Four isothermal sections at 298.15K,308.15K,318.15K and 328.15K in system water-n-hexane-ethanol were measured by gas chromatograph method.The innerscaling method was used to determine the concentrations of n-hexane a...Four isothermal sections at 298.15K,308.15K,318.15K and 328.15K in system water-n-hexane-ethanol were measured by gas chromatograph method.The innerscaling method was used to determine the concentrations of n-hexane and ethanol in this ternary system.Ethy1 acetate was chosen as the sample of inner-scaling because of its separability and fit retainning time.Acetylacetone was chosen as diluent of the oil phase andn-butyl alcohol was chosen as diluent of the water phase.The experimental data of four isothermal sections at 298.15K,308.15K,318.15K adn 328.15K in system water-n-hexane-ethanol at normal pressure were given.Four schematic figures were also given.The character of these phase diagrams was analysed.They were compared with the phase diagram of system water-n-hexane-methanol.The possible causes of experimental error were discussed.The root mean square error of measurement is 1.47%.展开更多
An isothermal section of the Mg-Nd-Gd ternary system at 723 K was established by diffusion triple technique and electron probe microanalysis （EPMA）. Mg3Gd and Mg3Nd form a continuous solid solution （Gd,Nd）3Mg, and...An isothermal section of the Mg-Nd-Gd ternary system at 723 K was established by diffusion triple technique and electron probe microanalysis （EPMA）. Mg3Gd and Mg3Nd form a continuous solid solution （Gd,Nd）3Mg, and a continuous solid solution （Gd,Nd）Mg is also formed between MgGd and MgNd. Mg7Gd, Mg5Gd, Mg2Gd, Mg41Nd5, （Gd,Nd）3Mg and （Gd,Nd）Mg are found in the ternary system. In these intermetallic phases, Mg7Gd has been reported to be a metastable phase in previous literatures. The solubilities of Mg, Gd and Nd in all the phases were detected. Furthermore, four three-phase equilibria, α（Mg）＋Mg7Gd＋Mg41Nd5, Mg7Gd＋Mg5Gd＋Mg41Nd5, Mg5Gd＋Mg41Nd5＋（Gd,Nd）3Mg and （Gd,Nd）3Mg＋（Gd,Nd）Mg＋Mg2Gd, were identified in the isothermal section.展开更多
The Collins model is introduced into the two-dimensional (2D) alternative ternary system having the Lennard-Jones (L-J) potential. The Gibbs free energy of this ternary system is calculated, and according to thermodyn...The Collins model is introduced into the two-dimensional (2D) alternative ternary system having the Lennard-Jones (L-J) potential. The Gibbs free energy of this ternary system is calculated, and according to thermodynamic theory, a group of equations that determine the solid-liquid diagram of ternary system are derived, someisothermal sectional diagrams of the 2D ternary system are obtained. The results are quite similar to the behavior ofthree-dimensional substances.展开更多
Phase diagrams of two isothermal sections of the Ni-Ti-Ta ternary system at 1000 and 1200℃in a full composition range were determined by X-ray diffraction and electron probe microanalysis.The experimental results ind...Phase diagrams of two isothermal sections of the Ni-Ti-Ta ternary system at 1000 and 1200℃in a full composition range were determined by X-ray diffraction and electron probe microanalysis.The experimental results indicated a ternary compoundτphase with low solid solubility and composition ranges of(16.3-22.4)at.%Ta,(15.9-24.1)at.%Ti and(58.5-60.0)at.%Ni at 1000℃.The two terminal solid solutions(bcc-(Ta)andβ-Ti)formed a continuous solid solution at 1000 and 1200℃.A certain amount of Ti can dissolve into Ni-Ta intermetallic compounds near the Ni-Ta side,with the highest value of 21.9 at.%observed in the Ni;Ta compound at 1000℃.展开更多
The isothermal section of Ag-Ti-Zr ternary system at 1023 K was determined by diffusion triple and electron probe microanalysis. The results indicate that four binary intermetallic phases of AgTi, AgTi2, AgZr and AgZr...The isothermal section of Ag-Ti-Zr ternary system at 1023 K was determined by diffusion triple and electron probe microanalysis. The results indicate that four binary intermetallic phases of AgTi, AgTi2, AgZr and AgZr2 are found in Ag-Ti-Zr ternary system at 1 023 K. AgZr2 and AgTi2 form a continuous solid solution, namely Ag(Ti,Zr)2. Four three-phase regions: AgTi +AgZr + Ag, AgTi +AgZr + Ag (Ti, Zr)2, α-Zr +β(Ti, Zr) + Ag (Ti, Zr) 2 and α-Ti +β(Ti, Zr) + Ag (Ti, Zr)2 exist in the isothermal section. No ternary compound is observed.展开更多
The phase diagram of ZrO_(2)−CaO−TiO_(2)system was essential for the development of photocatalytic materials and refractory materials.In this work,the ZrO_(2)−CaO−TiO_(2)system was accessed by using the CALPHAD method...The phase diagram of ZrO_(2)−CaO−TiO_(2)system was essential for the development of photocatalytic materials and refractory materials.In this work,the ZrO_(2)−CaO−TiO_(2)system was accessed by using the CALPHAD method.The substitutional solution models were used to describe liquid and solid solution phases,the sub-lattice models were used to describe ternary compounds,and then the thermodynamic parameters were obtained by the least square method combined with literature experiment results.The acquired thermodynamic parameters were used to calculate the isothermal sections of the ZrO_(2)−CaO−TiO_(2)system at 1473 and 1673 K.There existed a good agreement between experimental and predicted phase relationships,the experimental points which were inconsistent with calculated results may be attributed to experimental errors and the sluggish kinetics of cations for ZrO_(2)-based materials.In order to further verify the validity of the database,the thermodynamic parameters were also used to simulate the thermodynamic properties(specific heat capacity,enthalpy,and entropy)of CaZrTi_(2)O_(7) within 5%errors.Good consistency demonstrated that the present thermodynamic database was self-consistent and credible.展开更多
文摘Four isothermal sections at 298.15K,308.15K,318.15K and 328.15K in system water-n-hexane-ethanol were measured by gas chromatograph method.The innerscaling method was used to determine the concentrations of n-hexane and ethanol in this ternary system.Ethy1 acetate was chosen as the sample of inner-scaling because of its separability and fit retainning time.Acetylacetone was chosen as diluent of the oil phase andn-butyl alcohol was chosen as diluent of the water phase.The experimental data of four isothermal sections at 298.15K,308.15K,318.15K adn 328.15K in system water-n-hexane-ethanol at normal pressure were given.Four schematic figures were also given.The character of these phase diagrams was analysed.They were compared with the phase diagram of system water-n-hexane-methanol.The possible causes of experimental error were discussed.The root mean square error of measurement is 1.47%.
