In this paper, progresses of color maintenance, also known as color shift, in solid-state lighting(SSL) systems are thoroughly reviewed. First, color shift is introduced and a few examples are given from different rea...In this paper, progresses of color maintenance, also known as color shift, in solid-state lighting(SSL) systems are thoroughly reviewed. First, color shift is introduced and a few examples are given from different real-life industrial conditions. Different degradation mechanisms in different parts of the system are also explained. Different materials used as lenses/encapsulants in light-emitting diode(LED)-based products are introduced and their contributions to color shift are discussed. Efforts put into standardization, characterizing, and predicting lumen maintenance are also briefly reviewed in this paper.展开更多
The factors and mechanisms of oxidative degradation of three organophosphorus pesticides (dichlorvos, methamidophos and phoxim) were studied with sodium percarbonate (SPC) as a solid oxidant. The result showed tha...The factors and mechanisms of oxidative degradation of three organophosphorus pesticides (dichlorvos, methamidophos and phoxim) were studied with sodium percarbonate (SPC) as a solid oxidant. The result showed that SPC has highly activity in degrading these organophosphous pesticides. The most efficient degradation of pesticides occurred under basic conditions and the degradation rates increased with time extension and high temperature. The degradation of organophosphorus pesticides was expected to get even better results at lower initial concentration. Furthermore, we analyzed the intermediate products by NMP, spectrometry. On the basis of the analytical result, the oxidative degradation mechanism was proposed for each organophosphous pesticide. It is significant to understand the environment chemistry of organophosphorus pesticides in environmental system.展开更多
Zn 2+-TiO2 nanotube arrays were prepared by anodic oxidation method.The current-time curves were used to investigate their growth mechanism.Scanning electron microscopy and X-ray diffractometry were applied to charact...Zn 2+-TiO2 nanotube arrays were prepared by anodic oxidation method.The current-time curves were used to investigate their growth mechanism.Scanning electron microscopy and X-ray diffractometry were applied to characterizing their structures and properties.The photoelectrochemical properties were studied by electrochemical impedance spectrum(EIS).The optimised working conditions for TiO2 nanotube arrays were found to be pH 1,0.5%HF(mass fraction),20 V oxidation voltage and for 2 h.The produced sample was in anatase form,with length of 70-100 nm,thickness of 10 nm,uniform diameter and structure that does not collapse under the preparation conditions.The EIS results show that TiO2 nanotube arrays prepared with 0.5%HF(mass fraction) present a low impedance and TiO2 nanotube arrays loaded by Zn 2+could have a decreased resistance.This decrease could likely accelerate the transfer of carriers and even increase photoelectric conversion.展开更多
Under the highly competitive market economy management system, economic management of Chinese enterprises tends to be diversity. With the continuous development of market economy, enterprises need choose the appropria...Under the highly competitive market economy management system, economic management of Chinese enterprises tends to be diversity. With the continuous development of market economy, enterprises need choose the appropriate management methods according to the actual situation, which is to help enterprises to survive in the highly competitive environment. However, due to a variety of external factors, economic management situation is not optimistic. And it increases their sense of crisis. This article will make a systematic analysis of management strategies as the point of the enterprise management mode and innovation strategy under market economy.展开更多
Quantum-sized CdS-coated TiO2 nanotube array (Q-CdS-TiO2 NTA) was fabricated by the modified successive ionic layer absorption and reaction method. Scanning electron microscope and transmission electron microscope i...Quantum-sized CdS-coated TiO2 nanotube array (Q-CdS-TiO2 NTA) was fabricated by the modified successive ionic layer absorption and reaction method. Scanning electron microscope and transmission electron microscope images showed the regular structure of TiO2 NTA, where quantum-sized CdS (diameter 〈10nm) deposited on both the inside and outside of TiO2 nanotube wall. Fabrication conditions including immersing cycles, calcination temperature and drying process were well optimized, and the Q-CdS-TiO2 NTA and its photoelectrochemical (PEC) properties were characterized by X-ray fluorescence spectrometer, UV-Vis diffuse reflectance spectra and photovoltage. Distinct increases in visible light absorption and photocurrent were observed as the immersing cycle was increased from 5 to 20 times. The additional drying process accelerated the CdS crystal growth rate, and thus, the fabrication time could be shortened accordingly. Calcination temperature influenced the PEC property of Q-CdS-TiO2 NTA deeply, and the optimized calcination temperature was found as 500 ℃. As the Q-CdS-TiO2 NTA was fabricated under such condition, the visible photocurrent density increased to 2.8 mA/cm and the photovoltage between 350 and 480 nm was enhanced by 2.33 times than that without calcination. This study is expected to optimize Q-CdS-TiO2 NTA fabrication conditions for the purpose of improving its PEC performance.展开更多
基金project (M71.9.10380) in the framework of the Research Program of the Materials Innovation Institute M2i (www.m2i.nl)
文摘In this paper, progresses of color maintenance, also known as color shift, in solid-state lighting(SSL) systems are thoroughly reviewed. First, color shift is introduced and a few examples are given from different real-life industrial conditions. Different degradation mechanisms in different parts of the system are also explained. Different materials used as lenses/encapsulants in light-emitting diode(LED)-based products are introduced and their contributions to color shift are discussed. Efforts put into standardization, characterizing, and predicting lumen maintenance are also briefly reviewed in this paper.
