用于微反应器塑件整平的等温热压工艺

以一种微流控微反应器塑件为对象,提出了用于微塑件整平的等温热压工艺,研究了等温热压工艺对平板微塑件的整平机理。建立了描述该工艺的弹塑性数学模型,计算分析了外加压力和温度对塑件表面形貌的影响。综合考虑塑件整平效果和微结构保形,开展等温热压整平工艺实验,分析了关键工艺参数对器件整平精度的影响。研究结果表明：与压力载荷相比,热载荷对不平度的改善效果更明显;由于塑件端部区域受力面积大,其两端变形量均大于中间反应腔的变形量。在相同压力条件下,70℃时平面度和不平度的变化率均为最高。通过工艺优化,微反应器塑件平面度提高到了10μm内,最大变化率可达72.7%;而不同区域的不平度变化率为3.50%~53.50%,微结构尺寸变化可控制在5μm以下。本文研究成果对提高平板微塑件平整精度有借鉴作用。

等温热压印法制备超疏水薄膜

以刷涂有疏水性SiO_2微球的筛网作为模具,通过等温热压印的方法,在聚乙烯(PE)塑铝复合薄膜上制备出超疏水表面。对压印压力、筛网目数、SiO_2微球直径等参数对制品表面微结构形貌和疏水性能的影响进行了研究。结果表明,该方法可以在PE塑铝复合薄膜表面构筑出具有良好疏水效果的二级复合微结构;在压力作用下,SiO_2微球会与PE基体共混形成复合体系,使得SiO_2微球与基体的连接更加稳定;增加热压印压力可以增大微米级结构的深度,但是过大的压力会导致SiO_2微球被PE覆盖,合理的压印压力应在8～12MPa之间;减小SiO_2微球的粒径可以进一步提高接触角数值;制品对水的接触角达到150°,滚动角低至1°,达到了超疏水的标准。

等温等效替代热压印法成型超薄导光板的工艺分析

针对超薄导光板微结构模具难加工的问题,结合等温热压印法,提出了一种新型的"等效替代"压印工艺,即通过控制成型工艺参数来降低微结构复制高度,实现了在基片上成型出小于模具微结构尺寸的等效结构,突破了热压印过程中模具微结构完全等大复制的思想禁锢,降低了微结构模具加工难度,从而革新了高质量超薄导光板的成型工艺。以聚甲基丙烯酸甲酯(PMMA)为基片,设计具体实验,加工0.25 mm厚的导光板,验证这一方法的可行性。实验结果表明,这种新型的"等效替代"压印工艺不仅可以降低模具的制造难度和加工成本,而且可以大大改善超薄导光板的性能,与等温热压印工艺相比均匀度提高了23%,整个成型时间缩短到了20 s。

聚合物微纳制造技术

微纳制造技术属国际前沿技术,作为未来制造业赖以生存的基础和可持续发展的关键,其研发和应用标志着人类可以在微、纳米尺度认识和改造世界。以聚合物为基础材料的微纳系统在整个微纳系统中占有极其重要地位,是最具产业化开发前景的微纳系统之一,聚合物微纳制造技术也已经开始得到应用并具有极大的发展空间。本文集中介绍了多种典型聚合物微纳器件及系统,并对微注塑成型、微挤出成型和微纳压印成型等聚合物微纳制造技术进行了系统的阐述,比较了各种聚合物微纳制造技术的优缺点和使用条件。最后,结合国内外研究人员的研究成果,对聚合物微纳制造技术的未来发展做出展望。

聚甲基丙烯酸甲酯类固态温度区静态力学松弛特性

为了探究聚甲基丙烯酸甲酯(PMMA)在类固态温度区静态力学松弛特性(蠕变与应力松弛)的相关规律,在保压模式下对其进行不同温度的蠕变实验,分析广义Kelvin模型、标准线性体模型、三元件修正模型建模结果,根据拟合效果最好的三元件修正模型参数和不同温度下定应变应力松弛实验,推导松弛模量表达式,结合理论模型,进行不同温度、不同保压时间条件下的半球阵列与Prism微结构类固态等温热压印实验,为得到基于高复制精度和短压印周期的类固态等温热压印工艺提供理论与实验依据。

Effects of magnetic field and hot rolling on microstructures and properties of cryo ECAPed 1050 aluminum alloy during annealing

The evolution of hardness and microstructures of 1050 aluminum alloy prepared by hot rolling and subsequent equal- channel angular pressing at cryogenic temperature (cryoECAP) after annealing at 150?400 °C for 1 h without and with magnetic field of 12 T was investigated. The electron back scattering diffraction pattern (EBSD) and transmission electron microscopy (TEM) were utilized to characterize the grain microstructures and dislocations. It is demonstrated that the hot rolling before cryoECAP produces more equiaxed grains with a smaller average size and a higher fraction of high angle boundaries (HABs) in the subsequent cryoECAPed 1050 aluminum alloy, thus accelerating the recovery and recrystallization of cryoECAPed alloy and produces more homogeneous microstructure during annealing. The magnetic field promotes the recovery and recrystallization and leads to much lower hardness at 150?250 °C, while it can suppress the abnormal grain growth and form more homogeneous grain size distributions annealed at 300?400 °C.

Superplastic bulging capability of Ti-6Al-4V buttcover plate

The investigation on the superplastic bugling capability of 1.5?mm mill annealed Ti 6Al 4V buttcover plate by means of manual gas tungsten arc welding (M GTAW) and fusion type plasma arc welding (F PAW) have been evaluated respectively. The result shows that untreated Ti 6Al 4V buttcover plate by M GTAW exhibits no superplasticity, while the same untreated plate by F PAW, shows good superplastic ability because of extremely fine acicular martensite microstructure of weld metal. To the buttcover plate by M GTAW, the microstructure of weld metal changed into streaky α structure which exhibits good superplasticity from the original β structure under the condition of the constant temperature of 940?℃ with the deformation degree of 45%, and changed into the fine equiaxed grain which possesses excellent superplastic ability under the condition of the constant temperature of 800?℃ with the deformation degree of 40%.

