NiO_(x)as a hole transport material for inverted perovskite solar cells has received great attention owing to its high transparency,low fabrication temperature,and superior stability.However,the mismatched energy leve...NiO_(x)as a hole transport material for inverted perovskite solar cells has received great attention owing to its high transparency,low fabrication temperature,and superior stability.However,the mismatched energy levels and possible redox reactions at the NiO_(x)/perovskite interface severely limit the performance of NiO_(x) based inverted perovskite solar cells.Herein,we introduce a p-type self-assembled monolayer between NiO_(x)and perovskite layers to modify the interface and block the undesirable redox reaction between perovskite and NiO_(x)The selfassembled monolayer molecules all contain phosphoric acid function groups,which can be anchored onto the NiOr surface and passivate the surface defect.Moreover,the introduction of self-assembled monolayers can regulate the energy level structure of NiO_(x),reduce the interfacial band energy offset,and hence promote the hole transport from perovskite to NiO_(x)layer.Consequently,the device performance is significantly enhanced in terms of both power conversion efficiency and stability.展开更多
Various ordered mesoporous carbons （OMCs） have been prepared by evaporation-induced trieonstituent co-assembly method. Their mesostructural stability under different carbon content, aging time and acidity were conve...Various ordered mesoporous carbons （OMCs） have been prepared by evaporation-induced trieonstituent co-assembly method. Their mesostructural stability under different carbon content, aging time and acidity were conveniently monitored by X-ray diffraction, transmission electron microscopy, and N2 sorption isotherms techniques. The results show mesostruetural stability of OMCs is enhanced as the carbon content increases from 36% to 46%, further increasing carbon content deteriorates the mesostructural stability. Increasing aging time from 0.5 h to 5.0 h make the mesostructural stability go through an optimum （2.0 h） and gradually reduce framework shrinkage of the OMCs. Highly OMCs can only be obtained in the acidity range of 0.2-1.2 mol/L HC1, when the acidity is near the isoelectrie point of silica, the resulting OMCs have the best mesostructure stability. Under the optimum condition, the carbon content of 46%, aging time of 2.0 h, and 0.2 mol/L HCl, the resulting OMCs have the best mesostrueture stability and the highest BET surface areas of 2281 m2/g.展开更多
The mechanism of a hydro-viscous soft start is of great importance in the design of a hydro-viscous clutch and its control system. To explain the mechanism of a hydro-viscous soft start, the startup process of a belt ...The mechanism of a hydro-viscous soft start is of great importance in the design of a hydro-viscous clutch and its control system. To explain the mechanism of a hydro-viscous soft start, the startup process of a belt conveyor was numerically analyzed with the modified Reynolds equation, an energy equation and a temperature-viscosity equation. The effect of temperature and grooves of the friction disk surface on torque transfer and load capacity of the oil film have also been analyzed. The results show that 1) the grooves are the basis of forming dynamic pressure but they may reduce the capacity of torque transfer to a certain extent, 2) during the startup process, temperature has little effect on torque transfer and load capacity and the variation in load capacity of the oil film is very small, indicating that it is preferable to use the flow rate as a control object than the pressure of the feed cylinder. The results have been verified by an experiment.展开更多
Over the past decade,multistable mechanical metamaterials have been widely investigated because of their novel shape reconfigurability and programmable energy landscape.The ability to reversibly reshape among diverse ...Over the past decade,multistable mechanical metamaterials have been widely investigated because of their novel shape reconfigurability and programmable energy landscape.The ability to reversibly reshape among diverse stable states with different energy levels represents the most important feature of the multistable mechanical metamaterials.We summarize main design strategies of multistable mechanical metamaterials,including those based on self-assembly scheme,snap-through instability,structured mechanism and geometrical frustration,with a focus on the number and controllability of accessible stable states.Then we concentrate on unusual mechanical properties of these multistable mechanical metamaterials,and present their applications in a wide range of areas,including tunable electromagnetic devices,actuators,robotics,and mechanical logic gates.Finally,we discuss remaining challenges and open opportunities of designs and applications of multistable mechanical metamaterials.展开更多
