Platinum group metals(PGMs)usually exhibit promising aerobic catalytic abilities,providing a green and feasible oxidative desulfurization method.However,often,the PGM nanoparticles(NPs)get leached,and the catalysts ar...Platinum group metals(PGMs)usually exhibit promising aerobic catalytic abilities,providing a green and feasible oxidative desulfurization method.However,often,the PGM nanoparticles(NPs)get leached,and the catalysts are deactivated.In this work,Pt NPs with particle sizes of approximately 4–5 nm were encapsulated effectively and uniformly on the surface of vanadium pentoxide(V2O5)nanosheets(with thicknesses of approximately six atomic layers)through strong metal-support interactions.The synthesized catalysts promote catalytic aerobic oxidation reactions,realizing deep desulfurization(99.1%,<5μg g^(–1))under atmospheric pressure and 110℃reaction temperature.Remarkable degrees of sulfur removal could be achieved for oils with different initial S-concentrations and substrates.Additionally,the as-prepared catalysts could be recycled for reuse at least seven times.展开更多
This paper discusses the evolution regularity and the absorption characters of sulfide for bituminous briquette burned in a horizontal burning fornace. The evolution rate of sulphur is affected by some factors, such a...This paper discusses the evolution regularity and the absorption characters of sulfide for bituminous briquette burned in a horizontal burning fornace. The evolution rate of sulphur is affected by some factors, such as the sulphur content in the burning coal, burning time and the mean excess air coefficient in the furnace. With processing the experimental result, the calculation related expression has been obtained to predict the evolution rate of sulfide. The sulphur absorption efficiency of briquette is affected by tbe factors such as the character of the sulphur sorbent, the type of the coal and the operating parameters. By means of appropriately adjusting the calciumsulphur mole ratio, the mean excess air coefficient and the time-interval between pushing two layer briquettes, a high sulphur absorption efficiency (>74% ) can be obtained.展开更多
文摘Platinum group metals(PGMs)usually exhibit promising aerobic catalytic abilities,providing a green and feasible oxidative desulfurization method.However,often,the PGM nanoparticles(NPs)get leached,and the catalysts are deactivated.In this work,Pt NPs with particle sizes of approximately 4–5 nm were encapsulated effectively and uniformly on the surface of vanadium pentoxide(V2O5)nanosheets(with thicknesses of approximately six atomic layers)through strong metal-support interactions.The synthesized catalysts promote catalytic aerobic oxidation reactions,realizing deep desulfurization(99.1%,<5μg g^(–1))under atmospheric pressure and 110℃reaction temperature.Remarkable degrees of sulfur removal could be achieved for oils with different initial S-concentrations and substrates.Additionally,the as-prepared catalysts could be recycled for reuse at least seven times.
文摘This paper discusses the evolution regularity and the absorption characters of sulfide for bituminous briquette burned in a horizontal burning fornace. The evolution rate of sulphur is affected by some factors, such as the sulphur content in the burning coal, burning time and the mean excess air coefficient in the furnace. With processing the experimental result, the calculation related expression has been obtained to predict the evolution rate of sulfide. The sulphur absorption efficiency of briquette is affected by tbe factors such as the character of the sulphur sorbent, the type of the coal and the operating parameters. By means of appropriately adjusting the calciumsulphur mole ratio, the mean excess air coefficient and the time-interval between pushing two layer briquettes, a high sulphur absorption efficiency (>74% ) can be obtained.
