We present the design and performance of a home-built scanning tunneling microscope (STM), which is compact (66 mm tall and 25 mm in diameter), yet equipped with a 3D atomic precision piezoelectric motor in which ...We present the design and performance of a home-built scanning tunneling microscope (STM), which is compact (66 mm tall and 25 mm in diameter), yet equipped with a 3D atomic precision piezoelectric motor in which the Z coarse approach relies on a high simplic-ity friction-type walker (of our own invention) driven by an axially cut piezoelectric tube. The walker is vertically inserted in a piezoelectric scanner tube (PST) with its brim laying at on the PST end as the inertial slider (driven by the PST) for the XZ (sample plane) motion. The STM is designed to be capable of searching rare microscopic targets (defects, dopants, boundaries, nano-devices, etc.) in a macroscopic sample area (square millimeters) under extreme conditions (low temperatures, strong magnetic elds, etc.) in which it ts. It gives good atomic resolution images after scanning a highly oriented pyrolytic graphite sample in air at room temperature.展开更多
The thermal decomposition process of basic magnesium carbonate was investigated. Firstly, Basic magnesium carbonate was prepared from magnesite, and the characteristics of the product were detected by X-ray diffracti...The thermal decomposition process of basic magnesium carbonate was investigated. Firstly, Basic magnesium carbonate was prepared from magnesite, and the characteristics of the product were detected by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Subsequently, the thermal decomposition process of basic magnesium carbonate in air was studied by thermogravimetry-differential thermogravimetry (TG-DTG). The results of XRD confirm that the chemical composition of basic magnesium carbonate is 4MgCO3·Mg(OH)2·4H2O. And the SEM images show that the sample is in sheet structure, with a diameter of 0.1-1 μm. The TG-DTG results demonstrate that there are two steps in the thermal decomposition process of basic magnesium carbonate. The apparent activation energies (E) were calculated by Flyrm-Wall-Ozawa method. It is obtained from Coats-Redfem's equation and Malek method that the mechanism functions of the two decomposition stages are D3 and A1.5, respectively. And then, the kinetic equations of the two steps were deduced as well.展开更多
The variation in Arctic sea ice has significant implications for climate change due to its huge influence on the global heat balance. In this study, we quantified the spatio-temporal variation of Arctic sea ice distri...The variation in Arctic sea ice has significant implications for climate change due to its huge influence on the global heat balance. In this study, we quantified the spatio-temporal variation of Arctic sea ice distribution using Advanced Microwave Scanning Radiometer(AMSR-E) sea-ice concentration data from 2003 to 2013. The results found that, over this period, the extent of sea ice reached a maximum in 2004, whereas in 2007 and 2012, the extent of summer sea ice was at a minimum. It declined continuously from 2010 to 2012, falling to its lowest level since 2003. Sea-ice extent fell continuously each summer between July and mid-September before increasing again. It decreased most rapidly in September, and the summer reduction rate was 1.35 × 10~5 km^2/yr, twice as fast as the rate between 1979 and 2006, and slightly slower than from 2002 to 2011. Area with >90% sea-ice concentration decreased by 1.32 × 10~7 km^2/yr, while locations with >50% sea-ice concentration, which were mainly covered by perennial ice, were near the North Pole, the Beaufort Sea, and the Queen Elizabeth Islands. Perennial Arctic ice decreased at a rate of 1.54 × 10~5 km^2 annually over the past 11 years.展开更多
Chronic intestinal pseudo-obstruction(CIPO) is a rare disease due to a severe gastrointestinal motility disorder which may mimic,on both clinical and radiological grounds,mechanical obstruction.We report a case of a 2...Chronic intestinal pseudo-obstruction(CIPO) is a rare disease due to a severe gastrointestinal motility disorder which may mimic,on both clinical and radiological grounds,mechanical obstruction.We report a case of a 26-year-old woman who presented to our institution for plain abdominal radiography for referred long-lasting constipation with recurrent episodes of abdominal pain and distension.At X-ray,performed both in the upright and supine position,an isolated air-fluid level was depicted in the left flank,together with a number of radiological signs suggestive of pneumoperitoneum.First,subphrenic radiolucency could be observed in the upright