The series Variantia Ching et S. H. Wu mainly occur in China and its members are highly variable in morphology. The denomination on this group of Asplenium is very confused in the herbaria. We hop e by means of a bios...The series Variantia Ching et S. H. Wu mainly occur in China and its members are highly variable in morphology. The denomination on this group of Asplenium is very confused in the herbaria. We hop e by means of a biosystematic study to find out their genetic relationships in the reticulate evolution, and to raise a suggestion on their taxonomic treatment. Evidence from cytology, allozyme, morphology, and palynology shows that three ancestor diploids have formed Asplenium sarelii complex comprising 13 members. A. sarelii Hook. should be typified as a diploid. The so-called tetraploid 'A. sarelii' before is an allotetraploid that comes from the doubled hybrid between diploid A. sarelii and A. tenuicaule Hayata, which should be treated as a new species A. wudangense Z. R. Wang et X. Hou. A. pekinense Hance is an autotetraploid that comes from the doubled diploid ancestor A. sarelii. A. lushanense C. Chr., a diploid species and the only ancestor of A. yunnariense group, should not been sunk as a synonym of tetraploid A. yunnariense Franch. Most probably, A. varians Wall. ex Hook. et Grev. is an autotetraploid of A. tenuicaule Hayata. Three new natural tetraploid hybrids and their origins have been found out: they are A. x longmenense ( = A. pekinense x varians), A. x jingyunense ( = A. pekinense x yunnanense) and A. x kidoi ( = A. pekinense x wudangense). Three other new natural triploid hybrids have been found and their origins have been inferred: they are A. X huawuense ( = A. sarelii X wudangense), A. x luyunense ( = A. lushanense x yunnanense) and A. x teniuvaians ( = A. tenuicaule x varians). The method of allozyme comparion combined with cytological observation is employed to reveal the complicated relationships among the members of Asplenium sarelii complex in reticulate evolution and proved to be a highly effective tool to investigate the origin of polyploid and hybrid.展开更多
Ni@Pd core-shell nanoparticles with a mean particle size of 8–9 nm were prepared by solvothermal reduction of bivalent nickel and palladium in oleylamine and trioctylphosphine.Subsequently,the first-ever deposition o...Ni@Pd core-shell nanoparticles with a mean particle size of 8–9 nm were prepared by solvothermal reduction of bivalent nickel and palladium in oleylamine and trioctylphosphine.Subsequently,the first-ever deposition of Ni@Pd core-shell nanoparticles having different compositions on a metal-organic framework(MIL-101)was accomplished by wet impregnation in n-hexane.The Ni@Pd/MIL-101 materials were characterized by powder X-ray diffraction,Fourier transform infrared spectroscopy,transmission electron microscopy,and energy-dispersive X-ray spectroscopy and also investigated as catalysts for the hydrogenation of nitrobenzene under mild reaction conditions.At 30 °C and 0.1 MPa of H2 pressure,the Ni@Pd/MIL-101 gives a TOF as high as 375 h–1 for the hydrogenation of nitrobenzene and is applicable to a wide range of substituted nitroarenes.The exceptional performance of this catalyst is believed to result from the significant Ni-Pd interaction in the core-shell structure,together with promotion of the conversions of aromatics by uncoordinated Lewis acidic Cr sites on the MIL-101 support.展开更多
Plants in genus Kadsura,belong to the Schisandraceae family including genus Schisandra and genus Kadsura,revealed folk efficacy and medicinal application in the treatment of rheumatoid arthritis and gastroenteric diso...Plants in genus Kadsura,belong to the Schisandraceae family including genus Schisandra and genus Kadsura,revealed folk efficacy and medicinal application in the treatment of rheumatoid arthritis and gastroenteric disorders for a long history.Previous study indicated that plants from genus Kadsura mainly contain lignans,triterpenoids and essential oils,and showed the active compounds were lignans and triterpenoids.Among all compounds from Schisandraceae family,the triterpenoids between the genus Schisandra and genus Kadsura had obvious differences.In this paper,we reviewed214triterpenoids and their pharmacological activities reported from genus Kadsura in the past30years(from1987to2017),aiming to provide reference for further study.展开更多
