文章依托君康顺义养老社区项目及国内目前老龄化现象加剧的现状,对养老住宅社区进行深入的设计研究。首先对国内外养老住宅社区进行查找梳理,吸取优秀项目的设计经验及成熟的设计手法,其次针对适老化设计板块查阅大量相关资料及文献,将...文章依托君康顺义养老社区项目及国内目前老龄化现象加剧的现状,对养老住宅社区进行深入的设计研究。首先对国内外养老住宅社区进行查找梳理,吸取优秀项目的设计经验及成熟的设计手法,其次针对适老化设计板块查阅大量相关资料及文献,将养老住宅设计进行详细的子项细分及模式分类,最终选取较为合适的设计手法用于其中。针对国内老龄化发展较为迅速及顺义新城的地理位置和项目的自身特点,采用现在国际上较为成熟的持续照料退休社区(continuing care retirement community,CCRC)的养老社区模式。在项目的设计过程中主要针对总图规划、功能分区、产品设计及造型立面等模块进行逐一专项设计,在保证满足适老化规范的前提下更好地营造一个老有所养、老有所依的复合型高端养老住宅社区。展开更多
Quasi-classical trajectory calculations have been employed to investigate the influence of collision energy on the stereodynamics of the title reaction C+CD--~C2+D on the poten- tial energy surface of the 12AI state...Quasi-classical trajectory calculations have been employed to investigate the influence of collision energy on the stereodynamics of the title reaction C+CD--~C2+D on the poten- tial energy surface of the 12AI state developed by Boggio-Pasqua et al. [Mol. Phys. 98, 1925 (2000)]. The product angular distributions which reflect the vector correlation have been calculated. In addition, two polarization-dependent different cross-sections are also presented in the center-of-mass frame respectively. The results indicate that the product C2 is sensitively affected by collision energy.展开更多
In this paper, the effect of of flank wear polycrystalline cubic boron nitride (PCBN) tools on residual stresses, white layer and roughness of machined workpiece surfaces is studied. Experimental results indicate th...In this paper, the effect of of flank wear polycrystalline cubic boron nitride (PCBN) tools on residual stresses, white layer and roughness of machined workpiece surfaces is studied. Experimental results indicate that with the increase of the tool wear, the surface of the machined workpiece tends to generate tensile residual stresses, and white layer becomes clearly thicker and uneven on the workpiece surface. The effect of the flank wear on the surface roughness is less within some range of flank wear value. The results show that it is possible to produce ideal surface integrality levels by controlling the tool flank wear.展开更多
The oxygen reduction reaction(ORR)on the cathode of a polymer electrolyte fuel cell requires the use of a catalyst based on Pt,one of the most expensive metals on the earth.A number of strategies,including optimizatio...The oxygen reduction reaction(ORR)on the cathode of a polymer electrolyte fuel cell requires the use of a catalyst based on Pt,one of the most expensive metals on the earth.A number of strategies,including optimization of a different metal into the core,have been investigated to enhance the activity of a Pt-based catalyst and thus reduce the loading of Pt.By dedicating to compounding high catalytic activity Pt_(2.7)Pd_(0.3)Ni concave cubic with high index crystal face,the paper shows that concave structures can offer more active site and high level of catalytic activity and if mixed with other metal,decrease the proportion of Pt and improve its mass activity.The paper also makes an exploration into the theory and conditions behind the formation of Pt_(2.7)Pd_(0.3)Ni concave cubic structure,and investigates the difference it demonstrates by modifying the reactive conditions.The results of the oxygen reduction performance of the electrochemical test are as follows:the concave cube-shaped Pt-Pd-Ni catalyst has a mass activity of 1.28 A mg_(Pt)^(–1) at 0.9 V,its highest mass activity is 8.20 times that of commercial Pt/C,and its specific activity is 8.68 times of that commercial Pt/C.And the Pt-Pd-Ni ternary nanocage has excellent structural invariance.After the stability test,there is no obvious structural change and performance degradation in the nanostructure.展开更多
Theoretical investigations on the stereodynamics of the O(3P)+D2 reaction have been calculated by means of the quasi-classical trajectory to study the product rotational polarization at collision energy of 104.5 k ...Theoretical investigations on the stereodynamics of the O(3P)+D2 reaction have been calculated by means of the quasi-classical trajectory to study the product rotational polarization at collision energy of 104.5 k J/tool on the potential energy surface of the ground 3A" triplet state. The vector properties including angular momentum alignment distributions and four polarization dependent generalized differential cross-sections of product have been presented. Furthermore, the influence of reagent vibrational excitation on the product vector properties has also been studied. The results indicate that the vector properties are sensitively affected by reagent vibrational excitation.展开更多