film.Second,the intestinal wall of some jejunal loops appeared to be outlined in the right flank.Third,the inferior cardiac border was clearly depicted in the upright film.The patient however had no evidence ofperitoneal signs but only hypoactive bowel movements.Unenhanced multi-detector computed tomography(MDCT) of the abdomen and pelvis was therefore performed.MDCT revealed abnormal air-driven distension of the small and large bowel,without evidence of extraluminal air.All radiological signs of pneumoperitoneum turned out to be false-positive results.The patient was submitted to pan-colonoscopy and to anorectal manometry to rule out Hirshprung's disease,and was finally discharged with a diagnosis of CIPO.展开更多
The error sources related to the laser rangefinder, GPS and INS are analyzed in details. Several coordinates systems used in airborne laser scanning are set up, and then the basic formula of system is given. This pape...The error sources related to the laser rangefinder, GPS and INS are analyzed in details. Several coordinates systems used in airborne laser scanning are set up, and then the basic formula of system is given. This paper emphasizes on discussing the kinematic offset correction between GPS antenna phase center and laser fired point. And kinematic time delay influence on laser footprint position, the ranging errors, positioning errors, attitude errors and integration errors of the system are also explored. Finally, the result shows that the kinematic time delay can be neglected as compared with other error sources. The accuracy of the coordinates is not only influenced by the amplitude of the error, but also controlled by the operation parameters such as flight height, scanning angle amplitude and attitude magnitude of the platform.展开更多
Air pollution is harm and discomfort to human or other living organisms, it also causes damage to the environment. The aim of this project was to study the effect of air pollutions on structure and pollen grains devel...Air pollution is harm and discomfort to human or other living organisms, it also causes damage to the environment. The aim of this project was to study the effect of air pollutions on structure and pollen grains development in Chenopodium album. Anthers of Chenopodium album L. were collected at different stages of development from control (less polluted) and polluted areas (mainly SO2, NO2, CO and APM). Structure and development of pollen grains were studied and compared. The effects of pollution on pollen structure was investigated under Light and Scanning electron microscopy and the results showed that when pollen grains were exposed to polluted air they became abnormality in form and covered with large amounts of pollutants compared to control ones. Pollen abnormalities were seen as irregularity, shrinkage, thinning and breakage of the exine. Cellular material release was induced also. The data presented suggest that prolonged exposures of plants to air pollution may cause different biological effects at the cellular tissue and organ levels.展开更多
The arc corrosion evolution of Cu-20 vol.% Ti_3 AlC_2 cathodes is presented here. After eroded by 3, 4, 5, 6, 7, 8, 9, 10 kV DC voltage, respectively, the surface morphologies were characterized by field emission scan...The arc corrosion evolution of Cu-20 vol.% Ti_3 AlC_2 cathodes is presented here. After eroded by 3, 4, 5, 6, 7, 8, 9, 10 kV DC voltage, respectively, the surface morphologies were characterized by field emission scanning electron microscope with craters and protrusions. Compared to small craters and dense protrusions of the morphology by high voltage, the eroded surface was covered with bigger craters and sparse protrusions at low voltage. No crack was discovered on the surface even at 10 kV. By means of energy dispersive spectroscopy and Raman spectroscopy, the decomposition of Cu-20 vol.% Ti_3 AlC_2 cathode to CuO,Al__2 O_3 and TiO_2 were proved. Meanwhile, W anode is oxidized to WO_2. The peak current increases with the increasing breakdown voltage, which is recorded by a digital memory oscilloscope.展开更多
