针对单矢量水听器多重信号分类(Multiple Signal Classification,MUSIC)算法在低信噪比条件下,存在谱峰宽度变宽、估计精度变低等性能恶化的问题,提出一种基于单矢量水听器空间谱增强的改进MUSIC算法。该算法的基本原理是:单声源入射到...针对单矢量水听器多重信号分类(Multiple Signal Classification,MUSIC)算法在低信噪比条件下,存在谱峰宽度变宽、估计精度变低等性能恶化的问题,提出一种基于单矢量水听器空间谱增强的改进MUSIC算法。该算法的基本原理是:单声源入射到单只矢量水听器上时,加一参考信号源,若两者方位相同,则同方位叠加使空间谱增强;若两者方位不相同,则两方位合成,使空间谱估计产生偏差。因此,改变参考信号源的方位,当参考信号源的方位与信号源的方位一致时,将使谱峰得到增强,此时空间谱达到最大值,其对应的角度即为信号源的方位角。仿真分析及实验数据处理结果表明,与常规MUSIC算法相比,该算法具有更尖锐的谱峰、更高的估计精度,能够实现更好的空间谱估计。展开更多
Single-molecule tip-enhanced Raman spectroscopy(TERS)has emerged as an important technique for structural analysis at sub-molecular scale.Here in this work,we report a TERS study of an isolated free-base porphyrin mol...Single-molecule tip-enhanced Raman spectroscopy(TERS)has emerged as an important technique for structural analysis at sub-molecular scale.Here in this work,we report a TERS study of an isolated free-base porphyrin molecule adsorbed on the Ag(100)surface at cryogenic temperature(~7 K).Site-dependent TERS spectra reveal distinct local vibrational information for the chemical constituents within a single molecule.Moreover,distinct spatial features among different Raman peaks can be resolved from the TERS mapping images.These images are found to associate with related vibrational modes,enabling to resolve the mode associated with N-H bonds at the sub-nanometer level.This study will provide deep insights into the symmetry of adsorption configurations and local vibrational information within a single molecule.展开更多
文摘针对单矢量水听器多重信号分类(Multiple Signal Classification,MUSIC)算法在低信噪比条件下,存在谱峰宽度变宽、估计精度变低等性能恶化的问题,提出一种基于单矢量水听器空间谱增强的改进MUSIC算法。该算法的基本原理是:单声源入射到单只矢量水听器上时,加一参考信号源,若两者方位相同,则同方位叠加使空间谱增强;若两者方位不相同,则两方位合成,使空间谱估计产生偏差。因此,改变参考信号源的方位,当参考信号源的方位与信号源的方位一致时,将使谱峰得到增强,此时空间谱达到最大值,其对应的角度即为信号源的方位角。仿真分析及实验数据处理结果表明,与常规MUSIC算法相比,该算法具有更尖锐的谱峰、更高的估计精度,能够实现更好的空间谱估计。
基金supported by the National Key R&D Program of China(No.2016YFA0200600)the National Natural Science Foundation of China,the Chinese Academy of Sciences+1 种基金Anhui Initiative in Quantum Information TechnologiesAtif Ghafoor acknowledges support by the China Scholarship Council
文摘Single-molecule tip-enhanced Raman spectroscopy(TERS)has emerged as an important technique for structural analysis at sub-molecular scale.Here in this work,we report a TERS study of an isolated free-base porphyrin molecule adsorbed on the Ag(100)surface at cryogenic temperature(~7 K).Site-dependent TERS spectra reveal distinct local vibrational information for the chemical constituents within a single molecule.Moreover,distinct spatial features among different Raman peaks can be resolved from the TERS mapping images.These images are found to associate with related vibrational modes,enabling to resolve the mode associated with N-H bonds at the sub-nanometer level.This study will provide deep insights into the symmetry of adsorption configurations and local vibrational information within a single molecule.
