AB-8 resin was used as an adsorbent for the removal of trans-1,2-cyclohexandiol(CHD) from aqueous solutions.Batch experiments were carried out to investigate the effect of contact time and temperature on sorption effi...AB-8 resin was used as an adsorbent for the removal of trans-1,2-cyclohexandiol(CHD) from aqueous solutions.Batch experiments were carried out to investigate the effect of contact time and temperature on sorption efficiency.The adsorptive thermodynamic properties and kinetics of CHD from water onto AB-8 resin were studied.The Langmuir and Freundlich isotherm models were employed to discuss the adsorption behavior.Thermodynamic parameters such as G,H and S were calculated.The results indicate that the equilibrium data are perfectly represented by Langmuir isotherm model.Thermodynamic study reveals that it is an exothermic process in nature and mainly physical adsorption enhanced by chemisorption with a decrease of entropy process.The kinetics of CHD adsorption is well described by the pseudo second-order model.The adsorbed CHD can be eluted from AB-8 resin by 5% ethanol aqueous solution with 100% elution percentage.展开更多
The Microcystis aeruginosa(MA) was immobilized on sodium alginate and used as biosorbent for removal of Cd(Ⅱ) ions from aqueous solution.The biosorption process is pH dependent,and the optimum biosorption was observe...The Microcystis aeruginosa(MA) was immobilized on sodium alginate and used as biosorbent for removal of Cd(Ⅱ) ions from aqueous solution.The biosorption process is pH dependent,and the optimum biosorption was observed at pH 6.0 with the biosorption capacity of 98.38 mg/g.Among Langmuir,Freundlich and Temkin isotherm models,the Freundlich and the Temkin isotherm fit well with the experimental data.Cd(Ⅱ) ions biosorption follows the pseudo-second-order kinetic model.The rate controlling mechanism study reveals that film diffusion is the rate-limiting step and intraparticle diffusion is also involved in biosorption.Thermodynamic parameters,such as Gibbs free energy(ΔG°),the enthalpy(ΔH°) and entropy(ΔS°) were calculated,and revealed that the biosorption process is spontaneous,exothermic and random.Furthermore,the immobilized MA can be regenerated using 0.1 mol/L HCl solutions.展开更多
In this study, quaternized chitosan microspheres （QCMS） were prepared and its Cr （VI） removal potential was investigated. Batch experiments were conducted to examine kinetics, adsorption isotherm, pH effect, and t...In this study, quaternized chitosan microspheres （QCMS） were prepared and its Cr （VI） removal potential was investigated. Batch experiments were conducted to examine kinetics, adsorption isotherm, pH effect, and thermodynamic parameters. Equilibrium was attained within 50 rain and maximum removal of 97.34% was achieved under the optimum conditions at pH 5. Adsorption data for Cr （VI） uptake by the QCMS were analyzed according to Langmuir, Freundlich, and Temkin adsorption models. The maximum uptake of Cr （VI） was 39.1 mg.g-a. Thermodynamic parameters for the adsorption system were determinated at 293 K, 303 K, 313 K and 323 K. （AH° = 16.08 kJ.mol- 1;AG° = -5.84 to -8.08 kJ.mo1-1 and AS° = 74.81 J.K-1 .tool-l）. So the positive values of both A/-F and AS° suggest an endothermic reaction and increase in randomness at the solid-liquid interface during the adsorption. AG° values obtained were negative indicating a spontaneous adsorp- tion process. The kinetic process was described by a pseudo-second-order rate equation very well. The results of the present study indicated that the QCMS could he considered as a potential adsorbent for Cr （V1） in aqueous solutions.展开更多
A modified cellular automaton(CA) program was developed to simulate the process of dynamic recrystallization(DRX) for 23Co13Ni11Cr3Mo ultrahigh strength steel.In this model,influences of deformation parameters on hard...A modified cellular automaton(CA) program was developed to simulate the process of dynamic recrystallization(DRX) for 23Co13Ni11Cr3Mo ultrahigh strength steel.In this model,influences of deformation parameters on hardening rate and solute drag effect were considered.Moreover,an inverse analysis method was proposed for parameters identification of dislocation model and solute drag effect based on the results of isothermal compression tests on Gleeble-1500.Then,simulated microstructures under different deformation conditions were compared with those of experiments.A good agreement is achieved.Furthermore,influences of deformation parameters on microstructure evolution for 23Co13Ni11Cr3Mo steel were investigated in details.High strain is an effective measure to refine grain and improve homogeneity.Meanwhile,the desired deformation parameters are temperature of 1000-1050 °C and strain rate of 0.008-0.01 s-1 for obtaining grains smaller than 22.5 μm.展开更多
