The adherence strength between the metal and the inorganic coating can be greatly increased by mill addition of Li2Ni8O10. The interface structure between metal and the inorganic coating with excellent adherence has b...The adherence strength between the metal and the inorganic coating can be greatly increased by mill addition of Li2Ni8O10. The interface structure between metal and the inorganic coating with excellent adherence has been studied by investigating the chemical composition and the microstrncture as well as elements valence bond on the interface with the help of scanning electron microscope （SEM）, electron microprobe, and Auger elctron spectroscope （AES）. The results show that there is a non-stoichiometrieal transitional layer on the interface between metal and the inorganic coating with excellent adherence, the adherence between metal and the non-stoichiometrical transitional layer is achieved by the metallic bond and the adherence between the non- stoichiometrical transitional layer and the inorganic coating is produced by ionic and covalent bond. The non-stoichiometrical transitional layer results in the strong adherence.展开更多
In order to prepare high-performance Mo with fine and homogeneous microstructure to meet the demand of high-technology applications such as metallurgical,mechanical,national defense,aerospace and electronics applicati...In order to prepare high-performance Mo with fine and homogeneous microstructure to meet the demand of high-technology applications such as metallurgical,mechanical,national defense,aerospace and electronics applications,the microwave sintering process and densification mechanism of Mo nanopowder were studied.In this experiment,Mo nanopowder and micropowder were used for conventional sintering and microwave sintering at different sintering temperatures and sintering time,respectively.The results showed that with the increase in the sintering temperature,the increase rates of the relative density and hardness increased rapidly at first and then slowed down.The relative density rapidly reached 95%,followed by a small change.Mo nanopowder with a relative density of 98.03% and average grain size of 3.6 μm was prepared by microwave sintering at 1873 K for30 min.According to the analysis of the sintering kinetics,its densification is attributed to the combination of volumetric diffusion and grain boundary diffusion mechanisms.The calculated sintering activation energy of Mo nanopowder was 203.65 kJ/mol,which was considerably lower than that in the conventional sintering,suggesting that the microwave sintering was beneficial to the enhancement in the atom diffusion and densification for the powder.The results confirm that the microwave sintering is a promising method to economically prepare molybdenum with high properties.展开更多
In this study, the mechanical properties （tensile strength, elongation at break and folding resistance） of edible biopolymer film blends formed from blended cassava starch and rice flour at different compositions wi...In this study, the mechanical properties （tensile strength, elongation at break and folding resistance） of edible biopolymer film blends formed from blended cassava starch and rice flour at different compositions with sorbital used as a plasticizer. A suitable ratio of cassava starch and rice flour to water at 10% w/v was used to form a film solution. The addition of a plasticizer agent up to 30% w/w of blending compositions improved the mechanical properties of the generated films. The mechanical properties of the edible blended films with 30% plasticizer were strongly dependent on the blending compositions. Our results pointed out that the cassava starch and rice flour films at a ratio of 70：30 with sorbitol 30% （w/w） had the highest tensile strength which related to folding endurance of the films.展开更多
基金Shanghai Leading Academic Discipline Project,China (No.P1502)
文摘The adherence strength between the metal and the inorganic coating can be greatly increased by mill addition of Li2Ni8O10. The interface structure between metal and the inorganic coating with excellent adherence has been studied by investigating the chemical composition and the microstrncture as well as elements valence bond on the interface with the help of scanning electron microscope （SEM）, electron microprobe, and Auger elctron spectroscope （AES）. The results show that there is a non-stoichiometrieal transitional layer on the interface between metal and the inorganic coating with excellent adherence, the adherence between metal and the non-stoichiometrical transitional layer is achieved by the metallic bond and the adherence between the non- stoichiometrical transitional layer and the inorganic coating is produced by ionic and covalent bond. The non-stoichiometrical transitional layer results in the strong adherence.
基金Project(2017YFB0305601) supported by the National Key R&D Program of ChinaProjects(51874368,51274246) supported by the National Natural Science Foundation of China
文摘In order to prepare high-performance Mo with fine and homogeneous microstructure to meet the demand of high-technology applications such as metallurgical,mechanical,national defense,aerospace and electronics applications,the microwave sintering process and densification mechanism of Mo nanopowder were studied.In this experiment,Mo nanopowder and micropowder were used for conventional sintering and microwave sintering at different sintering temperatures and sintering time,respectively.The results showed that with the increase in the sintering temperature,the increase rates of the relative density and hardness increased rapidly at first and then slowed down.The relative density rapidly reached 95%,followed by a small change.Mo nanopowder with a relative density of 98.03% and average grain size of 3.6 μm was prepared by microwave sintering at 1873 K for30 min.According to the analysis of the sintering kinetics,its densification is attributed to the combination of volumetric diffusion and grain boundary diffusion mechanisms.The calculated sintering activation energy of Mo nanopowder was 203.65 kJ/mol,which was considerably lower than that in the conventional sintering,suggesting that the microwave sintering was beneficial to the enhancement in the atom diffusion and densification for the powder.The results confirm that the microwave sintering is a promising method to economically prepare molybdenum with high properties.
文摘In this study, the mechanical properties （tensile strength, elongation at break and folding resistance） of edible biopolymer film blends formed from blended cassava starch and rice flour at different compositions with sorbital used as a plasticizer. A suitable ratio of cassava starch and rice flour to water at 10% w/v was used to form a film solution. The addition of a plasticizer agent up to 30% w/w of blending compositions improved the mechanical properties of the generated films. The mechanical properties of the edible blended films with 30% plasticizer were strongly dependent on the blending compositions. Our results pointed out that the cassava starch and rice flour films at a ratio of 70：30 with sorbitol 30% （w/w） had the highest tensile strength which related to folding endurance of the films.
