研究片钠铝石形成后保持稳定的pH值临界条件,对含片钠铝石砂岩展开了不同pH值条件下水-岩反应实验。结果表明:在封闭反应体系条件下,相同pH值(pH值为4)、不同体积(10、80、500 m L)条件下,随着反应溶液体积的增大,片钠铝石溶蚀程度增强...研究片钠铝石形成后保持稳定的pH值临界条件,对含片钠铝石砂岩展开了不同pH值条件下水-岩反应实验。结果表明:在封闭反应体系条件下,相同pH值(pH值为4)、不同体积(10、80、500 m L)条件下,随着反应溶液体积的增大,片钠铝石溶蚀程度增强,片钠铝石稳定性降低;相同体积(500 m L)、不同pH值(4<pH<9)条件下,pH值的增大对片钠铝石溶解速率影响不显著;pH值不是片钠铝石溶解程度发生改变的主控因素,在研究天然片钠铝石稳定性时,可以排除pH值造成的影响。展开更多
Microstructure stability of in situ synthesized Ti2AlN/Ti-48Al-2Cr-2Nb composite during aging at 900 ℃ was investigated by XRD, OM and TEM, and the unreinforced Ti-48Al-2Cr-2Nb alloy was also examined for comparison....Microstructure stability of in situ synthesized Ti2AlN/Ti-48Al-2Cr-2Nb composite during aging at 900 ℃ was investigated by XRD, OM and TEM, and the unreinforced Ti-48Al-2Cr-2Nb alloy was also examined for comparison. The result showed that in the TiAl alloy,α2 lamellae thinned and were broken down, and became discontinuous with increasing aging time. The decomposition ofα2 lamella toγ which was characterized by parallel decomposition and breakdown ofα2 lamellae led to the degradation of the lamellar structure. While in the composite, lamellar structure remained relatively stable even after aging at 900 ℃ for 100 h. No breakdown ofα2 lamellae except parallel decomposition and precipitation of fine nitride particles was observed. The better microstructural stability of the composite was mainly attributed to the precipitation of Ti2AlN particles at theα2/γ interface which played an important role in retarding the coarsening of lamellar microstructure in the matrix of composite.展开更多
The soil masses of slopes were assumed to follow a nonlinear failure criterion and a nonassociated flow rule.The stability factors of slopes were calculated using vertical slice method based on limit analysis.The pote...The soil masses of slopes were assumed to follow a nonlinear failure criterion and a nonassociated flow rule.The stability factors of slopes were calculated using vertical slice method based on limit analysis.The potential sliding mass was divided into a series of vertical slices as well as the traditional slice technique.Equating the external work rate to the internal energy dissipation,the optimum solutions to stability factors were determined by the nonlinear programming algorithm.From the numerical results,it is found that the present solutions agree well with previous results when the nonlinear criterion reduces to the linear criterion,and the nonassociated flow rule reduces to the associated flow rule.The stability factors decrease by 39.7%with nonlinear parameter varying from 1.0 to 3.0.Dilation and nonlinearity have significant effects on the slope stability factors.展开更多
Four fat and elongated(F&E)contents(0%,original,30%,and 40%)were investigated to evaluate the effects of F&Eparticles on the performance of porous asphalt mixture(P A).Laboratory tests including volumetric det...Four fat and elongated(F&E)contents(0%,original,30%,and 40%)were investigated to evaluate the effects of F&Eparticles on the performance of porous asphalt mixture(P A).Laboratory tests including volumetric determination,two-dimensional image analysis,Cantabro loss tests,breakdown tests,and permeability tests were conducted to evaluate the volumetric properties,the state of stone-onstone contact,durability,skeleton stability and permeability of PA,respectively.The test results indicate that the F&E content was a significant factor for total air voids,aggregate skeleton break down,and permeability.The functionality,rutting resistance,long-term durability,and skeleton stability decrease with the increase of F&E content since F&E aggregates in porous asphalt mixtures have a tendency to breakdown.Compared with traditional dense graded mixtures,PA is more sensitive to the F&E content due to an open graded aggregate structure.Therefore,the stricter requiement for F&E content should be met for porous asphalt mixtures than the one for traditional deese graded mixture.展开更多
Based on the slice method of the non-circular slip surface for the calculation of integral stability of slope, an improved genetic algorithm was proposed, which can freely search for the most dangerous slip surface of...Based on the slice method of the non-circular slip surface for the calculation of integral stability of slope, an improved genetic algorithm was proposed, which can freely search for the most dangerous slip surface of slope and the corresponding minimum safety factor without supposing the geometric shape of the most dangerous slip surface. This improved genetic algorithm can simulate the genetic evolution process of organisms and avoid the local minimum value compared with the classical methods. The results of engineering cases show that it is a global optimal algorithm and has many advantages, such as higher efficiency and shorter time than the simple genetic algorithm.展开更多
