The effect of Zn addition on microstructure and mechanical properties of the Mg-2Er alloy was investigated by X-ray diffraction （XRD） and scanning electron microscope （SEM）. The results show that the alloys with 1...The effect of Zn addition on microstructure and mechanical properties of the Mg-2Er alloy was investigated by X-ray diffraction （XRD） and scanning electron microscope （SEM）. The results show that the alloys with 1%and 2%Zn （mass fraction） are composed of the W-phase and theα-Mg matrix. Meanwhile, the addition of 4%-10%Zn results in the formation of the I-phase, the W-phase and theα-Mg matrix. When the addition of Zn reaches 12%, the W-phase disappears and the phase constituents of the alloys mainly include the I-phase and the Mg4Zn7 phase besides theα-Mg solid solution. The alloy containing 6%Zn has better mechanical properties, of which the ultimate tensile strength （UTS） and the yield tensile strength （YTS） are about 224 MPa and 134 MPa, respectively, companying an elongation of 10.4%.展开更多
Mg-14Li-1Al （LA141）, LA141-0.3Y, LA141-0.3Sr, and LA141-0.3Y-0.3Sr alloys were prepared in an induction furnace in the argon atmosphere. The microstructures of these alloys were investigated through scanning electro...Mg-14Li-1Al （LA141）, LA141-0.3Y, LA141-0.3Sr, and LA141-0.3Y-0.3Sr alloys were prepared in an induction furnace in the argon atmosphere. The microstructures of these alloys were investigated through scanning electron microscope （SEM）, X-ray diffractometer （XRD） and energy dispersive spectrometer （EDS）. The results show that yttrium and/or strontium additions produce a strong grain refining effect in LA141 alloy. The mean grain sizes of the alloys with addition of Y and/or Sr are reduced remarkably from 600 to 500, 260, 230 μm, respectively. Al 2 Y, Al 4 Sr and Mg 17 Sr 2 phases with different morphologies are verified and exist inside the grain or at the grain boundaries, thus possibly act as heterogeneous nucleation sites and pin up grain boundaries, which restrain the grain growth.展开更多
Wrought magnesium alloy sheets were butt welded with gas metal arc welding process. Pores in the weld were investigated under different welding parameters, the causes of pore formation were systematically disposed, an...Wrought magnesium alloy sheets were butt welded with gas metal arc welding process. Pores in the weld were investigated under different welding parameters, the causes of pore formation were systematically disposed, and the effects of porosity on the microstructure and mechanical properties of the joint were analyzed. The microstructure examination shows that the pores mainly appear close to the top or bottom part of the weld, and could connect to each other and lead to the formation of cracks in the welds. However, the pores can be controlled with proper welding parameters. The tensile testing results reveal that the average joint strength is close to or higher than that of the base metal. The microhardness in the weld can be even higher than that in the base metal due to the second ohase strengthening of β-Mg17（A1, Zn）12 formed in the weld.展开更多
The corrosion behaviors and mechanism of the as-rolled Mg-x Zn-0.5Er(x=0.5, 2.0, 3.0 and 4.0, in wt.%)alloys were investigated. The potential difference between the second phase and matrix was determined by the type a...The corrosion behaviors and mechanism of the as-rolled Mg-x Zn-0.5Er(x=0.5, 2.0, 3.0 and 4.0, in wt.%)alloys were investigated. The potential difference between the second phase and matrix was determined by the type and size of the second phases. The dominated nano-scale W-phase on matrix in the Mg-0.5Zn-0.5Er alloy induced a sharp local pitting corrosion. However, as the volume fraction of the coarse W-phase or I-phase increased, the corrosion reaction was inclined to happen around the coarse W-phase or I-phase preferentially, leading to an obvious uniform corrosion and great acceleration of corrosion rate. The long-term immersion(14 d) results indicated that the corrosion resistance decreasing sequence was Mg-0.5Zn-0.5Er > Mg-2.0Zn-0.5Er > Mg-3.0Zn-0.5Er > Mg-4.0Zn-0.5Er.展开更多
The effects of solution treatment on the evolution of the second phases and mechanical properties of7075Al alloy werestudied with scanning electron microscopy(SEM),energy dispersive X-ray spectrometry(EDS),differentia...The effects of solution treatment on the evolution of the second phases and mechanical properties of7075Al alloy werestudied with scanning electron microscopy(SEM),energy dispersive X-ray spectrometry(EDS),differential scanning calorimetry(DSC),hardness and tensile tests.The results show that Mg(Zn,Cu,Al)2phases gradually dissolve into the matrix,yet the size andmorphology of Al7Cu2Fe phase exhibit no change with the increase of the solution treatment temperature and time due to its highmelting point.When the solution treatment temperature and time continue to increase,the formation of coarse black Mg2Si particlesoccurs.Compared to the as-cast alloy,the microhardness,tensile strength,and elongation of the sample under solution heat treatmentat460°C for5h are increased by55.1%,40.9%and109.1%,respectively.This is because the eutectic Mg(Zn,Cu,Al)2phases almostcompletely dissolve and basically no coarse black Mg2Si particles are formed.展开更多
