The lifespan models of commercial 18650-type lithium ion batteries (nominal capacity of 1150 mA-h) were presented. The lifespan was extrapolated based on this model. The results indicate that the relationship of cap...The lifespan models of commercial 18650-type lithium ion batteries (nominal capacity of 1150 mA-h) were presented. The lifespan was extrapolated based on this model. The results indicate that the relationship of capacity retention and cycle number can be expressed by Gaussian function. The selecting function and optimal precision were verified through actual match detection and a range of alternating current impedance testing. The cycle life model with high precision (〉99%) is beneficial to shortening the orediction time and cutting the prediction cost.展开更多
A resistivity distribution with a space of 3mm between test points was measured on a slice-of-silicon monocrystal (diameter 75mm) using an inclined four-point probe. This paper has determined the number of resistivi...A resistivity distribution with a space of 3mm between test points was measured on a slice-of-silicon monocrystal (diameter 75mm) using an inclined four-point probe. This paper has determined the number of resistivity divisions and their separations by statistical methods and introduced fuzzy mathematics to place the data into different fuzzy sets, after choosing the exponent function as a membership function for fuzzy sets and suitable values of thresholds. One fuzzy set corresponds to one resistivity isocontour. Then,the resistivity isocontours can be drawn with a definite separation and fi- nally shown in a map with MATLAB. The deviation of resistivity data on an isocontour is small and there are few residual test points without connections. So, the connection of the isocontours are high-quality and useful in application for instructing practical production.展开更多
In this paper, the influence of working electrolyte on high-frequency electrical performance of wet tantalum capacitors is studied. Emphasis is especially put on the study of the contribution of depolariser in reducin...In this paper, the influence of working electrolyte on high-frequency electrical performance of wet tantalum capacitors is studied. Emphasis is especially put on the study of the contribution of depolariser in reducing Equivalent Series Resistance(ESR). According to the theory of depolarization in electrochemistry and the theory of cathode capacitance of electrolytic capacitor, different kinds of depolarisers are added separately into the foregone electrolyte. Then capacitors are assembled with tantalum cores dipped with the compounded electrolytes. The best depolariser and its concentration in the whole electrolyte could be selected according to the test results of the capacitance and ESR of the capacitors. The results of our experiment show that depolariser Fe 2(SO 4) 3 used in working electrolyte of 100 V/100 μF wet tantalum capacitors can help to obtain lower ESR and higher capacitance at frequency from 0.1 kHz to 100 kHz.展开更多
The influence of implantation of N+ions of different energies on the nanostructure of7049Al substrates and the corrosioninhibition of produced Al samples in a3.5%NaCl solution was studied.The X-ray diffraction(XRD)res...The influence of implantation of N+ions of different energies on the nanostructure of7049Al substrates and the corrosioninhibition of produced Al samples in a3.5%NaCl solution was studied.The X-ray diffraction(XRD)results confirmed the formationof AlN as a result of N+ion implantation.The atomic force microscope(AFM)results showed that grains of larger scale are formedby increasing N+energy which can be due to heat accumulation in the sample during implantation causing higher rate of diffusion inthe sample,hence decreasing the number of defects.Corrosion resistance of the samples was studied by the electrochemicalimpedance spectroscopy(EIS)measurements.Results showed that corrosion resistance of implanted Al increases with increasing N+ion energy.The equivalent circuits for the N+implanted Al samples with different energies were obtained,using the EIS data whichshowed strong dependence of the equivalent circuit elements on the surface morphology of the samples.Finally,the relationshipbetween corrosion inhibition and equivalent circuit elements was investigated.展开更多