A new scheme for the preparation of highly dispersed precious metal catalysts is proposed in this work. Samples of LaCol-xPtxO3/SiO2 (x = 0.03, 0.05, 0.07, 0.09, and 0.10) were prepared through a simple method of ci...A new scheme for the preparation of highly dispersed precious metal catalysts is proposed in this work. Samples of LaCol-xPtxO3/SiO2 (x = 0.03, 0.05, 0.07, 0.09, and 0.10) were prepared through a simple method of citrate acid complexa-tion combined with impregnation. In a nanocrystallite of LaCOl-xPtxO3, ions of lanthanum, cobalt, and platinum are evenly mixed at the atomic level and confined within the nanocrystallite. In the reduction process, platinum ions were reduced and migrated onto the surface of the nanocrystallite, and the platinum should be highly dispersed owing to the even mixing of the platinum ions in the precursor. When x = 0.05 or lower, the highest dispersion of Pt could be achieved. The highly dispersed Pt is stable, because of the strong interaction between Pt atoms and the support. The catalysts were characterized by BET surface area, temperature-programmed reduction, X-ray diffraction, transmission electron microscopy, CO temperature-programmed desorption, and turnover frequency. Compared with general precious metal Pt catalysts, the LaCo0.95Pt0.05O3/ SiO2 catalyst exhibited better activity for CO oxidation, and it maintained stability at a high temperature of 400 ℃ for 250 h with complete CO conversion.展开更多
As one of the most appealing and attractive technologies, photocatalysis is widely used as a promising method to circumvent the environmental and energy problems. Due to its chemical stability and unique physicochemic...As one of the most appealing and attractive technologies, photocatalysis is widely used as a promising method to circumvent the environmental and energy problems. Due to its chemical stability and unique physicochemical, graphitic carbon nitride (g-C3N4) has become research hotspots in the community. However, g-C3N4 photocatalyst still suffers from many problems, resulting in unsatisfactory photocatalytic activity such as low specific surface area, high charge recombination and insufficient visible light utilization. Since 2009, g-C3N4-based heterostructures have attracted the attention of scientists worldwide for their greatly enhanced photocatalytic performance. Overall, this review summarizes the recent advances of g-C3N4-based nanocomposites modified with transition metal sulfide (TMS), including (1) preparation of pristine g-C3N4,(2) modification strategies of g-C3N4,(3) design principles of TMS-modified g-C3N4 heterostructured photocatalysts, and (4) applications in energy conversion. What is more, the characteristics and transfer mechanisms of each classification of the metal sulfide heterojunction system will be critically reviewed, spanning from the following categories:(1) Type I heterojunction,(2) Type II heterojunction,(3) p-n heterojunction,(4) Schottky junction and (5) Z-scheme heterojunction. Apart from that, the application of g-C3N4-based heterostructured photocatalysts in H2 evolution, CO2 reduction, N2 fixation and pollutant degradation will also be systematically presented. Last but not least, this review will conclude with invigorating perspectives, limitations and prospects for further advancing g-C3N4-based heterostructured photocatalysts toward practical benefits for a sustainable future.展开更多