We determi:ned a suitable gate road layout in slice mining in an ultra-thick unstable coal seam, using theoretical anallysis and numerical calculations. Based on plasticity theory in terms of limiting equilibrium, th...We determi:ned a suitable gate road layout in slice mining in an ultra-thick unstable coal seam, using theoretical anallysis and numerical calculations. Based on plasticity theory in terms of limiting equilibrium, the width of chain pillar in the upper slice was calculated to be 18 m. The stress distribution in the chain pillar after the upper slice was mined out was described with numerical simulation. The extent of the effect of stress on the upper chain pillar on the lower solid coal was obtained on the basis of an elastic solution of a distributed force loaded on a half-plane. Three layout designs for lower gate roads were pro- posed and a stability factor was introduced to analyze the stability of the lower pillar with numerical calculation. Gate road translation was determined as the most suitable layout method, which maximizes the extraction rate on the basis of the pillar stability.展开更多
Palladium-supported cobalt hydroxide(Co(OH)_(2)-Pd) nanoplates were fabricated in an aqueous solution and employed as a catalyst for the reduction of 4-nitrophenol.For the preparation of Co(OH)2-Pd,Pd nanoparticles we...Palladium-supported cobalt hydroxide(Co(OH)_(2)-Pd) nanoplates were fabricated in an aqueous solution and employed as a catalyst for the reduction of 4-nitrophenol.For the preparation of Co(OH)2-Pd,Pd nanoparticles were anchored on the Co(OH)_(2) nanoplates after the reduction of Na;PdCl;by ascorbic acid in the absence of a stabilizer at room temperature.The observations under transmission and scanning electron microscopy reveal that Pd nanoparticles with a size of 2-5 nm are uniformly dispersed on the surface of the Co(OH)_(2) nanoplates.In catalytic test,the conversion of 4-nitrophenol to 4-aminophenol is completed within 6 min in the presence of Co(OH)_(2)-Pd(1000) nanoplates with2.18 at.% Pd,and the corresponding kinetic constant is 0.0089 s;in the first test.The catalyst retains relatively high activity after several cycles.The results demonstrate that the Co(OH)_(2)-Pd(1000) nanoplates exhibit high catalytic activity toward the reduction of 4-nitrophenol in the presence of NaBH;.展开更多
Spinel oxides containing Co and Ni are a promising substitute as a noble metal catalyst for methane combustion.Achieving a complete oxidation of methane under 400°C remains challenging,andhydrothermal 60 h NiClit...Spinel oxides containing Co and Ni are a promising substitute as a noble metal catalyst for methane combustion.Achieving a complete oxidation of methane under 400°C remains challenging,andhydrothermal 60 h NiClittle impact on activity,especially at high space velocities due to the long hydrothermal time with less absorbed oxygen species and crystal defects.Overall,these results help clarify methane activa-tion mechanisms and aid the development of more efficient low-cost catalysts.展开更多
Aptamers are molecular recognition elements with high specificity that are selected from deoxyribonucleic acid/ribonucleic acid (DNA/RNA) library. Compared with the traditional protein recognition elements,aptamers ha...Aptamers are molecular recognition elements with high specificity that are selected from deoxyribonucleic acid/ribonucleic acid (DNA/RNA) library. Compared with the traditional protein recognition elements,aptamers have excellent properties such as cost-effective,stable,easy for synthesis and modification. In recent years,electrochemistry plays an important role in biosensor field because of its high sensitivity,high stability, fast response and easy miniaturization. Through the combination of these two technologies and our rational design,we constructed a series of biosensors and biochips that are simple,fast,cheap and miniaturized. Firstly,we designed an adenosine triphosphate (ATP) electrochemical biosensor based on the strand displacement strategy. We can detect as low as 10 nmol/L of ATP both in pure solution and complicated cell lysates. Secondly,we creatively split the aptamers into two fragments and constructed the sandwich assay platform only based on single aptamer sequence. We successfully transferred this design on biochips with multiple micro electrodes (6×6) and accomplished multiplex detection. In the fields of biochips and biocomputers,we designed several DNA logic gates with electric (electrochemical) signal as output which paves a new way for the development of DNA computer.展开更多