An explosive blast mitigation alternative has increased the safety of structures by using " catcher" systems. These systems " catch" or repel the failure of the window or in-fill wall pro-tecting l...An explosive blast mitigation alternative has increased the safety of structures by using " catcher" systems. These systems " catch" or repel the failure of the window or in-fill wall pro-tecting life and property from ballistic shards or fragments. They can be designed to be stand-alone in new construction and structural retrofits or used to augment structural hardening tech-niques. Cables, fabrics, and thin gauge sheet steel are examples of catcher systems used in the past. A new and evolving category of catcher systems are based on polymeric materials that can be used for both wall and window upgrades. These products are a proven blast mitigation concept and K&C Protective Technologies Pte Ltd (KCPT) together with Sherwin-Williams(SW) use KCPT′s blast engineering capacity and SW′s material engineering principles to create engineered systems for even greater in-use performance.展开更多
Knowledge of the environment is essential for the survival of organisms; but those organisms have to have the capacity to stabilize such knowledge. The aim of this article is to analyze the various strategies for stab...Knowledge of the environment is essential for the survival of organisms; but those organisms have to have the capacity to stabilize such knowledge. The aim of this article is to analyze the various strategies for stabilizing human knowledge, with a special focus on its material anchors and their interactions with other stabilization means. In particular, I consider how such stabilization is reflected in scientific activity and practice, and what its repercussions are for the models of science that have dominated the philosophical landscape of the 20th century. My starting hypothesis will be that the role of material anchors in stabilizing conceptual blends is analogous to that of technology in grounding scientific knowledge. The framework I adopt with regard to conceptualization is that of Fauconnier and Turner （2002） on conceptual blends. Just as technology intervenes in scientific practice in conjunction with conceptual elements, so do material anchors, which conjoin other non-material strategies of knowledge stabilization. Endowing knowledge with a material basis may be understood firstly as an element （sometimes a key element） for representing knowledge and offering an explanation, and secondly as a way of providing a scientific hypothesis with empirical grounding. It is this second sense that connects with scientific experimentation and the use of instruments and technology.展开更多
文摘NiO_(x)as a hole transport material for inverted perovskite solar cells has received great attention owing to its high transparency,low fabrication temperature,and superior stability.However,the mismatched energy levels and possible redox reactions at the NiO_(x)/perovskite interface severely limit the performance of NiO_(x) based inverted perovskite solar cells.Herein,we introduce a p-type self-assembled monolayer between NiO_(x)and perovskite layers to modify the interface and block the undesirable redox reaction between perovskite and NiO_(x)The selfassembled monolayer molecules all contain phosphoric acid function groups,which can be anchored onto the NiOr surface and passivate the surface defect.Moreover,the introduction of self-assembled monolayers can regulate the energy level structure of NiO_(x),reduce the interfacial band energy offset,and hence promote the hole transport from perovskite to NiO_(x)layer.Consequently,the device performance is significantly enhanced in terms of both power conversion efficiency and stability.
基金This work was supported by the National Natural Science Foundation of China （No.20872135）.
文摘Various ordered mesoporous carbons （OMCs） have been prepared by evaporation-induced trieonstituent co-assembly method. Their mesostructural stability under different carbon content, aging time and acidity were conveniently monitored by X-ray diffraction, transmission electron microscopy, and N2 sorption isotherms techniques. The results show mesostruetural stability of OMCs is enhanced as the carbon content increases from 36% to 46%, further increasing carbon content deteriorates the mesostructural stability. Increasing aging time from 0.5 h to 5.0 h make the mesostructural stability go through an optimum （2.0 h） and gradually reduce framework shrinkage of the OMCs. Highly OMCs can only be obtained in the acidity range of 0.2-1.2 mol/L HC1, when the acidity is near the isoelectrie point of silica, the resulting OMCs have the best mesostructure stability. Under the optimum condition, the carbon content of 46%, aging time of 2.0 h, and 0.2 mol/L HCl, the resulting OMCs have the best mesostrueture stability and the highest BET surface areas of 2281 m2/g.