The distinction between two microwave equivalent-circuit models,quasi Esaki tunneling model (QETM) and quantum well injection transit model (QWITM),for the resonant tunneling diode (RTD) is discussed in details,and tw...The distinction between two microwave equivalent-circuit models,quasi Esaki tunneling model (QETM) and quantum well injection transit model (QWITM),for the resonant tunneling diode (RTD) is discussed in details,and two groups of circuit parameters are extracted from experiment data by the least square fit method.Both theory analysis and the comparison of fit results demonstrate that QWITM is much more precise than QETM.In addition,the rationality of QWITM circuit's parameters confirms it too.On this basis,the resistive frequency is calculated,whose influence factors and improvement method are simply discussed as well.展开更多
Dielectric barrier discharge(DBD) plasma is considered to be a promising method to synthesize solid catalysts. In this work, DBD plasma was used to synthesize a nitrogen‐vacancy‐doped g‐C3N4 catalyst in situ for ...Dielectric barrier discharge(DBD) plasma is considered to be a promising method to synthesize solid catalysts. In this work, DBD plasma was used to synthesize a nitrogen‐vacancy‐doped g‐C3N4 catalyst in situ for the first time. X‐ray diffraction, N2 adsorption, ultraviolet–visible spectroscopy, scanning electron microscopy, transmission electron microscopy, X‐ray photoelectron spectrosco‐py, electrochemical impedance spectroscopy, electron paramagnetic resonance, O2 tempera‐ture‐programmed desorption, and photoluminescence were used to characterize the obtained cat‐alysts. The photocatalytic H2O2 production ability of the as‐prepared catalyst was investigated. The results show that plasma treatment influences the morphology, structure, and optical properties of the as‐prepared catalyst. Nitrogen vacancies are active centers, which can adsorb reactant oxygen molecules, trap photoelectrons, and promote the transfer of photoelectrons from the catalyst to the adsorbed oxygen molecules for the subsequent reduction reaction. This work provides a new strat‐egy for synthesizing g‐C3N4‐based catalysts.展开更多
Vanadium pentoxide xerogel films used for lithium rechargeable batteries were prepared from crystalline c-V2O5 by melt quenching method,then the electrochemical process of lithium intercalation into vanadium pentoxide...Vanadium pentoxide xerogel films used for lithium rechargeable batteries were prepared from crystalline c-V2O5 by melt quenching method,then the electrochemical process of lithium intercalation into vanadium pentoxide xerogel films was simulated with an equivalent circuit model, which was derived from the mechanism of electrode reactions. Measured electrochemical impedance spectra at various electrode potentials were analyzed by using the complex non-linear least-squares fitting method. The results show that impedance spectra consist of 2 high-to- medium frequency depressed arcs and a low frequency straight line. The high frequency arc is attributed to the absorption reaction of lithium ions into the oxide film, the medium frequency arc is attributed to the charge transfer reaction at the vanadium oxide/electrolyte interface and the low frequency is characterized by a straight line with a phase angle of 45° corresponding to the diffusion of lithium ion through vanadium oxide phase. The experimental and calculated results are compared and discussed focusing on the electrochemical performance and the state of charge of the electrode. Moreover, the high consistence of the fitted values of the model to the experimental data indicates that this mathematical model does give a satisfying description of the intercalation process of vanadium pentoxide xerogel films.展开更多
In view of the application importance of resistance network in modern science and technology, this paper presents the basic structure of a three terminals ladder shaped resistance network, for which, to study in- dept...In view of the application importance of resistance network in modern science and technology, this paper presents the basic structure of a three terminals ladder shaped resistance network, for which, to study in- depth the equivalent resistance, carry out network analysis by applying virtual current method and construct a model of two elements three orders differential equation. Based on different marginal conditions, two general adaptive rules for the three-terminal ladder shaped inlet resistance, as well as two ultimate rules for the equiva- lent resistance of three-terminal infinite ladder shaped were given.展开更多