To understand the effects of leaf physiological and morphological characteristics on δ13C of alpine trees, we examined leaf δ13C value, LA, SD, LNC, LPC, LKC, Chla+b, LDMC, LMA and Narea in one-year-old needles of P...To understand the effects of leaf physiological and morphological characteristics on δ13C of alpine trees, we examined leaf δ13C value, LA, SD, LNC, LPC, LKC, Chla+b, LDMC, LMA and Narea in one-year-old needles of Picea schrenkiana var. tianschanica at ten points along an altitudinal gradient from 1420 m to 2300 m a.s.l. on the northern slopes of the Tianshan Mountains in northwest China. Our results indicated that all the leaf traits differed significantly among sampling sites along the altitudinal gradient(P<0.001). LA, SD, LPC, LKC increased linearly with increasing elevation, whereas leaf δ13C, LNC, Chla+b, LDMC, LMA and Narea varied non-linearly with changes in altitude. Stepwise multiple regression analyses showed that four controlled physiological and morphological characteristics influenced the variation of δ13C. Among these four controlled factors, LKC was the most profound physiological factor that affected δ13C values, LA was the secondary morphological factor, SD was the third morphological factor, LNC was the last physiological factor. This suggested that leaf δ13C was directly controlled by physiological and morphological adjustments with changing environmental conditions due to the elevation.展开更多
The enhancement of energy density and cycling stability is in urgent need for the widespread applications of aqueous rechargeable Ni-Zn batteries.Herein,a facile strategy has been employed to construct hierarchical Co...The enhancement of energy density and cycling stability is in urgent need for the widespread applications of aqueous rechargeable Ni-Zn batteries.Herein,a facile strategy has been employed to construct hierarchical Co-doped NiMoO4nanosheets as the cathode for high-performance Ni-Zn battery.Benefiting from the merits of substantially improved electrical conductivity and increased concentration of oxygen vacancies,the NiMoO4with 15%cobalt doping(denoted as CNMO-15)displays the best capacity of 361.4 m A h g-1at a current density of 3 A g-1and excellent cycle stability.Moreover,the assembled CNMO-15//Zn battery delivers a satisfactory specific capacity of 270.9 mA h g-1at 2 A g-1and a remarkable energy density of 474.1 W h kg-1at 3.5 kW kg-1,together with a maximum power density of 10.3 kW kg-1achieved at 118.8 W h kg-1.Noticeably,there is no capacity decay with a 119.8%retention observed after 5000 cycles,demonstrating its outstanding long lifespan.This work might provide valuable inspirations for the fabrication of high-performance Ni-Zn batteries with superior energy density and impressive stability.展开更多
Unsteady numerical simulations of a high-load transonic turbine stage have been carried out to study the influences of vane trailing edge outer-extending shockwave on rotor blade leading edge film cooling performance....Unsteady numerical simulations of a high-load transonic turbine stage have been carried out to study the influences of vane trailing edge outer-extending shockwave on rotor blade leading edge film cooling performance. The turbine stage used in this paper is composed of a vane section and a rotor one which are both near the root section of a transonic high-load turbine stage. The Mach number is 0.94 at vane outlet, and the relative Mach number is above 1.10 at rotor outlet. Various positions and oblique angles of film cooling holes were investigated in this research. Results show that the cooling efficiency on the blade surface of rotor near leading edge is significantly affected by vane trailing edge outer-extending shockwave in some cases. In the cases that film holes are close to leading edge, cooling performance suffers more from the sweeping vane trailing edge outer-extending shockwave.In addition, coolant flow ejected from oblique film holes is harder to separate from the blade surface of rotor, and can cover more blade area even under the effects of sweeping vane trailing edge shockwave. As a result, oblique film holes can provide better film cooling performance than vertical film holes do near the leading edge on turbine blade which is swept by shockwaves.展开更多
