely recognized to be caused by increases in soil weight, seepage force and pore water pressure or decreases in soil mechanical properties. However, even when all these factors are considered, some landslides still cannot be explained well. The increased pore water pressure in a slope reduces the effective stress of the soil and may trigger slope failure. Similarly, the pore gas pressure in a slope also reduces the effective stress of the soil but has been neglected in previous studies. As the viscosity of air is nearly negligible when compared with that of water, the pore gas pressure spreads faster, and its influence is wider, which is harmful for the stability of the slope. In this paper, the effects of pore gas pressure are considered in a shallow slope stability analysis, and a self-designed experiment is conducted to validate the force transfer mechanism.Numerical simulation results show that the pore gas pressure in the slope increases sharply at different locations under heavy rainfall conditions and that the pore gas pressure causes a rapid decrease in the slope safety factor. Laboratory experimental results show that the pore gas pressure throughout the whole unsaturated zone has the same value, which indicates that the gas pressure could spread quickly to the whole sample.展开更多
The use of organic hole transport layer(HTL)Spiro-OMeTAD in various solar cells imposes serious stabil-ity and cost problems,and thus calls for inorganic substitute materials.In this work,a novel inorganic MnS film pr...The use of organic hole transport layer(HTL)Spiro-OMeTAD in various solar cells imposes serious stabil-ity and cost problems,and thus calls for inorganic substitute materials.In this work,a novel inorganic MnS film prepared by thermal evaporation has been demonstrated to serve as a decent HTL in high-performance Sb_(2)(S,Se)_(3)solar cells,providing a cost-effective all-inorganic solution.A low-temperature air-annealing process for the evaporated MnS layer was found to result in a significant positive effect on the power conversion efficiency(PCE)of Sb_(2)(S,Se)_(3)solar cells,due to its better-matched energy band alignment after partial oxidation.Impressively,the device with the optimized MnS HTL has achieved an excellent PCE of about 9.24%,which is the highest efficiency among all-inorganic Sb_(2)(S,Se)_(3)solar cells.Our result has revealed that MnS is a feasible substitute for organic HTL in Sb-based solar cells to achieve high PCE,low cost,and high stability.展开更多
Li^(+) solvation structures have a decisive influence on the electrode/electrolyte interfacial properties and battery performances.Reduced salt concentration may result in an organic rich solid electrolyte interface(S...Li^(+) solvation structures have a decisive influence on the electrode/electrolyte interfacial properties and battery performances.Reduced salt concentration may result in an organic rich solid electrolyte interface(SEI)and catastrophic cycle stability,which makes low concentration electrolytes(LCEs)rather challenging.Solvents with low solvating power bring in new chances to LCEs due to the weak salt-solvent interactions.Herein,an LCE with only 0.25 mol L^(-1) salt is prepared with fluoroethylene carbonate(FEC)and 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropylether(D_(2)).Molecular dynamics simulations and experiments prove that the low solvating power solvent FEC not only renders reduced desolvation energy to Li^(+) and improves the battery kinetics,but also promotes the formation of a LiF-rich SEI that hinders the electrolyte consumption.Li||Cu cell using the LCE shows a high coulombic efficiency of 99.20%,and LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)||Li cell also exhibits satisfying capacity retention of 89.93%in 200 cycles,which demonstrates the great potential of solvating power regulation in LCEs development.展开更多
Lithium-sulfur batteries have attracted increasing attention because of their high theoretical capadty. Using sulfur/carbon composites as the cathode materials has been demonstrated as an effective strategy to optimiz...Lithium-sulfur batteries have attracted increasing attention because of their high theoretical capadty. Using sulfur/carbon composites as the cathode materials has been demonstrated as an effective strategy to optimize sulfur utilization and enhance cycle stability as well. In this work hollow-in-hollow carbon spheres with hollow foam-like cores （HCSF@C） are prepared to improve both capability and cycling stability of lithium-sulfur batteries. With high surface area and large pore volumes, the loading of sulfur in HCSF@C reaches up to 70 wt.%. In the resulting S/HCSF@C composites, the outer carbon shell serves as an effective protection layer to trap the soluble polysulfide intermediates derived from the inner component. Consequently, the S/HCSF@C cathode retains a high capacity of 780 mAh/g after 300 cycles at a high charge/discharge rate of 1 A/g.展开更多
基金Projects 2008ZX05009-004 supported by the National Key Sci-Tech Major Special Item2006CB705805 by the National Basic Research Program of Chinasupported by the National Basic Research Program of China and "enhanced oil recovery basic theory for low permeability reservoirs" under grant 2002CCA00700
文摘In order to study the effect of time lag and stress loading rates on rock deformation,the conventional stepped stress loading mode was changed into a continuous mode to investigate the effect of effective pressure on permeability and porosity.The time lag effect of rock deformation illustrating the relationship between changes in permeability and steady time was studied.Permeability reduction ratios were measured under different stress loading rates which were achieved by different pump rate settings.The results show that permeability and porosity gradually decrease with increases in effective pressure.Permeability at high effective pressure attains stability quickly.Steady times at low effective pressure are very long.Reduction in permeability at lower stress loading rates is small,while,in contrast,it is large at high stress loading rates.
