The lanthanum aluminum mesoporous materials were synthesized using sodium dodecyl sulfate as a template agent by ultrasonic hydrothermal method.The resulting samples were characterized by low angle X-ray diffraction（...The lanthanum aluminum mesoporous materials were synthesized using sodium dodecyl sulfate as a template agent by ultrasonic hydrothermal method.The resulting samples were characterized by low angle X-ray diffraction（XRD）,N2 adsorption-desorption studies,transmission electron microscopy（TEM）and surface morphology analysis（SEM）,surface acid（NH3-TPD）,reducibility properties（TPR）,X-ray energy dispersive spectrometer（EDS）and thermogravimetric analysis（TG/DTG）.A l/La composite mesoporous material were synthesized with n（Al）︰n（La）=70︰1.0,80°C of reaction temperature,20 h of reaction time,12 h of crystallization time,650°C of calcination temperature.The specific surface area of the sample is 273.90 m 2 ·g ？1 ,with the average diameter 5.642 nm and pore volume 0.2354 cm 3 ·g ？1 .The samples have mesoporous structure and its particles are similar to a worm-shaped tubular structure.The influence of calcination temperature on the surface physical and chemical properties of Al/La composited mesoporous materials was examined,and the results showed that the acid strength was increased but the amount of acidic sites is decreased as the calcination temperature increased.It was found that the sample calcined at 650°C had appropriate acid content,acid strength and better reducibility.展开更多
A numerical study of bitubular tubes with diaphragms compared with single and bitubular tubes subjected to dynamic axial impact force was presented. At first, the energy absorption response of the composite structure ...A numerical study of bitubular tubes with diaphragms compared with single and bitubular tubes subjected to dynamic axial impact force was presented. At first, the energy absorption response of the composite structure under axial loading was analyzed by finite element simulation. The results show that the efficiency of energy absorption can be improved by introducing diaphragms to the double-walled columns. Then, the effect of the amount and location of diaphragms, the shape and the size of the inner tubes, and the thickness of the composite structures were also studied numerically. The collision performance of the composite structure is affected by the deformation of diaphragms, as well as the interaction of outer and inner tube. The non-uniform distribution of diaphragms can improve the energy absorption efficiency of structures for a constant number of diaphragms. The specific energy absorption of the hexagonal inner tube is the highest, followed by the circular, octagonal and square ones.展开更多
The mechanical and strain sensing properties of carbon nanotube composite yarns （CNTs/PDMS） with different weight percent of PDMS were studied. The CNT/PDMS composite yarn was prepared by infiltration method. Pictur...The mechanical and strain sensing properties of carbon nanotube composite yarns （CNTs/PDMS） with different weight percent of PDMS were studied. The CNT/PDMS composite yarn was prepared by infiltration method. Pictures of diameter of CNT composite yarns were obtained though polarized light microscope. Resistance change values of CNT composites under stretching were obtained though the single fiber strength tester and digital multimeter and related mechanical, electrical software. The changes of mechanical properties. electrical properties and sensing pertbrmance of pure and composite CNT yarns were discussed and analyzed. The results showed that the strength of CNT yarn declined after it was composited with PDMS polymer. In addition, the conductivity and sensing performance of CNT yarns improved significantly. The most suitable CNT composite yam occurs at PDMS mass fraction of 1% when strength and sensing properties were all considered.展开更多
Entrance region may have important effect on gases flow characteristics in micro-channels. It's concluded in the available papers that the entrance effect causes significant difference. An experimental system of s...Entrance region may have important effect on gases flow characteristics in micro-channels. It's concluded in the available papers that the entrance effect causes significant difference. An experimental system of single-phase gas flow characteristics in microchannels was set up. Flow characteristics of nitrogen in PEEK polymer micro-tube (hydraulic diameter is 553btm) was studied experimentally. According to the data of nitrogen flow in the micro-tube with the length ranging from 0. 1m to1.524m, it is shown that the friction constant becomes higher when the tube becomes shorter. By using pipe cutting methods, it's confirmed that entrance effect is one of the key factors that cause friction constant higher than conventional theory. It's found that friction constant of fully developed flow is lower than the value predicted by conventional theory in turbulent region. The result indicates that the flow transition occurs at Reynolds number ranging from 1600-2000. The phenomenon of obvious early transition is not found.展开更多
