The aim of the article concerns to the achieved research results regarding the viability of a megawatt-class space power plant based on the Rankine cycle for which the main objectives are to highlight the key issues r...The aim of the article concerns to the achieved research results regarding the viability of a megawatt-class space power plant based on the Rankine cycle for which the main objectives are to highlight the key issues responsible for improving the Rankine cycle efficiency. Two working fluids are studied (water and ammonia) on the basis of its well known characteristics. Cycles operating under top and bottom temperatures approaching the state of the art technology associated to cooling fluid reservoirs are key to improve the efficiency. With such strategy, the achieved thermal efficiency increases more than 20% with respect to conventional power plants. Mentioned benefits associated to the strategy based on the reduction of the required payload capacity, the condenser radiation surface and the power plant mass represent the main advantages of the proposed innovation techniques.展开更多
Interfacial engineering for the regulation of the charge carrier dynamics in solar cells is a critical factor in the fabrication of high-efficiency devices.Based on the successful preparation of highly dispersible gra...Interfacial engineering for the regulation of the charge carrier dynamics in solar cells is a critical factor in the fabrication of high-efficiency devices.Based on the successful preparation of highly dispersible graphdiyne oxide(GDYO)with a large number of functional groups,we fabricated organic solar cells employing GDYO-modified poly(3,4-ethylenedioxythiophene)/poly(styrene sulfonate)(PEDOT:PSS)as hole transport materials.Results show that theπ±πinteraction between GDYO and PEDOT:PSS is beneficial to the formation of an optimized charge carrier transfer channel and improves the conductivity and charge carrier mobility in the hole transport layer.Moreover,the improved interfacial contact contributes to the suppression of charge carrier recombination and the elevation of charge carrier extraction between the hole transport layer and the active layer.More importantly,the occurrence of charge carrier separation benefits from the optimized morphology of the active layer,which efficiently improves the performance,as proven by the results of transient absorption measurements.Therefore,with the holistic management approach to the multiobjective optimization of the charge carrier dynamics,a photoelectric conversion efficiency of 17.5%(with the certified value of 17.2%)is obtained for binary organic solar cells.All of these results indicate the potential application of the functionalized graphdiyne in the field of organic optoelectronic devices.展开更多
文摘The aim of the article concerns to the achieved research results regarding the viability of a megawatt-class space power plant based on the Rankine cycle for which the main objectives are to highlight the key issues responsible for improving the Rankine cycle efficiency. Two working fluids are studied (water and ammonia) on the basis of its well known characteristics. Cycles operating under top and bottom temperatures approaching the state of the art technology associated to cooling fluid reservoirs are key to improve the efficiency. With such strategy, the achieved thermal efficiency increases more than 20% with respect to conventional power plants. Mentioned benefits associated to the strategy based on the reduction of the required payload capacity, the condenser radiation surface and the power plant mass represent the main advantages of the proposed innovation techniques.
基金supported by the National Natural Science Foundation of China(21975273,21801014,21773012,and U2032112)Shandong Provincial Natural Science Foundation(ZR2021QE191)+3 种基金the Scientific Research Starting Foundation of Outstanding Young Scholar of Shandong Universitythe Future Young Scholars Program of Shandong Universitythe Fundamental Research Funds of Shandong Universitysupported by the Analysis&Testing Center of Beijing Institute of Technology。
文摘Interfacial engineering for the regulation of the charge carrier dynamics in solar cells is a critical factor in the fabrication of high-efficiency devices.Based on the successful preparation of highly dispersible graphdiyne oxide(GDYO)with a large number of functional groups,we fabricated organic solar cells employing GDYO-modified poly(3,4-ethylenedioxythiophene)/poly(styrene sulfonate)(PEDOT:PSS)as hole transport materials.Results show that theπ±πinteraction between GDYO and PEDOT:PSS is beneficial to the formation of an optimized charge carrier transfer channel and improves the conductivity and charge carrier mobility in the hole transport layer.Moreover,the improved interfacial contact contributes to the suppression of charge carrier recombination and the elevation of charge carrier extraction between the hole transport layer and the active layer.More importantly,the occurrence of charge carrier separation benefits from the optimized morphology of the active layer,which efficiently improves the performance,as proven by the results of transient absorption measurements.Therefore,with the holistic management approach to the multiobjective optimization of the charge carrier dynamics,a photoelectric conversion efficiency of 17.5%(with the certified value of 17.2%)is obtained for binary organic solar cells.All of these results indicate the potential application of the functionalized graphdiyne in the field of organic optoelectronic devices.