Effects of various sintering methods such as spark plasma sintering(SPS), hot pressing(HP) and electric resistance sintering(ERS) on the microstructure and mechanical properties of commercial pure titanium(CP-Ti) powd...Effects of various sintering methods such as spark plasma sintering(SPS), hot pressing(HP) and electric resistance sintering(ERS) on the microstructure and mechanical properties of commercial pure titanium(CP-Ti) powder consolidations with particle size of <147 μm, <74 μm and <43 μm were studied. The smaller particle powders are densified to proceed at a higher rate. Dense titanium with relative density up to 99% is found to take place at 850 °C under 30 MPa of SPS and HP condition. However, in case of ERS, CP-Ti powders were densified almost at 950 °C under 30 MPa. The microstructure of sintered titanium is composed of equiaxed grains at 850-950 °C. The yield strength of sintered body composed of <43 μm powder is 858 MPa by using SPS at 850 °C under 30 MPa. When there is a higher content of small particle, the higher yield strength value is obtained both by using SPS and HP. However, when ERS is introduced, the highest yield strength is 441 MPa at 950 °C under 30 MPa, which shows much lower values than those by SPS and HP methods. ERS method takes much less sintering time compared with SPS and HP. Nevertheless, higher sintering temperature results in lower strength and elongation because of brittle fracture.展开更多
Experimental research of anode current and anode voltage influence on the speed of decaying plasma resistance change and the time ofthyratron cutoff. Anode current resistance increase is shown to cause thyratron cutof...Experimental research of anode current and anode voltage influence on the speed of decaying plasma resistance change and the time ofthyratron cutoff. Anode current resistance increase is shown to cause thyratron cutoff time increase in case of fixed anode voltage. In turn anode voltage increase in case of fixed anode current causes earlier increase of decaying plasma resistance growth speed and quicker apparatus cutoff:展开更多
Li Fe PO4/C was prepared via solid state reaction and characterized with X-ray powder diffraction and charge–discharge test. As-prepared Li Fe PO4/C has a triphylite structure and exhibits an excellent rate capabilit...Li Fe PO4/C was prepared via solid state reaction and characterized with X-ray powder diffraction and charge–discharge test. As-prepared Li Fe PO4/C has a triphylite structure and exhibits an excellent rate capability and capacity retention. Electrochemical impedance spectroscopy(EIS) was applied to investigate LixFe PO4/C(0<x<1) electrode on temperature variation. The valid equivalent circuit for EIS fitting was determined which contains an intercalation capacitance for Li+ ion accumulation and consumption in the electrode reaction. The surface layer impedance needs to be included in the equivalent circuit when Li Fe PO4/C is deeply delithiated at a relatively high temperature. EIS examination indicates that a temperature rise leads to a better reversibility, lower charge transfer resistance, higher exchange current density J0 and greater Li+ ion diffusion coefficient for the LixFe PO4/C electrode process. The Li+ ion concentration in LixFe PO4/C is potential to impact the Li+ ion diffusion coefficient, and a decrease in the former results in an increase in the latter.展开更多
The inhibition ability of 4-amino-5-phenyl-4H-1, 2, 4-trizole-3-thiol (APTT), ethylenediaminetetra-acetic acid (EDTA) and thiourea (TU) for mild steel corrosion in 1.0 moFL HC1 solution at 30 ℃ was investigated...The inhibition ability of 4-amino-5-phenyl-4H-1, 2, 4-trizole-3-thiol (APTT), ethylenediaminetetra-acetic acid (EDTA) and thiourea (TU) for mild steel corrosion in 1.0 moFL HC1 solution at 30 ℃ was investigated. Tafel polarization and electrochemical impedance spectroscopy (EIS) were used to investigate the influence of these organic compounds as corrosion inhibitors of mild steel in 1.0 mol/L HC1 solution at 30 ℃. The inhibition mechanism was discussed in terms of Langrnuir isotherm model. Results obtained from Tafel polarization and impedance measurements are in a good agreement. The inhibition efficiency increases with the increase of the inhibitor concentration. The adsorption of the inhibitors on the mild steel surface follows Langmuir adsorption isotherm and the free energy of adsorption AGads indicates that the adsorption of APTT, EDTA, and TU molecules is a spontaneous process and a typical chemisorption.展开更多
