有机分子的空间结构式与旋光性的关系

有机分子的空间结构可用不同的方式表示 。

Spatial Structural Pattern and Vulnerability of China-Japan-Korea Shipping Network

The economies of China-Japan-Korea （CJK） are complementary, with their proximity resulting in the three countries having a high degree of interdependence with respect to trade. Currently, trade among these countries relies mainly on port-centered shipping. The development of the shipping network is integral for in-depth integration of CJK trade. This paper analyzes the overall characteristics, centrality, spatial structure, and vulnerability of the CJK shipping network using the methods of complex network analysis, blocking flow theory, and interruption and deletion of hub ports. The main findings are as follows： 1） The CJK shipping network has a small average path length and clustering coefficient, and its degree distribution follows a power-law distribution, which make the network present obvious characteristics of a Barabasi-Albert scale-free. 2） The characteristics of the multi-center point of the CJK shipping network can alleviate traffic pressure. At the same time, the network shows a clear hierarchy in the port transportation system, with cargo transport relying mainly on the ‘hub port-hub port＇ connection. 3） The CJK shipping network is relatively stable. Compared with ports in Japan and Korea, the main hub ports in China have a greater impact on the stability of the shipping network, in particular those ports of the central coastal region, including Shanghai, Ningbo, and Lianyungang.

Changing Spatial and Structural Patterns of Non-agricultural Activities in Outward-moving Beijing Urban Fringe

As responses to metropolitan suburbanization and rural urbanization,the formation and evolution of urban fringes should be understood against the background of overall economic development and spatial reconstruction of entire metropolises.At the same time,however,endogenous interactions between industrial structure and spatial patterns of non-agricultural activities are also worthy of scholarly attention.Since the 1980s,studies on urban fringes in China have been restricted by the lack of micro-level data.This paper investigates the spatial expansion and structural evolution of the urban fringe by taking the case of Beijing and uses systematic firm-level data in 1996 and 2001 from the National Census of Basic Units.The diversity of distribution patterns across industrial sectors brings about two interrelated results.On the one hand,structural adjustment of non-agricultural industries promotes the expansion and spatial evolution of the urban fringe.On the other hand,the stability and dynamics of industrial structure coexist in the moving urban fringe.This study also reveals that the outward-moving urban fringe is the optimal location for manufacturing,especially heavy manufacturing,as well as traditional producer and consumer services.However,industries with spatial stickiness such as tourism and sports have not moved with the fringe.Most advanced services remain concentrated in the city center.The authors argue that it is essential for understanding and managing urban fringes to take into account spatial evolution and industrial structural adjustment together with their interaction with each other.

Observation of the abyssal western boundary current in the Philippine Sea

Mooring observations were conducted from July 16, 2011 to March 30, 2012 east of Mindanao, Philippines （127°2.8＇E, 8°0.3＇N） to observe the abyssal current at about 5 600 m deep and 500 m above the ocean bottom. Several features were revealed： 1） the observed abyssal current was highly variable with standard deviations of 57.3 mrn/s and 34.0 ram/s, larger than the mean values of-31.9 and 16.6 mm/s for the zonal and meridional components, respectively; 2） low-frequency current longer than 6 days exhibited strong seasonal variation, flowing southeastward （mean flow direction of 119.0° clockwise from north） before about October 1, 2011 and northwestward （mean flow direction of 60.5° counter-clockwise from north） thereafter; 3） the high-frequency flow bands were dominated by tidal currents O1, K1, M2, and S2, and near-inertial currents, whose frequencies were higher than the local inertial frequency. The two diurnal tidal constituents were much stronger than the two semidiumal ones. This study provides for the first time an observational insight into the abyssal western boundary current east of Mindanao based on long-term observations at one site. It is meaningful for further research into the deep and abyssal circulation over the whole Philippine Sea and the 3D structure of the westem boundary current system in this region. More observational and high-resolution model studies are needed to examine the spatial structure and temporal variation of the abyssal current over a much larger space and longer period, their relation to the upper-layer circulation, and the underlying dynamics.