In this paper, we use the optimum interpolation sea surface temperature (OISST) provided by the National Center for Environmental Prediction (NCEP) to replace the temperature in the top three layers in the ISHII data,...In this paper, we use the optimum interpolation sea surface temperature (OISST) provided by the National Center for Environmental Prediction (NCEP) to replace the temperature in the top three layers in the ISHII data, and make use of the modified ISHII temperature data to calculate the thermosteric sea level (called modified steric sea level (SSL) hereafter). We subtract the modified SSL and the steric sea level (called ordinary SSL hereafter) derived from the ISHII temperature and salinity from the steric sea level (SSL) provided by the Gravity Recovery and Climate Experiment (GRACE), respectively, and find that the rms error of the difference of the former is obviously smaller than that of the latter. Therefore we reach the conclusion that under the assumption that the GRACE SSL is accurate, the modified SSL can reflect the true steric sea level more accurately. Making use of the modified SSL, we can find that the modified SSL in sea areas of different spatial scales shows an obvious rising trend in the upper 0-700 m layer for the period 1982-2006. The global mean SSL rises with a rate of 0.6 mm year-1 .The modified SSLs in sea areas of different spatial scales all show obvious oscillations with period of one year. There are oscillations with periods of 4-8 years in global oceans and with periods of 2-7 years in the Pacific. The Empirical Orthogonal Function method is applied to the sea areas of different spatial scales and we find that the first modes all have obvious 1-year period oscillations, the first mode of the global ocean has 4-8 year period oscillations, and that of the Pacific has 2-6 year period oscillations. The spatial distribution of the linear rising trend of the global modified SSL in the upper 0-700 m layer is inhomogeneous with intense regional characteristics. The modified SSL linear trend indicates a zonal dipole in the tropical Pacific, rising in the west and descending in the east. In the North Atlantic, the modified SSL indicates a meridional dipole, rising in the latitude band of 20°N-40°N and 45°N-65.5°N and descending obviously in the latitude band of 40°N-45°N.展开更多
A recent study has revealed a full 3-dimentional reactive scattering picture of the reaction CI+CHD3(v1=1) as the C1 atoms attack CHD3 from various directions respective to the C-H stretching bond. The reported pol...A recent study has revealed a full 3-dimentional reactive scattering picture of the reaction CI+CHD3(v1=1) as the C1 atoms attack CHD3 from various directions respective to the C-H stretching bond. The reported polarization-dependent differential cross sections provide the most detailed characterization of the influences of reagent alignments on reactivity. To convey the stereo-specific information more accessible to general chemists, we show here, by proper symmetry considerations, how to retrieve from the measurements the relative integral and differential cross sections of two most common collision geometries: the end-on versus side-on attacks. The results, albeit coarse-grained, provide an appealing picture that not only reinforces our intuition about chemical reactivity, but also sheds more light on the conventional (unpolarized) attributes.展开更多