文摘The mechanism of a hydro-viscous soft start is of great importance in the design of a hydro-viscous clutch and its control system. To explain the mechanism of a hydro-viscous soft start, the startup process of a belt conveyor was numerically analyzed with the modified Reynolds equation, an energy equation and a temperature-viscosity equation. The effect of temperature and grooves of the friction disk surface on torque transfer and load capacity of the oil film have also been analyzed. The results show that 1) the grooves are the basis of forming dynamic pressure but they may reduce the capacity of torque transfer to a certain extent, 2) during the startup process, temperature has little effect on torque transfer and load capacity and the variation in load capacity of the oil film is very small, indicating that it is preferable to use the flow rate as a control object than the pressure of the feed cylinder. The results have been verified by an experiment.
基金supported by the National Natural Science Foundation of China(No.11722217)the Tsinghua University,China Initiative Scientific Research Program(No.2019Z08QCX10)the Institute for Guo Qiang,Tsinghua University,China(No.2019GQG1012)。
文摘Over the past decade,multistable mechanical metamaterials have been widely investigated because of their novel shape reconfigurability and programmable energy landscape.The ability to reversibly reshape among diverse stable states with different energy levels represents the most important feature of the multistable mechanical metamaterials.We summarize main design strategies of multistable mechanical metamaterials,including those based on self-assembly scheme,snap-through instability,structured mechanism and geometrical frustration,with a focus on the number and controllability of accessible stable states.Then we concentrate on unusual mechanical properties of these multistable mechanical metamaterials,and present their applications in a wide range of areas,including tunable electromagnetic devices,actuators,robotics,and mechanical logic gates.Finally,we discuss remaining challenges and open opportunities of designs and applications of multistable mechanical metamaterials.
文摘An explosive blast mitigation alternative has increased the safety of structures by using " catcher" systems. These systems " catch" or repel the failure of the window or in-fill wall pro-tecting life and property from ballistic shards or fragments. They can be designed to be stand-alone in new construction and structural retrofits or used to augment structural hardening tech-niques. Cables, fabrics, and thin gauge sheet steel are examples of catcher systems used in the past. A new and evolving category of catcher systems are based on polymeric materials that can be used for both wall and window upgrades. These products are a proven blast mitigation concept and K&C Protective Technologies Pte Ltd (KCPT) together with Sherwin-Williams(SW) use KCPT′s blast engineering capacity and SW′s material engineering principles to create engineered systems for even greater in-use performance.
文摘Knowledge of the environment is essential for the survival of organisms; but those organisms have to have the capacity to stabilize such knowledge. The aim of this article is to analyze the various strategies for stabilizing human knowledge, with a special focus on its material anchors and their interactions with other stabilization means. In particular, I consider how such stabilization is reflected in scientific activity and practice, and what its repercussions are for the models of science that have dominated the philosophical landscape of the 20th century. My starting hypothesis will be that the role of material anchors in stabilizing conceptual blends is analogous to that of technology in grounding scientific knowledge. The framework I adopt with regard to conceptualization is that of Fauconnier and Turner （2002） on conceptual blends. Just as technology intervenes in scientific practice in conjunction with conceptual elements, so do material anchors, which conjoin other non-material strategies of knowledge stabilization. Endowing knowledge with a material basis may be understood firstly as an element （sometimes a key element） for representing knowledge and offering an explanation, and secondly as a way of providing a scientific hypothesis with empirical grounding. It is this second sense that connects with scientific experimentation and the use of instruments and technology.
