预筛分细料-膨润土渗透性能研究

以建筑垃圾预筛分细料、膨润土为研究对象,研究膨润土掺量、种类对其渗透系数的影响,从而为建筑垃圾预筛分细料作为土-膨润土材料可行性提供理论依据。结果表明,相同膨润土掺量下,随固结压力增大,预筛分细料-膨润土渗透系数随之减小,因此当膨润土膨胀性能较差或者母土颗粒粒径较大可通过增加膨润土掺量大大降低预筛分细料-膨润土渗透系数,从而满足竖向隔离墙设计标准要求;膨润土掺量相同时,由于蒙脱石含量不同,相同固结压力下怀俄明膨润土的渗透系数明显比高庙子膨润土小,渗透性能优于高庙子的;试验为建筑垃圾预筛分细料以及质量较差膨润土的综合利用提供了可行性和新思路。

对炭化料破碎及筛分系统的改造

对破碎机加料、提升机与振动筛、去石机、除尘4个方面进行了改进。

中浓压力筛筛鼓缝宽对烟草基片浆料分布及其物理性能的影响

为了分析不同筛鼓缝宽对烟草基片浆料分布和其物理性能的影响,采用中浓压力筛对烟草基片浆料进行处理,观察烟草基片筛前浆料、筛后良浆和尾浆的纤维组分分布,并分别检测其基片松厚度、抗张指数等物理性能。结果表明,与筛前浆料相比,筛后良浆16目以下组分占比明显降低,200目以上组分占比明显增加,纤维分布更加集中、均匀;筛后浆料基片的柔软性能有较大改善,松厚度有所提高,但抗张指数、撕裂指数分别下降。与旧筛(0.55 mm缝宽)相比,增大压力筛筛缝宽度后,筛后良浆纤维组分并未出现明显变化,但筛后浆料基片松厚度相比筛前基片提高了4.55%,大于采用旧筛时基片松厚度的提高幅度1.33%。尾浆纤维组分主要集中在16目以下范围,占比可达50%。尾浆基片松厚度优于筛前和筛后基片,但伸长率和柔软性能较差,抗张指数及撕裂指数与筛后基片相近,但低于筛前基片。

沥青混合料生产配合比的确定

在沥青混合料目标配合比给定之后,针对间歇式热拌沥青混合料生产设备的工作特点,在振动筛倾斜角和振动筛振动频率等已知条件下,根据现有矿料初次筛分,再经过热料仓取料二次筛分、矿粉含量优化等过程后,准确确定生产配合比。通过进行此配比的沥青混合料的抽提和马歇尔试验,表明各项指标达到设计要求,从根本上保证了沥青混合料的质量及路用性能。

大宗原料自动划包投料设备在饲料厂的应用

饲料厂生产配合饲料时,传统的投料方式劳动强度大、扬尘严重、工人易患尘肺病。随着科技的进步,自动化投料设备逐渐被应用到饲料生产中。其具有自动化程度高、作业效率高、可靠性好、物料浪费少等特点,适用于大宗袋装物料的快速投料入仓。文章主要介绍了自动划包投料设备的工作原理和实施方案,旨在为饲料厂投料口技改和新建饲料厂投料口的工艺设计提供参考。

小浪底土石坝反滤设计

阐述了小浪底土石坝反滤设计的原则、方法和成果。设计中，根据大坝防渗体的结构特点设置了多种反滤。按各个部位反滤的工作条件和重要性，将反滤分为关键性反滤和非关键性反滤。对这两类不同性质的反滤采用了不同的设计原则和方法。对于关键性反滤着重强调在防渗体发生集中渗漏时应不致于产生渗透破坏而危及大坝安全，而对于非关键性反滤则根据不同情况进行适当简化。根据料场砂卵石级配特点和反滤设计要求，综合利用筛分料和轧制料改善了反滤料的级配，提高了反滤料的质量，同时也减少了料场砂卵石开采量。

浆砌石用砂粒径模数分析

通过施工实际,以及国际国内砂细度模数计算方法和规程控制范围,证明,在计算砂细度模数时,将5～10 mm粒径模数计算在内,可使砂模数提高。

Study on Oxidative Desulfurization Performance of Mesoporous Alumina Material

This article refers to the study on the performance of mesoporous silica used as the catalyst for oxidative desulfurization reactions. The test results revealed that under mild reaction conditions using tert-butyl hydroperoxide as the oxidizing agent the content of dibenzothiophene(DBT) contained in oil samples could be reduced from 5000 ppm to less than 5 ppm. Furthermore,the mesoporous silica material can be easily regenerated and recycled.