The aim of this paper is to predict the phenomenon of laminar separation, transition and reattachment in a low-pressure turbine (LPT). Self-developed large eddy simulation program of compressible N-S equations was u...The aim of this paper is to predict the phenomenon of laminar separation, transition and reattachment in a low-pressure turbine (LPT). Self-developed large eddy simulation program of compressible N-S equations was used to describe the flow structures of T 106A LPT blade profile at Reynolds number of 1.1×10^5 based on the exit isentropic velocity and chord length. The com- putational results show the distributions of time-averaged wall-static pressure coefficient and mean skin-friction coefficient on the blade surface. The locations of laminar separation and reattachment points occur around 87% and 98% axial chord, which agree well with experiment data. The two-dimensional shear layer is gradually unstable along the downstream half of the suc- tion side as a result of the spanwise fluctuation and the roll up of shear layer via Kelvin-Helmholtz (KH) instability. Three-dimensional motions appear near 84% axial chord which later triggers spanwise vortexes and streamwise vortexes, leading to transition to turbulence in the separation bubble. Through introducing the concept of dissipation function, the high loss mainly comes from the places where strong shear layer and intense fluctuation exist. Furthermore, the separation region is only an accumulation center of the low-energy fluid rather than an area of loss source.展开更多
This paper treats the flow instabilities in a mixed flow pump with a vaned diffuser. Test pump has a positive slope of a head-flow performance curve at 65% flow rate of BEP (Best Efficiency Point) because of a rotatin...This paper treats the flow instabilities in a mixed flow pump with a vaned diffuser. Test pump has a positive slope of a head-flow performance curve at 65% flow rate of BEP (Best Efficiency Point) because of a rotating stall. Dynamic Particle Image Velocimetry (PIV) and pressure fluctuation measurements are used for investigating the propagation mechanism of a rotating stall. It was found that unstable performance was caused by periodical large scale abrupt backflow generated from the vaned diffuser to the outlet of impeller. Further, the relation between the static pressure at the inlet of diffuser vane and the internal flow condition was clarified. From these experimental results, in order to improve the positive slope of a head-flow performance curve, to suppress the growth of strong vortex toward the inlet of diffuser vane was proved to be a key point.展开更多
文摘研究片钠铝石形成后保持稳定的pH值临界条件,对含片钠铝石砂岩展开了不同pH值条件下水-岩反应实验。结果表明:在封闭反应体系条件下,相同pH值(pH值为4)、不同体积(10、80、500 m L)条件下,随着反应溶液体积的增大,片钠铝石溶蚀程度增强,片钠铝石稳定性降低;相同体积(500 m L)、不同pH值(4<pH<9)条件下,pH值的增大对片钠铝石溶解速率影响不显著;pH值不是片钠铝石溶解程度发生改变的主控因素,在研究天然片钠铝石稳定性时,可以排除pH值造成的影响。
基金Project(2011CB605502)supported by the National Basic Research Program of ChinaProject(B08040)supported by Introducing Talents of Discipline to Universities,China
文摘Microstructure stability of in situ synthesized Ti2AlN/Ti-48Al-2Cr-2Nb composite during aging at 900 ℃ was investigated by XRD, OM and TEM, and the unreinforced Ti-48Al-2Cr-2Nb alloy was also examined for comparison. The result showed that in the TiAl alloy,α2 lamellae thinned and were broken down, and became discontinuous with increasing aging time. The decomposition ofα2 lamella toγ which was characterized by parallel decomposition and breakdown ofα2 lamellae led to the degradation of the lamellar structure. While in the composite, lamellar structure remained relatively stable even after aging at 900 ℃ for 100 h. No breakdown ofα2 lamellae except parallel decomposition and precipitation of fine nitride particles was observed. The better microstructural stability of the composite was mainly attributed to the precipitation of Ti2AlN particles at theα2/γ interface which played an important role in retarding the coarsening of lamellar microstructure in the matrix of composite.