Net blotch disease caused by the fungus Pyrenophora teres belongs to the complex of leaf blotch diseases that decrease the yield and the quality of barley (Hordeum vulgate L.). This study deals with the use of micro...Net blotch disease caused by the fungus Pyrenophora teres belongs to the complex of leaf blotch diseases that decrease the yield and the quality of barley (Hordeum vulgate L.). This study deals with the use of microsatellites localized nearby the quantitative trait loci, associated with the resistance to P. teres to screen barley lines and varieties that could be introduced into a net blotch resistance breeding program. Thirty-five barley microsatellite loci and 65 barley genotypes, 265 alleles were detected. The number of alleles per locus ranged from 2 to 26. The arrangement of genotypes into clusters based on microsatellite data does not correspond to their resistance level to P. teres even though chosen microsatellite markers have been localized nearby QTLs associated with the resistance to P. teres.展开更多
The Li Ni1/3Co1/3Mn1/3O2 is first obtained by the controlled crystallization method and then coated with Ni3(PO4)2particles. The effects of the coating on rate capability and cycle life at high cut-off voltage are inv...The Li Ni1/3Co1/3Mn1/3O2 is first obtained by the controlled crystallization method and then coated with Ni3(PO4)2particles. The effects of the coating on rate capability and cycle life at high cut-off voltage are investigated by electrochemical impedance spectroscopy and galvanostatic measurements. The element ratio of Ni:Mn:Co is tested by inductively-coupled plasma spectrometer(ICP) analysis and it testified to be 1:1:1. It is indicated that Ni3(PO4)2-coated Li Ni1/3Co1/3Mn1/3O2 has an outstanding capacity retention, where 99% capacity retention is maintained after 10 cycles at 5C discharge rate between 2.7 V and 4.6 V. The electrochemical impedance spectroscopy(EIS) results show that the current exchange density i0 of the coated sample is higher than that of Li Ni1/3Co1/3Mn1/3O2, which is beneficial to its electrochemical performances. All the conclusions show that the Ni3(PO4)2coating can prominently enhance the high rate performance of the Li Ni1/3Co1/3Mn1/3O2, especially at high cut-off voltage.展开更多
Based on constructal theory and entransy theory,the optimal designs of constant-and variable-cross-sectional cylindrical heat sources are carried out by taking dimensionless equivalent resistance minimization as optim...Based on constructal theory and entransy theory,the optimal designs of constant-and variable-cross-sectional cylindrical heat sources are carried out by taking dimensionless equivalent resistance minimization as optimization objective.The effects of the cylindrical height,the cylindrical shape and the ratio of thermal conductivity of the fin to that of the heat source are analyzed.The results show that when the volume of the heat source is fixed,there exists an optimal ratio of the center-to-centre distance of the fin and the heat source to the cylinder radius which leads to the minimum dimensionless equivalent thermal resistance.With the increase in the height of the cylindrical heat source and the ratio of thermal conductivity,the minimum dimensionless equivalent thermal resistance decreases gradually.For the heat source model with inverted variable-cross-sectional cylinder,there exist an optimal ratio of the center-to-centre distance of the fin and the heat source to the cylinder radius and an optimal radius ratio of the smaller and bigger circles of the cylindrical fin which lead to a double minimum dimensionless equivalent thermal resistance.Therefore,the heat transfer performance of the cylindrical heat source is improved by adopting the cylindrical model with variable-cross-section.The optimal constructs of the cylindrical heat source based on the minimizations of dimensionless maximum thermal resistance and dimensionless equivalent thermal resistance are different.When the thermal security is ensured,the optimal construct of the cylindrical heat source based on minimum equivalent thermal resistance can provide a new alternative scheme for the practical design of heat source.The results obtained herein enrich the work of constructal theory and entransy theory in the optimal design field of the heat sources,and they can provide some guidelines for the designs of practical heat source systems.展开更多
