应用多光子非线性Compton散射和实验探测的方法,对超强激光瞬态等离子体的频率响应特性进行了研究,提出了将入射超强激光和Compton散射光作为形成等离子体碰撞频率的新机制,给出了电子碰撞频率的时空演化方程和实验结果 .结果表明：与...应用多光子非线性Compton散射和实验探测的方法,对超强激光瞬态等离子体的频率响应特性进行了研究,提出了将入射超强激光和Compton散射光作为形成等离子体碰撞频率的新机制,给出了电子碰撞频率的时空演化方程和实验结果 .结果表明：与散射前相比,4.17 k Hz以下的功率谱线较平滑,不同时刻抖动幅度不大,且抖动的频率降低了1.63 k Hz.当频率达到6.12 k Hz时,功率谱线出现了35 m W幅度抖动,且大幅抖动的频率降低了0.88 k Hz,幅度增大了5 m W.当频率达到9.7 k Hz时,功率谱线的峰值近似于全谱峰值,且该谱线峰值的频率降低了1.3 k Hz.由4.17～9.7 k Hz低频谱产生的功率谱线缩小了0.21k Hz.超过9.1 k Hz后,功率谱线抖动对功率谱线峰值的贡献是次要的.这主要是由于散射使等离子体的高频非线性成分增大,低频成分缩小,且4.17～9.7 k Hz中亦包含有散射贡献的缘故.展开更多
The bimetallic nanostructures that mix a plasmonic metal with a transition metal in the form of the core-shell nanoparticles are promising to promote catalytic performance.But it is still unclear how the heat(hot elec...The bimetallic nanostructures that mix a plasmonic metal with a transition metal in the form of the core-shell nanoparticles are promising to promote catalytic performance.But it is still unclear how the heat(hot electrons and phonons)transfers on the interface between two metals.We have designed and synthesized Au@Cu bimetallic nanoparticles with Au as core and Cu as shell.By using transient absorption spectroscopy,we find that there are two plasmon induced heat funneling processes from Au core to Cu shell.One is the electron temperature equilibrium(electron heat transfer)with equilibration time of~560 fs.The other is the lattice temperature equilibrium(lattice heat transfer)with equilibration time of~13 ps.This plasmon induced heat funneling may be universal in similar bimetallic nanostructures,so our finding could contribute to further understanding the catalytic mechanism of bimetallic plasmonic photothermal catalysis.展开更多
Study of the morphology, aggregation structure and properties ofBombyx mori silk treated by low temperature oxygen plasma showed that slight flutes appeared on the surface of Bombyx mori silk fiber and that its surfac...Study of the morphology, aggregation structure and properties ofBombyx mori silk treated by low temperature oxygen plasma showed that slight flutes appeared on the surface of Bombyx mori silk fiber and that its surface structure changed after plasma treatment. The conformation also changed and crystalline degree decreased. The stannic filling rate of treated fiber was improved. Because of etching, the weight of the fiber decreased but the breaking strength changed little after short-time treatment.展开更多
Objective To analyze the role of resistin in insulin resistance (IR) through investigating the variation of plasma resistin levels and single-nucleotide polymorphisms (SNPs) in resistin gene 5’ flanking region in str...Objective To analyze the role of resistin in insulin resistance (IR) through investigating the variation of plasma resistin levels and single-nucleotide polymorphisms (SNPs) in resistin gene 5’ flanking region in stroke patients.Methods In 103 atherothrombotic cerebral infarction (ACI) patients, 85 lacunar infarction (LI) patients, 70 intracerebral hemorrhage (ICH) patients, and 86 healthy controls, plasma resistin and insulin levels were measured by ELISA , SNPs in resistin gene 5’ flanking region were detected by PCR and direct DNA sequencing. The subjects’ body height and weight, the body mass index, quantitative insulin sensitivity check index (QUICKI), blood pressure, and the concentration of fasting plasma glucose, triglyceride, total cholesterol, creatinine, low-density lipoprotein, and high-density lipoprotein were also determined. Results QUICKI was significantly lower in the ACI and ICH patients (0.316±0.037 and 0.309±0.032, respectively) than that in the controls (0.342±0.043, P<0.001), while plasma resistin level was significantly higher in the ACI and ICH patients (6.36±3.79 and 7.15±4.27 ng/mL, respectively) than that in the controls (5.28±2.56 ng/mL, P<0.05), but such difference was not observed in the LI patients compared with controls. There was a statistically negative correlation between plasma resistin level with QUICKI (r=-0.228, P<0.001). The distributions of allele and genotype frequencies of resistin gene -420C>G and -537A>C SNPs were not significantly different among the different groups, and those SNPs were not correlated with other clinical and biochemical parameters.Conclusions Plasma resistin is associated with stroke by participating in the development of IR. The SNPs in resistin gene 5’ flanking region has no impact on the plasma resistin level.展开更多