In this study, the ability of macroalgae Gracilaria sp. of removing eutrophication factors and toxic heavy metals A1, Cr, and Zn in a closed cultivation system is reported. The results show that the concentration of t...In this study, the ability of macroalgae Gracilaria sp. of removing eutrophication factors and toxic heavy metals A1, Cr, and Zn in a closed cultivation system is reported. The results show that the concentration of the three heavy metals decreased significantly during the experimental period in an algal biomass dependent manner. The biofiltration capacity of the alga for A1, Cr, and Zn is 10.1%-72.6%, 52.5%-83.4% and 36.5%,91.7%, respectively. Using more materials resulted in stronger heavy metal removal. Additionally, the concentration of chl-a, TN, TP and DIN of water samples fxom aquariums involving large, medium, and small algal biomass cultivation increased first and then decreased during the experiment. COD value of all three groups decreased with time and displayed algal biomass dependency: more algae resulting in a greater COD value than those of less biomass. Furthermore, changes in COD reflect an obvious organic particles deprivation process of algae. This is the first report on heavy metal removal effect by Gracilaria species. The results suggest that macroalgae can be used as a biofilter for the treatment of nutrient-enriched or heavy-metal polluted water, to which an appropriate time range should be carefully determined.展开更多
The intermetallic compound (IMC) is hard and brittle,and its forming and growth at soldering joint interface is an important issue in joint reliability.The data obtained by digital optical electronic microscope indica...The intermetallic compound (IMC) is hard and brittle,and its forming and growth at soldering joint interface is an important issue in joint reliability.The data obtained by digital optical electronic microscope indicate that the addition of element Co changes the IMC morphology from ball-like and bar-like to distinct and sharp in crest lines and edges.The addition of elements Ni and Co in Sn-3Ag-0.5Cu solder promotes the nucleation and makes the IMC size finer.The electron probe microanalysis (EPMA) determines the chemical compositions and confirms that the IMC is changed into the (Cu,Co,Ni)6Sn5+(Cu,Co,Ni)3Sn4 mixed type from the type of Cu6Sn5 with the elements Ni and Co in the solder.展开更多
The enzyme activities of phenylalanine ammonia-lyase from six years old Ginkgo biloba leaves in the potted orchard were induced by four groups of metal ions respectively. The PAL activities and flavonoids content were...The enzyme activities of phenylalanine ammonia-lyase from six years old Ginkgo biloba leaves in the potted orchard were induced by four groups of metal ions respectively. The PAL activities and flavonoids content were measured by the UV-Vis spectrophotometer. Changes of the whole year were also studied. The results showed that four groups of metal ion treatments had significant effects on the PAL activities and flavonoids contents in Ginkgo leaves. The treatments with 0.1% and 0.3% FeSO4, 0.1%, 0.2% and 0.3% ZnSO4, 0.1%, 0.3% and 0.5% MnSO4, 0.1% and 0.4% CuSO4 not only enhanced flavonoids contents, but also extended the optimum harvest dates of ginkgo leaves. The optimum combination was 0.1% FeSO4, 0.2% ZnSO4, 0.3% MnSO4, and 0.4% CuSO4. It could improve flavonoids content up to 1.619 4%.展开更多
Antioxidants are used to minimize lipid oxidation. Antioxidants can act as metal chelators and free radical or oxygen scavengers, which can slow the progression of lipid oxidation. Lipid oxidation may have negative ef...Antioxidants are used to minimize lipid oxidation. Antioxidants can act as metal chelators and free radical or oxygen scavengers, which can slow the progression of lipid oxidation. Lipid oxidation may have negative effects on the quality of meat and meat products, causing changes in sensory attributes such as color, texture, odor and flavor, and nutritional quality. Several synthetic antioxidants have been used to successfully prevent lipid oxidation in the meat industry, but consumers are concerned about the health risks related to consumption of some synthetic antioxidants. Therefore, there has been a growing interest in natural antioxidants. Nowadays, compounds obtained from natural sources such as grains, oilseeds, spices, fruit and vegetables have been investigated to decrease the lipid oxidation. In this review, the potential effects of natural antioxidants were evaluated that are widely used in meat and meat products.展开更多