基金Projects(50731002,50971136)supported by the National Natural Science Foundation of China
文摘An isothermal section of the Mg-Nd-Gd ternary system at 723 K was established by diffusion triple technique and electron probe microanalysis （EPMA）. Mg3Gd and Mg3Nd form a continuous solid solution （Gd,Nd）3Mg, and a continuous solid solution （Gd,Nd）Mg is also formed between MgGd and MgNd. Mg7Gd, Mg5Gd, Mg2Gd, Mg41Nd5, （Gd,Nd）3Mg and （Gd,Nd）Mg are found in the ternary system. In these intermetallic phases, Mg7Gd has been reported to be a metastable phase in previous literatures. The solubilities of Mg, Gd and Nd in all the phases were detected. Furthermore, four three-phase equilibria, α（Mg）＋Mg7Gd＋Mg41Nd5, Mg7Gd＋Mg5Gd＋Mg41Nd5, Mg5Gd＋Mg41Nd5＋（Gd,Nd）3Mg and （Gd,Nd）3Mg＋（Gd,Nd）Mg＋Mg2Gd, were identified in the isothermal section.
基金The project supported by National Natural Science Foundation of China
文摘The Collins model is introduced into the two-dimensional (2D) alternative ternary system having the Lennard-Jones (L-J) potential. The Gibbs free energy of this ternary system is calculated, and according to thermodynamic theory, a group of equations that determine the solid-liquid diagram of ternary system are derived, someisothermal sectional diagrams of the 2D ternary system are obtained. The results are quite similar to the behavior ofthree-dimensional substances.
基金financially supported by the National Natural Science Foundation of China(No.51831007)National Key R&D Program of China(No.2017YFB0702901)。
文摘Phase diagrams of two isothermal sections of the Ni-Ti-Ta ternary system at 1000 and 1200℃in a full composition range were determined by X-ray diffraction and electron probe microanalysis.The experimental results indicated a ternary compoundτphase with low solid solubility and composition ranges of(16.3-22.4)at.%Ta,(15.9-24.1)at.%Ti and(58.5-60.0)at.%Ni at 1000℃.The two terminal solid solutions(bcc-(Ta)andβ-Ti)formed a continuous solid solution at 1000 and 1200℃.A certain amount of Ti can dissolve into Ni-Ta intermetallic compounds near the Ni-Ta side,with the highest value of 21.9 at.%observed in the Ni;Ta compound at 1000℃.
基金Projects(50371104 50401011) supported by the National Natural Science Foundation of China
文摘The isothermal section of Ag-Ti-Zr ternary system at 1023 K was determined by diffusion triple and electron probe microanalysis. The results indicate that four binary intermetallic phases of AgTi, AgTi2, AgZr and AgZr2 are found in Ag-Ti-Zr ternary system at 1 023 K. AgZr2 and AgTi2 form a continuous solid solution, namely Ag(Ti,Zr)2. Four three-phase regions: AgTi +AgZr + Ag, AgTi +AgZr + Ag (Ti, Zr)2, α-Zr +β(Ti, Zr) + Ag (Ti, Zr) 2 and α-Ti +β(Ti, Zr) + Ag (Ti, Zr)2 exist in the isothermal section. No ternary compound is observed.
基金the Open Project of State Key Laboratory of Advanced Special Steel and Shanghai Key Laboratory of Advanced Ferrometallurgy,China(No.SKLASS2019-11)the National Natural Science Foundation of China(No.52104305).
文摘The phase diagram of ZrO_(2)−CaO−TiO_(2)system was essential for the development of photocatalytic materials and refractory materials.In this work,the ZrO_(2)−CaO−TiO_(2)system was accessed by using the CALPHAD method.The substitutional solution models were used to describe liquid and solid solution phases,the sub-lattice models were used to describe ternary compounds,and then the thermodynamic parameters were obtained by the least square method combined with literature experiment results.The acquired thermodynamic parameters were used to calculate the isothermal sections of the ZrO_(2)−CaO−TiO_(2)system at 1473 and 1673 K.There existed a good agreement between experimental and predicted phase relationships,the experimental points which were inconsistent with calculated results may be attributed to experimental errors and the sluggish kinetics of cations for ZrO_(2)-based materials.In order to further verify the validity of the database,the thermodynamic parameters were also used to simulate the thermodynamic properties(specific heat capacity,enthalpy,and entropy)of CaZrTi_(2)O_(7) within 5%errors.Good consistency demonstrated that the present thermodynamic database was self-consistent and credible.
