[Objective] This study aimed to investigate the adsorption and desorption characteristics of cadmium and lead in typical paddy soils of Jiangxi Province. [Method] Gleyed paddy soil and waterloggogenic paddy soil were ...[Objective] This study aimed to investigate the adsorption and desorption characteristics of cadmium and lead in typical paddy soils of Jiangxi Province. [Method] Gleyed paddy soil and waterloggogenic paddy soil were collected from Jiangxi Province and used as experimental materials to investigate single and com- petitive adsorption and desorption behaviors of cadmium and lead by batch equilib- rium method. The environmental risk of the presence of cadmium and lead in paddy soils was assessed using distribution coefficients. [Result] Under equal ratio condi- tions, the adsorption capacity of lead by two types of paddy soils was higher than that of cadmium, and the adsorption rate in waterloggogenic paddy soil was higher than that in gleyed paddy soil. The desorption capacity of cadmium by two types of paddy soils was higher than that of lead, and the desorption rate in gleyed paddy soil was higher than that in waterloggogenic paddy soil. Under competitive condi- tions, the adsorption capacity of cadmium and lead by paddy soils was significantly reduced compared with single ion system, while the desorption rate was remarkably improved. The potential environmental risk of cadmium contamination was greater than that of lead in paddy soils. Moreover, environmental risks of cadmium and lead were reduced with the increase of pH, which increased significantly under the coex- istence state. [Conclusion] In the coexistence of cadmium and lead, cadmium con- tamination should be controlled and avoided compared with lead contamination in paddy soils.展开更多
[Objective] This study was conducted to investigate the adsorption and desorption characteristics of Cu and Pb in typical paddy soils in Jiangxi Province. [Method] Two kinds of typical paddy soils (Gley type, Waterlo...[Objective] This study was conducted to investigate the adsorption and desorption characteristics of Cu and Pb in typical paddy soils in Jiangxi Province. [Method] Two kinds of typical paddy soils (Gley type, Waterloggogenic type) in Jiangxi Province were chosen as test materials. The single and competitive adsorption behaviors of Cu and Pb in paddy soils were investigated with batch equilibrium method, and the environmental risk under coexistence of Cu and Pb in these soils was estimated with distribution coefficient. The results showed that under equal proportion, the adsorption affinity of Pb was greater than that of Cu in the two paddy soils, and the adsorption capacities in waterloggogenic paddy soil (WPS) were significantly higher than those in gley paddy soil (GTPS), but the desorption capacities of Cu were greater than those of Pb in the two paddy soils, and the desorption capacities in GTPS were significantly higher than those in the WPS. The adsorption capacities of Cu and Pb ions under competitive condition were obviously lower than those in single system, while the desorption rates significantly increased. The potential environmental risk of Cu pollution was greater than that of Pb in paddy soils, and their environmental risk decreased with the increase of pH, but increased significantly under coexistence of lead and copper. [Conclusion] This research suggests that when Cu and Pb ions coexist in the paddy soils, compared with lead pollution, we should pay attention to the pollution of Cu.展开更多
基金Supported by Science and Technology Research Project of Jiangxi Education Department(GJJ14289)Science and Technology Research Project of Environmental Protection Department of Jiangxi Province(JXHBKJ2013-4)Special Fund for Visiting Scholars from the Development Program for Middle-aged and Young Teachers in Colleges of Jiangxi Province(GJGH[2014]N0.15)
文摘[Objective] This study aimed to investigate the adsorption and desorption characteristics of cadmium and lead in typical paddy soils of Jiangxi Province. [Method] Gleyed paddy soil and waterloggogenic paddy soil were collected from Jiangxi Province and used as experimental materials to investigate single and com- petitive adsorption and desorption behaviors of cadmium and lead by batch equilib- rium method. The environmental risk of the presence of cadmium and lead in paddy soils was assessed using distribution coefficients. [Result] Under equal ratio condi- tions, the adsorption capacity of lead by two types of paddy soils was higher than that of cadmium, and the adsorption rate in waterloggogenic paddy soil was higher than that in gleyed paddy soil. The desorption capacity of cadmium by two types of paddy soils was higher than that of lead, and the desorption rate in gleyed paddy soil was higher than that in waterloggogenic paddy soil. Under competitive condi- tions, the adsorption capacity of cadmium and lead by paddy soils was significantly reduced compared with single ion system, while the desorption rate was remarkably improved. The potential environmental risk of cadmium contamination was greater than that of lead in paddy soils. Moreover, environmental risks of cadmium and lead were reduced with the increase of pH, which increased significantly under the coex- istence state. [Conclusion] In the coexistence of cadmium and lead, cadmium con- tamination should be controlled and avoided compared with lead contamination in paddy soils.
基金Supported by the Research Project of Jiangxi Education Department(GJJ14289)the Research Project of Environmental Protection Department of Jiangxi Province(JXHBKJ2013-4)the Special Fund for Visiting Scholar of the Development Plan for Middle-aged and Young Teachers in Colleges of Jiangxi Province(No.GJGH[2014]15)~~
文摘[Objective] This study was conducted to investigate the adsorption and desorption characteristics of Cu and Pb in typical paddy soils in Jiangxi Province. [Method] Two kinds of typical paddy soils (Gley type, Waterloggogenic type) in Jiangxi Province were chosen as test materials. The single and competitive adsorption behaviors of Cu and Pb in paddy soils were investigated with batch equilibrium method, and the environmental risk under coexistence of Cu and Pb in these soils was estimated with distribution coefficient. The results showed that under equal proportion, the adsorption affinity of Pb was greater than that of Cu in the two paddy soils, and the adsorption capacities in waterloggogenic paddy soil (WPS) were significantly higher than those in gley paddy soil (GTPS), but the desorption capacities of Cu were greater than those of Pb in the two paddy soils, and the desorption capacities in GTPS were significantly higher than those in the WPS. The adsorption capacities of Cu and Pb ions under competitive condition were obviously lower than those in single system, while the desorption rates significantly increased. The potential environmental risk of Cu pollution was greater than that of Pb in paddy soils, and their environmental risk decreased with the increase of pH, but increased significantly under coexistence of lead and copper. [Conclusion] This research suggests that when Cu and Pb ions coexist in the paddy soils, compared with lead pollution, we should pay attention to the pollution of Cu.