船舶轮机管子材料选择与性能优化

本文综合分析了船舶轮机管子材料的力学性能、耐腐蚀性能、耐高温性能以及焊接性和加工性等关键性能指标;研究了新型合金钢和高性能不锈材料的开发,以及复合材料在船舶轮机管路系统中的潜在应用;进一步地提出了材料选择的优化策略、结构设计优化、工艺流程优化以及性能模拟与仿真分析方法。通过这些研究,可以显著提高船舶轮机管路系统的可靠性和耐久性,降低维护成本,同时满足日益严格的环保和安全标准。

Nitrogen⁃doped 3D graphene⁃carbon nanotube network for efficient lithium storage

A 3D nitrogen⁃doped graphene/multi⁃walled carbon nanotube(CS⁃GO⁃NCNT)crosslinked network mate⁃rial was successfully synthesized utilizing chitosan and melamine as carbon and nitrogen sources,concomitant with the incorporation of multi⁃wall carbon nanotubes and employing freeze drying technology.The material amalgamates the merits of 1D/2D hybrid carbon materials,wherein 1D carbon nanotubes confer robustness and expedited elec⁃tron transport pathways,while 2D graphene sheets facilitate rapid ion migration.Furthermore,the introduction of nitrogen heteroatoms serves to furnish additional active sites for lithium storage.When served as an anode material for lithium⁃ion batteries,the CS⁃GO⁃NCNT electrode delivered a reversible capacity surpassing 500 mAh·g^(-1),mark⁃edly outperforming commercial graphite anodes.Even after 300 cycles at a high current density of 1 A·g^(-1),it remained a reversible capacity of up to 268 mAh·g^(-1).

Improving the Dispersion and Integration of Multi-Walled Carbon Nanotubes in PolyvinyI-Alcohol Composite Thin Film through Surface Modification

The article investigated the influence of modification process parameters on dispersity of MWNTs DI （in deionized） water and PVA/MWNT composite＇s electrical conductivity. Experimental results obtained by SEM （scanning electron microscope）, TEM （transmission electron microscope）, transform Fourier infrared spectroscopy, pH meter confirmed the most effective conditions in modifying the MWNT surface at the 1：3 mixture of nitric and sulfuric acid at 60 ℃. The extinction coefficient value of functionalized MWNTs at 500 nm wavelength was determined to be 41.24 cm^2·mg^-1, while their dispersibility in DI water was about 12.85 mg/mL and stable in more than 3 weeks via UV-vis spectroscopy. The other important result is the decrease of volume resistivity from 7.98 × 10^6 MΩ·m ofPVA （polyvinyl alcohol） to 4.15 × 10^4 MΩ·m of PVA/1 wt% modified MWNT thin film.

Diamond-structured hollow-tube lattice Ni materials via 3D printing

Light-weight and high-strength materials have attracted considerable attention owing to their outstanding properties, such as weight-reducing, acoustic absorption, thermal insulation, shock and vibration damping. Diamond possesses specific stiffness and strength arising from its special crystal structure. In this work, inspired by the diamond crystal structure, hollow-tube nickel materials with the diamond structure were fabricated using a diamond structured polymer template based on the Stereo Lithography Appearance technology. The diamond structured template was coated with Ni-P by electroless plating. Finally, the template was removed by high temperature calcinations. The density of the hollow tube nickel materials is about 20 mg/cm3. The morphology and composition of the resultant materials were characterized by scanning electron microscope, energy-dispersive spectrometry, and X-ray diffraction. The results showed that the surface of the Ni film was uniform with the thickness of 4 gm. The mechanical property was also measured by stress and strain tester. The maximum compression stress can be reached to 40.6 KPa.

A novel crosslinkable electron injection/transporting material for solution processed polymer light-emitting diodes

A novel crosslinkable water/alcohol soluble conjugated polymer PFN-C containing oxetane groups and aminoalkyl groups in the side chains has been developed and used as highly efficient electron injection and transporting material for polymer light-emitting diodes (PLEDs). The unique solubility in polar solvents and crosslinkable ability of PFN-C render it a good can- didate for solution processed multilayer PLEDs. It was found that PFN-C can greatly enhance the electron injection from high work-function metal cathode, due to its pendant amino groups. As a result, PLEDs with PFN-C/Al cathode exhibited compara- ble device performance to the devices with Ba/Al cathode. The resulting green light-emitting device showed promising perfor- mance with a maximum luminance efficiency of 13.53 cd A-1.

Wafer-scale arrayed p-n junctions based on few-layer epitaxial GaTe

Two-dimensional （2D） materials have attracted substantial attention in electronic and optoelectronic applications with the superior advantages of being flexible, transparent, and highly tunable. Gapless graphene exhibits ultra-broadband and fast photoresponse while the 2D semiconducting MoS2 and GaTe exhibit high sensitivity and tunable responsivity to visible light. However, the device yield and repeatability call for further improvement to achieve large-scale uniformity. Here, we report a layer-by-layer growth of wafer-scale GaTe with a high hole mobility of 28.4 cm^2/（V.s） by molecular beam epitaxy. The arrayed p-n ）unctions were developed by growing few-layer GaTe directly on fhree-inch Si wafers. The resultant diodes reveal good rectifying characteristics and a high photovoltaic external quantum efficiency up to 62% at 4.8 μW under zero bias. The photocurrent reaches saturation fast enough to capture a time constant of 22 μs and shows no sign of device degradation after 1.37 million cycles of operation. Most strikingly, such high performance has been achieved across the entire wafer, making the volume production of devices accessible. Finally, several photoimages were acquired by the GaTe/Si photodiodes with reasonable contrast and spatial resolution, demonstrating the potential of integrating the 2D materials with silicon technology for novel optoelectronic devices.