Chemical constituents of the whole herb of Bidens pilosa L. were investigated. By using various column chromatography (CC) and spectroscopic methods, 13 flavonoids were isolated and identified as follows: 2′-hydro...Chemical constituents of the whole herb of Bidens pilosa L. were investigated. By using various column chromatography (CC) and spectroscopic methods, 13 flavonoids were isolated and identified as follows: 2′-hydroxy-4,4′-dimethoxy-chalcone (1), isoliquiritigenin (2), 3,2′,4′-trihydroxy-4-methoxy-chalcone (3), licochalcone A (4),4′-O-β-D-glucopyranosyl-2′,3-dihydroxy-4-methoxy-chalcone (5), butein (6), apigenin (7), luteolin (8), diosmetin (9), chrysoeriol (10), 3,5,6,7,3′,4′,5′-heptamethoxyflavone (11), 7-O-β-D-glucopyranosyt-5,3′dihydroxy-3,6,4′-trimethoxyfiavone (12), sulfuretin (13). Compounds 1-5, 9, 11 were obtained from the genus Bidens for the first time.展开更多
We report rational design and syntheses of ternary noble metal-metalloid-nonmetal alloy nanowires(NWs)as a novel electrocatalyst for electrochemical ethanol oxidation reaction(EOR).This novel electrocatalyst is formed...We report rational design and syntheses of ternary noble metal-metalloid-nonmetal alloy nanowires(NWs)as a novel electrocatalyst for electrochemical ethanol oxidation reaction(EOR).This novel electrocatalyst is formed in an aqueous solution via anisotropic nucleation and growth of ternary PdBP alloy NWs along assembled cylinder template of Plurolic F127 on a nitrogen-functionalized graphene support(denoted as PdBP NWs@N-G).We find that uniformly alloying B and P intrinsically modulates the electronic states of Pd catalyst and also introduces new functions into the catalyst,while NW structure supported on the N-G exposes more electrocatalytic active sites and accelerates electron/mass transfers.Such add-in synergies of PdBP NWs@N-G kinetically facilitate the removal and/or further oxidation of CO-based poisoning intermediates,thus remarkably enhancing the electrocatalytic EOR performance.They exhibit a high mass activity of 4.15 A mgPd^-1 and superior cycling and chronoamperometric stability for electrocatalytic EOR,much better than previously reported monometallic Pd-based nanocatalysts.More interestingly,this design strategy can be easily extended to develop more sophisticated NWs catalysts with more compositions(for example quaternary PdCuBP NWs@N-G)that further tunes the electronic and bifuntional effects for various desired catalysis and electrocatalysis.展开更多
文摘The series Variantia Ching et S. H. Wu mainly occur in China and its members are highly variable in morphology. The denomination on this group of Asplenium is very confused in the herbaria. We hop e by means of a biosystematic study to find out their genetic relationships in the reticulate evolution, and to raise a suggestion on their taxonomic treatment. Evidence from cytology, allozyme, morphology, and palynology shows that three ancestor diploids have formed Asplenium sarelii complex comprising 13 members. A. sarelii Hook. should be typified as a diploid. The so-called tetraploid 'A. sarelii' before is an allotetraploid that comes from the doubled hybrid between diploid A. sarelii and A. tenuicaule Hayata, which should be treated as a new species A. wudangense Z. R. Wang et X. Hou. A. pekinense Hance is an autotetraploid that comes from the doubled diploid ancestor A. sarelii. A. lushanense C. Chr., a diploid species and the only ancestor of A. yunnariense group, should not been sunk as a synonym of tetraploid A. yunnariense Franch. Most probably, A. varians Wall. ex Hook. et Grev. is an autotetraploid of A. tenuicaule Hayata. Three new natural tetraploid hybrids and their origins have been found out: they are A. x longmenense ( = A. pekinense x varians), A. x jingyunense ( = A. pekinense x yunnanense) and A. x kidoi ( = A. pekinense x wudangense). Three other new natural triploid hybrids have been found and their origins have been inferred: they are A. X huawuense ( = A. sarelii X wudangense), A. x luyunense ( = A. lushanense x yunnanense) and A. x teniuvaians ( = A. tenuicaule x varians). The method of allozyme comparion combined with cytological observation is employed to reveal the complicated relationships among the members of Asplenium sarelii complex in reticulate evolution and proved to be a highly effective tool to investigate the origin of polyploid and hybrid.