The direct synthesis of C2 hydrocarbons （ethylene, acetylene and ethane） from methane is one of the most important task in C1 chemistry. Higher conversion of methane and selectivity to C2 hydrocarbons can be real-iz...The direct synthesis of C2 hydrocarbons （ethylene, acetylene and ethane） from methane is one of the most important task in C1 chemistry. Higher conversion of methane and selectivity to C2 hydrocarbons can be real-ized through plasma reaction. In order to explore the reaction process and mechanism, the possible reaction paths （1）—（4） were proposed on coupling reaction of methane through plasma and studied theoretically using semi-PM3 method [PM3 is parameterization method of modified neglect of diatomic overlap （MNDO）] including determining the transition state, calculating the activation energy and thermodynamic state functions and analyzing the bond or-der and intrinsic reaction coordinate. The reaction heat results indicate that the reactions （2） and （4） are exothermic, while reactions of （1） and （3） are endothermic. The activation energy results show that activation energy for reac-tions （1） and （2） was much lower than that of reaction paths （3） and （4）. Therefore, paths （1） and （2） is the favorable reaction path energetically. More interestingly by comparing the intrinsic reaction coordinated （IRC） of the reaction paths （1） and （2）, it is found that the variations of bond lengths in reaction path （1） has a crucial effect on the poten-tial energy, while in reaction path （2）, the adjustment of the system geometry also contributes to the whole potential energy of the system.展开更多
Bound states, such as qq and q^-q, may exist the volume of the bound states may evoke a reduction in investigate qualitatively the volume effect on the properties states start to be completely melted.
The present work extends the previous work^[2] on 5-ion system to consider 7-ion system （i.e., Au^47＋ -Au^53＋）. It is found that more highly charged ions, e.g., Au^53＋, Au^54＋ etc., could be able to be neglected...The present work extends the previous work^[2] on 5-ion system to consider 7-ion system （i.e., Au^47＋ -Au^53＋）. It is found that more highly charged ions, e.g., Au^53＋, Au^54＋ etc., could be able to be neglected, however, less highly charged ions, e.g., Au^47＋, Au^46＋ etc., are rather important. Therefore, a new idea to consider 8-ion system, i.e., Au^46＋ - Au^53＋, is under way. As a supplement, we discuss the simultaneous reaction, which would be important in this sort of works.展开更多
文摘应用多光子非线性Compton散射和实验探测的方法,对超强激光瞬态等离子体的频率响应特性进行了研究,提出了将入射超强激光和Compton散射光作为形成等离子体碰撞频率的新机制,给出了电子碰撞频率的时空演化方程和实验结果 .结果表明：与散射前相比,4.17 k Hz以下的功率谱线较平滑,不同时刻抖动幅度不大,且抖动的频率降低了1.63 k Hz.当频率达到6.12 k Hz时,功率谱线出现了35 m W幅度抖动,且大幅抖动的频率降低了0.88 k Hz,幅度增大了5 m W.当频率达到9.7 k Hz时,功率谱线的峰值近似于全谱峰值,且该谱线峰值的频率降低了1.3 k Hz.由4.17～9.7 k Hz低频谱产生的功率谱线缩小了0.21k Hz.超过9.1 k Hz后,功率谱线抖动对功率谱线峰值的贡献是次要的.这主要是由于散射使等离子体的高频非线性成分增大,低频成分缩小,且4.17～9.7 k Hz中亦包含有散射贡献的缘故.
基金supported by the National Naural Science Foudation of China(No.21873013 and No.22273006).
文摘The bimetallic nanostructures that mix a plasmonic metal with a transition metal in the form of the core-shell nanoparticles are promising to promote catalytic performance.But it is still unclear how the heat(hot electrons and phonons)transfers on the interface between two metals.We have designed and synthesized Au@Cu bimetallic nanoparticles with Au as core and Cu as shell.By using transient absorption spectroscopy,we find that there are two plasmon induced heat funneling processes from Au core to Cu shell.One is the electron temperature equilibrium(electron heat transfer)with equilibration time of~560 fs.The other is the lattice temperature equilibrium(lattice heat transfer)with equilibration time of~13 ps.This plasmon induced heat funneling may be universal in similar bimetallic nanostructures,so our finding could contribute to further understanding the catalytic mechanism of bimetallic plasmonic photothermal catalysis.