Novel and highly durable air cathode electrocatalyst with three dimensional (3D)-clam-shaped structure, MnO2 nanotubes-supported Fe2O3 (Fe2O3/MnO2) composited by carbon nanotubes (CNTs) ((Fe2O3/ MnO2)3/4-(C...Novel and highly durable air cathode electrocatalyst with three dimensional (3D)-clam-shaped structure, MnO2 nanotubes-supported Fe2O3 (Fe2O3/MnO2) composited by carbon nanotubes (CNTs) ((Fe2O3/ MnO2)3/4-(CNTs)1/4) is synthesized using a facile hydrothermal process and a following direct heat- treatment in the air. The morphology and composition of this catalyst are analyzed using scanning elec- tronic microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and energy dispersive X-ray spectroscopy (EDX). The morphology characteristics reveal that flower-like Fe2O3 parti- cles are highly dispersed on both MnO2 nanotubes and CNT surfaces, coupling all three components firmly. Electrochemical measurements indicate that the synergy of catalyst exhibit superior bi- functional catalytic activity for both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) as well as stability than Pt/C and lrO2 catalysts. Using these catalysts for air-cathodes, both primary and rechargeable zinc-air batteries (ZABs) are assembled for performance validation. In a primary ZAB, this 3D-clamed catalyst shows a decent open circuit voltage (OCV, -1.48 V) and a high discharge peak power density (349 mW cm 2), corresponding to a coulomhic efficiency of 92%. In a rechargeahle ZABs with this bifunctional catalyst, high OCV (〉1.3 V) and small charge-discharge voltage gap (〈1.1 V) are achieved along with high specific capacity (780 mAh g 1 at 30 mA cm-2) and robust cycle-life (1,390 cycles at cycle profile of 20 mA/10 min).展开更多
Electrostatic torsional micromirrors are widely applied in the fields·of micro-optical switches,optical attenuators,optical scanners,and optical displays.In previous lectures,most of the micromirrors were twisted...Electrostatic torsional micromirrors are widely applied in the fields·of micro-optical switches,optical attenuators,optical scanners,and optical displays.In previous lectures,most of the micromirrors were twisted along the urtiaxial or biaxial direction,which limited the range of light reflection.In this·paper,a quasicrystal torsional micromirror that can be deflected in any direction is designed and the dynamic model of the electrostatically driven micromirror is established.The static and dynamic phenomena and pull-in characteristics are analyzed through the numerical solution of the strain gradient theory.The results of three kinds of mirror deflection directions are compared and analyzed.The results show the significant differences in the torsion models with different deflection axis directions.When the deflection angle along the oblique axis reaches 45°,the instability voltage is the smallest.The pull-in instability voltage increases with the increment ofphonon-phason coupling elastic modulus and phason elastic modulus.The perrriittivity of quasicrystal,the strain gradient parameter,and the air damping influence the torsion of the micromirror dynaniic system.A larger pull-in instability voltage generates with the decrease of surface distributed forces.展开更多
文摘We present the design and performance of a home-built scanning tunneling microscope (STM), which is compact (66 mm tall and 25 mm in diameter), yet equipped with a 3D atomic precision piezoelectric motor in which the Z coarse approach relies on a high simplic-ity friction-type walker (of our own invention) driven by an axially cut piezoelectric tube. The walker is vertically inserted in a piezoelectric scanner tube (PST) with its brim laying at on the PST end as the inertial slider (driven by the PST) for the XZ (sample plane) motion. The STM is designed to be capable of searching rare microscopic targets (defects, dopants, boundaries, nano-devices, etc.) in a macroscopic sample area (square millimeters) under extreme conditions (low temperatures, strong magnetic elds, etc.) in which it ts. It gives good atomic resolution images after scanning a highly oriented pyrolytic graphite sample in air at room temperature.
基金Project(20876160) supported by the National Natural Science Foundation of China
文摘The thermal decomposition process of basic magnesium carbonate was investigated. Firstly, Basic magnesium carbonate was prepared from magnesite, and the characteristics of the product were detected by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Subsequently, the thermal decomposition process of basic magnesium carbonate in air was studied by thermogravimetry-differential thermogravimetry (TG-DTG). The results of XRD confirm that the chemical composition of basic magnesium carbonate is 4MgCO3·Mg(OH)2·4H2O. And the SEM images show that the sample is in sheet structure, with a diameter of 0.1-1 μm. The TG-DTG results demonstrate that there are two steps in the thermal decomposition process of basic magnesium carbonate. The apparent activation energies (E) were calculated by Flyrm-Wall-Ozawa method. It is obtained from Coats-Redfem's equation and Malek method that the mechanism functions of the two decomposition stages are D3 and A1.5, respectively. And then, the kinetic equations of the two steps were deduced as well.