基金supported by the National Natural Science Foundation of China(21322606 and 21436005)the Specialized Research Fund for the Doctoral Program of Higher Education(20120172110012)+1 种基金the Fundamental Research Funds for the Central Universitiesthe Natural Science Foundation of Guangdong Province(S2011020002397 and 2013B090500027)~~
文摘Ni@Pd core-shell nanoparticles with a mean particle size of 8–9 nm were prepared by solvothermal reduction of bivalent nickel and palladium in oleylamine and trioctylphosphine.Subsequently,the first-ever deposition of Ni@Pd core-shell nanoparticles having different compositions on a metal-organic framework(MIL-101)was accomplished by wet impregnation in n-hexane.The Ni@Pd/MIL-101 materials were characterized by powder X-ray diffraction,Fourier transform infrared spectroscopy,transmission electron microscopy,and energy-dispersive X-ray spectroscopy and also investigated as catalysts for the hydrogenation of nitrobenzene under mild reaction conditions.At 30 °C and 0.1 MPa of H2 pressure,the Ni@Pd/MIL-101 gives a TOF as high as 375 h–1 for the hydrogenation of nitrobenzene and is applicable to a wide range of substituted nitroarenes.The exceptional performance of this catalyst is believed to result from the significant Ni-Pd interaction in the core-shell structure,together with promotion of the conversions of aromatics by uncoordinated Lewis acidic Cr sites on the MIL-101 support.
基金funding support from Hunan Province Universities 2011 Collaborative Innovation Center of Protection and Utilization of Huxiang Chinese Medicine Resources, Hunan Provincial Key Laboratory of Diagnostics in Chinese Medicine, and National Natural Science Foundation of China (No. 81673579)
文摘Plants in genus Kadsura,belong to the Schisandraceae family including genus Schisandra and genus Kadsura,revealed folk efficacy and medicinal application in the treatment of rheumatoid arthritis and gastroenteric disorders for a long history.Previous study indicated that plants from genus Kadsura mainly contain lignans,triterpenoids and essential oils,and showed the active compounds were lignans and triterpenoids.Among all compounds from Schisandraceae family,the triterpenoids between the genus Schisandra and genus Kadsura had obvious differences.In this paper,we reviewed214triterpenoids and their pharmacological activities reported from genus Kadsura in the past30years(from1987to2017),aiming to provide reference for further study.
基金supported by the National Natural Science Foundation of China(Nos.21576192,21776214)
文摘A new scheme for the preparation of highly dispersed precious metal catalysts is proposed in this work. Samples of LaCol-xPtxO3/SiO2 (x = 0.03, 0.05, 0.07, 0.09, and 0.10) were prepared through a simple method of citrate acid complexa-tion combined with impregnation. In a nanocrystallite of LaCOl-xPtxO3, ions of lanthanum, cobalt, and platinum are evenly mixed at the atomic level and confined within the nanocrystallite. In the reduction process, platinum ions were reduced and migrated onto the surface of the nanocrystallite, and the platinum should be highly dispersed owing to the even mixing of the platinum ions in the precursor. When x = 0.05 or lower, the highest dispersion of Pt could be achieved. The highly dispersed Pt is stable, because of the strong interaction between Pt atoms and the support. The catalysts were characterized by BET surface area, temperature-programmed reduction, X-ray diffraction, transmission electron microscopy, CO temperature-programmed desorption, and turnover frequency. Compared with general precious metal Pt catalysts, the LaCo0.95Pt0.05O3/ SiO2 catalyst exhibited better activity for CO oxidation, and it maintained stability at a high temperature of 400 ℃ for 250 h with complete CO conversion.