We have developed a new method to grow uniform graphene films directly on various substrates, such as insulators, semiconductors, and even metals, without using any catalyst. The growth was carried out using a remote ...We have developed a new method to grow uniform graphene films directly on various substrates, such as insulators, semiconductors, and even metals, without using any catalyst. The growth was carried out using a remote plasma enhancement chemical vapor deposition (r-PECVD) system at relatively low temperatures, enabling the deposition of graphene films up to 4-inch wafer scale. Scanning tunneling microscopy (STM) confirmed that the films are made up of nanocrystalline graphene particles of tens of nanometers in lateral size. The growth mechanism for the nanographene is analogous to that for diamond grown by PECVD methods, in spite of sp2 carbon atoms being formed in the case of graphene rather than sp3 carbon atoms as in diamond. This growth approach is simple, low-cost, and scalable, and might have potential applications in fields such as thin film resistors, gas sensors, electrode materials, and transparent conductive films.展开更多
基金Projects(51204209,51274240)supported by the National Natural Science Foundation of ChinaProject(HNDLKJ[2012]001-1)supported by Henan Electric Power Science&Technology Supporting Program,China
文摘The lifespan models of commercial 18650-type lithium ion batteries (nominal capacity of 1150 mA-h) were presented. The lifespan was extrapolated based on this model. The results indicate that the relationship of capacity retention and cycle number can be expressed by Gaussian function. The selecting function and optimal precision were verified through actual match detection and a range of alternating current impedance testing. The cycle life model with high precision (〉99%) is beneficial to shortening the orediction time and cutting the prediction cost.
文摘A resistivity distribution with a space of 3mm between test points was measured on a slice-of-silicon monocrystal (diameter 75mm) using an inclined four-point probe. This paper has determined the number of resistivity divisions and their separations by statistical methods and introduced fuzzy mathematics to place the data into different fuzzy sets, after choosing the exponent function as a membership function for fuzzy sets and suitable values of thresholds. One fuzzy set corresponds to one resistivity isocontour. Then,the resistivity isocontours can be drawn with a definite separation and fi- nally shown in a map with MATLAB. The deviation of resistivity data on an isocontour is small and there are few residual test points without connections. So, the connection of the isocontours are high-quality and useful in application for instructing practical production.
文摘In this paper, the influence of working electrolyte on high-frequency electrical performance of wet tantalum capacitors is studied. Emphasis is especially put on the study of the contribution of depolariser in reducing Equivalent Series Resistance(ESR). According to the theory of depolarization in electrochemistry and the theory of cathode capacitance of electrolytic capacitor, different kinds of depolarisers are added separately into the foregone electrolyte. Then capacitors are assembled with tantalum cores dipped with the compounded electrolytes. The best depolariser and its concentration in the whole electrolyte could be selected according to the test results of the capacitance and ESR of the capacitors. The results of our experiment show that depolariser Fe 2(SO 4) 3 used in working electrolyte of 100 V/100 μF wet tantalum capacitors can help to obtain lower ESR and higher capacitance at frequency from 0.1 kHz to 100 kHz.
基金University of Tehran and the Iran National Science Foundation(INSF)center of excellence for structural and microscopic properties of matter,Department of Physics,University of Tehran for partial support of this work
文摘The influence of implantation of N+ions of different energies on the nanostructure of7049Al substrates and the corrosioninhibition of produced Al samples in a3.5%NaCl solution was studied.The X-ray diffraction(XRD)results confirmed the formationof AlN as a result of N+ion implantation.The atomic force microscope(AFM)results showed that grains of larger scale are formedby increasing N+energy which can be due to heat accumulation in the sample during implantation causing higher rate of diffusion inthe sample,hence decreasing the number of defects.Corrosion resistance of the samples was studied by the electrochemicalimpedance spectroscopy(EIS)measurements.Results showed that corrosion resistance of implanted Al increases with increasing N+ion energy.The equivalent circuits for the N+implanted Al samples with different energies were obtained,using the EIS data whichshowed strong dependence of the equivalent circuit elements on the surface morphology of the samples.Finally,the relationshipbetween corrosion inhibition and equivalent circuit elements was investigated.