The community structure and seasonal dynamics of plankton in Bange Lake, northern Tibet, China

The seasonal variations in biomass, abundance, and species composition of plankton in relation to hydrography were studied in the saline Bange Lake, northern Tibet, China. Sampling was carried out between one to three times per month from May 2001 to July 2002. Salinity ranged from 14 to 146. The air and water temperature exhibited a clear seasonal pattern, and mean annual temperatures were approximately 4.8℃ and 7.3℃, respectively. The lowest water temperature occurred in winter from December to March at-2℃ and the highest in June and July at 17.7℃. Forty-one phytoplankton taxa, 21 zooplankton, and 5 benthic or facultative zooplankton were identifi ed. The predominant phytoplankton species were Gloeothece linearis, Oscillatoria tenuis, Gloeocapsa punctata, Ctenocladus circinnatus, Dunaliella salina, and Spirulina major. The predominant zooplankton species included H olophrya actra, Brachionus plicatilis, Daphniopsis tibetana, Cletocamptus dertersi, and A rctodiaptomus salinus. The mean annual total phytoplankton density and biomass for the entire lake were 4.52×10^7 cells/L and 1.60 mg/L, respectively. The annual mean zooplankton abundance was 52, 162, 322, and 57, 144 ind./L, in the three sublakes. The annual mean total zooplankton biomass in Lakes 1–3 was 1.23, 9.98, and 2.13 mg/L, respectively. The annual mean tychoplankton abundances in Bg1, 2, and 3 were 47, 67, and 654 ind./L. The annual mean tychoplankton biomass was 2.36, 0.16, and 2.03 mg/L, respectively. The zooplankton biomass（including tychoplankton） in the lake was 9.11 mg/L. The total number of plankton species in the salt lake was signifi cantly negatively correlated with salinity.

Implications of tree species–environment relationships for the responsiveness of Himalayan krummholz treelines to climate change

Climate warming is expected to advance treelines to higher elevations. However, empirical studies in diverse mountain ranges give evidence of both advancing alpine treelines as well as rather insignificant responses. In this context, we aim at investigating the sensitivity and responsiveness of the near-natural treeline ecotone in Rolwaling Himal, Nepal, to climate warming. We analysed population densities of tree species along the treeline ecotone from closed forest stands via the krummholz belt to alpine dwarf shrub heaths （3700-4200 m） at 50 plots in 2013 and 2014. We quantified species - environment relationships, i.e. the change of environmental conditions （e.g., nutrient and thermal deficits, plant interactions） across the ecotone by means of redundancy analyses, variation partitioning and distance-based Moran＇s eigenvector maps. In particular, we focus on explaining the high competitiveness of Rhododendron campanulatum forming a dense krummholz belt and on the implications for the responsiveness of Himalayan krummholz treelines to climate change. Results indicate that treeline trees in the ecotone show species-specific responses to the influence of environmental parameters, and that juvenile and adult tree responses are modulated by environmental constraints in differing intensity. Moreover, the species - environment relationships suggest that the investigated krummholz belt will largely prevent the upward migration of other tree constrain the future response species and thus of Himalayan krummholz treelines to climate warming.

Experiment research on mechanical behavior of the aluminum laminate in the low-high temperature

Aluminum laminate is one kind of the rigidizable composite materials and plays an important role in construction of the inflatable space structure(ISS),which has potential application in space in the future.But the study of the predecessors mainly focuses on the research of the mechanical behavior in the room temperature,for this reason,mechanical properties of the aluminum laminate in low-high temperature have been studied in this paper.The failure mechanism of the aluminum laminate is also analyzed in the microscopic view by JCXA-T33 electron probe.The results show uhat the temperature has significant influence on the strength and Young's modulus of the aluminum laminate.With the increase of temperature,both the strength and Young's modulus of the aluminum laminate decrease.A model between Young's modulus of the aluminum laminate and temperatures is obtained by using Arrhenius equation.The predicted values by the model agree well with the experiment values.