基金Under the auspices of National Natural Science Foundation of China(No.41676171)Qingdao National Laboratory for Marine Science and Technology of China(No.2016ASKJ02)+1 种基金Natural Science Foundation of Shandong(No.ZR2015DM015)Yantai Science&Technology Project(No.2013ZH094)
文摘The variation in Arctic sea ice has significant implications for climate change due to its huge influence on the global heat balance. In this study, we quantified the spatio-temporal variation of Arctic sea ice distribution using Advanced Microwave Scanning Radiometer(AMSR-E) sea-ice concentration data from 2003 to 2013. The results found that, over this period, the extent of sea ice reached a maximum in 2004, whereas in 2007 and 2012, the extent of summer sea ice was at a minimum. It declined continuously from 2010 to 2012, falling to its lowest level since 2003. Sea-ice extent fell continuously each summer between July and mid-September before increasing again. It decreased most rapidly in September, and the summer reduction rate was 1.35 × 10~5 km^2/yr, twice as fast as the rate between 1979 and 2006, and slightly slower than from 2002 to 2011. Area with >90% sea-ice concentration decreased by 1.32 × 10~7 km^2/yr, while locations with >50% sea-ice concentration, which were mainly covered by perennial ice, were near the North Pole, the Beaufort Sea, and the Queen Elizabeth Islands. Perennial Arctic ice decreased at a rate of 1.54 × 10~5 km^2 annually over the past 11 years.
文摘Chronic intestinal pseudo-obstruction(CIPO) is a rare disease due to a severe gastrointestinal motility disorder which may mimic,on both clinical and radiological grounds,mechanical obstruction.We report a case of a 26-year-old woman who presented to our institution for plain abdominal radiography for referred long-lasting constipation with recurrent episodes of abdominal pain and distension.At X-ray,performed both in the upright and supine position,an isolated air-fluid level was depicted in the left flank,together with a number of radiological signs suggestive of pneumoperitoneum.First,subphrenic radiolucency could be observed in the upright film.Second,the intestinal wall of some jejunal loops appeared to be outlined in the right flank.Third,the inferior cardiac border was clearly depicted in the upright film.The patient however had no evidence ofperitoneal signs but only hypoactive bowel movements.Unenhanced multi-detector computed tomography(MDCT) of the abdomen and pelvis was therefore performed.MDCT revealed abnormal air-driven distension of the small and large bowel,without evidence of extraluminal air.All radiological signs of pneumoperitoneum turned out to be false-positive results.The patient was submitted to pan-colonoscopy and to anorectal manometry to rule out Hirshprung's disease,and was finally discharged with a diagnosis of CIPO.
文摘The error sources related to the laser rangefinder, GPS and INS are analyzed in details. Several coordinates systems used in airborne laser scanning are set up, and then the basic formula of system is given. This paper emphasizes on discussing the kinematic offset correction between GPS antenna phase center and laser fired point. And kinematic time delay influence on laser footprint position, the ranging errors, positioning errors, attitude errors and integration errors of the system are also explored. Finally, the result shows that the kinematic time delay can be neglected as compared with other error sources. The accuracy of the coordinates is not only influenced by the amplitude of the error, but also controlled by the operation parameters such as flight height, scanning angle amplitude and attitude magnitude of the platform.
文摘Air pollution is harm and discomfort to human or other living organisms, it also causes damage to the environment. The aim of this project was to study the effect of air pollutions on structure and pollen grains development in Chenopodium album. Anthers of Chenopodium album L. were collected at different stages of development from control (less polluted) and polluted areas (mainly SO2, NO2, CO and APM). Structure and development of pollen grains were studied and compared. The effects of pollution on pollen structure was investigated under Light and Scanning electron microscopy and the results showed that when pollen grains were exposed to polluted air they became abnormality in form and covered with large amounts of pollutants compared to control ones. Pollen abnormalities were seen as irregularity, shrinkage, thinning and breakage of the exine. Cellular material release was induced also. The data presented suggest that prolonged exposures of plants to air pollution may cause different biological effects at the cellular tissue and organ levels.