基金Project(200550)supported by the Foundation for the Author of National Excellent Doctoral Dissertation of ChinaProject(200631878557)supported by West Traffic of Science and Technology of China
文摘The soil masses of slopes were assumed to follow a nonlinear failure criterion and a nonassociated flow rule.The stability factors of slopes were calculated using vertical slice method based on limit analysis.The potential sliding mass was divided into a series of vertical slices as well as the traditional slice technique.Equating the external work rate to the internal energy dissipation,the optimum solutions to stability factors were determined by the nonlinear programming algorithm.From the numerical results,it is found that the present solutions agree well with previous results when the nonlinear criterion reduces to the linear criterion,and the nonassociated flow rule reduces to the associated flow rule.The stability factors decrease by 39.7%with nonlinear parameter varying from 1.0 to 3.0.Dilation and nonlinearity have significant effects on the slope stability factors.
基金Transportation Science and Technology Project of Jiangsu Province(No.7621000115)Science and Technology Project of Nanjing Committee of Housing and Urban-Rural Development(No.ks1611)
文摘Four fat and elongated(F&E)contents(0%,original,30%,and 40%)were investigated to evaluate the effects of F&Eparticles on the performance of porous asphalt mixture(P A).Laboratory tests including volumetric determination,two-dimensional image analysis,Cantabro loss tests,breakdown tests,and permeability tests were conducted to evaluate the volumetric properties,the state of stone-onstone contact,durability,skeleton stability and permeability of PA,respectively.The test results indicate that the F&E content was a significant factor for total air voids,aggregate skeleton break down,and permeability.The functionality,rutting resistance,long-term durability,and skeleton stability decrease with the increase of F&E content since F&E aggregates in porous asphalt mixtures have a tendency to breakdown.Compared with traditional dense graded mixtures,PA is more sensitive to the F&E content due to an open graded aggregate structure.Therefore,the stricter requiement for F&E content should be met for porous asphalt mixtures than the one for traditional deese graded mixture.
文摘Based on the slice method of the non-circular slip surface for the calculation of integral stability of slope, an improved genetic algorithm was proposed, which can freely search for the most dangerous slip surface of slope and the corresponding minimum safety factor without supposing the geometric shape of the most dangerous slip surface. This improved genetic algorithm can simulate the genetic evolution process of organisms and avoid the local minimum value compared with the classical methods. The results of engineering cases show that it is a global optimal algorithm and has many advantages, such as higher efficiency and shorter time than the simple genetic algorithm.
基金provided by the Research Fund of the Fundamental Research Funds for the Central Universities of China University of Mining & Technology (No. 2010ZDP02B02)the State Key Laboratory of Coal Resources and Mine Safety (No.SKLCRSM08X2)+2 种基金the Jiangsu "333"High Qualified Talentsthe National Natural Science Foundation of China (Nos. 50904063 and51004101)the Scientific Research Foundation of China University of Mining & Technology (Nos. 2008A003 and 2009A001)
文摘We determi:ned a suitable gate road layout in slice mining in an ultra-thick unstable coal seam, using theoretical anallysis and numerical calculations. Based on plasticity theory in terms of limiting equilibrium, the width of chain pillar in the upper slice was calculated to be 18 m. The stress distribution in the chain pillar after the upper slice was mined out was described with numerical simulation. The extent of the effect of stress on the upper chain pillar on the lower solid coal was obtained on the basis of an elastic solution of a distributed force loaded on a half-plane. Three layout designs for lower gate roads were pro- posed and a stability factor was introduced to analyze the stability of the lower pillar with numerical calculation. Gate road translation was determined as the most suitable layout method, which maximizes the extraction rate on the basis of the pillar stability.