Ultrasonic speeds of 4-aminobutyric acid in 0.0041,0.0125 and 0.0207 mol·kg^-1 aqueous salbutamol sulphate（SBS） solutions are measured at 308.15,313.15 and 318.15 K.Isentropic compressibility kS,change in isent...Ultrasonic speeds of 4-aminobutyric acid in 0.0041,0.0125 and 0.0207 mol·kg^-1 aqueous salbutamol sulphate（SBS） solutions are measured at 308.15,313.15 and 318.15 K.Isentropic compressibility kS,change in isentropic compressibility△k S,relative change in isentropic compressibility（ △kS /kS^0） ,apparent molal compressibility kφ,limiting apparent molal compressibility kφ^0 ,transfer limiting apparent molal compressibility k φ^0,hydration number nH,pair and triplet interaction parameters kAS,kASS are estimated.The above parameters are used to interpret the solute-solute and solute-solvent interactions of 4-aminobutyric acid in the aqueous salbutamol sulphate solutions.展开更多
Because of the importance of gravity waves （GWs） in coupling different atmospheric regions, further studies are necessary to investigate the characteristics of GW propagation in a non-isothermal atmosphere. Using a ...Because of the importance of gravity waves （GWs） in coupling different atmospheric regions, further studies are necessary to investigate the characteristics of GW propagation in a non-isothermal atmosphere. Using a nonlinear numerical model, we simulate the propagation of small amplitude GWs with various wavelengths in different non-isothermal atmospheres. Our re- sults show that the GW vertical wavelength undergoes sharp changes above the stratopause and mesopause region. Specifically for a GW with an initial vertical wavelength of 5 km, the seasonal background temperature structure difference at 50° latitude can cause the vertical wavelength to vary by -2 krn in the mesosphere and by as large as -4.5 km in the lower thermosphere. In addition, the GW paths exhibit great divergence in the height range of -65-110 kin. Our results also show that the variations of GW path, vertical wavelength and horizontal phase velocity are not synchronized in a non-isothermal atmosphere as in an isothermal atmosphere. Despite the fact that all GWs change their characteristics as they propagate upward in a non-isothermal atmosphere, the variations relative to the initial parameters at a reference height are similar for different initial vertical wavelengths. Our results indicate that the changing characteristics of a gravity wave in a non-isothermal atmosphere need to be considered when investigating the relationship of GWs at two different heights.展开更多
文摘AB-8 resin was used as an adsorbent for the removal of trans-1,2-cyclohexandiol(CHD) from aqueous solutions.Batch experiments were carried out to investigate the effect of contact time and temperature on sorption efficiency.The adsorptive thermodynamic properties and kinetics of CHD from water onto AB-8 resin were studied.The Langmuir and Freundlich isotherm models were employed to discuss the adsorption behavior.Thermodynamic parameters such as G,H and S were calculated.The results indicate that the equilibrium data are perfectly represented by Langmuir isotherm model.Thermodynamic study reveals that it is an exothermic process in nature and mainly physical adsorption enhanced by chemisorption with a decrease of entropy process.The kinetics of CHD adsorption is well described by the pseudo second-order model.The adsorbed CHD can be eluted from AB-8 resin by 5% ethanol aqueous solution with 100% elution percentage.
基金Project(41271332) supported by the National Natural Science Foundation of ChinaProject(11JJ2031) supported by the Natural Science Foundation of Hunan Province,China+1 种基金Project(2012SK2021) supported by the Science and Technology Planning Program of Hunan Province,ChinaProject(CX2012B138) supported by the Hunan Provincial Innovation Foundation for Postgraduate,China
文摘The Microcystis aeruginosa(MA) was immobilized on sodium alginate and used as biosorbent for removal of Cd(Ⅱ) ions from aqueous solution.The biosorption process is pH dependent,and the optimum biosorption was observed at pH 6.0 with the biosorption capacity of 98.38 mg/g.Among Langmuir,Freundlich and Temkin isotherm models,the Freundlich and the Temkin isotherm fit well with the experimental data.Cd(Ⅱ) ions biosorption follows the pseudo-second-order kinetic model.The rate controlling mechanism study reveals that film diffusion is the rate-limiting step and intraparticle diffusion is also involved in biosorption.Thermodynamic parameters,such as Gibbs free energy(ΔG°),the enthalpy(ΔH°) and entropy(ΔS°) were calculated,and revealed that the biosorption process is spontaneous,exothermic and random.Furthermore,the immobilized MA can be regenerated using 0.1 mol/L HCl solutions.