基金supported by the National Natural Science Foundation of China(Grant No.51571078)
文摘The arc corrosion evolution of Cu-20 vol.% Ti_3 AlC_2 cathodes is presented here. After eroded by 3, 4, 5, 6, 7, 8, 9, 10 kV DC voltage, respectively, the surface morphologies were characterized by field emission scanning electron microscope with craters and protrusions. Compared to small craters and dense protrusions of the morphology by high voltage, the eroded surface was covered with bigger craters and sparse protrusions at low voltage. No crack was discovered on the surface even at 10 kV. By means of energy dispersive spectroscopy and Raman spectroscopy, the decomposition of Cu-20 vol.% Ti_3 AlC_2 cathode to CuO,Al__2 O_3 and TiO_2 were proved. Meanwhile, W anode is oxidized to WO_2. The peak current increases with the increasing breakdown voltage, which is recorded by a digital memory oscilloscope.
基金supported by the National Natural Science Foundation of China(U1510120)Natural Science Foundation of Shanghai(14ZR1400700)+2 种基金the Project of Introducing Overseas Intelligence High Education of China(2017-2018)the Graduate Thesis Innovation Foundation of Donghua University(EG2017031,EG2016034)the College of Environmental Science and Engineering,State Environmental Protection Engineering Centre for Pollution Treatment and Control in Textile Industry,Donghua University
文摘Novel and highly durable air cathode electrocatalyst with three dimensional (3D)-clam-shaped structure, MnO2 nanotubes-supported Fe2O3 (Fe2O3/MnO2) composited by carbon nanotubes (CNTs) ((Fe2O3/ MnO2)3/4-(CNTs)1/4) is synthesized using a facile hydrothermal process and a following direct heat- treatment in the air. The morphology and composition of this catalyst are analyzed using scanning elec- tronic microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and energy dispersive X-ray spectroscopy (EDX). The morphology characteristics reveal that flower-like Fe2O3 parti- cles are highly dispersed on both MnO2 nanotubes and CNT surfaces, coupling all three components firmly. Electrochemical measurements indicate that the synergy of catalyst exhibit superior bi- functional catalytic activity for both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) as well as stability than Pt/C and lrO2 catalysts. Using these catalysts for air-cathodes, both primary and rechargeable zinc-air batteries (ZABs) are assembled for performance validation. In a primary ZAB, this 3D-clamed catalyst shows a decent open circuit voltage (OCV, -1.48 V) and a high discharge peak power density (349 mW cm 2), corresponding to a coulomhic efficiency of 92%. In a rechargeahle ZABs with this bifunctional catalyst, high OCV (〉1.3 V) and small charge-discharge voltage gap (〈1.1 V) are achieved along with high specific capacity (780 mAh g 1 at 30 mA cm-2) and robust cycle-life (1,390 cycles at cycle profile of 20 mA/10 min).
基金supported by the National Natural Science Foundation of China(Grant Nos.11572191,51701117,and 51779139).
文摘Electrostatic torsional micromirrors are widely applied in the fields·of micro-optical switches,optical attenuators,optical scanners,and optical displays.In previous lectures,most of the micromirrors were twisted along the urtiaxial or biaxial direction,which limited the range of light reflection.In this·paper,a quasicrystal torsional micromirror that can be deflected in any direction is designed and the dynamic model of the electrostatically driven micromirror is established.The static and dynamic phenomena and pull-in characteristics are analyzed through the numerical solution of the strain gradient theory.The results of three kinds of mirror deflection directions are compared and analyzed.The results show the significant differences in the torsion models with different deflection axis directions.When the deflection angle along the oblique axis reaches 45°,the instability voltage is the smallest.The pull-in instability voltage increases with the increment ofphonon-phason coupling elastic modulus and phason elastic modulus.The perrriittivity of quasicrystal,the strain gradient parameter,and the air damping influence the torsion of the micromirror dynaniic system.A larger pull-in instability voltage generates with the decrease of surface distributed forces.