基于Drucker-Prager/Cap模型的Ti-30Cu粉末轧制过程模拟

对钛和铜质量比为7∶3的Ti-30Cu混合粉末进行单轴压缩、巴西圆盘和模压试验,获得该粉末Drucker-Prager/Cap本构参数与相对密度的关系;利用Abaqus软件建立粉末轧制模型,研究喂料高度对板料相对密度的影响,并进行了试验验证;采用该模型研究了辊缝宽度、轧速对Ti-30Cu合金板料相对密度的影响。结果表明:在辊缝宽度为1 mm、轧速为10 mm·s^(-1)条件下,随着喂料高度由150 mm增加到300 mm,板料的相对密度增大,模拟结果与试验结果基本吻合,最大相对误差为2.15%,验证了轧制模型的有效性;随着喂料高度的增加、辊缝宽度或轧速的减小,板料的相对密度增大。

激光熔覆的数值模型研究进展

针对激光熔覆工艺参数选择及数值模型建立的问题,对激光熔覆各个阶段的数值模型进行了研究。对主要过程中的粉末流体动力学模型、熔池模型和熔覆层模型的建立进行了归纳,提出了考虑不同因素条件下各个模型的发展进程,利用激光熔覆过程各个阶段之间的作用关系,在输入、输出参数和输出精度上对熔覆层及其性能进行了评价分析。研究结果表明:各个阶段的数值模型都需要在选择合适的工艺参数和考虑综合因素下建立稳定的模型,可为激光熔覆实验研究和后续相关模型以及预置粉末系统的数值模型研究提供参考依据;该结果对激光熔覆过程中缺陷的在线检测具有一定的实用意义。

Thermodynamic consistent phase field model for sintering process with multiphase powders

A thermodynamic consistent phase field model is developed to describe the sintering process with multiphase powders. In this model, the interface region is assumed to be a mixture of different phases with the same chemical potential, but with different compositions. The interface diffusion and boundary diffusion are also considered in the model. As an example, the model is applied to the sintering process with Fe-Cu powders. The free energy of each phase is described by the well-developed thermodynamic models, together with the published optimized parameters. The microstructure and solute distribution during the sintering process can both be obtained quantitively.

Effects of h-BN content on properties of Ni-Cr/h-BN composite

Ni-Cr/h-BN self-lubricating composities were prepared by powder metallurgy (P/M) method.The effects of hexagonal boron nitride (h-BN) content on the mechanical and tribological properties of the Ni-Cr/h-BN composites were investigated.The corresponding frictional models were established to analyze the formation of the lubricant h-BN films on the surfaces of the Ni-Cr/h-BN composites.The results show that,when the content of h-BN increases from 5% to 15% (mass fraction),the bending strength of the Ni-Cr/h-BN composite decreases from 96.670 MPa to 17.319 MPa,and the hardness (HB) decreases from 33 to 14.The friction coefficient of the Ni-Cr/h-BN composite decreases firstly from 0.385 to 0.216,and then increases to 0.284,while the wear rate decreases firstly from 4.14×10-9 kg/(N·m) to 1.35×10-9 kg/(N·m),then increases to 2.36×10-9 kg/(N·m).The best comprehensive mechanical and tribological properties can be obtained between 10% and 12% h-BN addition.

Adsorption of Cholesterol on Carbon Powders

Carbon powders have the ability to remove cholesterol from solution by adsorption. Various combinations from among 12 different types of carbon powders （including two medical carbons）, having a wide range of surface area and porosity, were used to perform cholesterol adsorption experiments. The cholesterol concentration in a cyclohexane solvent （37 ~C, shaking 200 rpm） was detected at 215 nm using ultraviolet spectroscopy. Most adsorption occurred in the first 30 to 60 minutes. A Langmuir model was used to fit the amount of cholesterol adsorbed per gram of carbon. The medical carbon, Natural Elements Activated Charcoal, adsorbed 234 mg of cholesterol adsorption per gram of carbon. The experimental percentages of cholesterol removed from solution （maximum 98%） were correlated with nitrogen Branauer-Emmett-Teller （BET） surface areas and micro, meso, and macropore volume distributions. Surface area alone was not a suitable predictor of cholesterol adsorption. However, carbon powders exhibiting a large surface area along with significant meso and macropores were shown to be effective in adsorbing cholesterol from a nonpolar environment. Ingestion of a medically approved carbon powder with a large surface area and sufficient meso and macroporosity may be able to adsorb cholesterol in the intestinal tract and thereby lower cholesterol levels in the body.

Development of a pentaethylenehexamine-modified solid support adsorbent for CO_2 capture from model flue gas

A novel solid support adsorbent for CO2capture was developed by loading pentaethylenehexamine(PEHA)on commercially available mesoporous molecular sieve MCM-41 using wet impregnation method.MCM-41 samples before and after PEHA loading were characterized by X-ray powder diffraction,N2adsorption/desorption,thermal gravimetric analysis and scanning electron microscope to investigate the textural and thermo-physical properties.CO2adsorption performance was evaluated in a fixed bed adsorption system.Results indicated that the structure of MCM-41 was preserved after loading PEHA.Surface area and total pore volume of PEHA loaded MCM-41 decreased with the increase of loading.The working adsorption capacity of CO2could be significantly improved at 60%of PEHA loading and 75°C.The effect of the height of adsorbent bed was investigated and the best working adsorption capacity for MCM-41-PEHA-60 reached 165 mg·(g adsorbent)-1at 75°C.Adsorption/desorption circle showed that the CO2working adsorption capacity of MCM-41-PEHA kept stable.

激光增材制造过程数值仿真技术综述

数值仿真是研究激光增材制造过程中各类物理现象、揭示零件缺陷形成机理、优化增材制造工艺参数的重要手段,该领域学者针对增材制造过程中的热分析、金属粉末颗粒性质分析、微观结构分析、质量缺陷成因分析等方面,开展了大量研究,提出了相应的数学模型和方法。激光增材制造过程的数值仿真是一个在空间和时间上均跨越多个尺度的复杂问题,微观、介观、宏观尺度下数值仿真所关注的对象和所使用的方法各不相同;多数研究聚焦于某一尺度下的过程仿真,另一部分研究则基于不同模型的数据关系建立模型间的耦合关系,实现热-相、热-力的综合分析。对现阶段激光增材制造数值仿真领域的主要技术进行了综述,在梳理数值仿真基本流程的基础上,对其中涉及的热源模型,粉末模型,力学模型以及微观结构模型进行了介绍,讨论了其特点和适用性;结合相关技术领域的发展,探讨了激光增材制造数值仿真技术的发展方向,旨在为本领域的技术研究与发展提供参考。