A quantitative relation between the γ/γ′ and γ/Laves intermetallics was investigated with the change of chemical composition, i.e., Ti, Al and Nb in the third generation of nickel-based superalloys. The ...A quantitative relation between the γ/γ′ and γ/Laves intermetallics was investigated with the change of chemical composition, i.e., Ti, Al and Nb in the third generation of nickel-based superalloys. The results demonstrated that the maximum amount of intermetallic eutectics （i.e., 41.5%, mass fraction） has been formed in 9.8% （Ti＋Al）. It is predicted that high level of intermetallics formed in the 3GSA-HNM-1 （γ-9.8%（Ti＋Al）） deteriorates its castability. The type and morphology of eutectic intermetallics change and the amount considerably diminishes by decreasing Ti＋Al in 3GSA-HNM-2 （γ-7.6%（Ti＋Al）, 1.5% Nb）. Thus, it is predicted that the castability for the 3GSA-HNM-2 improves. The amount of Laves intermetallics shows an ascending behavior again, however, with less intensity by increasing the Nb content in the 3GSA-HNM-3 （γ-5.7%（Ti＋Al）, 2.9% Nb）. It can be concluded that for 3GSA-HNM-3 with composition of γ-5.7%（Ti＋Al） and 2.9% Nb, the optimized castability can be anticipated, because the minimum amount of eutectic intermetallics （i.e., 4.7%） is formed.展开更多
The effects of solution treatment temperature and holding time on the microstructure and mechanical properties of extruded Al-6.02 wt.%Zn-1.94 wt.%Mg alloy were investigated by differential scanning calorimetry(DSC),o...The effects of solution treatment temperature and holding time on the microstructure and mechanical properties of extruded Al-6.02 wt.%Zn-1.94 wt.%Mg alloy were investigated by differential scanning calorimetry(DSC),optical microscopy(OM), scanning electron microscopy(SEM), X-ray diffraction(XRD), and tensile test. The results showed that the optimum solution treatment process for the alloy was 470 ℃, 2 h. The tensile strength, yield strength,and elongation of the samples after the aging treatment at 120℃ for 24 h were 486 MPa, 431 MPa, and 14.8%,respectively. The alloy produced more copious recrystallization with the augment of solution temperature and the extension of holding time. While the second phase of η(MgZn_(2)), and T(AlZnMgCu) in the matrix was not fully re-dissolved under the treatment condition of lower temperature or shorter holding time. Interestingly, the Zr aggregation was observed in the samples treated at 510 ℃ for 2 h, which led to the growth of the second phase particles and the increase of their area fraction.展开更多
基金Project(Z131100003213019)supported by the Science and Technology Commission of Beijing Municipal,ChinaProject(2144043)supported by the Natural Science Foundation of Beijing Municipal,China+1 种基金Project(KM201410005014)supported by the Education Commission of Beijing Municipal,ChinaProject(2014-RX-L07)supported by the Rixin Talents Plan of Beijing University of Technology,China
文摘The effect of Zn addition on microstructure and mechanical properties of the Mg-2Er alloy was investigated by X-ray diffraction （XRD） and scanning electron microscope （SEM）. The results show that the alloys with 1%and 2%Zn （mass fraction） are composed of the W-phase and theα-Mg matrix. Meanwhile, the addition of 4%-10%Zn results in the formation of the I-phase, the W-phase and theα-Mg matrix. When the addition of Zn reaches 12%, the W-phase disappears and the phase constituents of the alloys mainly include the I-phase and the Mg4Zn7 phase besides theα-Mg solid solution. The alloy containing 6%Zn has better mechanical properties, of which the ultimate tensile strength （UTS） and the yield tensile strength （YTS） are about 224 MPa and 134 MPa, respectively, companying an elongation of 10.4%.
基金Project(50725413)supported by the National Natural Science Foundation of ChinaProject(2010CSTC-BJLKR)supported by Chongqing Science and Technology Commission, ChinaProject(CDJXS10132203)supported by the Fundamental Research Funds for the Central Universities,China
文摘Mg-14Li-1Al （LA141）, LA141-0.3Y, LA141-0.3Sr, and LA141-0.3Y-0.3Sr alloys were prepared in an induction furnace in the argon atmosphere. The microstructures of these alloys were investigated through scanning electron microscope （SEM）, X-ray diffractometer （XRD） and energy dispersive spectrometer （EDS）. The results show that yttrium and/or strontium additions produce a strong grain refining effect in LA141 alloy. The mean grain sizes of the alloys with addition of Y and/or Sr are reduced remarkably from 600 to 500, 260, 230 μm, respectively. Al 2 Y, Al 4 Sr and Mg 17 Sr 2 phases with different morphologies are verified and exist inside the grain or at the grain boundaries, thus possibly act as heterogeneous nucleation sites and pin up grain boundaries, which restrain the grain growth.