基金supported by Xiamen University Malaysia Research Fund (XMUMRF/2019-C3/IENG/0013)financial assistance and faculty start-up grants/supports from Xiamen University~~
文摘As one of the most appealing and attractive technologies, photocatalysis is widely used as a promising method to circumvent the environmental and energy problems. Due to its chemical stability and unique physicochemical, graphitic carbon nitride (g-C3N4) has become research hotspots in the community. However, g-C3N4 photocatalyst still suffers from many problems, resulting in unsatisfactory photocatalytic activity such as low specific surface area, high charge recombination and insufficient visible light utilization. Since 2009, g-C3N4-based heterostructures have attracted the attention of scientists worldwide for their greatly enhanced photocatalytic performance. Overall, this review summarizes the recent advances of g-C3N4-based nanocomposites modified with transition metal sulfide (TMS), including (1) preparation of pristine g-C3N4,(2) modification strategies of g-C3N4,(3) design principles of TMS-modified g-C3N4 heterostructured photocatalysts, and (4) applications in energy conversion. What is more, the characteristics and transfer mechanisms of each classification of the metal sulfide heterojunction system will be critically reviewed, spanning from the following categories:(1) Type I heterojunction,(2) Type II heterojunction,(3) p-n heterojunction,(4) Schottky junction and (5) Z-scheme heterojunction. Apart from that, the application of g-C3N4-based heterostructured photocatalysts in H2 evolution, CO2 reduction, N2 fixation and pollutant degradation will also be systematically presented. Last but not least, this review will conclude with invigorating perspectives, limitations and prospects for further advancing g-C3N4-based heterostructured photocatalysts toward practical benefits for a sustainable future.
文摘In this study, the ability of macroalgae Gracilaria sp. of removing eutrophication factors and toxic heavy metals A1, Cr, and Zn in a closed cultivation system is reported. The results show that the concentration of the three heavy metals decreased significantly during the experimental period in an algal biomass dependent manner. The biofiltration capacity of the alga for A1, Cr, and Zn is 10.1%-72.6%, 52.5%-83.4% and 36.5%,91.7%, respectively. Using more materials resulted in stronger heavy metal removal. Additionally, the concentration of chl-a, TN, TP and DIN of water samples fxom aquariums involving large, medium, and small algal biomass cultivation increased first and then decreased during the experiment. COD value of all three groups decreased with time and displayed algal biomass dependency: more algae resulting in a greater COD value than those of less biomass. Furthermore, changes in COD reflect an obvious organic particles deprivation process of algae. This is the first report on heavy metal removal effect by Gracilaria species. The results suggest that macroalgae can be used as a biofilter for the treatment of nutrient-enriched or heavy-metal polluted water, to which an appropriate time range should be carefully determined.
文摘The intermetallic compound (IMC) is hard and brittle,and its forming and growth at soldering joint interface is an important issue in joint reliability.The data obtained by digital optical electronic microscope indicate that the addition of element Co changes the IMC morphology from ball-like and bar-like to distinct and sharp in crest lines and edges.The addition of elements Ni and Co in Sn-3Ag-0.5Cu solder promotes the nucleation and makes the IMC size finer.The electron probe microanalysis (EPMA) determines the chemical compositions and confirms that the IMC is changed into the (Cu,Co,Ni)6Sn5+(Cu,Co,Ni)3Sn4 mixed type from the type of Cu6Sn5 with the elements Ni and Co in the solder.
基金Acknowledgments: This work was funded by the New Century Talent Support Program (No. NCET-04-0746) and the Region Technology Development Program of Chinese Ministry of Education (No. 02095), and the Natural Science Foundation of Hubei province (No. 2002AB094), the Youth Talent Foundation of Hubei province (No. 2003AB014) and the Educational Office Key Research Program of Hubei Province of China (No. Z200627002).
