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氢气氛下半焦有机硫的脱除动力学 被引量:3
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作者 刘军利 唐惠庆 郭占成 《化工学报》 EI CAS CSCD 北大核心 2004年第8期1335-1340,共6页
研究了半焦颗粒在氢气氛下有机硫脱除的本征动力学行为 .实验采用微分反应器 ,研究结果表明 ,半焦颗粒的脱硫与气氛、温度和半焦硫含量有关 .通过比较粒子反应模型和随机孔模型 ,粒子反应模型仅适合于处理半焦颗粒氢气气氛脱硫的初始阶... 研究了半焦颗粒在氢气氛下有机硫脱除的本征动力学行为 .实验采用微分反应器 ,研究结果表明 ,半焦颗粒的脱硫与气氛、温度和半焦硫含量有关 .通过比较粒子反应模型和随机孔模型 ,粒子反应模型仅适合于处理半焦颗粒氢气气氛脱硫的初始阶段 ,而随机孔模型符合整个脱硫过程 . 展开更多
关键词 半焦 脱硫 有机硫 粒子反应模型 随机孔模型
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Particle swarm optimization and its application to seismic inversion of igneous rocks 被引量:3
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作者 Yang Haijun Xu Yongzhong +6 位作者 Peng Gengxin Yu Guiping Chen Meng Duan Wensheng Zhu Yongfeng Cui Yongfu Wang Xingjun 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2017年第2期349-357,共9页
In order to improve the fine structure inversion ability of igneous rocks for the exploration of underlying strata, based on particle swarm optimization(PSO), we have developed a method for seismic wave impedance inve... In order to improve the fine structure inversion ability of igneous rocks for the exploration of underlying strata, based on particle swarm optimization(PSO), we have developed a method for seismic wave impedance inversion. Through numerical simulation, we tested the effects of different algorithm parameters and different model parameterization methods on PSO wave impedance inversion, and analyzed the characteristics of PSO method. Under the conclusions drawn from numerical simulation, we propose the scheme of combining a cross-moving strategy based on a divided block model and high-frequency filtering technology for PSO inversion. By analyzing the inversion results of a wedge model of a pitchout coal seam and a coal coking model with igneous rock intrusion, we discuss the vertical and horizontal resolution, stability and reliability of PSO inversion. Based on the actual seismic and logging data from an igneous area, by taking a seismic profile through wells as an example, we discuss the characteristics of three inversion methods, including model-based wave impedance inversion, multi-attribute seismic inversion based on probabilistic neural network(PNN) and wave impedance inversion based on PSO.And we draw the conclusion that the inversion based on PSO method has a better result for this igneous area. 展开更多
关键词 Particle swarm optimization Seismic inversion Igneous rocks Probabilistic neutral network Model-based inversion
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Oxidation characteristics of boron particles 被引量:2
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作者 YU Dan KONG ChengDong +2 位作者 ZHUO JianKun LI ShuiQing YAO Qiang 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2015年第12期2016-2024,共9页
The oxidation characteristics of boron particles, boron-A with the diameter of 2.545 μm and boron-B with the diameter of 10.638 μm, at low temperature(1500 K) have been investigated by thermogravimetry(TG) coupl... The oxidation characteristics of boron particles, boron-A with the diameter of 2.545 μm and boron-B with the diameter of 10.638 μm, at low temperature(1500 K) have been investigated by thermogravimetry(TG) coupled with simultaneous differential scanning calorimetry(DSC), infrared and mass spectra. A rapid oxidation stage of boron particles, followed by a slow oxidation stage of sintered particles, is found from the TG and DSC curves. The onset temperatures of the oxidation process of boron-A particles are in the range of 806–889 K, which are at least 105 K lower than those of boron-B at the same condition. As the partial pressure of oxygen increases from 5% to 35%, the onset temperature of boron-A or boron-B particles decreases. However, when the partial pressure of oxygen is above 35%, the onset temperature becomes constant, implying a saturation effect of oxygen on the reaction rate. It indicates that the chemical adsorption of oxygen, i.e. chemical reaction, on the particle surface is the rate-limited step at the beginning of the rapid oxidation stage. Therefore, the first-order chemical reaction model is used to simulate the oxidation of boron particles, even that of the sinter. The average activation energies of the particles are 291.3 kJ/mol for boron-A and 338.4 k J/mol for boron-B. While the average activation energies of the sintered particles are 36.35 k J/mol for boron-A and 31.87 kJ/mol for boron-B. The pre-exponential factor of the particles is -10^4, while that of the sinter is 10^-1. The oxidation rate constant of boron is qualitatively mainly affected by the specific surface of the sample and the thickness of the oxide layer. 展开更多
关键词 boron particles OXIDATION activation energy saturation effect
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