Climatology and interannual variability of the annual mean Hadley circulation in CMIP5 models

Using 26 climate models from the Coupled Model Intercomparison Project Phase 5(CMIP5), climatology and the interannual variability of the annual mean Hadley circulation are evaluated. The results show that most of 26 models perform well in simulating the spatial structure of the climatology of the annual mean Hadley circulation, but the results derived from these models are generally weaker than that derived from the reanalysis dataset. Eighteen models can properly simulate well the asymmetric mode and symmetric mode of the annual mean Hadley circulation variability. Two models can only simulate asymmetric mode or symmetric mode and the other two models simulate reversed sequences of asymmetric mode and symmetric mode.The possible reason why some models cannot properly simulate the asymmetric mode and symmetric mode is that these models do not properly simulate the structure of zonal mean sea surface temperature(SST). Especially, not properly simulating variances of symmetric and asymmetric components of the SSTA will lead to reversed sequence of symmetric mode and asymmetric mode. And not properly simulated either symmetric or asymmetric component of the SSTA will lead to inability in simulating symmetric mode or asymmetric mode. On the other hand, some models properly simulate the asymmetric mode and symmetric mode, but do not properly simulate the responses to SST change.These models can not reflect the air sea coupling processes in associated with the Hadley circulation, therefore they should be taken more care when classify the models into groups.

Parameters and Trajectory Overall Optimization Design of the Combined Cycle Engine Reusable Launch Vehicle

Reusable launch vehicle is an important way to realize fast,cheap and reliable space transportation.A combined cycle engine system provides a more efficient and flexible form of power.The investigation on the research status of the combined cycle engine technology,including basic principle,research programs and classification of structure is firstly discussed in this paper.Then the bilevel hierarchical and integrated parameters/trajectory overall optimization technologies are applied to improve the efficiency and effectiveness of overall vehicle design.Simulations are implemented to compare and analyze the effectiveness and adaptability of the two algorithms,in order to provide the technical reserves and beneficial references for further research on combined cycle engine reusable launch vehicles.

Design and Implementation of Mobile Farmland Fertilization Expert System Based on iOS

In this study, taking cultivated land fertility evaluation data for example, we conducted a preliminary study of GIS theory and spatial data management, and construct the frame system of mobile structure based on the three layer structure model of application layer, business logic layer and data layer. Then we established a spatial data storage model, which has unified the data standards and achieved the management of spatial data and attribute database. Taking ArcGIS API for iOS as GIS platform, Xcode as the tool, we have realized the functions of data integration, data query, data statistics and fertilization recommendation, and constructed the management and service platform of mobile fertilization expert system.

An EcoCity model for regulating urban land cover structure and thermal environment： Taking Beijing as an example

Urban land-use/cover changes and their effects on the eco-environment have long been an active research topic in the urbanization field. However, the characteristics of urban inner spatial heterogeneity and its quantitative relationship with thermal environment are still poorly understood, resulting in ineffective application in urban ecological planning and management.Through the integration of "spatial structure theory" in urban geography and "surface energy balance" in urban climatology, we proposed a new concept of urban surface structure and thermal environment regulation to reveal the mechanism between urban spatial structure and surface thermal environment. We developed the EcoCity model for regulating urban land cover structure and thermal environment, and established the eco-regulation thresholds of urban surface thermal environments. Based on the comprehensive analysis of experimental observation, remotely sensed and meteorological data, we examined the spatial patterns of urban habitation, industrial, infrastructure service, and ecological spaces. We examined the impacts of internal land-cover components(e.g., urban impervious surfaces, greenness, and water) on surface radiation and heat flux. This research indicated that difference of thermal environments among urban functional areas is closely related to the proportions of the land-cover components.The highly dense impervious surface areas in commercial and residential zones significantly increased land surface temperature through increasing sensible heat flux, while greenness and water decrease land surface temperature through increasing latent heat flux. We also found that different functional zones due to various proportions of green spaces have various heat dissipation roles and ecological thresholds. Urban greening projects in highly dense impervious surfaces areas such as commercial, transportation, and residential zones are especially effective in promoting latent heat dissipation efficiency of vegetation, leading to strongly cooling effect of unit vegetation coverage. This research indicates that the EcoCity model provides the fundamentals to understand the coupled mechanism between urban land use structure and surface flux and the analysis of their spatiotemporal characteristics. This model provides a general computational model system for defining urban heat island mitigation, the greening ratio indexes, and their regulating thresholds for different functional zones.