文摘The distinction between two microwave equivalent-circuit models,quasi Esaki tunneling model (QETM) and quantum well injection transit model (QWITM),for the resonant tunneling diode (RTD) is discussed in details,and two groups of circuit parameters are extracted from experiment data by the least square fit method.Both theory analysis and the comparison of fit results demonstrate that QWITM is much more precise than QETM.In addition,the rationality of QWITM circuit's parameters confirms it too.On this basis,the resistive frequency is calculated,whose influence factors and improvement method are simply discussed as well.
基金supported by the Pilot Program of University of Liaoning Innovation and Education Reform~~
文摘Dielectric barrier discharge(DBD) plasma is considered to be a promising method to synthesize solid catalysts. In this work, DBD plasma was used to synthesize a nitrogen‐vacancy‐doped g‐C3N4 catalyst in situ for the first time. X‐ray diffraction, N2 adsorption, ultraviolet–visible spectroscopy, scanning electron microscopy, transmission electron microscopy, X‐ray photoelectron spectrosco‐py, electrochemical impedance spectroscopy, electron paramagnetic resonance, O2 tempera‐ture‐programmed desorption, and photoluminescence were used to characterize the obtained cat‐alysts. The photocatalytic H2O2 production ability of the as‐prepared catalyst was investigated. The results show that plasma treatment influences the morphology, structure, and optical properties of the as‐prepared catalyst. Nitrogen vacancies are active centers, which can adsorb reactant oxygen molecules, trap photoelectrons, and promote the transfer of photoelectrons from the catalyst to the adsorbed oxygen molecules for the subsequent reduction reaction. This work provides a new strat‐egy for synthesizing g‐C3N4‐based catalysts.
文摘Vanadium pentoxide xerogel films used for lithium rechargeable batteries were prepared from crystalline c-V2O5 by melt quenching method,then the electrochemical process of lithium intercalation into vanadium pentoxide xerogel films was simulated with an equivalent circuit model, which was derived from the mechanism of electrode reactions. Measured electrochemical impedance spectra at various electrode potentials were analyzed by using the complex non-linear least-squares fitting method. The results show that impedance spectra consist of 2 high-to- medium frequency depressed arcs and a low frequency straight line. The high frequency arc is attributed to the absorption reaction of lithium ions into the oxide film, the medium frequency arc is attributed to the charge transfer reaction at the vanadium oxide/electrolyte interface and the low frequency is characterized by a straight line with a phase angle of 45° corresponding to the diffusion of lithium ion through vanadium oxide phase. The experimental and calculated results are compared and discussed focusing on the electrochemical performance and the state of charge of the electrode. Moreover, the high consistence of the fitted values of the model to the experimental data indicates that this mathematical model does give a satisfying description of the intercalation process of vanadium pentoxide xerogel films.
基金a project financed by Natural Science Fund of Education Department of Jiangsu Province (02KJB140008)
文摘In view of the application importance of resistance network in modern science and technology, this paper presents the basic structure of a three terminals ladder shaped resistance network, for which, to study in- depth the equivalent resistance, carry out network analysis by applying virtual current method and construct a model of two elements three orders differential equation. Based on different marginal conditions, two general adaptive rules for the three-terminal ladder shaped inlet resistance, as well as two ultimate rules for the equiva- lent resistance of three-terminal infinite ladder shaped were given.