基金the financial supports from the National Natural Science Foundation of China (Nos. 51974116, 51874128)the Science Foundation of Hunan Province, China (Nos. 2020JJ4273, 2020JJ5130)。
文摘Palladium-supported cobalt hydroxide(Co(OH)_(2)-Pd) nanoplates were fabricated in an aqueous solution and employed as a catalyst for the reduction of 4-nitrophenol.For the preparation of Co(OH)2-Pd,Pd nanoparticles were anchored on the Co(OH)_(2) nanoplates after the reduction of Na;PdCl;by ascorbic acid in the absence of a stabilizer at room temperature.The observations under transmission and scanning electron microscopy reveal that Pd nanoparticles with a size of 2-5 nm are uniformly dispersed on the surface of the Co(OH)_(2) nanoplates.In catalytic test,the conversion of 4-nitrophenol to 4-aminophenol is completed within 6 min in the presence of Co(OH)_(2)-Pd(1000) nanoplates with2.18 at.% Pd,and the corresponding kinetic constant is 0.0089 s;in the first test.The catalyst retains relatively high activity after several cycles.The results demonstrate that the Co(OH)_(2)-Pd(1000) nanoplates exhibit high catalytic activity toward the reduction of 4-nitrophenol in the presence of NaBH;.
基金supported by the National Key Research and Development Program of China (2016YFC0204301)~~
文摘Spinel oxides containing Co and Ni are a promising substitute as a noble metal catalyst for methane combustion.Achieving a complete oxidation of methane under 400°C remains challenging,andhydrothermal 60 h NiClittle impact on activity,especially at high space velocities due to the long hydrothermal time with less absorbed oxygen species and crystal defects.Overall,these results help clarify methane activa-tion mechanisms and aid the development of more efficient low-cost catalysts.
基金100 Talents Program of Chinese Academy of SciencesNational Key Basic Research Program of China ("973"Program) (No. 2012CB932600)
文摘Aptamers are molecular recognition elements with high specificity that are selected from deoxyribonucleic acid/ribonucleic acid (DNA/RNA) library. Compared with the traditional protein recognition elements,aptamers have excellent properties such as cost-effective,stable,easy for synthesis and modification. In recent years,electrochemistry plays an important role in biosensor field because of its high sensitivity,high stability, fast response and easy miniaturization. Through the combination of these two technologies and our rational design,we constructed a series of biosensors and biochips that are simple,fast,cheap and miniaturized. Firstly,we designed an adenosine triphosphate (ATP) electrochemical biosensor based on the strand displacement strategy. We can detect as low as 10 nmol/L of ATP both in pure solution and complicated cell lysates. Secondly,we creatively split the aptamers into two fragments and constructed the sandwich assay platform only based on single aptamer sequence. We successfully transferred this design on biochips with multiple micro electrodes (6×6) and accomplished multiplex detection. In the fields of biochips and biocomputers,we designed several DNA logic gates with electric (electrochemical) signal as output which paves a new way for the development of DNA computer.
基金supported by the Major Research Plan of the National Natural Science Foundation of China (Grant No. Y411381001)the National Natural Science Foundation of China (Grant No. 91125025)the Postdoctoral Science Foundation of China (Grant No. 2013M532096)
文摘To understand the effects of leaf physiological and morphological characteristics on δ13C of alpine trees, we examined leaf δ13C value, LA, SD, LNC, LPC, LKC, Chla+b, LDMC, LMA and Narea in one-year-old needles of Picea schrenkiana var. tianschanica at ten points along an altitudinal gradient from 1420 m to 2300 m a.s.l. on the northern slopes of the Tianshan Mountains in northwest China. Our results indicated that all the leaf traits differed significantly among sampling sites along the altitudinal gradient(P<0.001). LA, SD, LPC, LKC increased linearly with increasing elevation, whereas leaf δ13C, LNC, Chla+b, LDMC, LMA and Narea varied non-linearly with changes in altitude. Stepwise multiple regression analyses showed that four controlled physiological and morphological characteristics influenced the variation of δ13C. Among these four controlled factors, LKC was the most profound physiological factor that affected δ13C values, LA was the secondary morphological factor, SD was the third morphological factor, LNC was the last physiological factor. This suggested that leaf δ13C was directly controlled by physiological and morphological adjustments with changing environmental conditions due to the elevation.
