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激光波长对煤激光诱导击穿光谱特性影响的试验研究 被引量:10
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作者 钱燕 钟厦 +3 位作者 何勇 Ronald Whiddon 王智化 岑可法 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2017年第6期1890-1895,共6页
我国电站入炉煤种复杂多变,实时快速获取煤质成分对保障锅炉的安全、高效、低污染运行具有重大意义。将激光诱导击穿光谱(LIBS)技术应用于燃煤煤质测量,观测了不同波长激光(355,532和1 064nm)诱导产生的等离子体时间演变特性和不同电离... 我国电站入炉煤种复杂多变,实时快速获取煤质成分对保障锅炉的安全、高效、低污染运行具有重大意义。将激光诱导击穿光谱(LIBS)技术应用于燃煤煤质测量,观测了不同波长激光(355,532和1 064nm)诱导产生的等离子体时间演变特性和不同电离特性元素的谱线时间特性,对比了出现屏蔽效应时的能量阈值随激光波长的变化特征,并研究了激光波长对煤LIBS光谱特性的影响规律。结果发现:使用532nm激光作为激发光源时,煤LIBS光谱具有最强的谱线信号强度,且出现等离子体屏蔽效应的能量阈值也较高,是一种较理想的激发光源,为LIBS技术在煤质测量领域的工业应用提供了实验依据。 展开更多
关键词 激光诱导击穿光谱 激光波长 等离子体时间演化 等离子体屏蔽效应
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Time Evolution of the Multicomponent Laser Plasma Parameters
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作者 Geza Laslov M.E Chuchman 《Journal of Chemistry and Chemical Engineering》 2013年第1期84-87,共4页
The emission of CulnSe2-based laser ablation plasma has been investigated at a distance of I mm from the target surface. The plasma was formed by radiation of the neodymium laser (5 ×10^8 W.cm^-2; 1,064 nm; 20 n... The emission of CulnSe2-based laser ablation plasma has been investigated at a distance of I mm from the target surface. The plasma was formed by radiation of the neodymium laser (5 ×10^8 W.cm^-2; 1,064 nm; 20 ns; 12 Hz). The temporal dynamics have been obtained for the plasma parameters, such as the population of excited states of atoms, electron temperature and density. Two peaks were observed in the temporal profile of the population of excited states. The temporal dependence of electron temperature was singly peaked. During the time interval of 0-300 ns, the electron temperature varied in the range of 1.6-1.2 eV and the density of electrons varied in the range of 1.3 × 10^16 cm^-3 to 9 × 10^14 cm^-3. It has been established that at the selected conditions of plasma formation saved ratio of copper and indium, which correspond to stoichoimetric target composition. 展开更多
关键词 Laser plasma optical emission spectroscopy electron temperature and concentration CulnSe2 compound.
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