文摘The enzyme activities of phenylalanine ammonia-lyase from six years old Ginkgo biloba leaves in the potted orchard were induced by four groups of metal ions respectively. The PAL activities and flavonoids content were measured by the UV-Vis spectrophotometer. Changes of the whole year were also studied. The results showed that four groups of metal ion treatments had significant effects on the PAL activities and flavonoids contents in Ginkgo leaves. The treatments with 0.1% and 0.3% FeSO4, 0.1%, 0.2% and 0.3% ZnSO4, 0.1%, 0.3% and 0.5% MnSO4, 0.1% and 0.4% CuSO4 not only enhanced flavonoids contents, but also extended the optimum harvest dates of ginkgo leaves. The optimum combination was 0.1% FeSO4, 0.2% ZnSO4, 0.3% MnSO4, and 0.4% CuSO4. It could improve flavonoids content up to 1.619 4%.
文摘Antioxidants are used to minimize lipid oxidation. Antioxidants can act as metal chelators and free radical or oxygen scavengers, which can slow the progression of lipid oxidation. Lipid oxidation may have negative effects on the quality of meat and meat products, causing changes in sensory attributes such as color, texture, odor and flavor, and nutritional quality. Several synthetic antioxidants have been used to successfully prevent lipid oxidation in the meat industry, but consumers are concerned about the health risks related to consumption of some synthetic antioxidants. Therefore, there has been a growing interest in natural antioxidants. Nowadays, compounds obtained from natural sources such as grains, oilseeds, spices, fruit and vegetables have been investigated to decrease the lipid oxidation. In this review, the potential effects of natural antioxidants were evaluated that are widely used in meat and meat products.
基金Research Platform for Quality Standard of TCM and Information System Building(Grant No.2009ZX09308-04)National S&T Major Project-Created Major New Drugs Projects (Grant No.2009ZX09311-004)
文摘Chemical constituents of the whole herb of Bidens pilosa L. were investigated. By using various column chromatography (CC) and spectroscopic methods, 13 flavonoids were isolated and identified as follows: 2′-hydroxy-4,4′-dimethoxy-chalcone (1), isoliquiritigenin (2), 3,2′,4′-trihydroxy-4-methoxy-chalcone (3), licochalcone A (4),4′-O-β-D-glucopyranosyl-2′,3-dihydroxy-4-methoxy-chalcone (5), butein (6), apigenin (7), luteolin (8), diosmetin (9), chrysoeriol (10), 3,5,6,7,3′,4′,5′-heptamethoxyflavone (11), 7-O-β-D-glucopyranosyt-5,3′dihydroxy-3,6,4′-trimethoxyfiavone (12), sulfuretin (13). Compounds 1-5, 9, 11 were obtained from the genus Bidens for the first time.
基金supported by Natural Science Foundation of Jiangsu Province(BK20180723,BK20191366)Jiangsu Specially Appointed Professor Plan+2 种基金the Program of Jiangsu Province Innovation TeamPriority Academic Program Development of Jiangsu Higher Education InstitutionsNational and Local Joint Engineering Research Center of Biomedical Functional Materials。
文摘We report rational design and syntheses of ternary noble metal-metalloid-nonmetal alloy nanowires(NWs)as a novel electrocatalyst for electrochemical ethanol oxidation reaction(EOR).This novel electrocatalyst is formed in an aqueous solution via anisotropic nucleation and growth of ternary PdBP alloy NWs along assembled cylinder template of Plurolic F127 on a nitrogen-functionalized graphene support(denoted as PdBP NWs@N-G).We find that uniformly alloying B and P intrinsically modulates the electronic states of Pd catalyst and also introduces new functions into the catalyst,while NW structure supported on the N-G exposes more electrocatalytic active sites and accelerates electron/mass transfers.Such add-in synergies of PdBP NWs@N-G kinetically facilitate the removal and/or further oxidation of CO-based poisoning intermediates,thus remarkably enhancing the electrocatalytic EOR performance.They exhibit a high mass activity of 4.15 A mgPd^-1 and superior cycling and chronoamperometric stability for electrocatalytic EOR,much better than previously reported monometallic Pd-based nanocatalysts.More interestingly,this design strategy can be easily extended to develop more sophisticated NWs catalysts with more compositions(for example quaternary PdCuBP NWs@N-G)that further tunes the electronic and bifuntional effects for various desired catalysis and electrocatalysis.