磷酸盐对粉煤灰-水泥体系影响的研究

本文研究了不同掺量磷酸盐对粉煤灰-水泥体系的强度、工作性能等宏观性能以及水化程度等微观性能的影响,结果表明:1随着磷酸钠掺量的增大,粉煤灰-水泥体系胶砂流动度随之增大,且胶砂流动度经时损失有所改善,各体系的初凝时间和终凝时间延长,标准稠度用水量略有降低;2粉煤灰-水泥体系掺入磷酸钠后,7d强度提高达15%,28d强度最多提高14%,粉煤灰激活效果显著;且化学结合水含量的变化规律与胶砂抗压强度发展变化是一致的;3掺加磷酸钠的胶砂试样安定性良好;将磷酸钠与硫酸钠等量复掺于粉煤灰-水泥体系后相互补偿缺陷,有效地激活了粉煤灰早期和后期强度,证明磷酸钠与硫酸钠相容性较好;4磷酸钠的掺入使粉煤灰反应程度在7d即高于基准组,28d龄期下相较硫酸钠仍体现了良好的促进水化进程的效果,佐证了磷酸盐对粉煤灰的激活作用。

粉煤灰活化剂的试制及应用试验

通过大量的正交试验，掌握了粉煤灰活化剂（或称激活剂）制造方法，试制出的粉煤灰活化剂能使粉煤灰的潜在活性得以充分发挥，使之成为可大量代替水泥的胶凝材料，提高其活性，大大提高粉煤灰水泥中的粉煤灰掺合量，并改善粉煤灰水泥的性能，增加水泥的强度．用粉煤灰活化剂试制的粉煤灰水泥（粉煤灰掺合量35％），其各项指标均达到GB1344-99粉煤灰水泥国家标准。

Study on extracting alumina from fly ash by compound additive activation method

According to the chemical and mineral composition characteristics of the fly ash,alumina can be extracted from fly ash through the calcining method by using sodium carbonate and calcium carbonate additives.The effects on leaching rate of alumina have been investigated. The results showed that the fly ash can be activated effectively and the leaching rate of alumina can be improved to more than 92% through this method. The best process parameters were the ratio of raw materials,i. e. the material weight ratio of fly ash,calcium carbonate and sodium carbonate was 1. 0∶1. 2∶0. 9. The activating temperature was 850℃-900℃,activating time was 3 h. This process has a potential application prospect and improves the value of comprehensive utilization of fly ash.