基金Project(K0004130) supported by the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Knowledge Economy,Korea
文摘Effects of various sintering methods such as spark plasma sintering(SPS), hot pressing(HP) and electric resistance sintering(ERS) on the microstructure and mechanical properties of commercial pure titanium(CP-Ti) powder consolidations with particle size of <147 μm, <74 μm and <43 μm were studied. The smaller particle powders are densified to proceed at a higher rate. Dense titanium with relative density up to 99% is found to take place at 850 °C under 30 MPa of SPS and HP condition. However, in case of ERS, CP-Ti powders were densified almost at 950 °C under 30 MPa. The microstructure of sintered titanium is composed of equiaxed grains at 850-950 °C. The yield strength of sintered body composed of <43 μm powder is 858 MPa by using SPS at 850 °C under 30 MPa. When there is a higher content of small particle, the higher yield strength value is obtained both by using SPS and HP. However, when ERS is introduced, the highest yield strength is 441 MPa at 950 °C under 30 MPa, which shows much lower values than those by SPS and HP methods. ERS method takes much less sintering time compared with SPS and HP. Nevertheless, higher sintering temperature results in lower strength and elongation because of brittle fracture.
文摘Experimental research of anode current and anode voltage influence on the speed of decaying plasma resistance change and the time ofthyratron cutoff. Anode current resistance increase is shown to cause thyratron cutoff time increase in case of fixed anode voltage. In turn anode voltage increase in case of fixed anode current causes earlier increase of decaying plasma resistance growth speed and quicker apparatus cutoff:
基金Project(2010ZC051)supported by the Natural Science Foundation of Yunnan Province,ChinaProject(20140439)supported by Analysis and Testing Foundation from Kunming University of Science and Technology,ChinaProject(14118245)supported by Starting Research Fund from Kunming University of Science and Technology,China
文摘Li Fe PO4/C was prepared via solid state reaction and characterized with X-ray powder diffraction and charge–discharge test. As-prepared Li Fe PO4/C has a triphylite structure and exhibits an excellent rate capability and capacity retention. Electrochemical impedance spectroscopy(EIS) was applied to investigate LixFe PO4/C(0<x<1) electrode on temperature variation. The valid equivalent circuit for EIS fitting was determined which contains an intercalation capacitance for Li+ ion accumulation and consumption in the electrode reaction. The surface layer impedance needs to be included in the equivalent circuit when Li Fe PO4/C is deeply delithiated at a relatively high temperature. EIS examination indicates that a temperature rise leads to a better reversibility, lower charge transfer resistance, higher exchange current density J0 and greater Li+ ion diffusion coefficient for the LixFe PO4/C electrode process. The Li+ ion concentration in LixFe PO4/C is potential to impact the Li+ ion diffusion coefficient, and a decrease in the former results in an increase in the latter.
基金Project(UKM-GUP-BTT-07-25-170) supported by Universiti Kebangsaan Malaysia
文摘The inhibition ability of 4-amino-5-phenyl-4H-1, 2, 4-trizole-3-thiol (APTT), ethylenediaminetetra-acetic acid (EDTA) and thiourea (TU) for mild steel corrosion in 1.0 moFL HC1 solution at 30 ℃ was investigated. Tafel polarization and electrochemical impedance spectroscopy (EIS) were used to investigate the influence of these organic compounds as corrosion inhibitors of mild steel in 1.0 mol/L HC1 solution at 30 ℃. The inhibition mechanism was discussed in terms of Langrnuir isotherm model. Results obtained from Tafel polarization and impedance measurements are in a good agreement. The inhibition efficiency increases with the increase of the inhibitor concentration. The adsorption of the inhibitors on the mild steel surface follows Langmuir adsorption isotherm and the free energy of adsorption AGads indicates that the adsorption of APTT, EDTA, and TU molecules is a spontaneous process and a typical chemisorption.
文摘Net blotch disease caused by the fungus Pyrenophora teres belongs to the complex of leaf blotch diseases that decrease the yield and the quality of barley (Hordeum vulgate L.). This study deals with the use of microsatellites localized nearby the quantitative trait loci, associated with the resistance to P. teres to screen barley lines and varieties that could be introduced into a net blotch resistance breeding program. Thirty-five barley microsatellite loci and 65 barley genotypes, 265 alleles were detected. The number of alleles per locus ranged from 2 to 26. The arrangement of genotypes into clusters based on microsatellite data does not correspond to their resistance level to P. teres even though chosen microsatellite markers have been localized nearby QTLs associated with the resistance to P. teres.
