The development of efficient and cost‐effective metal‐free electrocatalysts for oxygen reduction reaction(ORR)has become crucial for electrochemical energy systems.However,reasonably validating and precisely regulat...The development of efficient and cost‐effective metal‐free electrocatalysts for oxygen reduction reaction(ORR)has become crucial for electrochemical energy systems.However,reasonably validating and precisely regulating the active sites for designing optimized materials are still challenging.Herein,we report a precise and controllable tandem strategy to boost the ORR activity based on metal‐free covalent organic frameworks(MFCOFs)comprising imine‐N,thiophene‐S,or triazine‐N.Among these MFCOFs,post‐tandem BTT‐TAT‐COF structure displayed a more positive catalytic capability and excellent electrochemical stability,indicating that the synergistic catalysis of multiple active sites induced the ORR catalytic activity through the conjugated skeleton of the structure.Density‐functional theory calculations suggest that the series‐connected backbone contained highly effective electrocatalytic active centers and provided synergistic catalysis.More importantly,this strategy highlights new opportunities for the advancement of efficient COF‐based metal‐free ORR catalysts.展开更多
Carbon dioxide emissions have increased due to the consumption of fossil fuels,making the neutralization and utilization of CO_(2) a pressing issue.As a clean and efficient energy conversion process,electrocatalytic r...Carbon dioxide emissions have increased due to the consumption of fossil fuels,making the neutralization and utilization of CO_(2) a pressing issue.As a clean and efficient energy conversion process,electrocatalytic reduction can reduce carbon dioxide into a series of alcohols and acidic organic molecules,which can effectively realize the utilization and transformation of carbon dioxide.This review focuses on the tuning strategies and structure effects of catalysts for the electrocatalytic CO_(2) reduction reaction(CO_(2)RR).The tuning strategies for the active sites of catalysts have been reviewed from intrinsic and external perspectives.The structure effects for the CO_(2)RR catalysts have also been discussed,such as tandem catalysis,synergistic effects and confinement catalysis.We expect that this review about tuning strategies and structure effects can provide guidance for designing highly efficient CO_(2)RR electrocatalysts.展开更多
This study proposed a design and optimization strategy for a tandem arranged cascade using the Non-dominated Sorting Genetic Algorithm(NSGA) Ⅱ multi-objective optimization algorithm and Back Propagation(BP) neural ne...This study proposed a design and optimization strategy for a tandem arranged cascade using the Non-dominated Sorting Genetic Algorithm(NSGA) Ⅱ multi-objective optimization algorithm and Back Propagation(BP) neural network technology. The NASA Stage 35 was employed as the initial bench mark in the present study and five geometric control parameters were working as the optimization parameters aiming to enhance the aerodynamic performance in terms of total pressure rise and efficiency. Results showed that the feasibility and capability of the proposed optimization strategy was successfully examined. In view of the fact that the initial tandem cascade(directly scaling down from NASA Stage 35) cannot guarantee the aerodynamic performance, first optimization trial was conducted to optimize the initial design. Results showed that the optimum can improve the flow quality whereas the separation on the blade is decayed or even eliminated particularly at the tip and root regions. However, compared with the initial tandem design, the enhancement in total pressure ratio(0.47%) and efficiency(1%) are too small to be noticed. Second investigation was particularly emphasizing on a high turning tandem compressor with an increment by 28°. The pressure rise and efficiency were augmented by 1.44% and 2.34%(compared to the initial tandem design), respectively. An important conclusion can be drawn that the optimization strategy is worthy to be used in high turning compressors with a considerable performance improvement.展开更多
For a series plug-in hybrid electric vehicle,higher working efficiency can be achieved by the drive system with two small motors in parallel than that with one big motor alone.However,the overly complex structure will...For a series plug-in hybrid electric vehicle,higher working efficiency can be achieved by the drive system with two small motors in parallel than that with one big motor alone.However,the overly complex structure will inevitably lead to a substantial increase in the development cost.To improve the system price-performance ratio,a new kind of series-parallel hybrid system evolved from the series plug-in hybrid system is designed.According to the technical parameters of the selected components,the system model is established,and the vehicle dynamic property and pure electric drive economy are evaluated.Based on the dynamic programming,the energy management strategy for the drive system under the city driving cycle is developed,and the superiority validation of the system is completed.For the studied vehicle driven by the designed series-parallel plug-in hybrid system,compared with the one driven by the described series plug-in hybrid system,the dynamic property is significantly improved because of the multi-power coupling,and the fuel consumption is reduced by 11.4%with 10 city driving cycles.In a word,with the flexible configuration of the designed hybrid system and the optimized control strategy of the energy management,the vehicle performance can be obviously improved.展开更多
文摘The development of efficient and cost‐effective metal‐free electrocatalysts for oxygen reduction reaction(ORR)has become crucial for electrochemical energy systems.However,reasonably validating and precisely regulating the active sites for designing optimized materials are still challenging.Herein,we report a precise and controllable tandem strategy to boost the ORR activity based on metal‐free covalent organic frameworks(MFCOFs)comprising imine‐N,thiophene‐S,or triazine‐N.Among these MFCOFs,post‐tandem BTT‐TAT‐COF structure displayed a more positive catalytic capability and excellent electrochemical stability,indicating that the synergistic catalysis of multiple active sites induced the ORR catalytic activity through the conjugated skeleton of the structure.Density‐functional theory calculations suggest that the series‐connected backbone contained highly effective electrocatalytic active centers and provided synergistic catalysis.More importantly,this strategy highlights new opportunities for the advancement of efficient COF‐based metal‐free ORR catalysts.
