Conventional synthesis of monolith-supported zeolite catalysts is based on a hydrothermal strategy.Here,we report a solvent-free crystallization process to coat ZSM-5 zeolite crystals on a monolithic SiC foam with a h...Conventional synthesis of monolith-supported zeolite catalysts is based on a hydrothermal strategy.Here,we report a solvent-free crystallization process to coat ZSM-5 zeolite crystals on a monolithic SiC foam with a honeycomb structure(ZSM-5/SiC).Characterizations of the ZSM-5/SiC by scanning electron microscopy,N2 sorption,and X-ray diffraction indicate that the zeolite sheath has been ideally coated on the surface of the SiC foam with high purity and crystallinity.Fixing Pd nanoparticles within the ZSM-5 zeolite crystals delivers a bifunctional Pd@ZSM-5/SiC catalyst,which exhibits high activity and selectivity toward diesel range paraffins in the hydrodeoxygenation of methyl oleate,a model molecule for biofuel.In comparison to the powder Pd@ZSM-5,the Pd@ZSM-5/SiC monolith catalyst shows more efficiency,which is attributed to the fast mass transfer and high heat conductivity on the honeycomb SiC structure.The durability test indicates that the Pd@ZSM-5/SiC catalyst is stable under the reaction and high-temperature regeneration conditions.展开更多
A high-precision identification method for steam turbine rotor crack is presented. By providing me nrst three measured natural frequencies, contours for the specified natural frequency are plotted in the same coordi- ...A high-precision identification method for steam turbine rotor crack is presented. By providing me nrst three measured natural frequencies, contours for the specified natural frequency are plotted in the same coordi- nate, and the intersection of the three curves predicts the crack location and size. The cracked rotor system is mod- eled using B-spline wavelet on the interval （BSWI） finite element method, and a method based on empirical mode decomposition （EMD） and Laplace wavelet is implemented to improve the identification precision of the first three measured natural frequencies. Compared with the classical nondestructive testing, the presented method shows its effectiveness and reliability. It is feasible to apply this method to the online health monitoring for rotor structure.展开更多
文摘Conventional synthesis of monolith-supported zeolite catalysts is based on a hydrothermal strategy.Here,we report a solvent-free crystallization process to coat ZSM-5 zeolite crystals on a monolithic SiC foam with a honeycomb structure(ZSM-5/SiC).Characterizations of the ZSM-5/SiC by scanning electron microscopy,N2 sorption,and X-ray diffraction indicate that the zeolite sheath has been ideally coated on the surface of the SiC foam with high purity and crystallinity.Fixing Pd nanoparticles within the ZSM-5 zeolite crystals delivers a bifunctional Pd@ZSM-5/SiC catalyst,which exhibits high activity and selectivity toward diesel range paraffins in the hydrodeoxygenation of methyl oleate,a model molecule for biofuel.In comparison to the powder Pd@ZSM-5,the Pd@ZSM-5/SiC monolith catalyst shows more efficiency,which is attributed to the fast mass transfer and high heat conductivity on the honeycomb SiC structure.The durability test indicates that the Pd@ZSM-5/SiC catalyst is stable under the reaction and high-temperature regeneration conditions.
基金National Natural Science Foundation of China(No.51225501No.51035007)Program for Changjiang Scholars and Innovative Research Team in University
文摘A high-precision identification method for steam turbine rotor crack is presented. By providing me nrst three measured natural frequencies, contours for the specified natural frequency are plotted in the same coordi- nate, and the intersection of the three curves predicts the crack location and size. The cracked rotor system is mod- eled using B-spline wavelet on the interval （BSWI） finite element method, and a method based on empirical mode decomposition （EMD） and Laplace wavelet is implemented to improve the identification precision of the first three measured natural frequencies. Compared with the classical nondestructive testing, the presented method shows its effectiveness and reliability. It is feasible to apply this method to the online health monitoring for rotor structure.