SEAM沥青路面施工技术

文章以郑-石高速及京珠高速的路面施工的检验为例,对SEAM沥青路面的特点进行了分析,并对SEAM沥青路面施工方法及质量控制进行了阐述。

Application Progress of Porous Materials in Modern Pharmaceutical

Porous materials have regular three-dimensional pore structure, which has unique advantages in the field of modern pharmaceutical. At present, porous materials commonly used in the pharmaceutical field are mainly molecular sieves, macroporous adsorbent resins, activated carbon, etc. In this paper, the application status of these porous materials in the pharmaceutical field is reviewed, and the future development is prospected.

Study on Hydrothermal Stability and Catalytic Activity of Al-SBA-15 Mesoporous Materials Prepared by Impregnation Method

The mesoporous Al-SBA-15 zeolite was obtained via impregnation of pure silica-based SBA-15 zeolite with aluminum nitrate.The Al-SBA-15 sample was calcined in air at 800 ℃ for 6 h and hydrothermally treated at near 100 ℃ for 120 h,respectively,and then the thermal and hydrothermal stability of Al-SBA-15 sample was investigated by X-ray diffractometry (XRD),scanning electron microscopy (SEM),transmission electron microscopy (TEM) and nitrogen adsorption and desorption techniques.The Al-SBA-15 sample was also studied by 27 Al nuclear magnetic resonance (27 Al NMR) and ammonia temperature programmed desorption (NH 3-TPD) techniques.In addition,the catalytic activity of Al-SBA-15 zeolite was investigated by the Friedel-Crafts reactions of 2,4-di-tert-butylphenol with cinnamyl alcohol.The test results showed that the thermal and hydrothermal stability of Al-SBA-15 zeolite was better than that of SBA-15 zeo-lite.The Al-SBA-15 zeolite sample prepared by impregnation method exhibits more framework aluminum species and Al-O-Si units.Therefore,the number of the surface hydroxyl groups was reduced,resulting in the stabilization of framework structure ofAl-SBA-15 zeolite.The aluminum species can form weak and medium-strong acid sites with catalytic activity.

Hydrothermal Synthesis and Properties of Y-zeolite-containing Composite Material with Micro/mesoporous Structure

A Y-zeolite-containing composite material with micro/mesoporous structure had been synthesized from kaolin by means of the in-situ crystallization method. The obtained samples were investigated by XRD and BET methods. Evaluation of catalytic activity of both the commercial Y-zeolite and the novel Y-zeolite-containing composite material was carried out in the pulse micro-chromatography platform with two probe molecules of different molecular sizes： VGO feedstock and 1,3,5 tri-isopropyl benzene. It was found that the Y-zeolite-containing composite material was richer in external surface and meso-/macro-pores; the Y-zeolite-containing composite material demonstrated a smaller rate of deactivation compared to the commercial Y-zeolite.

Strategies to Overcome Filter Divergence in the DRP-4-DVar Approach

This paper discusses an important issue related to filter divergence in the dimension-reduced projection,four-dimensional variational data assimilation(DRP-4-DVar) approach.Idealized experiments with the Lorenz-96 model over a period of 200 days showed that the amplitudes of the root mean square errors(RMSEs) reached the same levels as those of the state variables after approximately 100 days because of the accumulation of sampling errors following the cycle of assimilation.Strategies to reduce sampling errors are critical to ensure the quality of ensemble-based assimilation.Numerical experiments showed that localization and reducing observational errors can alleviate,but cannot completely overcome,the filter divergence in the DRP-4-DVar approach,while the method of perturbing observations and the inflation technique can efficiently eliminate the filter divergence problem.