文摘Carbon dioxide emissions have increased due to the consumption of fossil fuels,making the neutralization and utilization of CO_(2) a pressing issue.As a clean and efficient energy conversion process,electrocatalytic reduction can reduce carbon dioxide into a series of alcohols and acidic organic molecules,which can effectively realize the utilization and transformation of carbon dioxide.This review focuses on the tuning strategies and structure effects of catalysts for the electrocatalytic CO_(2) reduction reaction(CO_(2)RR).The tuning strategies for the active sites of catalysts have been reviewed from intrinsic and external perspectives.The structure effects for the CO_(2)RR catalysts have also been discussed,such as tandem catalysis,synergistic effects and confinement catalysis.We expect that this review about tuning strategies and structure effects can provide guidance for designing highly efficient CO_(2)RR electrocatalysts.
基金financially supported by the National Natural Science Foundation of China(No.51376150)
文摘This study proposed a design and optimization strategy for a tandem arranged cascade using the Non-dominated Sorting Genetic Algorithm(NSGA) Ⅱ multi-objective optimization algorithm and Back Propagation(BP) neural network technology. The NASA Stage 35 was employed as the initial bench mark in the present study and five geometric control parameters were working as the optimization parameters aiming to enhance the aerodynamic performance in terms of total pressure rise and efficiency. Results showed that the feasibility and capability of the proposed optimization strategy was successfully examined. In view of the fact that the initial tandem cascade(directly scaling down from NASA Stage 35) cannot guarantee the aerodynamic performance, first optimization trial was conducted to optimize the initial design. Results showed that the optimum can improve the flow quality whereas the separation on the blade is decayed or even eliminated particularly at the tip and root regions. However, compared with the initial tandem design, the enhancement in total pressure ratio(0.47%) and efficiency(1%) are too small to be noticed. Second investigation was particularly emphasizing on a high turning tandem compressor with an increment by 28°. The pressure rise and efficiency were augmented by 1.44% and 2.34%(compared to the initial tandem design), respectively. An important conclusion can be drawn that the optimization strategy is worthy to be used in high turning compressors with a considerable performance improvement.
基金supported by the National Natural Science Foundation of China(Grant No.51405259)China Postdoctoral Science Foundation funded project(Grant Nos.2014T70072&2013M530608)Colleges and Universities in Hebei Province Science and Technology Research Project(Grant No.QN2015056)
文摘For a series plug-in hybrid electric vehicle,higher working efficiency can be achieved by the drive system with two small motors in parallel than that with one big motor alone.However,the overly complex structure will inevitably lead to a substantial increase in the development cost.To improve the system price-performance ratio,a new kind of series-parallel hybrid system evolved from the series plug-in hybrid system is designed.According to the technical parameters of the selected components,the system model is established,and the vehicle dynamic property and pure electric drive economy are evaluated.Based on the dynamic programming,the energy management strategy for the drive system under the city driving cycle is developed,and the superiority validation of the system is completed.For the studied vehicle driven by the designed series-parallel plug-in hybrid system,compared with the one driven by the described series plug-in hybrid system,the dynamic property is significantly improved because of the multi-power coupling,and the fuel consumption is reduced by 11.4%with 10 city driving cycles.In a word,with the flexible configuration of the designed hybrid system and the optimized control strategy of the energy management,the vehicle performance can be obviously improved.