Climate and extrema of ocean waves in the East China Sea

Wave climate plays an important role in the air-sea interaction over marginal seas. Extreme wave height provides fundamental information for various ocean engineering practices, such as hazard mitigation, coastal structure design, and risk assessment. In this paper, we implement a third generation wave model and conduct a high-resolution wave hindcast over the East China Sea to reconstruct a 15-year wave field from 1988 to 2002 for derivation of monthly mean wave parameters and analysis of extreme wave conditions. The numerical results of the wave field are validated through comparison with satellite altimetry measurements, low-resolution reanalysis, and the ocean wave buoy record. The monthly averaged wave height and wave period show seasonal variation and refined spatial patterns of surface waves in the East China Sea. The climatological significant wave height and mean wave period decrease from the open ocean in the southeast toward the continental area in the northwest, with the pattern generally following the bathymetry. Extreme analysis on the significant wave height at the buoy station indicates the hindcast data underestimate the extreme values relative to the observations. The spatial pattern of extreme wave height shows single peak emerges at the southwest of Ryukyu Island although a wind forcing with multi-core structure at the extreme is applied.

Spatial Structure and Development of Tourism Resources based on Point Pattern Analysis: A Case Study in Hainan Island, China

Tourism resources are the basic materials of tourism development, and they also provide the support for regional tourism spatial competition. The development of tourism depends on the degree to which tourism resources are utilized, and it is of great guiding significance for their development and utilization to study their spatial structure. Based on a large sample of data on tourism resources, and starting from the characteristics of multi-type,multi-level and multi-combination, this paper puts forward a framework and method for analyzing the spatial structure of tourism resources. Taking Hainan Island as an example, this paper describes the spatial structure of tourism resources in Hainan Island by using the method of point pattern analysis, identifies the tourism resource development zones, and puts forward some suggestions for the development of tourism resources. The results are as follows:(1) The characteristic scale of the spatial structure of tourism resources in Hainan Island is 30.5 km, and there are significant differences in the distributions of all kinds of tourism resources.(2) Through the spatial structure map of tourism resources, the tourism resource development zones are identified, including three tourist central city levels, “one horizontal and three vertical” tourist belts and four tourist combination areas.(3) By combing the distribution of tourism resources and the development zones in Hainan Island, the cross-border characteristics of the tourism resources and development zones are obvious. In order to give full play to the spatial combination and superposition effect of tourism resources, a change from a single isolated development mode to the overall combined development between regions is suggested. On the provincial scale, it is relatively accurate to describe the spatial structure of tourism resources for point data with a large sample size. However, the method of point pattern analysis can not only accurately describe the spatial structure of tourism resources, but it can also provide reference for other types of regional spatial analyses. The research results provide a scientific basis for the spatial planning of regional tourism resources and have practical significance for the development of regional tourism.

Dual Lie bialgebra structures of Poisson types

Let A = F [x, y] be the polynomial algebra on two variables x, y over an algebraically closed field F of characteristic zero. Under the Poisson bracket, A is equipped with a natural Lie algebra structure. It is proven that the maximal good subspace of A* induced from the multiplication of the associative commutative algebra A coincides with the maximal good subspace of A* induced from the Poisson bracket of the Poisson Lie algebra A. Based on this, structures of dual Lie bialgebras of the Poisson type are investigated. As by-products,five classes of new infinite-dimensional Lie algebras are obtained.

The theory of information images： Modeling based on diffusion equations

This work represents a formalized description of information and communicative interac- tions of individuals on the basis of theory of information images （II）. It also demonstrates how important it is to choose the models type adequate to the systems under research. It also introduces an explication of the possibility to create the model of information and communication interactions that can illustrate transmission of information between two and more individuals. Methods and approaches suggested in this paper allow us to compare different levels of the described processes depending on the chosen architecture of the model; the methods and approaches mentioned in the current work can be also used to simulate the processes of distortion and generation of information images while information and communication social interaction. Expansion and addition of informa- tion images theory in terms of transmission of information among individuals enables us to speak about the space of individual II. The existence of such a space and creation of correct formalized model help us to explain a number of characteristic phenomena of human thinking processes. As a result of this research, the authors introduce an equa- tion that describes the spatial and structural evolution of individual II. There is also an example of modeling on the basis of this theory taking into account the results of the experiment （bilingual Stroop test）.