A three-dimensional large eddy simulation （LES） of a spatially developing round jet is carried out in cylindrical coordinates using a dynamic subgrid model with strong inflow instability. Evolutions of large-scale v...A three-dimensional large eddy simulation （LES） of a spatially developing round jet is carried out in cylindrical coordinates using a dynamic subgrid model with strong inflow instability. Evolutions of large-scale vortex structures represented by tangential vortices are obtained and compared with flow visualization. Also presented are three-dimensional spatial evolutions of coherent structure, which are of quasi two-dimensional Kelvin-Helmholtz instability and vortex rings as well as breaking up of the vortex rings with fully three-dimensional characteristics. Predicted results of mean velocity and turbulent intensity agree well with experiments. They are also compared with the results predicted by LES using standard Smagorinsky model and show good self-similarity. Turbulence spectrum of the predicted velocity shows the -5/3 decay for higher wave number, as expected for turbulent round jet flows. In addition, fl-test and y-test are carded out for the instantaneous velocity, showing that the present LES method can successfully predict the hierarchical structure of round jet.展开更多
The construction of transition metal-based catalysts with high activity and stability has been widely regarded as a promising method to replace the precious metal Pt for oxygen reduction reaction(ORR).Herein,we synthe...The construction of transition metal-based catalysts with high activity and stability has been widely regarded as a promising method to replace the precious metal Pt for oxygen reduction reaction(ORR).Herein,we synthesized CoFe alloy nanoparticle-embedded N-doped graphitic carbon(CoFe/NC)nanostructures as ORR electrocatalysts.The ZIF-67(zeolitic imidazolate framework,ZIF)nanocubes were first synthesized,followed by an introduction of Fe2+ions to form CoFe-ZIF precursors via a simple ion-exchange route.Subsequently,the CoFe/NC composites were synthesized through a facile pyrolysis strategy.The ORR activity and the contents of cobalt and iron could be effectively adjusted by controlling the solution concentration of Fe2+ions used for the ion exchange and the pyrolysis temperature.The CoFe/NC-0.2-900 composite(synthesized with 0.2 mmol of FeSO4·7H2O at a pyrolysis temperature of 900℃)exhibited ORR activity that was superior to the other samples owing to a synergistic effect of the bimetal,especially considering the extremely high limiting current density of 6.4 mA cm^-2 compared with that of Pt/C(5.1 mA cm^-2).Rechargeable Zn-air batteries were assembled employing CoFe/NC-0.2-900 and NiFeP/NF(NiFeP supported on nickel foam(NF))as the catalysts for the discharging and charging processes,respectively,The above materials achieved reduced discharging and charging platforms,high power density,and prolonged cycling stability compared with conventional Pt/C+RuO2/C catalysts.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos. 50176027 and 50706021)a grant from the Research Committee of The Hong Kong Polytechnic University (Grant No.G-U294)
文摘A three-dimensional large eddy simulation （LES） of a spatially developing round jet is carried out in cylindrical coordinates using a dynamic subgrid model with strong inflow instability. Evolutions of large-scale vortex structures represented by tangential vortices are obtained and compared with flow visualization. Also presented are three-dimensional spatial evolutions of coherent structure, which are of quasi two-dimensional Kelvin-Helmholtz instability and vortex rings as well as breaking up of the vortex rings with fully three-dimensional characteristics. Predicted results of mean velocity and turbulent intensity agree well with experiments. They are also compared with the results predicted by LES using standard Smagorinsky model and show good self-similarity. Turbulence spectrum of the predicted velocity shows the -5/3 decay for higher wave number, as expected for turbulent round jet flows. In addition, fl-test and y-test are carded out for the instantaneous velocity, showing that the present LES method can successfully predict the hierarchical structure of round jet.
基金the support of the National Natural Science Foundation of China (21771059, 21631004 and 21571054)the Natural Science Foundation of Heilongjiang Province (JJ2019YX0122)+1 种基金Heilongjiang Provincial Postdoctoral Science Foundation (LBH-Q16194)the excellent Youth Foundation of Heilongjiang University (JC201706)
文摘The construction of transition metal-based catalysts with high activity and stability has been widely regarded as a promising method to replace the precious metal Pt for oxygen reduction reaction(ORR).Herein,we synthesized CoFe alloy nanoparticle-embedded N-doped graphitic carbon(CoFe/NC)nanostructures as ORR electrocatalysts.The ZIF-67(zeolitic imidazolate framework,ZIF)nanocubes were first synthesized,followed by an introduction of Fe2+ions to form CoFe-ZIF precursors via a simple ion-exchange route.Subsequently,the CoFe/NC composites were synthesized through a facile pyrolysis strategy.The ORR activity and the contents of cobalt and iron could be effectively adjusted by controlling the solution concentration of Fe2+ions used for the ion exchange and the pyrolysis temperature.The CoFe/NC-0.2-900 composite(synthesized with 0.2 mmol of FeSO4·7H2O at a pyrolysis temperature of 900℃)exhibited ORR activity that was superior to the other samples owing to a synergistic effect of the bimetal,especially considering the extremely high limiting current density of 6.4 mA cm^-2 compared with that of Pt/C(5.1 mA cm^-2).Rechargeable Zn-air batteries were assembled employing CoFe/NC-0.2-900 and NiFeP/NF(NiFeP supported on nickel foam(NF))as the catalysts for the discharging and charging processes,respectively,The above materials achieved reduced discharging and charging platforms,high power density,and prolonged cycling stability compared with conventional Pt/C+RuO2/C catalysts.