基金supported by National Key R&D Program of China (Grant No. 2017YFC1501100)the National Natural Science Foundation of China (Grant No. 51279090)Sponsored by Research Fund for Excellent Dissertation of China Three Gorges University
文摘Shallow slope failures induced by rainfall infiltration occur frequently, and the relevant triggering mechanisms have been widely studied.Rainfall-induced landslides are widely recognized to be caused by increases in soil weight, seepage force and pore water pressure or decreases in soil mechanical properties. However, even when all these factors are considered, some landslides still cannot be explained well. The increased pore water pressure in a slope reduces the effective stress of the soil and may trigger slope failure. Similarly, the pore gas pressure in a slope also reduces the effective stress of the soil but has been neglected in previous studies. As the viscosity of air is nearly negligible when compared with that of water, the pore gas pressure spreads faster, and its influence is wider, which is harmful for the stability of the slope. In this paper, the effects of pore gas pressure are considered in a shallow slope stability analysis, and a self-designed experiment is conducted to validate the force transfer mechanism.Numerical simulation results show that the pore gas pressure in the slope increases sharply at different locations under heavy rainfall conditions and that the pore gas pressure causes a rapid decrease in the slope safety factor. Laboratory experimental results show that the pore gas pressure throughout the whole unsaturated zone has the same value, which indicates that the gas pressure could spread quickly to the whole sample.
基金the Science and Technology Department of Hubei Province(2019AAA020)Wuhan Science and Technology Project of China(2019010701011420)+1 种基金Fundamental Research Funds for the Central University(2042021kf0069)the National Natural Science Foundation of China(61974028)。
文摘The use of organic hole transport layer(HTL)Spiro-OMeTAD in various solar cells imposes serious stabil-ity and cost problems,and thus calls for inorganic substitute materials.In this work,a novel inorganic MnS film prepared by thermal evaporation has been demonstrated to serve as a decent HTL in high-performance Sb_(2)(S,Se)_(3)solar cells,providing a cost-effective all-inorganic solution.A low-temperature air-annealing process for the evaporated MnS layer was found to result in a significant positive effect on the power conversion efficiency(PCE)of Sb_(2)(S,Se)_(3)solar cells,due to its better-matched energy band alignment after partial oxidation.Impressively,the device with the optimized MnS HTL has achieved an excellent PCE of about 9.24%,which is the highest efficiency among all-inorganic Sb_(2)(S,Se)_(3)solar cells.Our result has revealed that MnS is a feasible substitute for organic HTL in Sb-based solar cells to achieve high PCE,low cost,and high stability.
基金supported by the National Key Research and Development Program of China(2019YFA0705603)the National Natural Science Foundation of China(22078341)+1 种基金the Natural Science Foundation of Hebei Province(B2020103028)financial support from York University。
文摘Li^(+) solvation structures have a decisive influence on the electrode/electrolyte interfacial properties and battery performances.Reduced salt concentration may result in an organic rich solid electrolyte interface(SEI)and catastrophic cycle stability,which makes low concentration electrolytes(LCEs)rather challenging.Solvents with low solvating power bring in new chances to LCEs due to the weak salt-solvent interactions.Herein,an LCE with only 0.25 mol L^(-1) salt is prepared with fluoroethylene carbonate(FEC)and 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropylether(D_(2)).Molecular dynamics simulations and experiments prove that the low solvating power solvent FEC not only renders reduced desolvation energy to Li^(+) and improves the battery kinetics,but also promotes the formation of a LiF-rich SEI that hinders the electrolyte consumption.Li||Cu cell using the LCE shows a high coulombic efficiency of 99.20%,and LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)||Li cell also exhibits satisfying capacity retention of 89.93%in 200 cycles,which demonstrates the great potential of solvating power regulation in LCEs development.
基金We thank the National Basic Research Program of China （Nos. 2011CB932403 and 2015CB932300） and the National Natural Science Foundation of China （Nos. 21301144, 21390390, 21131005, 21333008, and 21420102001） for financial support.
文摘Lithium-sulfur batteries have attracted increasing attention because of their high theoretical capadty. Using sulfur/carbon composites as the cathode materials has been demonstrated as an effective strategy to optimize sulfur utilization and enhance cycle stability as well. In this work hollow-in-hollow carbon spheres with hollow foam-like cores （HCSF@C） are prepared to improve both capability and cycling stability of lithium-sulfur batteries. With high surface area and large pore volumes, the loading of sulfur in HCSF@C reaches up to 70 wt.%. In the resulting S/HCSF@C composites, the outer carbon shell serves as an effective protection layer to trap the soluble polysulfide intermediates derived from the inner component. Consequently, the S/HCSF@C cathode retains a high capacity of 780 mAh/g after 300 cycles at a high charge/discharge rate of 1 A/g.