基金Supported by the National Natural Science Foundation of China(51074096)
文摘The Li Ni1/3Co1/3Mn1/3O2 is first obtained by the controlled crystallization method and then coated with Ni3(PO4)2particles. The effects of the coating on rate capability and cycle life at high cut-off voltage are investigated by electrochemical impedance spectroscopy and galvanostatic measurements. The element ratio of Ni:Mn:Co is tested by inductively-coupled plasma spectrometer(ICP) analysis and it testified to be 1:1:1. It is indicated that Ni3(PO4)2-coated Li Ni1/3Co1/3Mn1/3O2 has an outstanding capacity retention, where 99% capacity retention is maintained after 10 cycles at 5C discharge rate between 2.7 V and 4.6 V. The electrochemical impedance spectroscopy(EIS) results show that the current exchange density i0 of the coated sample is higher than that of Li Ni1/3Co1/3Mn1/3O2, which is beneficial to its electrochemical performances. All the conclusions show that the Ni3(PO4)2coating can prominently enhance the high rate performance of the Li Ni1/3Co1/3Mn1/3O2, especially at high cut-off voltage.
基金supported by the National Natural Science Foundation of China(Grant Nos.5120618451176203&51356001)
文摘Based on constructal theory and entransy theory,the optimal designs of constant-and variable-cross-sectional cylindrical heat sources are carried out by taking dimensionless equivalent resistance minimization as optimization objective.The effects of the cylindrical height,the cylindrical shape and the ratio of thermal conductivity of the fin to that of the heat source are analyzed.The results show that when the volume of the heat source is fixed,there exists an optimal ratio of the center-to-centre distance of the fin and the heat source to the cylinder radius which leads to the minimum dimensionless equivalent thermal resistance.With the increase in the height of the cylindrical heat source and the ratio of thermal conductivity,the minimum dimensionless equivalent thermal resistance decreases gradually.For the heat source model with inverted variable-cross-sectional cylinder,there exist an optimal ratio of the center-to-centre distance of the fin and the heat source to the cylinder radius and an optimal radius ratio of the smaller and bigger circles of the cylindrical fin which lead to a double minimum dimensionless equivalent thermal resistance.Therefore,the heat transfer performance of the cylindrical heat source is improved by adopting the cylindrical model with variable-cross-section.The optimal constructs of the cylindrical heat source based on the minimizations of dimensionless maximum thermal resistance and dimensionless equivalent thermal resistance are different.When the thermal security is ensured,the optimal construct of the cylindrical heat source based on minimum equivalent thermal resistance can provide a new alternative scheme for the practical design of heat source.The results obtained herein enrich the work of constructal theory and entransy theory in the optimal design field of the heat sources,and they can provide some guidelines for the designs of practical heat source systems.
基金This work was supported by the Institute of Physics Start-up Founding, 100 Talents Program of the Chinese Academy of Sciences (CAS), the Science Foundation of CAS, the National Science Foundation of China (NSFC) (grant Nos. 10974226 and 11074288), and the National 973 project of China (grant No. 2010CB934202).
文摘We have developed a new method to grow uniform graphene films directly on various substrates, such as insulators, semiconductors, and even metals, without using any catalyst. The growth was carried out using a remote plasma enhancement chemical vapor deposition (r-PECVD) system at relatively low temperatures, enabling the deposition of graphene films up to 4-inch wafer scale. Scanning tunneling microscopy (STM) confirmed that the films are made up of nanocrystalline graphene particles of tens of nanometers in lateral size. The growth mechanism for the nanographene is analogous to that for diamond grown by PECVD methods, in spite of sp2 carbon atoms being formed in the case of graphene rather than sp3 carbon atoms as in diamond. This growth approach is simple, low-cost, and scalable, and might have potential applications in fields such as thin film resistors, gas sensors, electrode materials, and transparent conductive films.