The Greenland Sea,Iceland Sea,and Norwegian Sea (GIN seas) form the main channel connecting the Arctic Ocean with other Oceans,where significant water and energy exchange take place,and play an important role in globa...The Greenland Sea,Iceland Sea,and Norwegian Sea (GIN seas) form the main channel connecting the Arctic Ocean with other Oceans,where significant water and energy exchange take place,and play an important role in global climate change.In this study steric sea level,associated with temperature and salinity,in the GIN seas is examined based on analysis of the monthly temperature and salinity fields from Polar science center Hydrographic Climatology (PHC3.0).A method proposed by Tabata et al.is used to calculate steric sea level,in which,steric sea level change due to thermal expansion and haline contraction is termed as the thermosteric component (TC) and the halosteric component (SC),recpectively.Total steric sea level (TSSL) change is the sum of TC and SC.The study shows that SC is making more contributions than TC to the seasonal change of TSSL in the Greenland Sea,whereas TC contributes more in the Norwegian and the Iceland Seas.Annual variation of TSSL is larger than 50 mm over most regions of the GIN Seas,and can be larger than 200 mm at some locations such as 308 mm at 76.5 N,12.5 E and 246 mm at 77.5 N,17.5 W.展开更多
文摘文章依托君康顺义养老社区项目及国内目前老龄化现象加剧的现状,对养老住宅社区进行深入的设计研究。首先对国内外养老住宅社区进行查找梳理,吸取优秀项目的设计经验及成熟的设计手法,其次针对适老化设计板块查阅大量相关资料及文献,将养老住宅设计进行详细的子项细分及模式分类,最终选取较为合适的设计手法用于其中。针对国内老龄化发展较为迅速及顺义新城的地理位置和项目的自身特点,采用现在国际上较为成熟的持续照料退休社区(continuing care retirement community,CCRC)的养老社区模式。在项目的设计过程中主要针对总图规划、功能分区、产品设计及造型立面等模块进行逐一专项设计,在保证满足适老化规范的前提下更好地营造一个老有所养、老有所依的复合型高端养老住宅社区。
文摘Quasi-classical trajectory calculations have been employed to investigate the influence of collision energy on the stereodynamics of the title reaction C+CD--~C2+D on the poten- tial energy surface of the 12AI state developed by Boggio-Pasqua et al. [Mol. Phys. 98, 1925 (2000)]. The product angular distributions which reflect the vector correlation have been calculated. In addition, two polarization-dependent different cross-sections are also presented in the center-of-mass frame respectively. The results indicate that the product C2 is sensitively affected by collision energy.
基金Supported by the National Natural Science Foundation of China(No.50875068),and the National High Technology Research and Development Programme of China(No.2009AA044302).
文摘In this paper, the effect of of flank wear polycrystalline cubic boron nitride (PCBN) tools on residual stresses, white layer and roughness of machined workpiece surfaces is studied. Experimental results indicate that with the increase of the tool wear, the surface of the machined workpiece tends to generate tensile residual stresses, and white layer becomes clearly thicker and uneven on the workpiece surface. The effect of the flank wear on the surface roughness is less within some range of flank wear value. The results show that it is possible to produce ideal surface integrality levels by controlling the tool flank wear.
文摘The oxygen reduction reaction(ORR)on the cathode of a polymer electrolyte fuel cell requires the use of a catalyst based on Pt,one of the most expensive metals on the earth.A number of strategies,including optimization of a different metal into the core,have been investigated to enhance the activity of a Pt-based catalyst and thus reduce the loading of Pt.By dedicating to compounding high catalytic activity Pt_(2.7)Pd_(0.3)Ni concave cubic with high index crystal face,the paper shows that concave structures can offer more active site and high level of catalytic activity and if mixed with other metal,decrease the proportion of Pt and improve its mass activity.The paper also makes an exploration into the theory and conditions behind the formation of Pt_(2.7)Pd_(0.3)Ni concave cubic structure,and investigates the difference it demonstrates by modifying the reactive conditions.The results of the oxygen reduction performance of the electrochemical test are as follows:the concave cube-shaped Pt-Pd-Ni catalyst has a mass activity of 1.28 A mg_(Pt)^(–1) at 0.9 V,its highest mass activity is 8.20 times that of commercial Pt/C,and its specific activity is 8.68 times of that commercial Pt/C.And the Pt-Pd-Ni ternary nanocage has excellent structural invariance.After the stability test,there is no obvious structural change and performance degradation in the nanostructure.