文摘Study of the morphology, aggregation structure and properties ofBombyx mori silk treated by low temperature oxygen plasma showed that slight flutes appeared on the surface of Bombyx mori silk fiber and that its surface structure changed after plasma treatment. The conformation also changed and crystalline degree decreased. The stannic filling rate of treated fiber was improved. Because of etching, the weight of the fiber decreased but the breaking strength changed little after short-time treatment.
基金"135 Project"Key Talent Fund of Public Health Department of Jiangsu Province
文摘Objective To analyze the role of resistin in insulin resistance (IR) through investigating the variation of plasma resistin levels and single-nucleotide polymorphisms (SNPs) in resistin gene 5’ flanking region in stroke patients.Methods In 103 atherothrombotic cerebral infarction (ACI) patients, 85 lacunar infarction (LI) patients, 70 intracerebral hemorrhage (ICH) patients, and 86 healthy controls, plasma resistin and insulin levels were measured by ELISA , SNPs in resistin gene 5’ flanking region were detected by PCR and direct DNA sequencing. The subjects’ body height and weight, the body mass index, quantitative insulin sensitivity check index (QUICKI), blood pressure, and the concentration of fasting plasma glucose, triglyceride, total cholesterol, creatinine, low-density lipoprotein, and high-density lipoprotein were also determined. Results QUICKI was significantly lower in the ACI and ICH patients (0.316±0.037 and 0.309±0.032, respectively) than that in the controls (0.342±0.043, P<0.001), while plasma resistin level was significantly higher in the ACI and ICH patients (6.36±3.79 and 7.15±4.27 ng/mL, respectively) than that in the controls (5.28±2.56 ng/mL, P<0.05), but such difference was not observed in the LI patients compared with controls. There was a statistically negative correlation between plasma resistin level with QUICKI (r=-0.228, P<0.001). The distributions of allele and genotype frequencies of resistin gene -420C>G and -537A>C SNPs were not significantly different among the different groups, and those SNPs were not correlated with other clinical and biochemical parameters.Conclusions Plasma resistin is associated with stroke by participating in the development of IR. The SNPs in resistin gene 5’ flanking region has no impact on the plasma resistin level.
基金Supported by the National Natural Science Foundation of China (No.20606023).
文摘The direct synthesis of C2 hydrocarbons （ethylene, acetylene and ethane） from methane is one of the most important task in C1 chemistry. Higher conversion of methane and selectivity to C2 hydrocarbons can be real-ized through plasma reaction. In order to explore the reaction process and mechanism, the possible reaction paths （1）—（4） were proposed on coupling reaction of methane through plasma and studied theoretically using semi-PM3 method [PM3 is parameterization method of modified neglect of diatomic overlap （MNDO）] including determining the transition state, calculating the activation energy and thermodynamic state functions and analyzing the bond or-der and intrinsic reaction coordinate. The reaction heat results indicate that the reactions （2） and （4） are exothermic, while reactions of （1） and （3） are endothermic. The activation energy results show that activation energy for reac-tions （1） and （2） was much lower than that of reaction paths （3） and （4）. Therefore, paths （1） and （2） is the favorable reaction path energetically. More interestingly by comparing the intrinsic reaction coordinated （IRC） of the reaction paths （1） and （2）, it is found that the variations of bond lengths in reaction path （1） has a crucial effect on the poten-tial energy, while in reaction path （2）, the adjustment of the system geometry also contributes to the whole potential energy of the system.
基金The project supported in part by National Natural Science Foundation of China under Grant Nos. 90103019 and 10428510.We thank professor Yu-Xin Liu for useful discussions,
文摘Bound states, such as qq and q^-q, may exist the volume of the bound states may evoke a reduction in investigate qualitatively the volume effect on the properties states start to be completely melted.
基金The project supported by the National Key Laboratory for High Temperature and Density Plasma Physics under Grant No. 514800203055SC0101
文摘The present work extends the previous work^[2] on 5-ion system to consider 7-ion system （i.e., Au^47＋ -Au^53＋）. It is found that more highly charged ions, e.g., Au^53＋, Au^54＋ etc., could be able to be neglected, however, less highly charged ions, e.g., Au^47＋, Au^46＋ etc., are rather important. Therefore, a new idea to consider 8-ion system, i.e., Au^46＋ - Au^53＋, is under way. As a supplement, we discuss the simultaneous reaction, which would be important in this sort of works.