基金financially supported by the National Natural Science Foundation of China(51602049)the Fundamental Research Funds for the Central Universities(2232017D-15,GSIF-DH-M-2020002)China Postdoctoral Science Foundation(2017M610217 and 2018T110322)。
文摘The enhancement of energy density and cycling stability is in urgent need for the widespread applications of aqueous rechargeable Ni-Zn batteries.Herein,a facile strategy has been employed to construct hierarchical Co-doped NiMoO4nanosheets as the cathode for high-performance Ni-Zn battery.Benefiting from the merits of substantially improved electrical conductivity and increased concentration of oxygen vacancies,the NiMoO4with 15%cobalt doping(denoted as CNMO-15)displays the best capacity of 361.4 m A h g-1at a current density of 3 A g-1and excellent cycle stability.Moreover,the assembled CNMO-15//Zn battery delivers a satisfactory specific capacity of 270.9 mA h g-1at 2 A g-1and a remarkable energy density of 474.1 W h kg-1at 3.5 kW kg-1,together with a maximum power density of 10.3 kW kg-1achieved at 118.8 W h kg-1.Noticeably,there is no capacity decay with a 119.8%retention observed after 5000 cycles,demonstrating its outstanding long lifespan.This work might provide valuable inspirations for the fabrication of high-performance Ni-Zn batteries with superior energy density and impressive stability.
基金supported by National Natural Science Foundation of China,Grant No.51421063
文摘Unsteady numerical simulations of a high-load transonic turbine stage have been carried out to study the influences of vane trailing edge outer-extending shockwave on rotor blade leading edge film cooling performance. The turbine stage used in this paper is composed of a vane section and a rotor one which are both near the root section of a transonic high-load turbine stage. The Mach number is 0.94 at vane outlet, and the relative Mach number is above 1.10 at rotor outlet. Various positions and oblique angles of film cooling holes were investigated in this research. Results show that the cooling efficiency on the blade surface of rotor near leading edge is significantly affected by vane trailing edge outer-extending shockwave in some cases. In the cases that film holes are close to leading edge, cooling performance suffers more from the sweeping vane trailing edge outer-extending shockwave.In addition, coolant flow ejected from oblique film holes is harder to separate from the blade surface of rotor, and can cover more blade area even under the effects of sweeping vane trailing edge shockwave. As a result, oblique film holes can provide better film cooling performance than vertical film holes do near the leading edge on turbine blade which is swept by shockwaves.
基金supported by the Foundation for Innovative Research Groups of the National Natural Science Foundation of China(Grant No.51121004)the National Natural Science Foundation of China(Grant No.50976026)
文摘The aim of this paper is to predict the phenomenon of laminar separation, transition and reattachment in a low-pressure turbine (LPT). Self-developed large eddy simulation program of compressible N-S equations was used to describe the flow structures of T 106A LPT blade profile at Reynolds number of 1.1×10^5 based on the exit isentropic velocity and chord length. The com- putational results show the distributions of time-averaged wall-static pressure coefficient and mean skin-friction coefficient on the blade surface. The locations of laminar separation and reattachment points occur around 87% and 98% axial chord, which agree well with experiment data. The two-dimensional shear layer is gradually unstable along the downstream half of the suc- tion side as a result of the spanwise fluctuation and the roll up of shear layer via Kelvin-Helmholtz (KH) instability. Three-dimensional motions appear near 84% axial chord which later triggers spanwise vortexes and streamwise vortexes, leading to transition to turbulence in the separation bubble. Through introducing the concept of dissipation function, the high loss mainly comes from the places where strong shear layer and intense fluctuation exist. Furthermore, the separation region is only an accumulation center of the low-energy fluid rather than an area of loss source.
文摘This paper treats the flow instabilities in a mixed flow pump with a vaned diffuser. Test pump has a positive slope of a head-flow performance curve at 65% flow rate of BEP (Best Efficiency Point) because of a rotating stall. Dynamic Particle Image Velocimetry (PIV) and pressure fluctuation measurements are used for investigating the propagation mechanism of a rotating stall. It was found that unstable performance was caused by periodical large scale abrupt backflow generated from the vaned diffuser to the outlet of impeller. Further, the relation between the static pressure at the inlet of diffuser vane and the internal flow condition was clarified. From these experimental results, in order to improve the positive slope of a head-flow performance curve, to suppress the growth of strong vortex toward the inlet of diffuser vane was proved to be a key point.