Flow behavior and microstructure evolution of 6A82 aluminium alloy with high copper content during hot compression deformation at elevated temperatures

The flow behavior and microstructure evolution of 6A82 aluminum alloy (Al?Mg?Si?Cu) with high copper content were studied on a Gleeble?1500 system by isothermal hot compression test in the temperature range from 320 to 530 °C and the strain rate range from 0.001 to 10 s?1. The results reveal that the flow stress of the alloy exhibits a continuous flow softening behavior at low temperatures of 320?390 °C, whereas it reaches steady state at high temperatures (≥460°C), which are influenced greatly by the Zener?Hollomon parameter (Z) in the hyperbolic sine with the hot deformation activation energy of 325.12 kJ/mol. Microstructure characterizations show that prominent dynamic recrystallization and coarsening of dynamic precipitation may be responsible for the continuous flow softening behavior. Due to deformation heating at high strain rates (≥1 s?1), dynamic recrystallization is more prominent in the specimen deformed at 530 °C and 10 s?1 than in the specimen deformed at 460 °C and 0.1 s?1 even though they have very close lnZ values.

Isothermal compression behavior and constitutive modeling of Ti-5Al-5Mo-5V-1Cr-1Fe alloy

Hot compression behavior of Ti-5 Al-5 Mo-5 V-1 Cr-1 Fe alloy with an equiaxed（α＋β） starting microstructure was investigated by isothermal compression test and optical microscopy. Based on the true strain-stress data with temperature correction, constitutive models with a high accuracy were developed and processing maps were established. Strain inhomogeneity at different locations in the compressed sample is reduced by raising temperature, leading to a uniform distribution of α phases. For the temperature range of 800-840 ℃ with a strain rate of 10 s^-1, the transformed volume fraction of α phase increases and the average grain size of α phase decreases slightly with increasing the temperature, indicating co-existence of dynamic recovery and dynamic recrystallization. Flow localization and faint β grain boundaries are observed at the strain rate of 10 s^-1 in the temperature range of 860-900 ℃. The processing map analysis shows that hot working of Ti-5 Al-5 Mo-5 V-1 Cr-1 Fe alloy should be conducted with the strain rate lower than 0.01 s^-1 to extend its workability.

Cavity nucleation during hot forging of Ti-6Al-2Zr-1Mo-1V alloy with colony alpha microstructure

The initiation sites and influencing factors of cavity nucleation were investigated for a Ti-6Al-2Zr-1Mo-1V alloy with lamellar starting structure,using the isothermal hot compression test.All samples were deformed to a true strain of 0.70 in the temperature range of 750-950°C and strain rate range of 0.001-10 s-1.The corresponding microstructures were observed by means of the metallurgical microscopy and scanning electron microscopy(SEM).It was found that all cavities occurred at the bulge regions of the compression specimens.Most of cavities nucleated along prior beta boundaries oriented 45°to the compression axis,while others nucleated at the interfaces of lamellar alpha colonies.Cavity nucleation was inhibited with increasing the volume fraction of beta phase and the volume fraction spheroidized of lamellar alpha phase.

Microstructure and mechanical properties of CuAgZn/GH909 diffusion bonded joint fabricated by hot isostatic pressing

The hot isostatic pressing-diffusion bonding(HIP-DB)was proposed to achieve the joining of CuAgZn and GH909 directly without an interlayer.The microstructure of joint was characterized by scanning electron microscope(SEM),energy dispersive spectrometer(EDS)and X-ray diffraction(XRD).The microhardness and shear strength were tested to investigate the mechanical properties of joint.The results showed that the interface was complete,and the joint was compact,uniform and free of unbonded defects.The maximum microhardness of joint was HV 443,higher than that of two base alloys,and the average shear strength of joint reached 172 MPa.It is concluded that a good metallurgical bonding between CuAgZn and GH909 can be obtained by HIP-DB with the process parameters of 700℃,150 MPa and 3 h.

Non-isothermal decomposition kinetics of hydrogarnet in sodium carbonate solution

Carbonation decomposition of hydrogarnet is a significant reaction of the calcification-carbonation new method for alumina production by using low-grade bauxite.In this work,non-isothermal decomposition kinetics of hydrogarnet in sodium carbonate solution was studied by high-pressure differential scanning calorimetry(HPDSC) at different heating rates of 2,5,8,10,15 and 20 K·min^(-1),respectively.The activation energy(E_α) was calculated with the help of isoconversional method(model-free),and the reaction mechanism was determined by the differential equation method.The calculated activation energy of this reaction was 115.66 kJ·mol^(-1).Furthermore,the mechanism for decomposition reaction is Avrami-Erofeev(n=1.5),and the decomposition process is diffusion-controlled.

Subtransus deformation mechanisms of TC11 titanium alloy with lamellar structure

Isothermal compression tests are applied to study the deformation mechanisms of TCll titanium alloy with lamellar structure under the deformation temperature range of 890-995 ℃ and strain rate range of 0.01-10 s^-1. According to the flow stress data obtained by compression tests, the deformation activations are calculated based on kinetics analysis of high temperature deformation, which are then used for deformation mechanism analysis combined with microstructure investigation. The results show that deformation mechanisms vary with deformation conditions： at low strain rate range, the deformation mechanism is mainly dislocation slip; at low temperature and high strain rate range, twinning is the main mechanism; at high temperature and high strain rate range, the deformation is mainly controlled by diffusion offl phase.