基金Supported by the National Key Basic Research Development Plan(No.2013CB632602)the National Natural Science Foundation of China(No.21306198)
文摘In this study, quaternized chitosan microspheres （QCMS） were prepared and its Cr （VI） removal potential was investigated. Batch experiments were conducted to examine kinetics, adsorption isotherm, pH effect, and thermodynamic parameters. Equilibrium was attained within 50 rain and maximum removal of 97.34% was achieved under the optimum conditions at pH 5. Adsorption data for Cr （VI） uptake by the QCMS were analyzed according to Langmuir, Freundlich, and Temkin adsorption models. The maximum uptake of Cr （VI） was 39.1 mg.g-a. Thermodynamic parameters for the adsorption system were determinated at 293 K, 303 K, 313 K and 323 K. （AH° = 16.08 kJ.mol- 1;AG° = -5.84 to -8.08 kJ.mo1-1 and AS° = 74.81 J.K-1 .tool-l）. So the positive values of both A/-F and AS° suggest an endothermic reaction and increase in randomness at the solid-liquid interface during the adsorption. AG° values obtained were negative indicating a spontaneous adsorp- tion process. The kinetic process was described by a pseudo-second-order rate equation very well. The results of the present study indicated that the QCMS could he considered as a potential adsorbent for Cr （V1） in aqueous solutions.
基金Project(2011CB706802)supported by the National Basic Research Program of ChinaProject(2012ZX04010-081)supported by National Science and Technology Major Program of China
文摘A modified cellular automaton(CA) program was developed to simulate the process of dynamic recrystallization(DRX) for 23Co13Ni11Cr3Mo ultrahigh strength steel.In this model,influences of deformation parameters on hardening rate and solute drag effect were considered.Moreover,an inverse analysis method was proposed for parameters identification of dislocation model and solute drag effect based on the results of isothermal compression tests on Gleeble-1500.Then,simulated microstructures under different deformation conditions were compared with those of experiments.A good agreement is achieved.Furthermore,influences of deformation parameters on microstructure evolution for 23Co13Ni11Cr3Mo steel were investigated in details.High strain is an effective measure to refine grain and improve homogeneity.Meanwhile,the desired deformation parameters are temperature of 1000-1050 °C and strain rate of 0.008-0.01 s-1 for obtaining grains smaller than 22.5 μm.
文摘Ultrasonic speeds of 4-aminobutyric acid in 0.0041,0.0125 and 0.0207 mol·kg^-1 aqueous salbutamol sulphate（SBS） solutions are measured at 308.15,313.15 and 318.15 K.Isentropic compressibility kS,change in isentropic compressibility△k S,relative change in isentropic compressibility（ △kS /kS^0） ,apparent molal compressibility kφ,limiting apparent molal compressibility kφ^0 ,transfer limiting apparent molal compressibility k φ^0,hydration number nH,pair and triplet interaction parameters kAS,kASS are estimated.The above parameters are used to interpret the solute-solute and solute-solvent interactions of 4-aminobutyric acid in the aqueous salbutamol sulphate solutions.
基金supported by the National Natural Science Foundation of China (Grant Nos. 40921063, 41004063, 41074109, 40890165, and 41174127)the National Important Basic Research Project (Grant No. 2011CB811405)+3 种基金the China Postdoctoral Science Foundation (Grant No. 20100470506)supported in part by the Specialized Research Fundthe Open Research Program of the State Key Laboratory of Space Weatherthe National Science Foundation of Unites States grant-ATM-0633418 to Miami University
文摘Because of the importance of gravity waves （GWs） in coupling different atmospheric regions, further studies are necessary to investigate the characteristics of GW propagation in a non-isothermal atmosphere. Using a nonlinear numerical model, we simulate the propagation of small amplitude GWs with various wavelengths in different non-isothermal atmospheres. Our re- sults show that the GW vertical wavelength undergoes sharp changes above the stratopause and mesopause region. Specifically for a GW with an initial vertical wavelength of 5 km, the seasonal background temperature structure difference at 50° latitude can cause the vertical wavelength to vary by -2 krn in the mesosphere and by as large as -4.5 km in the lower thermosphere. In addition, the GW paths exhibit great divergence in the height range of -65-110 kin. Our results also show that the variations of GW path, vertical wavelength and horizontal phase velocity are not synchronized in a non-isothermal atmosphere as in an isothermal atmosphere. Despite the fact that all GWs change their characteristics as they propagate upward in a non-isothermal atmosphere, the variations relative to the initial parameters at a reference height are similar for different initial vertical wavelengths. Our results indicate that the changing characteristics of a gravity wave in a non-isothermal atmosphere need to be considered when investigating the relationship of GWs at two different heights.
