Herein,we report a novel ternary material comprised of Ag nanoparticles and carbon quantum dots(CDs),which are co-loaded using 2D Bi4Ti3O12(BIT)sheets.In this system,Ag can be applied as excited electron-hole pairs in...Herein,we report a novel ternary material comprised of Ag nanoparticles and carbon quantum dots(CDs),which are co-loaded using 2D Bi4Ti3O12(BIT)sheets.In this system,Ag can be applied as excited electron-hole pairs in the Bi4Ti3O12 by transferring the plasmonic energy from the metal to the semiconductor.The surface plasmon resonance of Ag can promote the electron transfer properties of the CDs,thereby improving the separation efficiency of the electron-hole pairs.Meanwhile,the CDs can act as an electron buffer to decrease the recombination rate of the electron hole.Moreover,CDs are prepared using a biomaterial,which can provide a chemical group to enhance the electron transfer and connection.The synergistic effects of CDs,Ag,and BIT enable the design of a photocatalytic application with a remarkably improved efficiency and operational stability.展开更多
In the context of ＂two-wheel drive＂ development mode, China＇s construction land shows significant expansion characteristics. The carbon emission effect of construction land changes is an important factor for the in...In the context of ＂two-wheel drive＂ development mode, China＇s construction land shows significant expansion characteristics. The carbon emission effect of construction land changes is an important factor for the increase of carbon emissions in the atmosphere. In this study, the drivers of carbon emissions in Anhui Province from 1997 to 2011 were quantitatively measured using the improved Kaya identity and Logarithmic Mean Divisia Index. The results show that： economic growth, expansion of construction land and changes in population density have incremental effects on carbon emissions. The average contribution rate of economic growth as the first driver is 266.32 percent. The construction land expansion is an important driving factor with annual mean carbon effect of 6.4057 million tons and annual mean contribution rate of 187.30 percent. But the change in population density has little impact on carbon emission driving. Energy structure changes and energy intensity reduction have inhibitory effects on carbon emissions, of which the annual mean contribution rate is -212.06 percent and -158.115 percent respectively. The targeted policy approaches of carbon emission reduction were put forward based on the decomposition of carbon emission factors, laying a scientific basis to rationally use the land for the Government, which is conducive to build an ecological province for Anhui and achieve the purpose of emission reduction, providing a reference for the research on carbon emission effect of changes in provincial-scale construction land.展开更多
基金financially supported by the National Natural Science Foundation of China(U1510126,21676115)the Natural Science Foundation of Jiangsu Provincial(BK20180884)~~
文摘Herein,we report a novel ternary material comprised of Ag nanoparticles and carbon quantum dots(CDs),which are co-loaded using 2D Bi4Ti3O12(BIT)sheets.In this system,Ag can be applied as excited electron-hole pairs in the Bi4Ti3O12 by transferring the plasmonic energy from the metal to the semiconductor.The surface plasmon resonance of Ag can promote the electron transfer properties of the CDs,thereby improving the separation efficiency of the electron-hole pairs.Meanwhile,the CDs can act as an electron buffer to decrease the recombination rate of the electron hole.Moreover,CDs are prepared using a biomaterial,which can provide a chemical group to enhance the electron transfer and connection.The synergistic effects of CDs,Ag,and BIT enable the design of a photocatalytic application with a remarkably improved efficiency and operational stability.
基金the Key Research Fund of Anhui Provincial Education Department (No.2010sk502zd)the National Natural Science Foundation of China (No.41071337)
文摘In the context of ＂two-wheel drive＂ development mode, China＇s construction land shows significant expansion characteristics. The carbon emission effect of construction land changes is an important factor for the increase of carbon emissions in the atmosphere. In this study, the drivers of carbon emissions in Anhui Province from 1997 to 2011 were quantitatively measured using the improved Kaya identity and Logarithmic Mean Divisia Index. The results show that： economic growth, expansion of construction land and changes in population density have incremental effects on carbon emissions. The average contribution rate of economic growth as the first driver is 266.32 percent. The construction land expansion is an important driving factor with annual mean carbon effect of 6.4057 million tons and annual mean contribution rate of 187.30 percent. But the change in population density has little impact on carbon emission driving. Energy structure changes and energy intensity reduction have inhibitory effects on carbon emissions, of which the annual mean contribution rate is -212.06 percent and -158.115 percent respectively. The targeted policy approaches of carbon emission reduction were put forward based on the decomposition of carbon emission factors, laying a scientific basis to rationally use the land for the Government, which is conducive to build an ecological province for Anhui and achieve the purpose of emission reduction, providing a reference for the research on carbon emission effect of changes in provincial-scale construction land.