文摘The factors and mechanisms of oxidative degradation of three organophosphorus pesticides (dichlorvos, methamidophos and phoxim) were studied with sodium percarbonate (SPC) as a solid oxidant. The result showed that SPC has highly activity in degrading these organophosphous pesticides. The most efficient degradation of pesticides occurred under basic conditions and the degradation rates increased with time extension and high temperature. The degradation of organophosphorus pesticides was expected to get even better results at lower initial concentration. Furthermore, we analyzed the intermediate products by NMP, spectrometry. On the basis of the analytical result, the oxidative degradation mechanism was proposed for each organophosphous pesticide. It is significant to understand the environment chemistry of organophosphorus pesticides in environmental system.
基金Project(20976016)supported by the National Natural Science Foundation of ChinaProject(09JJ606)supported by the Natural Science Foundation of Hunan Province,ChinaProject(08FJ1002)supported by Key Science Research Project of the Hunan Provincial Natural Science,China
文摘Zn 2+-TiO2 nanotube arrays were prepared by anodic oxidation method.The current-time curves were used to investigate their growth mechanism.Scanning electron microscopy and X-ray diffractometry were applied to characterizing their structures and properties.The photoelectrochemical properties were studied by electrochemical impedance spectrum(EIS).The optimised working conditions for TiO2 nanotube arrays were found to be pH 1,0.5%HF(mass fraction),20 V oxidation voltage and for 2 h.The produced sample was in anatase form,with length of 70-100 nm,thickness of 10 nm,uniform diameter and structure that does not collapse under the preparation conditions.The EIS results show that TiO2 nanotube arrays prepared with 0.5%HF(mass fraction) present a low impedance and TiO2 nanotube arrays loaded by Zn 2+could have a decreased resistance.This decrease could likely accelerate the transfer of carriers and even increase photoelectric conversion.
文摘Under the highly competitive market economy management system, economic management of Chinese enterprises tends to be diversity. With the continuous development of market economy, enterprises need choose the appropriate management methods according to the actual situation, which is to help enterprises to survive in the highly competitive environment. However, due to a variety of external factors, economic management situation is not optimistic. And it increases their sense of crisis. This article will make a systematic analysis of management strategies as the point of the enterprise management mode and innovation strategy under market economy.
基金supported by the National Natural Science Foundation of China(21377020)the Fundamental Research Funds for the Central Universities(DUT15QY17)
文摘Quantum-sized CdS-coated TiO2 nanotube array (Q-CdS-TiO2 NTA) was fabricated by the modified successive ionic layer absorption and reaction method. Scanning electron microscope and transmission electron microscope images showed the regular structure of TiO2 NTA, where quantum-sized CdS (diameter 〈10nm) deposited on both the inside and outside of TiO2 nanotube wall. Fabrication conditions including immersing cycles, calcination temperature and drying process were well optimized, and the Q-CdS-TiO2 NTA and its photoelectrochemical (PEC) properties were characterized by X-ray fluorescence spectrometer, UV-Vis diffuse reflectance spectra and photovoltage. Distinct increases in visible light absorption and photocurrent were observed as the immersing cycle was increased from 5 to 20 times. The additional drying process accelerated the CdS crystal growth rate, and thus, the fabrication time could be shortened accordingly. Calcination temperature influenced the PEC property of Q-CdS-TiO2 NTA deeply, and the optimized calcination temperature was found as 500 ℃. As the Q-CdS-TiO2 NTA was fabricated under such condition, the visible photocurrent density increased to 2.8 mA/cm and the photovoltage between 350 and 480 nm was enhanced by 2.33 times than that without calcination. This study is expected to optimize Q-CdS-TiO2 NTA fabrication conditions for the purpose of improving its PEC performance.