Understanding the roles of Brønsted/Lewis acid sites on manganese oxide-zeolite hybrid catalysts for low-temperature NH_(3)-SCR

Although metal oxide-zeolite hybrid materials have long been known to achieve enhanced catalytic activity and selectivity in NO_(x)removal reactions through the inter-particle diffusion of intermediate species,their subsequent reaction mechanism on acid sites is still unclear and requires investigation.In this study,the distribution of Brønsted/Lewis acid sites in the hybrid materials was precisely adjusted by introducing potassium ions,which not only selectively bind to Brønsted acid sites but also potentially affect the formation and diffusion of activated NO species.Systematic in situ diffuse reflectance infrared Fourier transform spectroscopy analyses coupled with selective catalytic reduction of NO_(x)with NH_(3)(NH_(3)-SCR)reaction demonstrate that the Lewis acid sites over MnO_(x)are more active for NO reduction but have lower selectivity to N_(2)than Brønsted acids sites.Brønsted acid sites primarily produce N_(2),whereas Lewis acid sites primarily produce N_(2)O,contributing to unfavorable N_(2)selectivity.The Brønsted acid sites present in Y zeolite,which are stronger than those on MnO_(x),accelerate the NH_(3)-SCR reaction in which the nitrite/nitrate species diffused from the MnO_(x)particles rapidly convert into the N_(2).Therefore,it is important to design the catalyst so that the activated NO species formed in MnO_(x)diffuse to and are selectively decomposed on the Brønsted acid sites of H-Y zeolite rather than that of MnO_(x)particle.For the physically mixed H-MnO_(x)+H-Y sample,the abundant Brønsted/Lewis acid sites in H-MnO_(x)give rise to significant consumption of activated NO species before their inter-particle diffusion,thereby hindering the enhancement of the synergistic effects.Furthermore,we found that the intercalated K+in K-MnO_(x)has an unexpected favorable role in the NO reduction rate,probably owing to faster diffusion of the activated NO species on K-MnO_(x)than H-MnO_(x).This study will help to design promising metal oxide-zeolite hybrid catalysts by identifying the role of the acid sites in two different constituents.

Independent thickness and lateral size sorting of two-dimensional materials

Two-dimensional(2D)materials possess unique thickness-and lateral-size-dependent properties.Many efforts have been devoted to obtaining 2D materials with narrow structure heterogeneity while it is still challenging to independently control their thickness and lateral size,limiting their widespread applications.Here,we develop a three-step method which achieves independent thickness and lateral size sorting of 2D materials.Taking 2D h-BN flakes as an example,their thickness and lateral size are independently sorted to different fractions with thicknesses smaller than 6 nm.In addition,the 2D h-BN flakes possess narrow distributions of both thickness and lateral size.We further develop a force field extraction method and achieve scalable size sorting of 2D h-BN,which is universal for sorting other 2D materials including MoS2 and graphene oxide.This work reports an effective method to produce structure homogenous 2D materials and will help fundamental studies and applications of 2D materials where thickness and lateral size are of concern.

A general strategy for high-throughput experimental screening of promising bulk thermoelectric materials

High-throughput(HTP)experiments play key roles in accelerating the discovery of advanced materials,but the HTP preparation and characterization,especially for bulk samples,are extremely difficult.In this work,we developed a novel and general strategy for HTP screening of high-performance bulk thermoelectric materials.The performed fullchain HTP experiments cover rapid synthesis of the bulk sample with quasi-continuous composition,microarea phase identification and structure analysis,and measurement of the spatial distribution of the sample composition,electrical and thermal transport properties.According to our experiments,bulk Bi_(2-x)Sb_(x)Te_(3)(x=1-2)and Bi_(2)Te_(3-x)Se_(x)(x=0-1.5)samples with quasi-continuous compositions have been rapidly fabricated by this HTP method.The target thermoelectric materials with the best Sb/Bi and Te/Se ratios are successfully screened out based on subsequent HTP characterization results,demonstrating that this HTP technique is effective in speeding up the exploration of novel high-performance thermoelectric materials.