Ultralight conducting PEDOT:PSS/carbon nanotube aerogels doped with silver for thermoelectric materials

A significant enhancement in the thermoelectric performance was observed for three-dimensional conducting aerogels,which were obtained from poly（3,4-ethylenedioxythiophene）：poly（4-styrenesulfonic）（PEDOTrPSS） and multiwalled carbon nanotubes（MWCNTs） suspensions by adding different concentrations of metallic silver（Ag）.It was found that the electrical conductivity and Seebeck coefficient could be simultaneously increased with the unique structure.Moreover,the conducting aerogels have an ultralow thermal conductivity（0.06 W m^（-1） K^（-1） and a large Brunauer-Emmett-Teller surface area（228 m^2 g^（-1）.The highest figure of merit（zT） value in this study was 7.56×10^（-3） at room temperature upon the addition of 33.32 wt.%Ag.Although the zT value was too low,our work may provide new insights into the design and development of the thermoelectric material for applications.Further investigation with PEDOTrPSS aerogels will be continued to get an economical,lightweight,and efficient polymer thermoelectric material.

Appending triphenyltriazine to 1,10-phenanthroline: a robust electron-transport material for stable organic light-emitting diodes

There has been an increasing demand for high-performance and cost-effective organic electron-transport materials for organic light-emitting diodes （OLEDs）. In this contribution, we present a simple compound 3-（3-（4,6-diphenyl-l,3,5-triazin-2-yl）phenyl）-1,10-phenanthroline through the facile Pd-catalyzed coupling of a triphenyltriazine boronic ester with 3-hromo-1,10-phenanthroline. It shows a high Tg of 112℃. The ultraviolet photoelectron spectroscopy measurements reveal a deep HOMO level of -6.5 eV. The LUMO level is derived as -3.0 eV, based on the optical bandgap. The low-temperature solid-state phosphorescent spectrum gives a triplet energy of -2.36eV. n-Doping with 8-hydroxyquinolatolithium （Liq, 1：1） leads to considerably improved electron mobility of 5.2 × 10 -6 -5.8 × 10 -5 cm2 v-1 S-1 at E=（2-5） × 10 5Vcm -1, in contrast with the triarylphosphine oxide- phenantroline molecular conjugate we reported previously. It has been shown that through optimizing the device structure and hence suppressing polaron-exciton annihilation, introducing this single Liq-doped electron-transport layer could offer high-efficiency and stable phosphorescent OLEDs.

NiaSi2O5（OH）4 Multi-Walled Nanotubes with Tunable Magnetic Properties and Their Application as Anode Materials for Lithium Batteries

Highly crystalline and thermally stable pure multi-walled Ni3Si2O5（OH）4 nanotubes with a layered structure have been synthesized in water at a relatively low temperature of 200-210 ℃ using a facile and simple method. The nickel ions between the layers could be reduced in situ to form size-tunable Ni nanocrystals, which endowed these nanotubes with tunable magnetic properties. Additionally, when used as the anode material in a lithium ion battery, the layered structure of the Ni3Si2O5（OH）4 nanotubes provided favorable transport kinetics for lithium ions and the discharge capacity reached 226.7 mA.h.g-1 after 21 cycles at a rate of 20 mA.g-1, Furthermore, after the nanotubes were calcined （600 ℃, 4 h） or reduced （180℃ 10 h）, the corresponding discharge capacities increased to 277.2 mA.h.g-1 and 308.5 mA.h.g-1, respectively.

Chemical regulation of metal halide perovskite nanomaterials for efficient light-emitting diodes

Metal halide perovskite nanomaterials emerged as attractive emitting materials for light-emitting diodes(LEDs) devices due to their high photoluminescence quantum yield(PLQY), narrow bandwidth, high charge-carrier mobility, bandgap tunability, and facile synthesis. In the past few years, it has been witnessed an unprecedented advance in the field of metal halide perovskite nanomaterials based LEDs(Pe LEDs) with a rapid external quantum efficiency(EQE) increase from 0.1% to 14.36%. From the viewpoint of material chemistry, the chemical regulation of metal halide perovskite nanomaterials made a great contribution to the efficiency improvement of Pe LEDs. In this review, we categorize the strategies of chemical regulation as A-site cation engineering, B-site ion doping, X-site ion exchange, dimensional confinement, ligand exchange, surface passivation and interface optimization of transport layers for improving the EQEs of Pe LEDs. We also show the potentials of chemical regulation strategies to enhance the stability of Pe LEDs. Finally, we present insight toward future research directions and an outlook to further improve EQEs and stabilities of Pe LEDs aiming to practical applications.

An important step towards commercialization of quantum-dot light-emitting diode displays

Colloidal quantum dots(QDs)are a unique class of emissive materials with size-tunable emission wavelengths,saturated emission colors,near-unity luminance efficiency,inherent photo-and thermal-stability,and excellent solution processability.Display based on quantum-dot light-emitting diodes(QLED)may combine the superior properties of QDs,the benefits of solution-based fabrication techniques,and the advantages of self-emission devices,which promises an unprecedented generation of cost-effective,large-area,energysaving,wide-color-gamut,ultra-thin and flexible displays.