The non-isothermal kinetics of CdO nanoparticles prepared from CdCO3 precursor using thermal decomposition method was investigated. A model-fitting Malek approach and a model-free advanced isoconversional method of Vy...The non-isothermal kinetics of CdO nanoparticles prepared from CdCO3 precursor using thermal decomposition method was investigated. A model-fitting Malek approach and a model-free advanced isoconversional method of Vyazovkin were applied to the analysis of the DSC and TGA data. The results showed that CdO nanoparticles prepared from CdCO3 followed an autocatalytic reaction. Sestak–Berggren model could favorably describe the studied reaction process. Moreover, the apparent activation energy of CdCO3 decomposition was calculated to be (119.19±9.97) kJ/mol and the explicit rate equation form of CdCO3 decomposition was established.展开更多
In the context of ＂two-wheel drive＂ development mode, China＇s construction land shows significant expansion characteristics. The carbon emission effect of construction land changes is an important factor for the in...In the context of ＂two-wheel drive＂ development mode, China＇s construction land shows significant expansion characteristics. The carbon emission effect of construction land changes is an important factor for the increase of carbon emissions in the atmosphere. In this study, the drivers of carbon emissions in Anhui Province from 1997 to 2011 were quantitatively measured using the improved Kaya identity and Logarithmic Mean Divisia Index. The results show that： economic growth, expansion of construction land and changes in population density have incremental effects on carbon emissions. The average contribution rate of economic growth as the first driver is 266.32 percent. The construction land expansion is an important driving factor with annual mean carbon effect of 6.4057 million tons and annual mean contribution rate of 187.30 percent. But the change in population density has little impact on carbon emission driving. Energy structure changes and energy intensity reduction have inhibitory effects on carbon emissions, of which the annual mean contribution rate is -212.06 percent and -158.115 percent respectively. The targeted policy approaches of carbon emission reduction were put forward based on the decomposition of carbon emission factors, laying a scientific basis to rationally use the land for the Government, which is conducive to build an ecological province for Anhui and achieve the purpose of emission reduction, providing a reference for the research on carbon emission effect of changes in provincial-scale construction land.展开更多
文摘The non-isothermal kinetics of CdO nanoparticles prepared from CdCO3 precursor using thermal decomposition method was investigated. A model-fitting Malek approach and a model-free advanced isoconversional method of Vyazovkin were applied to the analysis of the DSC and TGA data. The results showed that CdO nanoparticles prepared from CdCO3 followed an autocatalytic reaction. Sestak–Berggren model could favorably describe the studied reaction process. Moreover, the apparent activation energy of CdCO3 decomposition was calculated to be (119.19±9.97) kJ/mol and the explicit rate equation form of CdCO3 decomposition was established.
基金the Key Research Fund of Anhui Provincial Education Department (No.2010sk502zd)the National Natural Science Foundation of China (No.41071337)
文摘In the context of ＂two-wheel drive＂ development mode, China＇s construction land shows significant expansion characteristics. The carbon emission effect of construction land changes is an important factor for the increase of carbon emissions in the atmosphere. In this study, the drivers of carbon emissions in Anhui Province from 1997 to 2011 were quantitatively measured using the improved Kaya identity and Logarithmic Mean Divisia Index. The results show that： economic growth, expansion of construction land and changes in population density have incremental effects on carbon emissions. The average contribution rate of economic growth as the first driver is 266.32 percent. The construction land expansion is an important driving factor with annual mean carbon effect of 6.4057 million tons and annual mean contribution rate of 187.30 percent. But the change in population density has little impact on carbon emission driving. Energy structure changes and energy intensity reduction have inhibitory effects on carbon emissions, of which the annual mean contribution rate is -212.06 percent and -158.115 percent respectively. The targeted policy approaches of carbon emission reduction were put forward based on the decomposition of carbon emission factors, laying a scientific basis to rationally use the land for the Government, which is conducive to build an ecological province for Anhui and achieve the purpose of emission reduction, providing a reference for the research on carbon emission effect of changes in provincial-scale construction land.