文摘The lanthanum aluminum mesoporous materials were synthesized using sodium dodecyl sulfate as a template agent by ultrasonic hydrothermal method.The resulting samples were characterized by low angle X-ray diffraction（XRD）,N2 adsorption-desorption studies,transmission electron microscopy（TEM）and surface morphology analysis（SEM）,surface acid（NH3-TPD）,reducibility properties（TPR）,X-ray energy dispersive spectrometer（EDS）and thermogravimetric analysis（TG/DTG）.A l/La composite mesoporous material were synthesized with n（Al）︰n（La）=70︰1.0,80°C of reaction temperature,20 h of reaction time,12 h of crystallization time,650°C of calcination temperature.The specific surface area of the sample is 273.90 m 2 ·g ？1 ,with the average diameter 5.642 nm and pore volume 0.2354 cm 3 ·g ？1 .The samples have mesoporous structure and its particles are similar to a worm-shaped tubular structure.The influence of calcination temperature on the surface physical and chemical properties of Al/La composited mesoporous materials was examined,and the results showed that the acid strength was increased but the amount of acidic sites is decreased as the calcination temperature increased.It was found that the sample calcined at 650°C had appropriate acid content,acid strength and better reducibility.
基金Projects(U1334208,51405516,51275532) supported by the National Natural Science Foundation of ChinaProject(2015ZZTS045) supported by the Fundamental Research Funds for the Central Universities of China
文摘A numerical study of bitubular tubes with diaphragms compared with single and bitubular tubes subjected to dynamic axial impact force was presented. At first, the energy absorption response of the composite structure under axial loading was analyzed by finite element simulation. The results show that the efficiency of energy absorption can be improved by introducing diaphragms to the double-walled columns. Then, the effect of the amount and location of diaphragms, the shape and the size of the inner tubes, and the thickness of the composite structures were also studied numerically. The collision performance of the composite structure is affected by the deformation of diaphragms, as well as the interaction of outer and inner tube. The non-uniform distribution of diaphragms can improve the energy absorption efficiency of structures for a constant number of diaphragms. The specific energy absorption of the hexagonal inner tube is the highest, followed by the circular, octagonal and square ones.
文摘The mechanical and strain sensing properties of carbon nanotube composite yarns （CNTs/PDMS） with different weight percent of PDMS were studied. The CNT/PDMS composite yarn was prepared by infiltration method. Pictures of diameter of CNT composite yarns were obtained though polarized light microscope. Resistance change values of CNT composites under stretching were obtained though the single fiber strength tester and digital multimeter and related mechanical, electrical software. The changes of mechanical properties. electrical properties and sensing pertbrmance of pure and composite CNT yarns were discussed and analyzed. The results showed that the strength of CNT yarn declined after it was composited with PDMS polymer. In addition, the conductivity and sensing performance of CNT yarns improved significantly. The most suitable CNT composite yam occurs at PDMS mass fraction of 1% when strength and sensing properties were all considered.
基金supported by the National Natural Science Foundation of China (No. 50776006)"863" plan (No. 2006AA05Z228)Technological Innova tion Fund of Excellent Doctoral Candidate of Beijing Jiaotong University (No. 48013)
文摘Entrance region may have important effect on gases flow characteristics in micro-channels. It's concluded in the available papers that the entrance effect causes significant difference. An experimental system of single-phase gas flow characteristics in microchannels was set up. Flow characteristics of nitrogen in PEEK polymer micro-tube (hydraulic diameter is 553btm) was studied experimentally. According to the data of nitrogen flow in the micro-tube with the length ranging from 0. 1m to1.524m, it is shown that the friction constant becomes higher when the tube becomes shorter. By using pipe cutting methods, it's confirmed that entrance effect is one of the key factors that cause friction constant higher than conventional theory. It's found that friction constant of fully developed flow is lower than the value predicted by conventional theory in turbulent region. The result indicates that the flow transition occurs at Reynolds number ranging from 1600-2000. The phenomenon of obvious early transition is not found.