基金Project (09009) supported by the State Key Laboratory of Advanced Welding and Joining,Harbin Institute of Technology,China
文摘Wrought magnesium alloy sheets were butt welded with gas metal arc welding process. Pores in the weld were investigated under different welding parameters, the causes of pore formation were systematically disposed, and the effects of porosity on the microstructure and mechanical properties of the joint were analyzed. The microstructure examination shows that the pores mainly appear close to the top or bottom part of the weld, and could connect to each other and lead to the formation of cracks in the welds. However, the pores can be controlled with proper welding parameters. The tensile testing results reveal that the average joint strength is close to or higher than that of the base metal. The microhardness in the weld can be even higher than that in the base metal due to the second ohase strengthening of β-Mg17（A1, Zn）12 formed in the weld.
基金the financial supports from Beijing Natural Science Foundation, China (2172013)the National Key Research and Development Program, China (2016YFB0301101)。
文摘The corrosion behaviors and mechanism of the as-rolled Mg-x Zn-0.5Er(x=0.5, 2.0, 3.0 and 4.0, in wt.%)alloys were investigated. The potential difference between the second phase and matrix was determined by the type and size of the second phases. The dominated nano-scale W-phase on matrix in the Mg-0.5Zn-0.5Er alloy induced a sharp local pitting corrosion. However, as the volume fraction of the coarse W-phase or I-phase increased, the corrosion reaction was inclined to happen around the coarse W-phase or I-phase preferentially, leading to an obvious uniform corrosion and great acceleration of corrosion rate. The long-term immersion(14 d) results indicated that the corrosion resistance decreasing sequence was Mg-0.5Zn-0.5Er > Mg-2.0Zn-0.5Er > Mg-3.0Zn-0.5Er > Mg-4.0Zn-0.5Er.
基金Project(51364035)supported by the National Natural Science Foundation of ChinaProject(CX2015055)supported by the Innovation Special Funds of Nanchang University for Graduate Student,China
文摘The effects of solution treatment on the evolution of the second phases and mechanical properties of7075Al alloy werestudied with scanning electron microscopy(SEM),energy dispersive X-ray spectrometry(EDS),differential scanning calorimetry(DSC),hardness and tensile tests.The results show that Mg(Zn,Cu,Al)2phases gradually dissolve into the matrix,yet the size andmorphology of Al7Cu2Fe phase exhibit no change with the increase of the solution treatment temperature and time due to its highmelting point.When the solution treatment temperature and time continue to increase,the formation of coarse black Mg2Si particlesoccurs.Compared to the as-cast alloy,the microhardness,tensile strength,and elongation of the sample under solution heat treatmentat460°C for5h are increased by55.1%,40.9%and109.1%,respectively.This is because the eutectic Mg(Zn,Cu,Al)2phases almostcompletely dissolve and basically no coarse black Mg2Si particles are formed.
文摘A quantitative relation between the γ/γ′ and γ/Laves intermetallics was investigated with the change of chemical composition, i.e., Ti, Al and Nb in the third generation of nickel-based superalloys. The results demonstrated that the maximum amount of intermetallic eutectics （i.e., 41.5%, mass fraction） has been formed in 9.8% （Ti＋Al）. It is predicted that high level of intermetallics formed in the 3GSA-HNM-1 （γ-9.8%（Ti＋Al）） deteriorates its castability. The type and morphology of eutectic intermetallics change and the amount considerably diminishes by decreasing Ti＋Al in 3GSA-HNM-2 （γ-7.6%（Ti＋Al）, 1.5% Nb）. Thus, it is predicted that the castability for the 3GSA-HNM-2 improves. The amount of Laves intermetallics shows an ascending behavior again, however, with less intensity by increasing the Nb content in the 3GSA-HNM-3 （γ-5.7%（Ti＋Al）, 2.9% Nb）. It can be concluded that for 3GSA-HNM-3 with composition of γ-5.7%（Ti＋Al） and 2.9% Nb, the optimized castability can be anticipated, because the minimum amount of eutectic intermetallics （i.e., 4.7%） is formed.
基金Project(U1837207) supported by the National Natural Science Foundation of China。
文摘The effects of solution treatment temperature and holding time on the microstructure and mechanical properties of extruded Al-6.02 wt.%Zn-1.94 wt.%Mg alloy were investigated by differential scanning calorimetry(DSC),optical microscopy(OM), scanning electron microscopy(SEM), X-ray diffraction(XRD), and tensile test. The results showed that the optimum solution treatment process for the alloy was 470 ℃, 2 h. The tensile strength, yield strength,and elongation of the samples after the aging treatment at 120℃ for 24 h were 486 MPa, 431 MPa, and 14.8%,respectively. The alloy produced more copious recrystallization with the augment of solution temperature and the extension of holding time. While the second phase of η(MgZn_(2)), and T(AlZnMgCu) in the matrix was not fully re-dissolved under the treatment condition of lower temperature or shorter holding time. Interestingly, the Zr aggregation was observed in the samples treated at 510 ℃ for 2 h, which led to the growth of the second phase particles and the increase of their area fraction.