文摘Theoretical investigations on the stereodynamics of the O(3P)+D2 reaction have been calculated by means of the quasi-classical trajectory to study the product rotational polarization at collision energy of 104.5 k J/tool on the potential energy surface of the ground 3A" triplet state. The vector properties including angular momentum alignment distributions and four polarization dependent generalized differential cross-sections of product have been presented. Furthermore, the influence of reagent vibrational excitation on the product vector properties has also been studied. The results indicate that the vector properties are sensitively affected by reagent vibrational excitation.
基金supported by the National Natural Science Foundation of China (Grants 40806072, 40906002 and 41176009)Public Science and Technology Research Funds Projects of Ocean (201005019)
文摘In this paper, we use the optimum interpolation sea surface temperature (OISST) provided by the National Center for Environmental Prediction (NCEP) to replace the temperature in the top three layers in the ISHII data, and make use of the modified ISHII temperature data to calculate the thermosteric sea level (called modified steric sea level (SSL) hereafter). We subtract the modified SSL and the steric sea level (called ordinary SSL hereafter) derived from the ISHII temperature and salinity from the steric sea level (SSL) provided by the Gravity Recovery and Climate Experiment (GRACE), respectively, and find that the rms error of the difference of the former is obviously smaller than that of the latter. Therefore we reach the conclusion that under the assumption that the GRACE SSL is accurate, the modified SSL can reflect the true steric sea level more accurately. Making use of the modified SSL, we can find that the modified SSL in sea areas of different spatial scales shows an obvious rising trend in the upper 0-700 m layer for the period 1982-2006. The global mean SSL rises with a rate of 0.6 mm year-1 .The modified SSLs in sea areas of different spatial scales all show obvious oscillations with period of one year. There are oscillations with periods of 4-8 years in global oceans and with periods of 2-7 years in the Pacific. The Empirical Orthogonal Function method is applied to the sea areas of different spatial scales and we find that the first modes all have obvious 1-year period oscillations, the first mode of the global ocean has 4-8 year period oscillations, and that of the Pacific has 2-6 year period oscillations. The spatial distribution of the linear rising trend of the global modified SSL in the upper 0-700 m layer is inhomogeneous with intense regional characteristics. The modified SSL linear trend indicates a zonal dipole in the tropical Pacific, rising in the west and descending in the east. In the North Atlantic, the modified SSL indicates a meridional dipole, rising in the latitude band of 20°N-40°N and 45°N-65.5°N and descending obviously in the latitude band of 40°N-45°N.
文摘A recent study has revealed a full 3-dimentional reactive scattering picture of the reaction CI+CHD3(v1=1) as the C1 atoms attack CHD3 from various directions respective to the C-H stretching bond. The reported polarization-dependent differential cross sections provide the most detailed characterization of the influences of reagent alignments on reactivity. To convey the stereo-specific information more accessible to general chemists, we show here, by proper symmetry considerations, how to retrieve from the measurements the relative integral and differential cross sections of two most common collision geometries: the end-on versus side-on attacks. The results, albeit coarse-grained, provide an appealing picture that not only reinforces our intuition about chemical reactivity, but also sheds more light on the conventional (unpolarized) attributes.
基金funded by the National Natural Science Foundation of China (40806072)the National Science And Technology Supporting Plan (2007BAC03A0606)
文摘The Greenland Sea,Iceland Sea,and Norwegian Sea (GIN seas) form the main channel connecting the Arctic Ocean with other Oceans,where significant water and energy exchange take place,and play an important role in global climate change.In this study steric sea level,associated with temperature and salinity,in the GIN seas is examined based on analysis of the monthly temperature and salinity fields from Polar science center Hydrographic Climatology (PHC3.0).A method proposed by Tabata et al.is used to calculate steric sea level,in which,steric sea level change due to thermal expansion and haline contraction is termed as the thermosteric component (TC) and the halosteric component (SC),recpectively.Total steric sea level (TSSL) change is the sum of TC and SC.The study shows that SC is making more contributions than TC to the seasonal change of TSSL in the Greenland Sea,whereas TC contributes more in the Norwegian and the Iceland Seas.Annual variation of TSSL is larger than 50 mm over most regions of the GIN Seas,and can be larger than 200 mm at some locations such as 308 mm at 76.5 N,12.5 E and 246 mm at 77.5 N,17.5 W.