1-butyl-3-methylimidazolium perchlorate([BMIM]ClO4) was synthesized by two steps with N-methylimidazolium.Some physico-chemical properties,such as density,surface tension,viscosity,electrical conductivity as well as e...1-butyl-3-methylimidazolium perchlorate([BMIM]ClO4) was synthesized by two steps with N-methylimidazolium.Some physico-chemical properties,such as density,surface tension,viscosity,electrical conductivity as well as electrochemical window,were investigated and solvent performance was also studied.The results show that this kind of ionic liquid is an excellent electrolyte with low viscosity,high electrical conductivity and wide electrochemical window.In addition,[BMIM]ClO4 is soluble in most conventional solvents and some metal oxides have high solubility in it,which lays the foundation of direct electrolysis of metal oxides in this ionic liquid.展开更多
Ionic liquids （ILs） are organic salts with low melting points, which have many unusual properties like negligible vapor pressure, good thermal stability, non-flammability, wide liquid range and electrochemical windo...Ionic liquids （ILs） are organic salts with low melting points, which have many unusual properties like negligible vapor pressure, good thermal stability, non-flammability, wide liquid range and electrochemical window, and excellent solvation power for both organic and inorganic substances. The unique characteristics of ILs endow them with great potential for applications in different fields including chem- ical reactions, extraction and separation, material science, renewable energy, environment, and photoelectric trans- formations. Their properties can be tuned to suit various applications by changing the structures of the cations and/or anions.展开更多
基金Project(50574031) supported by the National Natural Science Foundation of China
文摘1-butyl-3-methylimidazolium perchlorate([BMIM]ClO4) was synthesized by two steps with N-methylimidazolium.Some physico-chemical properties,such as density,surface tension,viscosity,electrical conductivity as well as electrochemical window,were investigated and solvent performance was also studied.The results show that this kind of ionic liquid is an excellent electrolyte with low viscosity,high electrical conductivity and wide electrochemical window.In addition,[BMIM]ClO4 is soluble in most conventional solvents and some metal oxides have high solubility in it,which lays the foundation of direct electrolysis of metal oxides in this ionic liquid.
文摘Ionic liquids （ILs） are organic salts with low melting points, which have many unusual properties like negligible vapor pressure, good thermal stability, non-flammability, wide liquid range and electrochemical window, and excellent solvation power for both organic and inorganic substances. The unique characteristics of ILs endow them with great potential for applications in different fields including chem- ical reactions, extraction and separation, material science, renewable energy, environment, and photoelectric trans- formations. Their properties can be tuned to suit various applications by changing the structures of the cations and/or anions.
