Remediation of COPR sites requires the key information including chromium oxidation, speciation and spatial distribution. Samples were gathered from a COPR site in Luliang County in Qujing, Yunnan Province of China. T...Remediation of COPR sites requires the key information including chromium oxidation, speciation and spatial distribution. Samples were gathered from a COPR site in Luliang County in Qujing, Yunnan Province of China. The total Cr, Cr(VI) and chromium species were investigated. Results indicated the concentration of total Cr was between 110.5 and 21,774 mg/kg, and the concentration of Cr(VI) was between 0.1 and 1075 mg/kg. The map of total-Cr and ratio of Cr(VI)/total-Cr(%) showed that the maximum of total-Cr and Cr(VI) appeared in the layers near the surface. In the horizontal direction, the pollution was more serious in the middle and southeast part than that in the west. Additionally, acid extractable chromium increased in the layers at depth from-0.3 to-2.0 m, and it decreased in the deeper layers. There was a trend that the movable Cr(VI) migrated to the deeper layers, and then it turned into Cr(III). Water played an important role for the Cr distribution. Cr(VI) in COPR released to the soil solution after rainfall, and then gravity led the solution down to the deeper layers. After repeated rainfall and leaching,Cr(VI) moved to the deeper soil layers. Due to capillarity and evaporation, Cr(VI) migrated and was enriched at thesurface layer. Therefore, measures on controlling water movement should be taken in the remediation of the COPR site.展开更多
A detailed investigation on 3D spatial distribution rules of Banded Iron-bearing Formation(BIF) with methods of gravity-magnetic inversion and 3D modeling of iron mine is presented based on the former analysis in the ...A detailed investigation on 3D spatial distribution rules of Banded Iron-bearing Formation(BIF) with methods of gravity-magnetic inversion and 3D modeling of iron mine is presented based on the former analysis in the Anshan-Benxi area.Three dimension spatial distribution types of BIF are concluded as hook-like,tabularlike and "W"-like.BIF was mainly developed in three types of space including(1) the syncline cores,(2)cover coverage area,and(3) the deeper buried area where the range of tectonic uplift is small.The influences of tectonism,magmatic intrusion and uplift-erosion on the spatial distribution shapes of BIF are clarified.展开更多
基金supported by the Shandong Provincial Natural Science Foundation,China(Grant No.ZR2013DM008)the National Research Foundation for the Doctoral Program of Higher Education of China(No.20113718110007 for tutors)
文摘Remediation of COPR sites requires the key information including chromium oxidation, speciation and spatial distribution. Samples were gathered from a COPR site in Luliang County in Qujing, Yunnan Province of China. The total Cr, Cr(VI) and chromium species were investigated. Results indicated the concentration of total Cr was between 110.5 and 21,774 mg/kg, and the concentration of Cr(VI) was between 0.1 and 1075 mg/kg. The map of total-Cr and ratio of Cr(VI)/total-Cr(%) showed that the maximum of total-Cr and Cr(VI) appeared in the layers near the surface. In the horizontal direction, the pollution was more serious in the middle and southeast part than that in the west. Additionally, acid extractable chromium increased in the layers at depth from-0.3 to-2.0 m, and it decreased in the deeper layers. There was a trend that the movable Cr(VI) migrated to the deeper layers, and then it turned into Cr(III). Water played an important role for the Cr distribution. Cr(VI) in COPR released to the soil solution after rainfall, and then gravity led the solution down to the deeper layers. After repeated rainfall and leaching,Cr(VI) moved to the deeper soil layers. Due to capillarity and evaporation, Cr(VI) migrated and was enriched at thesurface layer. Therefore, measures on controlling water movement should be taken in the remediation of the COPR site.
文摘A detailed investigation on 3D spatial distribution rules of Banded Iron-bearing Formation(BIF) with methods of gravity-magnetic inversion and 3D modeling of iron mine is presented based on the former analysis in the Anshan-Benxi area.Three dimension spatial distribution types of BIF are concluded as hook-like,tabularlike and "W"-like.BIF was mainly developed in three types of space including(1) the syncline cores,(2)cover coverage area,and(3) the deeper buried area where the range of tectonic uplift is small.The influences of tectonism,magmatic intrusion and uplift-erosion on the spatial distribution shapes of BIF are clarified.
